ES2959186T3 - Composiciones poliméricas basadas en etileno para recubrimientos por extrusión mejorados - Google Patents
Composiciones poliméricas basadas en etileno para recubrimientos por extrusión mejorados Download PDFInfo
- Publication number
- ES2959186T3 ES2959186T3 ES15744758T ES15744758T ES2959186T3 ES 2959186 T3 ES2959186 T3 ES 2959186T3 ES 15744758 T ES15744758 T ES 15744758T ES 15744758 T ES15744758 T ES 15744758T ES 2959186 T3 ES2959186 T3 ES 2959186T3
- Authority
- ES
- Spain
- Prior art keywords
- composition
- ethylene
- polymer
- weight
- density
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 218
- 229920000642 polymer Polymers 0.000 title claims abstract description 130
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 83
- 239000005977 Ethylene Substances 0.000 title claims abstract description 75
- 238000007765 extrusion coating Methods 0.000 title description 39
- 238000010526 radical polymerization reaction Methods 0.000 claims abstract description 8
- 229920001684 low density polyethylene Polymers 0.000 claims description 41
- 239000004702 low-density polyethylene Substances 0.000 claims description 41
- 239000000155 melt Substances 0.000 claims description 41
- 229920001903 high density polyethylene Polymers 0.000 claims description 35
- 239000004700 high-density polyethylene Substances 0.000 claims description 34
- 238000000576 coating method Methods 0.000 claims description 31
- 239000011248 coating agent Substances 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 230000005540 biological transmission Effects 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 4
- 239000006260 foam Substances 0.000 claims description 4
- 238000002844 melting Methods 0.000 abstract description 11
- 230000008018 melting Effects 0.000 abstract description 11
- 239000000523 sample Substances 0.000 description 60
- 238000000034 method Methods 0.000 description 49
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 32
- -1 laminates Substances 0.000 description 31
- 229920000573 polyethylene Polymers 0.000 description 28
- 238000006243 chemical reaction Methods 0.000 description 27
- 238000005227 gel permeation chromatography Methods 0.000 description 27
- 239000004698 Polyethylene Substances 0.000 description 26
- 230000008569 process Effects 0.000 description 25
- 238000006116 polymerization reaction Methods 0.000 description 19
- 239000002904 solvent Substances 0.000 description 19
- 238000000149 argon plasma sintering Methods 0.000 description 17
- 239000000178 monomer Substances 0.000 description 15
- 238000012360 testing method Methods 0.000 description 15
- 239000010408 film Substances 0.000 description 14
- 239000003999 initiator Substances 0.000 description 12
- 238000007789 sealing Methods 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 11
- 238000001816 cooling Methods 0.000 description 10
- 238000010828 elution Methods 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 239000004793 Polystyrene Substances 0.000 description 9
- 238000000605 extraction Methods 0.000 description 9
- 239000000654 additive Substances 0.000 description 8
- 230000004888 barrier function Effects 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 8
- 239000000123 paper Substances 0.000 description 8
- 229920002223 polystyrene Polymers 0.000 description 8
- 238000012546 transfer Methods 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 7
- 238000000113 differential scanning calorimetry Methods 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000008187 granular material Substances 0.000 description 6
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- 230000014759 maintenance of location Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229920005638 polyethylene monopolymer Polymers 0.000 description 6
- 238000004364 calculation method Methods 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 229920002959 polymer blend Polymers 0.000 description 5
