FI64804C - Foerfarande foer framstaellning av n-fosfonometylglycinsalter - Google Patents

Foerfarande foer framstaellning av n-fosfonometylglycinsalter Download PDF

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Publication number
FI64804C
FI64804C FI773835A FI773835A FI64804C FI 64804 C FI64804 C FI 64804C FI 773835 A FI773835 A FI 773835A FI 773835 A FI773835 A FI 773835A FI 64804 C FI64804 C FI 64804C
Authority
FI
Finland
Prior art keywords
salt
oxidation
phosphonomethyliminodiacetic acid
process according
reaction
Prior art date
Application number
FI773835A
Other languages
English (en)
Finnish (fi)
Other versions
FI64804B (fi
FI773835A7 (fi
Inventor
John Edward Franz
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of FI773835A7 publication Critical patent/FI773835A7/fi
Publication of FI64804B publication Critical patent/FI64804B/fi
Application granted granted Critical
Publication of FI64804C publication Critical patent/FI64804C/fi

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Catalysts (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
FI773835A 1976-12-20 1977-12-19 Foerfarande foer framstaellning av n-fosfonometylglycinsalter FI64804C (fi)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US75323276A 1976-12-20 1976-12-20
US75323276 1976-12-20

Publications (3)

Publication Number Publication Date
FI773835A7 FI773835A7 (fi) 1978-06-21
FI64804B FI64804B (fi) 1983-09-30
FI64804C true FI64804C (fi) 1984-01-10

Family

ID=25029740

Family Applications (1)

Application Number Title Priority Date Filing Date
FI773835A FI64804C (fi) 1976-12-20 1977-12-19 Foerfarande foer framstaellning av n-fosfonometylglycinsalter

Country Status (33)

Country Link
US (1) US4147719A (enExample)
JP (1) JPS5377018A (enExample)
AR (1) AR220326A1 (enExample)
AT (1) AT364853B (enExample)
AU (1) AU515070B2 (enExample)
BE (1) BE861996A (enExample)
BG (1) BG42358A3 (enExample)
BR (1) BR7708434A (enExample)
CA (1) CA1090819A (enExample)
CH (1) CH634580A5 (enExample)
CS (1) CS194697B2 (enExample)
DD (1) DD133952A5 (enExample)
DE (1) DE2756577C2 (enExample)
DK (1) DK146656C (enExample)
EG (1) EG13039A (enExample)
ES (1) ES465139A1 (enExample)
FI (1) FI64804C (enExample)
FR (1) FR2374328A1 (enExample)
GB (1) GB1575769A (enExample)
HU (1) HU175020B (enExample)
IE (1) IE46121B1 (enExample)
IL (1) IL53634A (enExample)
IT (1) IT1089971B (enExample)
MX (1) MX4703E (enExample)
MY (1) MY8200120A (enExample)
NL (1) NL7713959A (enExample)
NO (1) NO774358L (enExample)
PH (1) PH14143A (enExample)
PL (1) PL124260B1 (enExample)
SE (1) SE436282B (enExample)
SU (1) SU692563A3 (enExample)
YU (1) YU41022B (enExample)
ZA (1) ZA777533B (enExample)

