FI113149B - Erittäin väkeviä kiinteitä mepikvaattikloridituotteita ja niiden valmistus - Google Patents
Erittäin väkeviä kiinteitä mepikvaattikloridituotteita ja niiden valmistus Download PDFInfo
- Publication number
- FI113149B FI113149B FI960269A FI960269A FI113149B FI 113149 B FI113149 B FI 113149B FI 960269 A FI960269 A FI 960269A FI 960269 A FI960269 A FI 960269A FI 113149 B FI113149 B FI 113149B
- Authority
- FI
- Finland
- Prior art keywords
- water
- dryer
- plant growth
- amorphous silica
- chloride
- Prior art date
Links
- 239000007787 solid Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims description 4
- DARPYRSDRJYGIF-PTNGSMBKSA-N (Z)-3-ethoxy-2-naphthalen-2-ylsulfonylprop-2-enenitrile Chemical compound C1=CC=CC2=CC(S(=O)(=O)C(\C#N)=C/OCC)=CC=C21 DARPYRSDRJYGIF-PTNGSMBKSA-N 0.000 title description 42
- 239000000203 mixture Substances 0.000 claims abstract description 59
- 239000000843 powder Substances 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 24
- NNCAWEWCFVZOGF-UHFFFAOYSA-N mepiquat Chemical class C[N+]1(C)CCCCC1 NNCAWEWCFVZOGF-UHFFFAOYSA-N 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 48
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 38
- 238000001035 drying Methods 0.000 claims description 19
- 239000007921 spray Substances 0.000 claims description 15
- 239000012527 feed solution Substances 0.000 claims description 13
- 230000008635 plant growth Effects 0.000 claims description 13
- 229910002029 synthetic silica gel Inorganic materials 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- VHOVSQVSAAQANU-UHFFFAOYSA-M mepiquat chloride Chemical compound [Cl-].C[N+]1(C)CCCCC1 VHOVSQVSAAQANU-UHFFFAOYSA-M 0.000 claims description 10
- 238000002347 injection Methods 0.000 claims description 9
- 239000007924 injection Substances 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- -1 synthetic amorphous silica hydrates Chemical class 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 7
- 230000001105 regulatory effect Effects 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 230000001276 controlling effect Effects 0.000 claims description 4
- 230000012010 growth Effects 0.000 claims description 4
- 238000001704 evaporation Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 4
- 238000007790 scraping Methods 0.000 claims 2
- 238000007666 vacuum forming Methods 0.000 claims 1
- 239000005648 plant growth regulator Substances 0.000 abstract description 20
- 238000009472 formulation Methods 0.000 abstract description 3
- 230000001413 cellular effect Effects 0.000 description 14
- 239000000546 pharmaceutical excipient Substances 0.000 description 13
- 239000000377 silicon dioxide Substances 0.000 description 13
- 241000196324 Embryophyta Species 0.000 description 11
- 239000011230 binding agent Substances 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 239000007884 disintegrant Substances 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- 239000004480 active ingredient Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000008399 tap water Substances 0.000 description 6
- 235000020679 tap water Nutrition 0.000 description 6
- 238000007906 compression Methods 0.000 description 5
- 230000006835 compression Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000001291 vacuum drying Methods 0.000 description 5
- PWVXXGRKLHYWKM-UHFFFAOYSA-N 5-[2-(benzenesulfonyl)ethyl]-3-[(1-methylpyrrolidin-2-yl)methyl]-1h-indole Chemical compound CN1CCCC1CC(C1=C2)=CNC1=CC=C2CCS(=O)(=O)C1=CC=CC=C1 PWVXXGRKLHYWKM-UHFFFAOYSA-N 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- 235000013312 flour Nutrition 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 239000007916 tablet composition Substances 0.000 description 4
- 229920002261 Corn starch Polymers 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 235000010980 cellulose Nutrition 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000008120 corn starch Substances 0.000 description 3
