FI63246B - Foerfarande foer framstaellning av en etylenpolymerisationskatalysator den sao framstaellda katalysatorn och dess anvaendning foer polymerisation av etylen - Google Patents
Foerfarande foer framstaellning av en etylenpolymerisationskatalysator den sao framstaellda katalysatorn och dess anvaendning foer polymerisation av etylen Download PDFInfo
- Publication number
- FI63246B FI63246B FI772791A FI772791A FI63246B FI 63246 B FI63246 B FI 63246B FI 772791 A FI772791 A FI 772791A FI 772791 A FI772791 A FI 772791A FI 63246 B FI63246 B FI 63246B
- Authority
- FI
- Finland
- Prior art keywords
- catalyst
- polymerization
- process according
- ethylene
- hydrocarbon
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Claims (10)
1. Förfarande för framställning av en katalysator son passar för polymerisation av etylen, kännetecknat därav, att 1. man torkar i en temperatur inom gränserna 100...800°C en oorga-nisk oxidkatalysatorbärare med stor yta, och bestäende av alu-miniumoxid, toriumoxid, kiseldioxid, zirkoniumoxid eller en blandning av dessa, 2. uppslammar den i skede 1) erhällna bäraren i ett huvudsakligen vattenfritt, vätskeformigt kolväte , 3. uppblandar det i skede 2) erhällna s lammet i en lösning, sora i vätskeformigt kolväte innehäller en kromocenförening och en i detta kolväte löslig titanförening, som kan kalcineras tili Ti02 sä, att den erhällna blandningen förutom kolväte innehäller 0,2...3 vikt-% krom räknat som grundämne och 1,0...10 vikt-% titan räknat som grundämne, 4. avlägsnar kolvätet sä att en fast rest blir kvar, 12 63246 5. tillsätter till den i skede 4) erhallna resten 0...2,5 vikt-% fluoreringsämne, räknat som F, och 6. upphettar den i skede 5) erhallna produkten i ett huvudsakligen vattenfritt syrehaltigt gasfyllt utrymme i 300...1000°C tills man erhäller en aktiv katalysator för polymerisation av etylen.
2. Förfarande enligt patentkravet 1, kännetecknat därav, att katalysatorns oorganiska oxidbärare är kiseldioxid.
3. Förfarande enligt patentkravet 1, kännetecknat därav, att kromocenföreningen är bis-(cyklopentadienyl)-krom-(II).
4. Förfarande enligt patentkravet 1, kännetecknat därav, att formeln för titanföreningen är (R')n"Ti(0R')m eller (R0)mTi(OR')n« där m är 1...4, n" är 0...3, m+n" =4, R är en alkyl-, aryl-eller cykloalkylgrupp som innehäller 1...12 kolatomer, och R' är R, en cyklopentadienylgrupp eller en alkenylgrupp innehällande 2...12 kolatomer.
5. Förfarande enligt patentkravet 1, kännetecknat därav, att man använder 0...5 vikt-% fluoreringsämne.
6. Förfarande enligt patentkravet 5, kännetecknat därav, att fluoreringsämnet är (N^^SiFg.
7. Förfarande enligt patentkravet 1, kännetecknat därav, att blandningen som erhalles i skede 5) i skede 6) upphettas vid 300...800°C. Θ. Förfarande enligt patentkravet 1, kännetecknat därav, att kolvätet är isopentan.