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4243591A (en) * 1979-03-02 1981-01-06 Monsanto Company Poly(vinyl phosphonomethylene amino carboxylates) and process for preparation
US4315765A (en) * 1980-12-04 1982-02-16 Stauffer Chemical Company Trialkylsulfonium salts of n-phosphonomethylglycine and their use as plant growth regulators and herbicides
US4384880A (en) * 1980-12-04 1983-05-24 Stauffer Chemical Company Trialkylsulfonium salts of N-phosphonomethyl-glycine and their use as plant growth regulators and herbicides
US4376644A (en) * 1980-12-04 1983-03-15 Stauffer Chemical Company Tri-mixed alkylsulfonium salts of N-phosphonomethylglycine and their use as plant growth regulators and herbicides
US4431594A (en) * 1983-01-13 1984-02-14 Stauffer Chemical Company Method for preparation of salts of N-phosphonomethylglycine
WO1983003608A1 (en) * 1982-04-06 1983-10-27 Stauffer Chemical Co Tetra-substituted ammonium salt of n-phosphonomethylglycine and their uses as herbicides and plant growth regulants
US4437874A (en) 1981-11-25 1984-03-20 Stauffer Chemical Company Tri-mixed alkylsulfonium salts of N-phosphonomethylgylcine and their use as plant growth regulators and herbicides
IL65187A (en) * 1982-03-08 1985-03-31 Geshuri Lab Ltd N-phosphonomethylglycine derivatives,processes for their preparation and herbicidal compositions containing them
IL66824A0 (en) * 1982-06-25 1982-12-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine derivatives and herbicidal compounds and compositions prepared thereby
US4442041A (en) * 1982-06-30 1984-04-10 Stauffer Chemical Company Method for preparation of N-phosphonomethylglycine
IL66494A (en) * 1982-08-08 1985-07-31 Geshuri Lab Ltd Isothiourea,diisothiourea and diiminourea n-phosphonomethylglycine derivatives and herbicidal compositions containing them
US4472189A (en) * 1982-12-27 1984-09-18 Stauffer Chemical Co. Stannic N-phosphonomethyglycine and its use as a herbicide
IL68716A (en) * 1983-05-17 1987-03-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine
US4582650A (en) * 1985-02-11 1986-04-15 Monsanto Company Oxidation with encapsulated co-catalyst
US4579689A (en) * 1985-02-11 1986-04-01 Monsanto Company Oxidation with coated catalyst
US4696772A (en) * 1985-02-28 1987-09-29 Monsanto Company Amine oxidation using carbon catalyst having oxides removed from surface
US5580841A (en) * 1985-05-29 1996-12-03 Zeneca Limited Solid, phytoactive compositions and method for their preparation
US5468718A (en) * 1985-10-21 1995-11-21 Ici Americas Inc. Liquid, phytoactive compositions and method for their preparation
JPS62135317U (enExample) * 1986-02-19 1987-08-26
US5047079A (en) * 1986-08-18 1991-09-10 Ici Americas Inc. Method of preparation and use of solid, phytoactive compositions
US4853159A (en) * 1987-10-26 1989-08-01 Monsanto Company Process for producing N-phosphonomethylglycine
FR2635522B1 (fr) * 1988-08-18 1990-11-16 Rhone Poulenc Agrochimie N-sulfonomethylglycinate procede de preparation, utilisation dans la preparation d'herbicides de type glyphosate
US5187292A (en) * 1988-08-18 1993-02-16 Rhone-Poulenc Agrochimie N-sulfomethylglycinate, use in the preparation of herbicides of the glyphosate type
US4952723A (en) * 1989-07-31 1990-08-28 Monsanto Company Process for producing N-phosphonomethylglycine
ES2021229A6 (es) * 1990-03-12 1991-10-16 Ercros Sa Perfeccionamientos introducidos en un procedimiento de obtencion de n-fosfonometilglicina por oxidacion de n-fosfonometiliminodiacetico.
US5077431A (en) * 1990-06-25 1991-12-31 Monsanto Company Peroxide process for producing n-phosphonomethylglycine
US5095140A (en) * 1990-06-25 1992-03-10 Monsanto Company Peroxide process for producing N-phosphonomethylglycine
US6930075B1 (en) 1990-11-02 2005-08-16 Monsanto Technology, Llc Fatty acid-based herbicidal composition
IL101539A (en) 1991-04-16 1998-09-24 Monsanto Europe Sa Non-hygroscopic mono-ammonium salts of n-phosphonomethyl glycine derivatives their preparation and pesticidal compositons containing them
DE19500121A1 (de) * 1995-01-04 1996-07-11 Bayer Ag Verfahren zur Herstellung von N-Phosphonomethylglycin
US6365772B1 (en) 1995-05-30 2002-04-02 Hampshire Chemical Corp. Facile synthesis of phosphonomethylglycine from phosphonomethyliminodiacetic acid
DE69834509T2 (de) * 1998-02-12 2007-05-03 Monsanto Technology Llc Verfahren zur herstellung von glyphosat durch oxidation von n-substituierten glyphosaten
US6232494B1 (en) * 1998-02-12 2001-05-15 Monsanto Company Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine
US6417133B1 (en) 1998-02-25 2002-07-09 Monsanto Technology Llc Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
WO1999045781A1 (en) 1998-03-09 1999-09-16 Monsanto Company Mixtures for weed control in glyphosate tolerant soybeans
US5942643A (en) * 1998-05-14 1999-08-24 Calgon Carbon Corporation Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a low temperature catalytic carbon
JP2003508344A (ja) * 1998-07-06 2003-03-04 シンジェンタ パーティシペーションズ アクチェンゲゼルシャフト Ｎ−ホスホノメチルグリシン塩の製造
IES980552A2 (en) 1998-07-09 1999-08-11 Agritech Chemical Ltd Improved process for preparing N-phosphonomethyl iminodiacetic acid
BR9907000A (pt) * 1998-09-08 2000-09-26 Hampshire Chemical Corp Sìntese de ácido fosfonometiliminodiacético com efluente reduzido
DK1198466T3 (da) 1999-07-23 2003-06-16 Basf Ag Fremgangsmåde til fremstilling af glyphosater eller et salt deraf
DE10007702A1 (de) * 2000-02-19 2001-08-23 Sueddeutsche Kalkstickstoff Verfahren zur Herstellung von N-(Phosphonomethyl)glycin
AU6293001A (en) * 2000-05-22 2001-12-11 Monsanto Technology Llc Reaction systems for making n-(phosphonomethyl)glycine compounds
AUPR682201A0 (en) 2001-08-03 2001-08-30 Nufarm Limited Glyphosate composition
US6921834B2 (en) 2002-05-22 2005-07-26 Dow Agrosciences Llc Continuous process for preparing N-phosphonomethyl glycine
AR037559A1 (es) * 2002-11-19 2004-11-17 Atanor S A Una formulacion herbicida solida de n-fosfonometilglicina, bajo la forma de polvo, granulos o escamas, soluble o dispersable en agua, y el procedimiento para preparar dicha composicion
EP1729580B1 (en) 2004-03-30 2018-04-11 Monsanto Technology LLC Methods for controlling plant pathogens using n-phosphonomethylglycine
TW200624171A (en) * 2004-09-15 2006-07-16 Monsanto Technology Llc Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
CA2579816C (en) * 2004-09-17 2014-04-29 Monsanto Technology Llc Glyphosate formulations with early burndown symptoms
US8252953B2 (en) 2008-05-01 2012-08-28 Monsanto Technology Llc Metal utilization in supported, metal-containing catalysts
PL2341778T3 (pl) * 2008-11-06 2014-06-30 Sn Biotech Tech Sp Z O O Sp K Ciekła, homogeniczna kompozycja herbicydowa, sposób zwalczania chwastów, sposób wytwarzania ciekłej, homogenicznej kompozycji herbicydu i zastosowanie ciekłej, homogenicznej kompozycji herbicydowej do zwalczania chwastów
CN101880293B (zh) * 2009-05-04 2012-09-26 浙江新安化工集团股份有限公司 一种改进的n-膦酰基甲基甘氨酸生产方法
CN101781332B (zh) * 2010-03-02 2012-10-24 广西壮族自治区化工研究院 活性炭催化空气氧化双甘膦制备草甘膦的方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3977860A (en) * 1971-08-09 1976-08-31 Monsanto Company Herbicidal compositions and methods employing esters of N-phosphonomethylglycine
US3950402A (en) * 1972-05-31 1976-04-13 Monsanto Company Process for producing N-phosphonomethyl glycine
US3835000A (en) * 1972-12-21 1974-09-10 Monsanto Co Electrolytic process for producing n-phosphonomethyl glycine
GB1494197A (en) * 1973-11-30 1977-12-07 Ici Ltd Electrochemical process for the preparation of n-phosphonomethyl glycine
US3969398A (en) * 1974-05-01 1976-07-13 Monsanto Company Process for producing N-phosphonomethyl glycine