- 238000000518 rheometry Methods 0.000 description 5
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical group ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 230000006835 compression Effects 0.000 description 4
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000004927 fusion Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000002655 kraft paper Substances 0.000 description 4
- 150000001451 organic peroxides Chemical class 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- 230000004044 response Effects 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000012986 chain transfer agent Substances 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 230000010354 integration Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000012429 reaction media Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- 125000005603 azodicarboxylic group Chemical group 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 239000003480 eluent Substances 0.000 description 2
- 238000011067 equilibration Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 230000003534 oscillatory effect Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
- 229920013716 polyethylene resin Polymers 0.000 description 2
- 229920006254 polymer film Polymers 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 239000012925 reference material Substances 0.000 description 2
- 238000001374 small-angle light scattering Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical class CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- DALNRYLBTOJSOH-UHFFFAOYSA-N 3,3,5,7,7-pentamethyl-1,2,4-trioxepane Chemical compound CC1CC(C)(C)OOC(C)(C)O1 DALNRYLBTOJSOH-UHFFFAOYSA-N 0.000 description 1
- QRIQYQXNFSXNGR-UHFFFAOYSA-N 3,3,6,6,9,9-hexamethyl-1,2,4,5-tetraoxonane Chemical compound CC1(C)CCC(C)(C)OOC(C)(C)OO1 QRIQYQXNFSXNGR-UHFFFAOYSA-N 0.000 description 1
- KVWLLOIEGKLBPA-UHFFFAOYSA-N 3,6,9-triethyl-3,6,9-trimethyl-1,2,4,5,7,8-hexaoxonane Chemical compound CCC1(C)OOC(C)(CC)OOC(C)(CC)OO1 KVWLLOIEGKLBPA-UHFFFAOYSA-N 0.000 description 1
- ZPQAKYPOZRXKFA-UHFFFAOYSA-N 6-Undecanone Chemical compound CCCCCC(=O)CCCCC ZPQAKYPOZRXKFA-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 238000000333 X-ray scattering Methods 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000013480 data collection Methods 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 238000001941 electron spectroscopy Methods 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000002356 laser light scattering Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
- 239000012803 melt mixture Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 239000012934 organic peroxide initiator Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 150000002976 peresters Chemical class 0.000 description 1
- 125000002081 peroxide group Chemical group 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000013074 reference sample Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000001370 static light scattering Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000003797 telogen phase Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
- 238000000196 viscometry Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2015/038626 WO2017003463A1 (en) | 2015-06-30 | 2015-06-30 | Ethylene-based polymer compositions for improved extrusion coatings |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2959186T3 true ES2959186T3 (es) | 2024-02-21 |
Family
ID=53762316
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES15744758T Active ES2959186T3 (es) | 2015-06-30 | 2015-06-30 | Composiciones poliméricas basadas en etileno para recubrimientos por extrusión mejorados |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US10457799B2 (enExample) |
| EP (1) | EP3317348B1 (enExample) |
| JP (1) | JP7385345B2 (enExample) |
| KR (1) | KR102397059B1 (enExample) |
| CN (2) | CN117659536A (enExample) |
