FI85496B - En metod att framstaella en polyolefin-vinylpolymerkomposit. - Google Patents

En metod att framstaella en polyolefin-vinylpolymerkomposit. Download PDF

Info

Publication number
FI85496B
FI85496B FI894461A FI894461A FI85496B FI 85496 B FI85496 B FI 85496B FI 894461 A FI894461 A FI 894461A FI 894461 A FI894461 A FI 894461A FI 85496 B FI85496 B FI 85496B
Authority
FI
Finland
Prior art keywords
weight
polyolefin
parts
vinyl monomer
vinyl
Prior art date
Application number
FI894461A
Other languages
English (en)
Swedish (sv)
Other versions
FI894461A (fi
FI85496C (fi
FI894461A0 (fi
Inventor
Torvald Vestberg
Ismo Lehtiniemi
Original Assignee
Neste Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Neste Oy filed Critical Neste Oy
Publication of FI894461A0 publication Critical patent/FI894461A0/fi
Priority to FI894461A priority Critical patent/FI85496C/fi
Priority to US07/584,359 priority patent/US5164456A/en
Priority to DE69029495T priority patent/DE69029495T2/de
Priority to EP90118029A priority patent/EP0418861B1/en
Priority to AT90118029T priority patent/ATE146805T1/de
Priority to ES90118029T priority patent/ES2099080T3/es
Priority to JP2254052A priority patent/JP2724908B2/ja
Publication of FI894461A publication Critical patent/FI894461A/fi
Application granted granted Critical
Publication of FI85496B publication Critical patent/FI85496B/fi
Publication of FI85496C publication Critical patent/FI85496C/fi

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/902—Core-shell
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31935—Ester, halide or nitrile of addition polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Claims (9)

1. Menetelmä polyolefiini-vinyylipolymeeri komposiitin valmistamiseksi, tunnettu siitä, että 5 a) 10-200 paino-osalla vinyylimonomeeria ja 0,01-4,0 paino-osalla, laskettuna vinyylimonomeerin 100 paino-osaa kohti, vapaa radikaali - initiaattoria, impregnoidaan 100 paino-osaa poly-olefiinipartLkkeleita siten, että näitä sekoitetaan hitaasti 10 kokonaan veden poissaollessa 20-100°C:n lämpötilassa säilyttäen polyolefiinin partikkelirakenne. b) valmistetaan tästä seoksesta impregnoinnin päätyttyä vesisuspensio lisäämällä 80-1000 paino-osaa vettä, laskettuna polyolefii- 15 nin + vinyylimonomeerin 100 paino-osaa kohti, sekä stabilointi ainetta, ja c) korottamalla sitten lämpötilaa vinyylimonomeerin polymeroimi-seksi. 20
2. Vaatimuksen 1 mukainen menetelmä, tunnettu siitä, että polyolefiini on polyeteenin tai eteenin kopolymeeri, jossa on yli 50 paino-% eteeniä ja jossa komonomeeri on esimerkiksi vinyyllasetaat-ti, jokin α-olefiini, akryyli- tai metakryylihappo tai -esteri, poly- 25 eeni tai vinyylikloridi.
3. Vaatimuksen 1 mukainen menetelmä, tunnettu siitä, että polyolefiini on polypropeeni tai propeenin kopolymeeri, jossa on yli 50 paino-% propeenia ja jossa komomeeri on esimerkiksi eteeni, jokin muu 30 α-olefiini tai jokin polaarinen tyydyttämätön monomeeri.
4. Vaatimuksen 1,2 tai 3 mukainen menetelmä, tunnettu siitä, että polyolefiinipartikkeleiden halkaisija on 0,5-10 mm.
5. Vaatimuksen 1-4 mukainen menetelmä, tunnettu siitä, että '> vinyylimonomeeri on aromaattinen vinyylimonomeeri esim. styreeni tai 17 85496 substituoitu styreeni, esimerkiksi α-metyyli-styreeni ja metyylisty-reeni.
6. Jonkin vaatimuksen 1-5 mukainen menetelmä, tunnettu siitä, 5 että korkeintaan 50 paino-% aromaattisen vinyylimonomeerin määrästä voidaan korvata jollakin toisella monomeerillä, joka voi olla akrylo-tai metakrylonitriili, (^-Cy- alkyyliakrylaatti tai -metakrylaatti, akryyli- tai metakryyliamidi, vinyylihalidi, tai maleiinihappo-anhydridi. 10
7. Jonkin edellisen vaatimuksen 1-6 mukainen menetelmä, tunnet-t u siitä, että initiaattori on orgaaninen vapaa radikaali-initiaatto-ri, kuten esimerkiksi peroksidi tai atsoyhdiste, joka on esimerkiksi bentsoyyliperoksidi, lauroyyliperoksidi, t-butyyliperoksibentsoaatti, 15 dikumyyliperoksidi tai atsobisisobutyronitriili.
8. Jonkin edellisen vaatimuksen 1-7 mukainen menetelmä, tunnet - t u siitä, että vinyylimonomeeri polymeroidaan 50-140°C:n lämpötilassa.
9. Jonkin edellisen vaatimuksen 1-8 mukainen menetelmä, tunnet- t u siitä, että vinyylimonomeeri polymeroidaan polyolefiinipartikke-lissa minkä seurauksena vinyylipolymeeri on homogeenisesti dispergoi-tuneena 0,05-2,0 /im:n suuruisina pyöreinä helminä polyolefiinimatrii-sissa. ; : 25
FI894461A 1989-09-20 1989-09-20 En metod att framstaella en polyolefin-vinylpolymerkomposit. FI85496C (fi)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FI894461A FI85496C (fi) 1989-09-20 1989-09-20 En metod att framstaella en polyolefin-vinylpolymerkomposit.
US07/584,359 US5164456A (en) 1989-09-20 1990-09-18 Method of preparing a polyolefin-vinyl polymer-composite
DE69029495T DE69029495T2 (de) 1989-09-20 1990-09-19 Verfahren zur Herstellung von Polyolefin-Vinylpolymer-Verbundmaterial
EP90118029A EP0418861B1 (en) 1989-09-20 1990-09-19 Method of preparing a polyolefine-vinylpolymer-composite
AT90118029T ATE146805T1 (de) 1989-09-20 1990-09-19 Verfahren zur herstellung von polyolefin- vinylpolymer-verbundmaterial
ES90118029T ES2099080T3 (es) 1989-09-20 1990-09-19 Metodo para preparar un material compuesto, de poliolefina-polimero vinilico.
JP2254052A JP2724908B2 (ja) 1989-09-20 1990-09-20 ポリオレフィン―ビニルポリマー組成物の製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI894461A FI85496C (fi) 1989-09-20 1989-09-20 En metod att framstaella en polyolefin-vinylpolymerkomposit.
FI894461 1989-09-20

