ES2818913T3 - Polímeros a base de etileno y procesos para prepararlos - Google Patents
Polímeros a base de etileno y procesos para prepararlos Download PDFInfo
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- ES2818913T3 ES2818913T3 ES13716496T ES13716496T ES2818913T3 ES 2818913 T3 ES2818913 T3 ES 2818913T3 ES 13716496 T ES13716496 T ES 13716496T ES 13716496 T ES13716496 T ES 13716496T ES 2818913 T3 ES2818913 T3 ES 2818913T3
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- polymer
- ethylene
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- film
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- 229920000642 polymer Polymers 0.000 title claims abstract description 150
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- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
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- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (2)
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| US201261707342P | 2012-09-28 | 2012-09-28 | |
| PCT/US2013/030787 WO2014051682A1 (en) | 2012-09-28 | 2013-03-13 | Ethylene-based polymers and processes to make the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2818913T3 true ES2818913T3 (es) | 2021-04-14 |
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| ES13716496T Active ES2818913T3 (es) | 2012-09-28 | 2013-03-13 | Polímeros a base de etileno y procesos para prepararlos |
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|---|---|
| US (2) | US8916667B2 (en:Method) |
| EP (1) | EP2900704B1 (en:Method) |
| JP (1) | JP6279584B2 (en:Method) |
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| CN (1) | CN104822713B (en:Method) |
| AR (1) | AR092728A1 (en:Method) |
| BR (1) | BR112015006812B1 (en:Method) |
| ES (1) | ES2818913T3 (en:Method) |
| IN (1) | IN2015DN02921A (en:Method) |
| WO (1) | WO2014051682A1 (en:Method) |
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| JP6279584B2 (ja) * | 2012-09-28 | 2018-02-14 | ダウ グローバル テクノロジーズ エルエルシー | エチレン系ポリマーおよびその製造方法 |
| ES2838748T3 (es) | 2013-05-22 | 2021-07-02 | Dow Global Technologies Llc | Composiciones a base de etileno de baja densidad con resistencia de masa fundida, producción, y propiedades mecánicas mejoradas |
| ES2975010T3 (es) | 2013-05-22 | 2024-07-02 | Dow Global Technologies Llc | Composiciones que contienen polímeros a base de etileno de baja densidad con alta resistencia en estado fundido y películas formadas a partir de las mismas |
| CN105440465B (zh) * | 2014-09-29 | 2017-11-24 | 中国石油化工股份有限公司 | 一种橡塑组合物及其制备方法和薄膜 |
| BR112017011665A2 (pt) | 2014-12-01 | 2018-01-16 | Dow Global Technologies Llc | composições de polímero, filmes retráteis e métodos de preparar os mesmos |
| WO2016089494A1 (en) | 2014-12-01 | 2016-06-09 | Dow Global Technologies Llc | Shrink films, and methods for making thereof |
| JP6536280B2 (ja) * | 2015-08-18 | 2019-07-03 | キョーラク株式会社 | 発泡成形用樹脂、発泡成形体の製造方法 |
| CN108391426B (zh) * | 2015-08-31 | 2020-11-06 | 陶氏环球技术有限责任公司 | 多层膜和其方法 |
| BR112018003282B1 (pt) * | 2015-09-02 | 2022-07-12 | Dow Global Technologies Llc | Composição polimérica reticulável, composição polimérica reticulada e condutor revestido |