| BR (1) | BR112017028455B1 (enExample) |
| ES (1) | ES2959186T3 (enExample) |
| WO (1) | WO2017003463A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112017028455B1 (pt) * | 2015-06-30 | 2022-08-09 | Dow Global Technologies Llc | Mistura de composições de polímero à base de etileno para revestimentos e artigo |
| BR102016002791B1 (pt) * | 2016-02-10 | 2020-12-08 | Fundação Universidade Federal De São Carlos | equipamento para detecção óptica de espalhamento de luz laser em baixo ângulo (lalls) in-line, uso do mesmo e método para o monitoramento morfológico em tempo real de sistemas polifásicos |
| CN110582400A (zh) * | 2017-05-15 | 2019-12-17 | 斯道拉恩索公司 | 挤出涂覆基于纤维的基材的改进的方法 |
| US11546647B2 (en) | 2019-06-07 | 2023-01-03 | Roku, Inc. | Content-modification system with probability-based selection feature |
| KR102616697B1 (ko) | 2019-10-11 | 2023-12-21 | 주식회사 엘지화학 | 폴리에틸렌 및 이의 제조방법 |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1983000490A1 (en) | 1981-07-28 | 1983-02-17 | Eastman Kodak Co | Two-component polyethylene extrusion coating blends |
| JP2874821B2 (ja) * | 1993-05-07 | 1999-03-24 | 昭和電工株式会社 | ポリエチレン組成物 |
| IL115911A0 (en) | 1994-11-14 | 1996-01-31 | Dow Chemical Co | Extrusion compositions having high drawdown and substantially reduced neck-in |
| FI111166B (fi) | 1997-01-10 | 2003-06-13 | Borealis Polymers Oy | Ekstruusiopäällystysrakenne |
| GB9911934D0 (en) | 1999-05-21 | 1999-07-21 | Borealis As | Polymer |
| AU2001256204A1 (en) | 2000-03-16 | 2001-09-24 | Basell Polyolefine Gmbh | Method for the production of polyethylene |
| PL360880A1 (en) | 2000-08-15 | 2004-09-20 | Akzo Nobel N.V. | Use of trioxepans in the process to make high-solid acrylic, styrenic, and ldpe-type resins |
| GB0319467D0 (en) | 2003-08-19 | 2003-09-17 | Bp Chem Int Ltd | Polymer blends |
| US7776987B2 (en) | 2003-09-05 | 2010-08-17 | Dow Global Technologies, Inc. | Resin compositions for extrusion coating |
| EP1555292B1 (en) * | 2004-01-13 | 2015-12-23 | Borealis Technology Oy | Extrusion coating polyethylene |
| DE602005001055T2 (de) | 2005-10-18 | 2007-12-27 | Borealis Technology Oy | Polyethylenmischungskomponente und diese enthaltende Mischungen |
| US8247065B2 (en) | 2006-05-31 | 2012-08-21 | Exxonmobil Chemical Patents Inc. | Linear polymers, polymer blends, and articles made therefrom |
| EP1878764B2 (en) | 2006-07-14 | 2015-04-22 | Borealis Technology Oy | High density polyethylene |
| EP2123707B1 (en) | 2008-05-19 | 2010-10-06 | Borealis Technology OY | Extrusion coating polyethylene composition |
| US9150681B2 (en) | 2010-10-29 | 2015-10-06 | Dow Global Technologies Llc | Ethylene-based polymers and processes for the same |
| JP2012255138A (ja) * | 2011-05-16 | 2012-12-27 | Asahi Kasei Chemicals Corp | 表面保護フィルム用ポリエチレン樹脂組成物 |
| JP5862055B2 (ja) | 2011-05-31 | 2016-02-16 | 大日本印刷株式会社 | ポリオレフィン樹脂フィルム |
| ES2742509T3 (es) | 2011-11-23 | 2020-02-14 | Dow Global Technologies Llc | Polímeros a base de etileno de baja densidad con distribuciones amplias de pesos moleculares y contenido de extraíbles bajo |
| IN2014CN03760A (enExample) | 2011-11-23 | 2015-09-04 | Dow Global Technologies Llc | |
| BR112014030072B1 (pt) | 2012-05-31 | 2021-08-31 | Borealis Ag | Polietileno de baixa densidade, composição que compreende o polietileno de baixa densidade, processo para a produção do polietileno de baixa densidade, método para um processo de revestimento por extrusão, artigo, uso de um polietileno de baixa densidade e uso de uma composição |
| EA026740B1 (ru) | 2012-05-31 | 2017-05-31 | Бореалис Аг | Полиэтилен для экструзионного покрытия, способ его получения и применение |
| US9394389B2 (en) * | 2012-11-20 | 2016-07-19 | Dow Global Technologies Llc | Low density ethylene-based polymers with high melt strength |
| KR102171521B1 (ko) | 2013-05-22 | 2020-10-30 | 다우 글로벌 테크놀로지스 엘엘씨 | 개선된 용융 강도, 출력 및 기계적 특성을 갖는 저밀도 에틸렌계 조성물 |
