FI56972C - Foerfarande foer massframstaellning av polymerer och kopolymerer som baserar sig pao vinylklorid - Google Patents
Foerfarande foer massframstaellning av polymerer och kopolymerer som baserar sig pao vinylklorid Download PDFInfo
- Publication number
- FI56972C FI56972C FI56/73A FI5673A FI56972C FI 56972 C FI56972 C FI 56972C FI 56/73 A FI56/73 A FI 56/73A FI 5673 A FI5673 A FI 5673A FI 56972 C FI56972 C FI 56972C
- Authority
- FI
- Finland
- Prior art keywords
- weight
- vinyl chloride
- polymerization
- prepolymer
- particle size
- Prior art date
Links
- 239000002245 particle Substances 0.000 claims description 98
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 64
- 238000006116 polymerization reaction Methods 0.000 claims description 62
- 229920000642 polymer Polymers 0.000 claims description 49
- 238000009826 distribution Methods 0.000 claims description 45
- 229920001577 copolymer Polymers 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 16
- 239000012429 reaction media Substances 0.000 claims description 15
- 239000000178 monomer Substances 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 10
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- -1 alkyl methacrylates Chemical class 0.000 claims description 7
- LTHJXDSHSVNJKG-UHFFFAOYSA-N 2-[2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOCCOC(=O)C(C)=C LTHJXDSHSVNJKG-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 3
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 3
- OWDBMKZHFCSOOL-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)propoxy]propoxy]propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)COC(C)COC(C)COC(=O)C(C)=C OWDBMKZHFCSOOL-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- JJBFVQSGPLGDNX-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)COC(=O)C(C)=C JJBFVQSGPLGDNX-UHFFFAOYSA-N 0.000 claims 1
- 150000002118 epoxides Chemical class 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 41
- UDHXJZHVNHGCEC-UHFFFAOYSA-N Chlorophacinone Chemical compound C1=CC(Cl)=CC=C1C(C=1C=CC=CC=1)C(=O)C1C(=O)C2=CC=CC=C2C1=O UDHXJZHVNHGCEC-UHFFFAOYSA-N 0.000 description 25
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 18
- 229910052760 oxygen Inorganic materials 0.000 description 18
- 239000001301 oxygen Substances 0.000 description 18
- 238000002309 gasification Methods 0.000 description 16
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 15
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 13
- 238000007872 degassing Methods 0.000 description 11
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 9
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 7
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 241000894007 species Species 0.000 description 6
- JDDQLBKEPJXSJL-UHFFFAOYSA-N C(O)(O)=O.C(C)OOCC Chemical compound C(O)(O)=O.C(C)OOCC JDDQLBKEPJXSJL-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- BSVQJWUUZCXSOL-UHFFFAOYSA-N cyclohexylsulfonyl ethaneperoxoate Chemical compound CC(=O)OOS(=O)(=O)C1CCCCC1 BSVQJWUUZCXSOL-UHFFFAOYSA-N 0.000 description 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- VZBZCLRLPBEOBO-UHFFFAOYSA-N carboxyoxy octan-3-yl carbonate Chemical compound CCCCCC(CC)OC(=O)OOC(O)=O VZBZCLRLPBEOBO-UHFFFAOYSA-N 0.000 description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 3
- 229920005671 poly(vinyl chloride-propylene) Polymers 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229920006163 vinyl copolymer Polymers 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- LYXYPAGJJYOXSH-UHFFFAOYSA-N carbonic acid 1-ethylperoxyhexane Chemical compound OC(O)=O.CCCCCCOOCC LYXYPAGJJYOXSH-UHFFFAOYSA-N 0.000 description 2
- KHBQOOHGCZONAK-UHFFFAOYSA-N carboxyoxy ethyl carbonate Chemical compound CCOC(=O)OOC(O)=O KHBQOOHGCZONAK-UHFFFAOYSA-N 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- PMJHHCWVYXUKFD-UHFFFAOYSA-N penta-1,3-diene Chemical group CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 2
- MKPHQUIFIPKXJL-UHFFFAOYSA-N 1,2-dihydroxypropyl 2-methylprop-2-enoate Chemical compound CC(O)C(O)OC(=O)C(C)=C MKPHQUIFIPKXJL-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical compound CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 241000797947 Paria Species 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- JFXVXZJYWSRCST-UHFFFAOYSA-N carboxyoxy octyl carbonate Chemical compound CCCCCCCCOC(=O)OOC(O)=O JFXVXZJYWSRCST-UHFFFAOYSA-N 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR727200766A FR2167254B1 (de) | 1972-01-11 | 1972-01-11 | |
