FI66582C - Foerfarande foer foerhindrande av polymerisation hos konjugerade diener - Google Patents
Foerfarande foer foerhindrande av polymerisation hos konjugerade diener Download PDFInfo
- Publication number
- FI66582C FI66582C FI803760A FI803760A FI66582C FI 66582 C FI66582 C FI 66582C FI 803760 A FI803760 A FI 803760A FI 803760 A FI803760 A FI 803760A FI 66582 C FI66582 C FI 66582C
- Authority
- FI
- Finland
- Prior art keywords
- furfural
- solvent
- weight
- polymerization
- foer
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 title claims description 18
- 238000012790 confirmation Methods 0.000 title 1
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 claims description 75
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 48
- 239000002904 solvent Substances 0.000 claims description 33
- 150000001993 dienes Chemical class 0.000 claims description 22
- 238000000605 extraction Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- 229930195733 hydrocarbon Natural products 0.000 claims description 11
- 150000002430 hydrocarbons Chemical class 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 239000004215 Carbon black (E152) Substances 0.000 claims description 9
- 239000003112 inhibitor Substances 0.000 claims description 9
- 238000000926 separation method Methods 0.000 claims description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 26
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 18
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 9
- 238000004821 distillation Methods 0.000 description 9
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 6
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- 230000002401 inhibitory effect Effects 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 description 2
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 125000002534 ethynyl group Chemical class [H]C#C* 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N iso-pentane Natural products CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 229960000907 methylthioninium chloride Drugs 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 235000010288 sodium nitrite Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical group CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 1
- XESZUVZBAMCAEJ-UHFFFAOYSA-N 4-tert-butylcatechol Chemical compound CC(C)(C)C1=CC=C(O)C(O)=C1 XESZUVZBAMCAEJ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- MATPIVOTMVPHDV-UHFFFAOYSA-N but-1-en-3-yne but-1-yne Chemical group CCC#C.C=CC#C MATPIVOTMVPHDV-UHFFFAOYSA-N 0.000 description 1
- QNRMTGGDHLBXQZ-UHFFFAOYSA-N buta-1,2-diene Chemical compound CC=C=C QNRMTGGDHLBXQZ-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- WFYPICNXBKQZGB-UHFFFAOYSA-N butenyne Chemical group C=CC#C WFYPICNXBKQZGB-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- IAQRGUVFOMOMEM-ARJAWSKDSA-N cis-but-2-ene Chemical compound C\C=C/C IAQRGUVFOMOMEM-ARJAWSKDSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000001941 cyclopentenes Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000895 extractive distillation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pentene-2 Natural products CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- MWWATHDPGQKSAR-UHFFFAOYSA-N propyne Chemical group CC#C MWWATHDPGQKSAR-UHFFFAOYSA-N 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- -1 tert-naphthylamine Chemical compound 0.000 description 1
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Inorganic Insulating Materials (AREA)
- Telephonic Communication Services (AREA)
- Cable Accessories (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15738479 | 1979-11-12 | ||
| JP15738479A JPS5681526A (en) | 1979-12-06 | 1979-12-06 | Polymerization prevention of conjugated dienes |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI803760L FI803760L (fi) | 1981-06-07 |