9. Katalysator passande för polymerisation av etylen, kännetecknat därav, att den är framställd genom att 1. i en temperatur inom gränserna 100...800°C torka en oorganisk oxidkatalysatorbärare med stor yta, och bestäende av aluminium-
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/725,542 US4101445A (en) | 1976-09-22 | 1976-09-22 | Preparation of modified and activated chromocene catalysts for ethylene polymerization |
| US72554276 | 1976-09-22 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI772791A FI772791A (fi) | 1978-03-23 |
| FI63246B true FI63246B (fi) | 1983-01-31 |
| FI63246C FI63246C (fi) | 1983-05-10 |
Family
ID=24914969
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI772791A FI63246C (fi) | 1976-09-22 | 1977-09-21 | Foerfarande foer framstaellning av en etylenpolymerisationskatalysator den sao framstaellda katalysatorn och dess anvaendning foer polymerisation av etylen |
Country Status (27)
| Country | Link |
|---|---|
| US (1) | US4101445A (sv) |
| JP (1) | JPS5339992A (sv) |
| AR (1) | AR222295A1 (sv) |
| AU (1) | AU519542B2 (sv) |
| BE (1) | BE858910A (sv) |
| BR (1) | BR7706288A (sv) |
| CA (1) | CA1098106A (sv) |
| CS (2) | CS221951B2 (sv) |
| DE (1) | DE2742543C2 (sv) |
| DK (1) | DK149205C (sv) |
| EG (1) | EG13094A (sv) |
| ES (2) | ES462508A1 (sv) |
| FI (1) | FI63246C (sv) |
| FR (1) | FR2365590A1 (sv) |
| GB (1) | GB1574877A (sv) |
| HK (1) | HK38981A (sv) |
| IN (1) | IN147225B (sv) |
| IT (1) | IT1085044B (sv) |
| MX (1) | MX4472E (sv) |
| MY (1) | MY8200080A (sv) |
| NL (1) | NL174723C (sv) |
| NO (2) | NO145680C (sv) |
| NZ (1) | NZ185222A (sv) |
| PH (1) | PH13455A (sv) |
| RO (1) | RO73241A (sv) |
| SE (2) | SE438314B (sv) |
| ZA (1) | ZA775232B (sv) |
Families Citing this family (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4424139A (en) | 1982-03-30 | 1984-01-03 | Phillips Petroleum Company | Catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound |
| US4690990A (en) * | 1982-03-30 | 1987-09-01 | Phillips Petroleum Company | Polymerization process using a catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound |
| US4803253A (en) * | 1982-03-30 | 1989-02-07 | Phillips Petroleum Company | Ethylene polymer produced using a catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound |
| US4522987A (en) * | 1982-07-09 | 1985-06-11 | Phillips Petroleum Company | Low density polyethylene |
| US4806513A (en) * | 1984-05-29 | 1989-02-21 | Phillips Petroleum Company | Silicon and fluorine-treated alumina containing a chromium catalyst and method of producing same |
| DE3609828A1 (de) * | 1986-03-22 | 1987-09-24 | Basf Ag | Verfahren zum herstellen von homo-sowie copolymerisaten des ethens durch phillips-katalyse |
| DE3618259A1 (de) * | 1986-05-30 | 1987-12-03 | Basf Ag | Verfahren zum herstellen von homo- sowie copolymerisaten des ethens durch phillips-katalyse |
| US5064796A (en) * | 1991-01-07 | 1991-11-12 | Exxon Chemical Patents Inc. | Support adjuvant for improved vanadium polymerization catalyst |
| US5211746A (en) * | 1992-06-22 | 1993-05-18 | Union Carbide Chemicals & Plastics Technology Corporation | Flame retardant compositions |
| US5401816A (en) * | 1993-09-27 | 1995-03-28 | Phillips Petroleum Company | Transition metal catalyst, method of preparing catalyst, polymerization process employing catalyst, and polymer produced |
| CN1152494A (zh) | 1995-07-21 | 1997-06-25 | 联合碳化化学品及塑料技术公司 | 聚乙烯的挤出方法 |
| US5925448A (en) | 1995-11-07 | 1999-07-20 | Union Carbide Chemicals & Plastics Technology Corporation | Film extruded from a blend of ethylene copolymers |
| BR9910611B1 (pt) * | 1998-05-18 | 2009-05-05 | processo para produção de uma composição de catalisador. | |
| US6165929A (en) * | 1998-05-18 | 2000-12-26 | Phillips Petroleum Company | Compositions that can produce polymers |
| US6107230A (en) * | 1998-05-18 | 2000-08-22 | Phillips Petroleum Company | Compositions that can produce polymers |
| US6300271B1 (en) | 1998-05-18 | 2001-10-09 | Phillips Petroleum Company | Compositions that can produce polymers |