| KR20200120756A (ko) | 2013-05-22 | 2020-10-21 | 다우 글로벌 테크놀로지스 엘엘씨 | 고용융 강도를 갖는 저밀도 에틸렌-기반 폴리머를 함유하는 조성물 및 이로부터 형성된 필름 |
| ES2637970T3 (es) | 2013-05-22 | 2017-10-18 | Dow Global Technologies Llc | Composiciones poliméricas basadas en etileno de baja densidad con alta resistencia en estado fundido y control de densidad medio-alto |
| KR102240585B1 (ko) | 2013-12-19 | 2021-04-16 | 다우 글로벌 테크놀로지스 엘엘씨 | 추출성 및 용융 탄성의 개선된 균형을 갖는 관상 저밀도 에틸렌 기반 폴리머 |
| CA2837591A1 (en) * | 2013-12-19 | 2015-06-19 | Nova Chemicals Corporation | Polyethylene composition for extrusion coating |
| BR112017028455B1 (pt) * | 2015-06-30 | 2022-08-09 | Dow Global Technologies Llc | Mistura de composições de polímero à base de etileno para revestimentos e artigo |
-
2015
- 2015-06-30 BR BR112017028455-3A patent/BR112017028455B1/pt active IP Right Grant
- 2015-06-30 WO PCT/US2015/038626 patent/WO2017003463A1/en not_active Ceased
- 2015-06-30 ES ES15744758T patent/ES2959186T3/es active Active
- 2015-06-30 JP JP2017566828A patent/JP7385345B2/ja active Active
- 2015-06-30 EP EP15744758.2A patent/EP3317348B1/en active Active
- 2015-06-30 CN CN202311425907.8A patent/CN117659536A/zh active Pending
- 2015-06-30 US US15/574,261 patent/US10457799B2/en active Active
- 2015-06-30 KR KR1020187002648A patent/KR102397059B1/ko active Active
- 2015-06-30 CN CN201580082310.5A patent/CN107922681A/zh active Pending
-
2019
- 2019-09-17 US US16/573,250 patent/US20200032039A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP3317348A1 (en) | 2018-05-09 |
| WO2017003463A1 (en) | 2017-01-05 |
| JP2018521175A (ja) | 2018-08-02 |
| BR112017028455A2 (pt) | 2018-08-28 |
| KR102397059B1 (ko) | 2022-05-12 |
| BR112017028455B1 (pt) | 2022-08-09 |
| EP3317348B1 (en) | 2023-08-30 |
| CN117659536A (zh) | 2024-03-08 |
| US20200032039A1 (en) | 2020-01-30 |
| JP7385345B2 (ja) | 2023-11-22 |
| KR20180022892A (ko) | 2018-03-06 |
| US20180134881A1 (en) | 2018-05-17 |
| US10457799B2 (en) | 2019-10-29 |
| CN107922681A (zh) | 2018-04-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US10611867B2 (en) | Broad orthogonal distribution metallocene polyethylenes for films | |
| KR101737140B1 (ko) | 다른 중합체와 블렌딩될 때 높은 생산량 및 양호한 광학성을 가능하게 하는 신규한 ｌｄｐｅ | |
| ES2582327T3 (es) | Una composición de mezcla de polietileno adecuada para películas sopladas, y las películas hechas a partir de la misma | |
| ES2661993T3 (es) | Una composición de polietileno de baja densidad lineal adecuada para una película moldeada por colada | |
| EP2798003B1 (en) | Improved resin compositions for extrusion coating | |
| ES2959186T3 (es) | Composiciones poliméricas basadas en etileno para recubrimientos por extrusión mejorados | |
| ES3004008T3 (en) | Ethylene-based polymers and processes to make the same | |
| CA2767071A1 (en) | Ethylene-based polymer compositions | |
| KR20120123310A (ko) | 필름용 고 용융 강도 폴리에틸렌 | |
| ES2572557T3 (es) | Una composición-mezcla de polietileno adecuada para películas sopladas, y películas preparadas a partir de las mismas | |
| ES2929929T3 (es) | Polímeros en base de etileno con óptica mejorada | |
| JP2022001643A (ja) | 幅広い直交分布のフィルム用メタロセンポリエチレン | |
| CA2955941A1 (en) | A polyethylene blend composition and film made therefrom | |
| CN110023353B (zh) | 乙烯/α-烯烃互聚物组合物 | |
| US20150175827A1 (en) | Polyethylene composition for extrusion coating | |
| ES2893526T3 (es) | Polímeros basados en etileno con buena aptitud de procesado para uso en películas multicapa | |
| ES2926229T3 (es) | Composiciones que comprenden copolímeros de etileno-monóxido de carbono | |
| ES2864959T3 (es) | Composiciones de resina para revestimientos por extrusión | |
| CA3031848C (en) | Compositions suitable for manufacturing polyethylene foam, and articles thereof | |
| BR112021010187B1 (pt) | Composição de polímero à base de etileno, artigo, e, processo | |
| BR112020026221A2 (pt) | Polímero à base de etileno, e, processo | |
| BR112020026221B1 (pt) | Polímero à base de etileno, e, processo |