| FR7200766 | 1972-01-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FI56972B FI56972B (fi) | 1980-01-31 |
| FI56972C true FI56972C (fi) | 1980-05-12 |
Family
ID=9091708
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI56/73A FI56972C (fi) | 1972-01-11 | 1973-01-09 | Foerfarande foer massframstaellning av polymerer och kopolymerer som baserar sig pao vinylklorid |
Country Status (23)
| Country | Link |
|---|---|
| JP (1) | JPS506488B2 (de) |
| AR (1) | AR193311A1 (de) |
| AT (1) | AT322206B (de) |
| BE (1) | BE793798A (de) |
| BR (1) | BR7300205D0 (de) |
| CA (1) | CA1026046A (de) |
| CH (1) | CH557393A (de) |
| DE (1) | DE2301116C3 (de) |
| DK (1) | DK135724B (de) |
| ES (1) | ES410492A1 (de) |
| FI (1) | FI56972C (de) |
| FR (1) | FR2167254B1 (de) |
| GB (1) | GB1408958A (de) |
| IE (1) | IE37098B1 (de) |
| IN (1) | IN137621B (de) |
| IT (1) | IT976807B (de) |
| NL (1) | NL171275C (de) |
| NO (1) | NO140768C (de) |
| PH (1) | PH12387A (de) |
| SE (1) | SE402780B (de) |
| SU (1) | SU471725A3 (de) |
| YU (1) | YU35606B (de) |
| ZA (1) | ZA73182B (de) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5330777U (de) * | 1976-08-23 | 1978-03-16 | ||
| JPS5330776U (de) * | 1976-08-23 | 1978-03-16 | ||
| FR2402669A1 (fr) * | 1977-09-12 | 1979-04-06 | Rhone Poulenc Ind | Procede de preparation en masse, en deux phases, de polymeres et copolymeres a base de chlorure de vinyle a faible teneur en produit grossier |
| JPS565843A (en) * | 1979-06-28 | 1981-01-21 | Chisso Corp | Vinyl chloride resin composition |
| JPS5611916A (en) * | 1979-07-10 | 1981-02-05 | Chisso Corp | Production of vinyl chloride copolymer |
| FR2508913A1 (fr) * | 1981-07-03 | 1983-01-07 | Chloe Chemie | Procede de preparation en masse, en deux phases, de polymeres et copolymeres a base de chlorure de vinyle en grains fins |
| JPS5847011A (ja) * | 1981-09-14 | 1983-03-18 | Chisso Corp | 塩化ビニル系重合体の製造方法 |
| JP7175886B2 (ja) * | 2016-11-08 | 2022-11-21 | ダウ グローバル テクノロジーズ エルエルシー | 制御された粒径分布 |
-
0
- BE BE793798D patent/BE793798A/xx not_active IP Right Cessation
-
1972
- 1972-01-11 FR FR727200766A patent/FR2167254B1/fr not_active Expired
-
1973
- 1973-01-04 IN IN28/CAL/73A patent/IN137621B/en unknown
- 1973-01-08 DK DK8573AA patent/DK135724B/da unknown
- 1973-01-09 FI FI56/73A patent/FI56972C/fi active
- 1973-01-09 NL NLAANVRAGE7300294,A patent/NL171275C/xx not_active IP Right Cessation
- 1973-01-10 BR BR73205A patent/BR7300205D0/pt unknown
- 1973-01-10 CH CH28573A patent/CH557393A/fr not_active IP Right Cessation
- 1973-01-10 IE IE34/73A patent/IE37098B1/xx unknown
- 1973-01-10 PH PH7314246A patent/PH12387A/en unknown
- 1973-01-10 ES ES410492A patent/ES410492A1/es not_active Expired
- 1973-01-10 IT IT47596/73A patent/IT976807B/it active
- 1973-01-10 DE DE2301116A patent/DE2301116C3/de not_active Expired
- 1973-01-10 AR AR246054A patent/AR193311A1/es active
- 1973-01-10 ZA ZA730182A patent/ZA73182B/xx unknown
- 1973-01-10 NO NO110/73A patent/NO140768C/no unknown
- 1973-01-10 YU YU46/73A patent/YU35606B/xx unknown
- 1973-01-10 SE SE7300306A patent/SE402780B/xx unknown
- 1973-01-10 GB GB127473A patent/GB1408958A/en not_active Expired
- 1973-01-10 CA CA160,955A patent/CA1026046A/en not_active Expired
- 1973-01-11 SU SU1877310A patent/SU471725A3/ru active
- 1973-01-11 AT AT23073A patent/AT322206B/de not_active IP Right Cessation
- 1973-01-11 JP JP48005586A patent/JPS506488B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL171275C (nl) | 1983-03-01 |
| NL7300294A (de) | 1973-07-13 |
| FI56972B (fi) | 1980-01-31 |
| BE793798A (fr) | 1973-07-09 |
| PH12387A (en) | 1979-01-29 |
| DE2301116C3 (de) | 1975-08-28 |
| ZA73182B (en) | 1973-12-19 |
| JPS4881982A (de) | 1973-11-01 |
| IN137621B (de) | 1975-08-23 |
| SU471725A3 (ru) | 1975-05-25 |
| JPS506488B2 (de) | 1975-03-14 |
| YU4673A (en) | 1980-10-31 |
| NO140768C (no) | 1979-11-07 |
| CA1026046A (en) | 1978-02-07 |
| ES410492A1 (es) | 1975-12-01 |
| FR2167254A1 (de) | 1973-08-24 |
| DE2301116A1 (de) | 1973-07-26 |
| FR2167254B1 (de) | 1974-06-21 |
| AR193311A1 (es) | 1973-04-11 |
| DE2301116B2 (de) | 1975-01-09 |
| AT322206B (de) | 1975-05-12 |
| CH557393A (fr) | 1974-12-31 |
| GB1408958A (en) | 1975-10-08 |
| IT976807B (it) | 1974-09-10 |
| NO140768B (no) | 1979-07-30 |
| IE37098L (en) | 1973-07-11 |
| DK135724B (da) | 1977-06-13 |
| BR7300205D0 (pt) | 1973-09-27 |
| SE402780B (sv) | 1978-07-17 |
| YU35606B (en) | 1981-04-30 |
| IE37098B1 (en) | 1977-05-11 |
| DK135724C (de) | 1977-10-31 |
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