| WO2017058493A1 (en) | 2015-09-29 | 2017-04-06 | Dow Global Technologies Llc | Shrink films, and methods of making thereof |
| KR101924198B1 (ko) | 2015-12-23 | 2018-11-30 | 주식회사 엘지화학 | 필름 가공성 및 투명도가 우수한 저밀도 폴리에틸렌 공중합체 |
| EP3420026B1 (en) * | 2016-02-23 | 2024-11-27 | Dow Global Technologies LLC | Ethylene-based polymers and processes to make the same |
| MX2018011809A (es) | 2016-03-31 | 2019-01-24 | Dow Global Technologies Llc | Resinas de polietileno modificadas y metodo para fabricarlas. |
| EP3238938A1 (en) | 2016-04-29 | 2017-11-01 | Borealis AG | Machine direction oriented films comprising multimodal copolymer of ethylene and at least two alpha-olefin comonomers |
| US10759928B2 (en) | 2016-05-18 | 2020-09-01 | Dow Global Technologies Llc | Ethylene-based polymers and processes to make the same |
| CN110300661B (zh) | 2017-02-28 | 2022-04-05 | 陶氏环球技术有限责任公司 | 用于多层膜中的具有良好可加工性的基于乙烯的聚合物 |
| ES2783948T3 (es) | 2017-03-10 | 2020-09-21 | Dow Global Technologies Llc | Películas multicapa y métodos de las mismas |
| MX2019010775A (es) * | 2017-03-21 | 2019-12-16 | Dow Global Technologies Llc | Polimeros a base de etileno con optica mejorada. |
| US11312120B2 (en) | 2017-07-06 | 2022-04-26 | Dow Global Technologies Llc | Low temperature multilayer shrink films, and methods of making thereof |
| US11193009B2 (en) | 2017-09-27 | 2021-12-07 | Dow Global Technologies Llc | Modified polyethylene compositions and method for making the same |
| CN111406075B (zh) * | 2017-11-28 | 2024-01-19 | 诺力昂化学品国际有限公司 | 改性ldpe的方法 |
| CN109323897A (zh) * | 2018-09-27 | 2019-02-12 | 安徽滁州德威新材料有限公司 | 一种电缆料用抗氧剂1024试片及其评估实验方法 |
| WO2020243426A1 (en) | 2019-05-31 | 2020-12-03 | Dow Global Technologies Llc | Low density polyethylene with improved processability |
| KR20220016483A (ko) | 2019-05-31 | 2022-02-09 | 다우 글로벌 테크놀로지스 엘엘씨 | 지글러-나타 촉매화된 폴리에틸렌 수지 및 이를 포함하는 필름 |
| AR119085A1 (es) | 2019-06-06 | 2021-11-24 | Dow Global Technologies Llc | Película soplada multicapa |
| MX2020008168A (es) | 2019-08-06 | 2021-02-08 | Dow Global Technologies Llc | Composiciones de polietileno. |
| JP7653410B2 (ja) | 2019-08-06 | 2025-03-28 | ダウ グローバル テクノロジーズ エルエルシー | 少なくとも５つの層を含む多層フィルムおよびその生成方法 |
| EP3772415B1 (en) | 2019-08-06 | 2022-12-14 | Dow Global Technologies Llc | Multilayer films comprising polyethylene and barrier layers and methods of producing the same |
| EP4010191B1 (en) | 2019-08-06 | 2023-07-26 | Dow Global Technologies LLC | Multilayer films having at least three layers and methods of producing the same |
| CN114555364A (zh) | 2019-10-17 | 2022-05-27 | 陶氏环球技术有限责任公司 | 多层膜和包含多层膜的制品 |
| EP4132982A1 (en) * | 2020-04-06 | 2023-02-15 | Dow Global Technologies LLC | Enhanced melt strength low-density polyethylene for use in films or blends |
| JP7516228B2 (ja) * | 2020-11-30 | 2024-07-16 | 住友化学株式会社 | 高圧法低密度ポリエチレン製造装置及び製造方法 |
| EP4259701A1 (en) | 2020-12-08 | 2023-10-18 | Dow Global Technologies LLC | Coated article |
| MX2023006339A (es) | 2020-12-08 | 2023-06-12 | Dow Global Technologies Llc | Articulo. |
| WO2022125247A1 (en) | 2020-12-08 | 2022-06-16 | Dow Global Technologies Llc | Article |