Publications (4)

Publication Number Publication Date
FI894461A0 FI894461A0 (fi) 1989-09-20
FI894461A FI894461A (fi) 1991-03-21
FI85496B true FI85496B (fi) 1992-01-15
FI85496C FI85496C (fi) 1992-04-27

Family

ID=8529027

Family Applications (1)

Application Number Title Priority Date Filing Date
FI894461A FI85496C (fi) 1989-09-20 1989-09-20 En metod att framstaella en polyolefin-vinylpolymerkomposit.

Country Status (7)

Country Link
US (1) US5164456A (fi)
EP (1) EP0418861B1 (fi)
JP (1) JP2724908B2 (fi)
AT (1) ATE146805T1 (fi)
DE (1) DE69029495T2 (fi)
ES (1) ES2099080T3 (fi)
FI (1) FI85496C (fi)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI86642C (fi) * 1990-09-18 1992-09-25 Neste Oy En metod att framstaella en vinylpolymer-polyolefinkomposit.
TW254949B (fi) * 1991-03-07 1995-08-21 Himont Inc
FI88170C (fi) * 1992-01-27 1993-04-13 Neste Oy En metod att framstaella en vinylpolymer-polyolefinkomposit
FI94255C (fi) * 1992-11-13 1995-08-10 Borealis Holding As Muovimateriaali pakkauksia varten
FI95038C (fi) * 1993-04-26 1995-12-11 Optatech Oy Polyolefiinipohjaisten termoplastisten elastomeerien valmistus
JP3372298B2 (ja) * 1993-06-10 2003-01-27 鐘淵化学工業株式会社 改質ポリオレフィン系樹脂組成物およびそれを含有してなるポリオレフィン系樹脂組成物
CN1068017C (zh) * 1993-11-12 2001-07-04 钟渊化学工业株式会社 聚烯烃类树脂组合物
EP0796295A1 (en) * 1994-05-10 1997-09-24 Borealis Holding A/S Plastic material for packaging
DE69508623T2 (de) * 1994-12-23 1999-09-02 Optatech Corp. Ein auf polyolefin-polyacrylat basierendes thermoplastisches elastomer
FI100808B (fi) * 1995-02-20 1998-02-27 Borealis As Värjättävä polyolefiinikuitu
JP4153577B2 (ja) 1997-11-28 2008-09-24 旭化成ケミカルズ株式会社 耐油性に優れた熱可塑性エラストマー
US6225402B1 (en) 1998-09-25 2001-05-01 Mcwhorter Technologies, Inc. Aqueous based dispersions for polyolefinic substrates
FI20011354A (fi) * 2001-06-25 2002-12-26 Optatech Corp Lämmön- ja öljynkestävä termoplastinen elastomeeri
JP4866569B2 (ja) 2005-05-27 2012-02-01 日東工器株式会社 研磨工具
DE102008024582A1 (de) 2008-05-21 2009-11-26 Lanxess Deutschland Gmbh Verfahren zur Herstellung von rieselfähigen thermoplastischen Elastomeren, neue rieselfähige thermoplastische Elastomere auf Basis eines ultrahochmolekularen Polyethylens und eines Polyacrylats und dessen Verwendung