| WO2000012565A1 (en) * | 1998-08-26 | 2000-03-09 | Exxon Chemical Patents Inc. | Highly active supported catalyst compositions |
| US6750302B1 (en) | 1999-12-16 | 2004-06-15 | Phillips Petroleum Company | Organometal catalyst compositions |
| US6388051B1 (en) | 2000-12-20 | 2002-05-14 | Union Carbide Chemicals & Plastics Technology Corporation | Process for selecting a polyethylene having improved processability |
| US6916892B2 (en) * | 2001-12-03 | 2005-07-12 | Fina Technology, Inc. | Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene |
| EP3498768A1 (en) | 2003-06-09 | 2019-06-19 | Union Carbide Chemicals & Plastics Technology LLC | Strippable semi-conductive insulation shield |
| US20050148742A1 (en) * | 2004-01-02 | 2005-07-07 | Hagerty Robert O. | Method for controlling sheeting in gas phase reactors |
| US7985811B2 (en) * | 2004-01-02 | 2011-07-26 | Univation Technologies, Llc | Method for controlling sheeting in gas phase reactors |
| US20070073012A1 (en) * | 2005-09-28 | 2007-03-29 | Pannell Richard B | Method for seed bed treatment before a polymerization reaction |
| US7629422B2 (en) | 2004-12-21 | 2009-12-08 | Univation Technologies, Llc | Process for transitioning between Ziegler-Natta-based and chromium-based catalysts |
| US7053163B1 (en) | 2005-02-22 | 2006-05-30 | Fina Technology, Inc. | Controlled comonomer distribution along a reactor for copolymer production |
| ATE455149T1 (de) * | 2006-04-07 | 2010-01-15 | Dow Global Technologies Inc | Polyolefinverbindungen, daraus hergestellte artikel und herstellungsverfahren dafür |
| US7446167B2 (en) * | 2006-04-13 | 2008-11-04 | Fina Technology, Inc. | Catalyst deactivation agents and methods for use of same |
| KR100718022B1 (ko) * | 2006-04-25 | 2007-05-14 | 한화석유화학 주식회사 | 트리 내성 가교 폴리올레핀 조성물 |
| US7863522B2 (en) * | 2006-12-20 | 2011-01-04 | Dow Global Technologies Inc. | Semi-conducting polymer compositions for the preparation of wire and cable |
| JP5784113B2 (ja) | 2010-06-10 | 2015-09-24 | ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー | チオビスフェノール酸化防止剤／ポリエチレングリコールブレンド |
| JP5848442B2 (ja) | 2011-05-20 | 2016-01-27 | ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー | チオビスフェノール系酸化防止剤／ポリエチレングリコールのブレンド |
| US8937139B2 (en) | 2012-10-25 | 2015-01-20 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| US8895679B2 (en) | 2012-10-25 | 2014-11-25 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| US9034991B2 (en) | 2013-01-29 | 2015-05-19 | Chevron Phillips Chemical Company Lp | Polymer compositions and methods of making and using same |
| US8877672B2 (en) | 2013-01-29 | 2014-11-04 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| EP3044258B1 (en) | 2013-09-13 | 2017-09-06 | Dow Global Technologies LLC | Peroxide-crosslinkable compositions and processes for their manufacture |
| US9914794B2 (en) | 2014-05-27 | 2018-03-13 | Sabic Global Technologies B.V. | Process for transitioning between incompatible catalysts |
| US10414892B2 (en) | 2014-11-28 | 2019-09-17 | Dow Global Technologies Llc | Process for foaming polyolefin compositions using a fluororesin/azodicarbonamide mixture as a nucleating agent |
| MX2017006284A (es) | 2014-11-28 | 2017-08-14 | Dow Global Technologies Llc | Proceso para la espumacion de composiciones de poliolefina usando una resina fluorada como agente de nucleacion. |
| WO2016102544A1 (en) | 2014-12-22 | 2016-06-30 | Sabic Global Technologies B.V. | Recovery of hydrocarbons from a hydrocarbon recycle |
| EP3237458B1 (en) | 2014-12-22 | 2022-06-22 | SABIC Global Technologies B.V. | Process for transitioning between incompatible catalysts |
| WO2016102548A1 (en) | 2014-12-22 | 2016-06-30 | Sabic Global Technologies B.V. | Process for transitioning between incompatible catalysts |
| WO2016151098A1 (en) | 2015-03-24 | 2016-09-29 | Sabic Global Technologies B.V. | Process for transitioning between incompatible catalysts |
| EP3294805B1 (en) | 2015-05-08 | 2020-01-15 | Dow Global Technologies LLC | Process for foaming polyolefin compositions using an azodicarbonamide/citrate mixture as a nucleating agent |