Also Published As

Publication number Publication date
YU301377A (en) 1982-06-30
US4147719A (en) 1979-04-03
CS194697B2 (en) 1979-12-31
AR220326A1 (es) 1980-10-31
IL53634A (en) 1981-03-31
GB1575769A (en) 1980-09-24
CA1090819A (en) 1980-12-02
AT364853B (de) 1981-11-25
YU41022B (en) 1986-10-31
DK146656C (da) 1984-05-07
NL7713959A (nl) 1978-06-22
SU692563A3 (ru) 1979-10-15
SE436282B (sv) 1984-11-26
DE2756577A1 (de) 1978-06-22
DK146656B (da) 1983-11-28
IT1089971B (it) 1985-06-18
HU175020B (hu) 1980-04-28
ZA777533B (en) 1978-10-25
FI64804B (fi) 1983-09-30
JPS5729038B2 (enExample) 1982-06-19
IE46121B1 (en) 1983-02-23
PL124260B1 (en) 1983-01-31
SE7714408L (sv) 1978-06-21
BG42358A3 (bg) 1987-11-14
MX4703E (es) 1982-08-04
MY8200120A (en) 1982-12-31
PH14143A (en) 1981-03-05
ES465139A1 (es) 1978-10-01
BE861996A (fr) 1978-06-19
AU3172577A (en) 1979-06-28
PL203139A1 (pl) 1978-10-09
EG13039A (en) 1980-07-31
IL53634A0 (en) 1978-03-10
FR2374328A1 (fr) 1978-07-13
CH634580A5 (de) 1983-02-15
NO774358L (no) 1978-06-21
JPS5377018A (en) 1978-07-08
ATA906877A (de) 1981-04-15
DK565977A (da) 1978-06-21
DE2756577C2 (de) 1987-04-30
FI773835A7 (fi) 1978-06-21
BR7708434A (pt) 1978-08-08
AU515070B2 (en) 1981-03-12
IE46121L (en) 1978-06-20
FR2374328B1 (enExample) 1983-01-07
DD133952A5 (de) 1979-01-31

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Owner name: MONSANTO COMPANY