- 229940099112 cornstarch Drugs 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 244000025254 Cannabis sativa Species 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- 240000003183 Manihot esculenta Species 0.000 description 2
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 2
- 229920000881 Modified starch Polymers 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 235000008504 concentrate Nutrition 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000008240 homogeneous mixture Substances 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- VOJUXHHACRXLTD-UHFFFAOYSA-N 1,4-dihydroxy-2-naphthoic acid Chemical compound C1=CC=CC2=C(O)C(C(=O)O)=CC(O)=C21 VOJUXHHACRXLTD-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 description 1
- 239000001763 2-hydroxyethyl(trimethyl)azanium Substances 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 229910002016 Aerosil® 200 Inorganic materials 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 229920000945 Amylopectin Polymers 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000019743 Choline chloride Nutrition 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 240000009226 Corylus americana Species 0.000 description 1
- 235000001543 Corylus americana Nutrition 0.000 description 1
- 235000007466 Corylus avellana Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 244000299507 Gossypium hirsutum Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010061217 Infestation Diseases 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 229920002774 Maltodextrin Polymers 0.000 description 1
- 239000005913 Maltodextrin Substances 0.000 description 1
- 239000005984 Mepiquat Substances 0.000 description 1
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000000164 antipsychotic agent Substances 0.000 description 1
- 229940005529 antipsychotics Drugs 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229960003178 choline chloride Drugs 0.000 description 1
- SGMZJAMFUVOLNK-UHFFFAOYSA-M choline chloride Chemical compound [Cl-].C[N+](C)(C)CCO SGMZJAMFUVOLNK-UHFFFAOYSA-M 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012526 feed medium Substances 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 210000003754 fetus Anatomy 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 238000011990 functional testing Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 239000002920 hazardous waste Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229940060367 inert ingredients Drugs 0.000 description 1
- 239000012678 infectious agent Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 229940035034 maltodextrin Drugs 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229940016286 microcrystalline cellulose Drugs 0.000 description 1
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 1
- 239000008108 microcrystalline cellulose Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 239000006199 nebulizer Substances 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 231100000208 phytotoxic Toxicity 0.000 description 1
- 230000000885 phytotoxic effect Effects 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000033764 rhythmic process Effects 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 230000007226 seed germination Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000009772 tissue formation Effects 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 235000010487 tragacanth Nutrition 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- 229940116362 tragacanth Drugs 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/095,122 US5468720A (en) | 1993-07-20 | 1993-07-20 | High concentrated, solid mepiquat chloride products and processes for making dry form solid mepiquat chloride powder and tablets |
| US9512293 | 1993-07-20 | ||
| EP9402253 | 1994-07-09 | ||
| PCT/EP1994/002253 WO1995002963A1 (en) | 1993-07-20 | 1994-07-09 | High concentrated, solid mepiquat chloride and chlormequat chloride products |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI960269L FI960269L (fi) | 1996-01-19 |