| EP3394111B1 (en) | 2015-12-22 | 2019-08-28 | SABIC Global Technologies B.V. | Process for transitioning between incompatible catalysts |
| CN109937233B (zh) | 2016-11-16 | 2021-11-09 | 陶氏环球技术有限责任公司 | 具有损耗因子和添加剂接受性的平衡的组合物 |
| TWI805586B (zh) | 2017-06-29 | 2023-06-21 | 美商陶氏全球科技有限責任公司 | 可交聯組合物、製品以及導電方法 |
| JP7237101B2 (ja) | 2018-06-29 | 2023-03-10 | ダウ グローバル テクノロジーズ エルエルシー | 発泡ビーズ及び焼結発泡構造体 |
| CN110878130B (zh) * | 2018-09-06 | 2023-04-07 | 中国石油化工股份有限公司 | 负载型铬和茂双金属催化剂、其制备方法及其应用 |
| US11993699B2 (en) | 2018-09-14 | 2024-05-28 | Fina Technology, Inc. | Polyethylene and controlled rheology polypropylene polymer blends and methods of use |
| JP7157875B2 (ja) | 2018-09-20 | 2022-10-20 | ダウ グローバル テクノロジーズ エルエルシー | エチレン系ポリマー発泡体を加硫ゴムで付着させるための接合方法 |
| WO2020172306A1 (en) | 2019-02-20 | 2020-08-27 | Fina Technology, Inc. | Polymer compositions with low warpage |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2882096A (en) * | 1956-09-25 | 1959-04-14 | Lyon George Albert | Wheel cover |
| US2879362A (en) * | 1956-11-14 | 1959-03-24 | Rauland Corp | Photosensitive device |
| US3622521A (en) * | 1967-08-21 | 1971-11-23 | Phillips Petroleum Co | Olefin polymerization with chromium and titanium-containing compounds |
| US3887494A (en) * | 1970-11-12 | 1975-06-03 | Phillips Petroleum Co | Olefin polymerization catalyst |
| CA995396A (en) * | 1971-03-18 | 1976-08-17 | Robert N. Johnson | Catalyst modified with strong reducing agent and silane compounds and use in polymerization of olefins |
| US3709853A (en) * | 1971-04-29 | 1973-01-09 | Union Carbide Corp | Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts |
| GB1429174A (en) * | 1972-06-12 | 1976-03-24 | Bp Chem Int Ltd | Polymerisation process and catalyst |
| US3806500A (en) * | 1972-07-21 | 1974-04-23 | Union Carbide Corp | Polymerization with thermally aged catalyst |
| US3950316A (en) * | 1974-05-03 | 1976-04-13 | Phillips Petroleum Company | Catalyst support formed by adding acidic material to silica containing titanium |
-
1976
- 1976-09-22 US US05/725,542 patent/US4101445A/en not_active Expired - Lifetime
-
1977
- 1977-08-29 ZA ZA00775232A patent/ZA775232B/xx unknown
- 1977-09-02 CA CA286,021A patent/CA1098106A/en not_active Expired
- 1977-09-19 AU AU28909/77A patent/AU519542B2/en not_active Expired
- 1977-09-20 PH PH20255A patent/PH13455A/en unknown
- 1977-09-21 FR FR7728407A patent/FR2365590A1/fr active Granted
- 1977-09-21 GB GB39409/77A patent/GB1574877A/en not_active Expired
- 1977-09-21 CS CS776117A patent/CS221951B2/cs unknown
- 1977-09-21 EG EG540/77A patent/EG13094A/xx active
- 1977-09-21 FI FI772791A patent/FI63246C/fi not_active IP Right Cessation
- 1977-09-21 JP JP11274877A patent/JPS5339992A/ja active Granted
- 1977-09-21 ES ES462508A patent/ES462508A1/es not_active Expired
- 1977-09-21 DK DK417277A patent/DK149205C/da not_active IP Right Cessation
- 1977-09-21 NL NLAANVRAGE7710349,A patent/NL174723C/xx not_active IP Right Cessation
- 1977-09-21 MX MX776202U patent/MX4472E/es unknown
- 1977-09-21 SE SE7710593A patent/SE438314B/sv not_active IP Right Cessation
- 1977-09-21 BR BR7706288A patent/BR7706288A/pt unknown
- 1977-09-21 DE DE2742543A patent/DE2742543C2/de not_active Expired
- 1977-09-21 CS CS805762A patent/CS221952B2/cs unknown
- 1977-09-21 NO NO773239A patent/NO145680C/no unknown
- 1977-09-21 NZ NZ185222A patent/NZ185222A/xx unknown
- 1977-09-21 IT IT27819/77A patent/IT1085044B/it active
- 1977-09-21 BE BE181083A patent/BE858910A/xx not_active IP Right Cessation
- 1977-09-21 AR AR269282A patent/AR222295A1/es active
- 1977-09-22 RO RO7791632A patent/RO73241A/ro unknown
- 1977-09-22 IN IN1430/CAL/77A patent/IN147225B/en unknown
- 1977-11-24 ES ES464417A patent/ES464417A1/es not_active Expired
-
1980
- 1980-03-24 NO NO800836A patent/NO153611C/no unknown
-
1981
- 1981-08-06 HK HK389/81A patent/HK38981A/xx unknown
-
1982
- 1982-12-30 MY MY80/82A patent/MY8200080A/xx unknown
-
1983
- 1983-01-26 SE SE8300395A patent/SE445460B/sv not_active IP Right Cessation
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed |
Owner name: UNION CARBIDE CO |