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3737483A (en) * 1970-06-26 1973-06-05 Toyo Soda Mfg Co Ltd Graft copolymerization of maleic anhydride and an alpha olefin onto an ethylene-vinyl acetate copolymer
US3853970A (en) * 1971-09-15 1974-12-10 Diamond Shamrock Corp Vinyl chloride graft polymers and process for preparation thereof
BE789984A (fr) * 1971-10-14 1973-04-12 Bayer Ag Polymeres greffes de l'ethylene
JPS53134891A (en) * 1977-04-30 1978-11-24 Hitachi Chem Co Ltd Preparation of impact and weather resistant graft copolymer
US4154777A (en) * 1976-08-27 1979-05-15 Hitachi Chemical Company, Ltd. Process for producing high impact and weather resistant graft copolymers
JPS54114547A (en) * 1978-02-27 1979-09-06 Sekisui Plastics Preparation of formed body coated with polyester resin
US4303756A (en) * 1978-10-16 1981-12-01 Sekisui Kaseihin Kogyo Kabushiki Kaisha Process for producing expandable thermoplastic resin beads
US4202845A (en) * 1978-11-20 1980-05-13 American Cyanamid Company Sulfur vulcanizable ethylene-vinyl acetate copolymer elastomers
JPS5662846A (en) * 1979-10-29 1981-05-29 Mitsubishi Petrochem Co Ltd Semiconductive resin composition
JPH01266104A (ja) * 1988-04-18 1989-10-24 Mitsubishi Rayon Co Ltd 懸濁重合方法

Also Published As

Publication number Publication date
FI894461A (fi) 1991-03-21
EP0418861A2 (en) 1991-03-27
FI85496C (fi) 1992-04-27
JPH03166207A (ja) 1991-07-18
FI894461A0 (fi) 1989-09-20
ES2099080T3 (es) 1997-05-16
US5164456A (en) 1992-11-17
EP0418861B1 (en) 1996-12-27
EP0418861A3 (en) 1991-11-21
DE69029495T2 (de) 1997-07-17
DE69029495D1 (de) 1997-02-06
ATE146805T1 (de) 1997-01-15
JP2724908B2 (ja) 1998-03-09

Similar Documents

Publication Publication Date Title
FI85496B (fi) En metod att framstaella en polyolefin-vinylpolymerkomposit.
EP2412748B1 (en) Method for reducing volatile organic compounds in composite resin particles
JPS6346106B2 (fi)
US5300578A (en) Method for preparing a vinyl polymer-polyolefine composite
EP1186635B1 (en) Bimodal high solids polymeric additive compositions, processes and products thereof
US4839423A (en) Method for production of graft resin composition
FI86642B (fi) En metod att framstaella en vinylpolymer-polyolefinkomposit.
EP0208382B1 (en) Rubber-reinforced styrenic polymer resins having improved flow and gloss characteristics
US4865917A (en) Thermoplastic silicone rubber graft polymers (I)
JPH0482021B2 (fi)
CA1126432A (en) Transparent blends of resinous copolymers and grafted elastomers
JPS5891716A (ja) 改質熱可塑性重合体粒子の製造方法
JP2013123851A (ja) 複合樹脂粒子中の臭気の低減方法、複合樹脂粒子、発泡性粒子、予備発泡粒子、発泡成形体及び自動車内装材
JPH04216808A (ja) 重合可能なモノマーとオレフィン／一酸化炭素コポリマーとのグラフトコポリマー
KR101775736B1 (ko) 복합 수지 입자 중의 악취의 저감 방법 및 복합 수지 입자
US5804656A (en) Compositions of the ABS type for processing by extrusion and deep drawing
US9963582B2 (en) Expandable polymeric composition with improved flexibility and relative preparation process
JPS632293B2 (fi)
EP0528600A1 (en) Polymer blends
JP3210056B2 (ja) 塩素含有樹脂組成物
JPS6315951B2 (fi)
JPS6129977B2 (fi)
JPH0673136A (ja) 改質塩化ビニル系重合体の製造法
JPH02281012A (ja) 新規重合体粒子の製造法
JPH01318026A (ja) 樹脂微粒子を内包したゴム粒子

Legal Events

Date Code Title Description
PC Transfer of assignment of patent

Owner name: OPTATECH OY

RC Patent held as pledge
MM Patent lapsed

Owner name: OPTATECH OY