| FI66582B FI66582B (fi) | 1984-07-31 |
| FI66582C true FI66582C (fi) | 1984-11-12 |
Family
ID=15648461
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI803760A FI66582C (fi) | 1979-12-06 | 1980-12-03 | Foerfarande foer foerhindrande av polymerisation hos konjugerade diener |
Country Status (23)
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4558168A (en) * | 1985-06-19 | 1985-12-10 | Air Products And Chemicals, Inc. | Production of high purity butene-1 from an n-butane feedstock |
| CN1147567C (zh) | 1997-03-11 | 2004-04-28 | 日本是恩株式会社 | 精制共轭二烯的制造方法 |
| PT1437336E (pt) * | 2001-09-28 | 2012-07-10 | Zeon Corp | Processo de separação/purificação de dienos conjugados e aparelho de separação/purificação |
| ES2384453T3 (es) * | 2001-10-19 | 2012-07-05 | Zeon Corporation | Proceso y aparato para separación y purificación de dienos conjugados |
| US7348466B2 (en) * | 2005-04-13 | 2008-03-25 | Equistar Chemicals, Lp | Solvent extraction |
| JP2008189569A (ja) * | 2007-02-02 | 2008-08-21 | Hakuto Co Ltd | 共役ジエン化合物の重合抑制剤組成物および重合抑制方法 |
| CN101289360B (zh) * | 2007-04-19 | 2012-10-24 | 中国石化上海石油化工股份有限公司 | 由石油碳五馏份分离制取2-戊烯的方法 |
| CN101289362B (zh) * | 2007-04-19 | 2012-10-24 | 中国石化上海石油化工股份有限公司 | 一种由石油碳五馏份分离制取1-戊烯的方法 |
| CN101289361B (zh) * | 2007-04-19 | 2012-10-24 | 中国石化上海石油化工股份有限公司 | 一种由石油碳五馏份分离制取2-戊烯的方法 |
| CN101289363B (zh) * | 2007-04-19 | 2013-06-19 | 中国石化上海石油化工股份有限公司 | 由石油碳五馏份分离制取1-戊烯的方法 |
| JP2014084290A (ja) * | 2012-10-23 | 2014-05-12 | Asahi Kasei Chemicals Corp | ブタジエン含有組成物 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3309412A (en) * | 1964-04-17 | 1967-03-14 | Japanese Geon Co Ltd | Method of preventing the polymerization of butadiene |
| SE353078B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1965-12-30 | 1973-01-22 | Japanese Geon Co Ltd | |
| US3405189A (en) * | 1966-05-25 | 1968-10-08 | Japanese Geon Co Ltd | Method for inhibiting polymerization of isoprene and/or 1, 3-pentadiene |
| US3515762A (en) * | 1967-07-26 | 1970-06-02 | Nippon Zeon Co | Method for inhibiting polymerization of conjugated dienes |
-
1979
- 1979-12-06 JP JP15738479A patent/JPS5681526A/ja active Granted
-
1980
- 1980-11-21 YU YU2955/80A patent/YU41224B/xx unknown
- 1980-11-25 US US06/210,334 patent/US4348260A/en not_active Expired - Lifetime
- 1980-11-26 AU AU64741/80A patent/AU534188B2/en not_active Expired
- 1980-11-26 CS CS808192A patent/CS230578B2/cs unknown
- 1980-11-28 AR AR283414A patent/AR224177A1/es active
- 1980-12-02 BR BR8007889A patent/BR8007889A/pt not_active IP Right Cessation
- 1980-12-02 EP EP80107519A patent/EP0030673B1/en not_active Expired
- 1980-12-02 DE DE8080107519T patent/DE3062785D1/de not_active Expired
- 1980-12-02 AT AT80107519T patent/ATE3026T1/de not_active IP Right Cessation
- 1980-12-03 HU HU802882A patent/HU182696B/hu unknown
- 1980-12-03 NO NO803665A patent/NO155534C/no unknown
- 1980-12-03 FI FI803760A patent/FI66582C/fi not_active IP Right Cessation
- 1980-12-04 PT PT72157A patent/PT72157B/pt unknown
- 1980-12-04 BG BG049873A patent/BG42007A3/xx unknown
- 1980-12-05 CA CA000366219A patent/CA1140158A/en not_active Expired
- 1980-12-05 DD DD80225777A patent/DD155072A5/de not_active IP Right Cessation
- 1980-12-05 MX MX185067A patent/MX156159A/es unknown
- 1980-12-05 ES ES497487A patent/ES8200908A1/es not_active Expired
- 1980-12-05 IN IN1345/CAL/80A patent/IN153409B/en unknown
- 1980-12-05 DK DK520880A patent/DK148593C/da not_active IP Right Cessation
- 1980-12-05 PL PL1980228297A patent/PL134739B1/pl unknown
- 1980-12-05 PH PH24952A patent/PH17836A/en unknown
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed | ||
| MM | Patent lapsed |
Owner name: NIPPON ZEON CO., LTD. |