| FI960269A0 FI960269A0 (fi) | 1996-01-19 |
| FI113149B true FI113149B (fi) | 2004-03-15 |
Family
ID=22249834
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI960269A FI113149B (fi) | 1993-07-20 | 1996-01-19 | Erittäin väkeviä kiinteitä mepikvaattikloridituotteita ja niiden valmistus |
Country Status (28)
| Country | Link |
|---|---|
| US (3) | US5468720A (cs) |
| EP (1) | EP0710071B1 (cs) |
| JP (1) | JP3578764B2 (cs) |
| CN (1) | CN1062411C (cs) |
| AT (1) | ATE158686T1 (cs) |
| AU (1) | AU679773B2 (cs) |
| BR (1) | BR9407085A (cs) |
| CA (1) | CA2167513A1 (cs) |
| CO (1) | CO4340591A1 (cs) |
| CZ (1) | CZ292602B6 (cs) |
| DE (1) | DE69406005T2 (cs) |
| DK (1) | DK0710071T3 (cs) |
| ES (1) | ES2108482T3 (cs) |
| FI (1) | FI113149B (cs) |
| GR (1) | GR3025823T3 (cs) |
| HU (1) | HU215080B (cs) |
| IL (1) | IL110149A (cs) |
| NZ (1) | NZ269554A (cs) |
| PE (1) | PE33595A1 (cs) |
| PL (1) | PL177599B1 (cs) |
| RU (1) | RU2137367C1 (cs) |
| SK (1) | SK281625B6 (cs) |
| TJ (1) | TJ273B (cs) |
| TW (1) | TW307663B (cs) |
| UA (1) | UA34483C2 (cs) |
| UY (1) | UY23807A1 (cs) |
| WO (1) | WO1995002963A1 (cs) |
| ZA (1) | ZA945277B (cs) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0791586B1 (en) * | 1992-06-04 | 2000-07-26 | Micro-Flo Company | Mepiquat chloride, sealed with a water soluble polymer |
| US6013272A (en) | 1996-12-19 | 2000-01-11 | Valent U.S.A. Corporation | Chemically stable, insecticidally active phosphoroamidothioate pellet compositions and methods for their manufacture |
| US6288009B1 (en) | 1998-04-10 | 2001-09-11 | Basf Corporation | Plant growth regulator compositions |
| DE19825687A1 (de) * | 1998-06-09 | 1999-12-16 | Degussa | Wirkstoffkonzentrat |
| TW568788B (en) * | 1998-10-12 | 2004-01-01 | Chugai Pharmaceutical Co Ltd | Polymer combining with phosphoric acid and preparation containing the same |
| WO2001058831A1 (en) * | 2000-02-08 | 2001-08-16 | Peter Warren English | A soil supplement containing plant available silicon |
| US6410783B1 (en) | 2000-10-19 | 2002-06-25 | Basf Corporation | Method of producing carboxylic acid salts |
| FR2833187B1 (fr) * | 2001-12-11 | 2004-09-10 | Pancosma Sa Pour L Ind Des Pro | Oligo-element en poudre, procede et dispositif pour sa fabrication |
| FR2843752B1 (fr) * | 2002-08-26 | 2007-05-18 | Pancosma Sa Pour L Ind Des Pro | Oligo-elements cristallins, et procedes pour leur fabrication |
| WO2003049850A2 (fr) * | 2001-12-11 | 2003-06-19 | Pancosma Societe Anonyme Pour L'industrie Des Produits Biochimiques | Oligo-element en poudre, procede et dispositif pour sa fabrication |
| US20040221631A1 (en) * | 2002-09-05 | 2004-11-11 | Kerrigan Kurt J. | Composition for fertilizer tablet |
| US7325688B1 (en) | 2003-09-26 | 2008-02-05 | Gowan Milling Company, L.L.C. | Pressurized water-soluble pouch |
| RU2335112C1 (ru) * | 2006-12-26 | 2008-10-10 | Федеральное государственное образовательное учреждение высшего профессионального образования Кубанский государственный аграрный университет | Способ посева амаранта |
| FR2935383B1 (fr) * | 2008-08-26 | 2010-10-01 | Pancosma Sa Pour L Ind Des Pro | Procede et dispositif pour la fabrication de complexes organometalliques en poudre. |
| RU2442645C1 (ru) * | 2010-09-10 | 2012-02-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ульяновский государственный технический университет" | Способ активации добавок природного цеолита в почву и устройство для его осуществления |
| RU2013133873A (ru) | 2010-12-21 | 2015-01-27 | БАЙЕР КРОПСАЙЕНС ЭлПи | ШЕРОХОВАТЫЕ МУТАНТЫ Bacillus И СПОСОБЫ ИХ ПРИМЕНЕНИЯ ДЛЯ УСКОРЕНИЯ РОСТА РАСТЕНИЙ, УЛУЧШЕНИЯ ЗДОРОВЬЯ РАСТЕНИЙ И БОРЬБЫ С БОЛЕЗНЯМИ И ВРЕДИТЕЛЯМИ |
| MX2014002890A (es) | 2011-09-12 | 2015-01-19 | Bayer Cropscience Lp | Metodo para mejorar la salud y/o promover el crecimiento de una planta y/o mejorar la maduracion de frutos. |
| CN103508784B (zh) * | 2012-06-28 | 2015-07-08 | 马辉 | 纯天然植物生长调节剂 |
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| DE101386C (cs) * | ||||
| US3356569A (en) * | 1964-05-27 | 1967-12-05 | Rohm & Haas | Choline chloride powder and method of production |
| DE1619865C3 (de) * | 1967-11-04 | 1978-06-01 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Anwendung einer feinstteiligen, amorphen Kieselsäure mit hoher Struktur als Trägerfüllstoff für Wirkstoffe |
| US3695989A (en) * | 1970-08-12 | 1972-10-03 | Robert E Albert | Cold water soluble foam plastic package |
| BE795534A (fr) * | 1972-02-18 | 1973-08-16 | Basf Ag | Agents pour la regulation de la croissance des plantes, contenant comme principe actif un sel azote |
| DD101386A1 (cs) * | 1972-12-21 | 1973-11-12 | ||
| CH604880A5 (cs) * | 1976-05-25 | 1978-09-15 | Ciba Geigy Ag | |
| DE3926055A1 (de) * | 1989-08-07 | 1991-02-14 | Basf Ag | Verwendung von diphenyletherderivaten zur desikkation und abszission von pflanzenorganen |
| US5222595A (en) * | 1990-07-18 | 1993-06-29 | Rhone-Poulenc Ag Company | Bag in a bag for containerization of toxic or hazardous material |
| IL101539A (en) * | 1991-04-16 | 1998-09-24 | Monsanto Europe Sa | Non-hygroscopic mono-ammonium salts of n-phosphonomethyl glycine derivatives their preparation and pesticidal compositons containing them |
| AU664997B2 (en) * | 1991-06-11 | 1995-12-14 | Rhone-Poulenc Agrochimie | New packaging/containerization system |
| EP0791586B1 (en) * | 1992-06-04 | 2000-07-26 | Micro-Flo Company | Mepiquat chloride, sealed with a water soluble polymer |
| PL173829B1 (pl) * | 1992-10-30 | 1998-05-29 | Basf Corp | Preparat pestycydowy w postaci rozpraszalnych w wodzie granulek oraz sposób wytwarzania preparatu pestycydowego w postaci rozpraszalnych w wodzie granulek |
| US5294594A (en) * | 1992-12-23 | 1994-03-15 | American Cyanamid Company | Water dispersible granular herbicidal compositions comprising dinitroaniline herbicides, montmorillonite carrier and water-swellable polymer |
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1993
- 1993-07-20 US US08/095,122 patent/US5468720A/en not_active Expired - Lifetime
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1994
- 1994-06-28 IL IL11014994A patent/IL110149A/en not_active IP Right Cessation
- 1994-07-08 TW TW083106224A patent/TW307663B/zh active
- 1994-07-09 SK SK85-96A patent/SK281625B6/sk unknown
- 1994-07-09 CN CN94192833A patent/CN1062411C/zh not_active Expired - Fee Related
- 1994-07-09 WO PCT/EP1994/002253 patent/WO1995002963A1/en not_active Ceased
- 1994-07-09 TJ TJ96000265A patent/TJ273B/xx unknown
- 1994-07-09 AT AT94923717T patent/ATE158686T1/de not_active IP Right Cessation
- 1994-07-09 EP EP94923717A patent/EP0710071B1/en not_active Expired - Lifetime
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- 1994-07-09 HU HU9503956A patent/HU215080B/hu not_active IP Right Cessation
- 1994-07-09 DK DK94923717.6T patent/DK0710071T3/da active
- 1994-07-09 BR BR9407085A patent/BR9407085A/pt not_active IP Right Cessation
- 1994-07-09 DE DE69406005T patent/DE69406005T2/de not_active Expired - Fee Related
- 1994-07-09 RU RU96103372/04A patent/RU2137367C1/ru not_active IP Right Cessation
- 1994-07-09 UA UA96020621A patent/UA34483C2/uk unknown
- 1994-07-09 AU AU73852/94A patent/AU679773B2/en not_active Ceased
- 1994-07-09 CA CA002167513A patent/CA2167513A1/en not_active Abandoned
- 1994-07-09 CZ CZ1996159A patent/CZ292602B6/cs not_active IP Right Cessation
- 1994-07-09 PL PL94312658A patent/PL177599B1/pl not_active IP Right Cessation
- 1994-07-09 NZ NZ269554A patent/NZ269554A/en unknown
- 1994-07-14 CO CO94030971A patent/CO4340591A1/es unknown
- 1994-07-19 ZA ZA945277A patent/ZA945277B/xx unknown
- 1994-07-19 UY UY23807A patent/UY23807A1/es not_active IP Right Cessation
- 1994-08-09 PE PE1994248169A patent/PE33595A1/es not_active Application Discontinuation
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1995
- 1995-03-30 US US08/415,124 patent/US5589438A/en not_active Expired - Fee Related
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