| KR102308311B1 (ko) * | 2020-12-30 | 2021-10-06 | 대진첨단소재 주식회사 | 인공지능을 이용하여 물성을 예측하기 위한 시스템 및 시스템의 동작 방법 |
| KR102308309B1 (ko) * | 2020-12-30 | 2021-10-06 | 대진첨단소재 주식회사 | 재생 abs의 물성을 예측하기 위한 시스템 및 시스템의 동작 방법 |
| US20240059876A1 (en) | 2021-02-19 | 2024-02-22 | Dow Global Technologies Llc | Modified low density polyethylene resins and method for making the same |
| WO2024163046A1 (en) | 2023-01-30 | 2024-08-08 | Dow Global Technologies Llc | Article made from recycled material containing solvent-based adhesive and process |
| TW202523766A (zh) | 2023-11-30 | 2025-06-16 | 美商陶氏全球科技有限責任公司 | 再循環聚烯烴膜與層壓體 |
| TW202523491A (zh) | 2023-11-30 | 2025-06-16 | 美商陶氏全球科技有限責任公司 | 可回收聚合物層壓體 |
| WO2025117421A1 (en) | 2023-11-30 | 2025-06-05 | Dow Global Technologies Llc | Recyclable polyolefin films and laminates |
| WO2025181065A1 (en) * | 2024-02-29 | 2025-09-04 | Basell Polyolefine Gmbh | Film with high weathering resistance |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| WO1993013143A1 (en) | 1991-12-30 | 1993-07-08 | The Dow Chemical Company | Ethylene interpolymer polymerizations |
| US6448341B1 (en) | 1993-01-29 | 2002-09-10 | The Dow Chemical Company | Ethylene interpolymer blend compositions |
| KR100301978B1 (ko) | 1993-01-29 | 2001-11-14 | 리챠드 지. 워터맨 | 에틸렌공중합법 |
| US5869575A (en) | 1995-08-02 | 1999-02-09 | The Dow Chemical Company | Ethylene interpolymerizations |
| MX2007005190A (es) | 2004-11-02 | 2007-11-08 | Dow Global Technologies Inc | Proceso para la produccion de composiciones de polietileno de baja densidad y polimeros producidos a partir de las mismas. |
| CN101970514B (zh) | 2008-03-13 | 2013-11-20 | 陶氏环球技术有限责任公司 | 乙烯与另一聚合物组合的长链支化(lcb)、嵌段或互联共聚物 |
| CA2738475A1 (en) | 2008-10-07 | 2010-04-15 | Dow Global Technologies Llc | High pressure low density polyethylene resins with improved optical properties produced through use of highly active chain transfer agents |
| US9243087B2 (en) * | 2009-06-11 | 2016-01-26 | Dow Global Technologies Llc | LDPE enabling high output and good optics when blended with other polymers |
| US20110003940A1 (en) | 2009-07-01 | 2011-01-06 | Dow Global Technologies Inc. | Ethylene-based polymer compositions for use as a blend component in shrinkage film applications |
| US9068032B2 (en) | 2009-08-10 | 2015-06-30 | Dow Global Technologies Llc | LDPE for use as a blend component in shrinkage film applications |
| EP2239283B1 (en) | 2009-11-10 | 2012-01-25 | Basell Polyolefine GmbH | High pressure LDPE for medical applications |
| US8653196B2 (en) * | 2010-01-11 | 2014-02-18 | Dow Global Technologies, Llc | Method for preparing polyethylene with high melt strength |
| AR083077A1 (es) * | 2010-09-30 | 2013-01-30 | Dow Global Technologies Llc | Proceso de polimerizacion para elaborar polietileno de baja densidad |
| KR101845119B1 (ko) * | 2010-12-17 | 2018-04-03 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌-기재 중합체 및 이의 제조 방법 |
| JP6279584B2 (ja) * | 2012-09-28 | 2018-02-14 | ダウ グローバル テクノロジーズ エルエルシー | エチレン系ポリマーおよびその製造方法 |
| EP2900703B1 (en) * | 2012-09-28 | 2018-10-17 | Dow Global Technologies LLC | Ethylene-based polymers and processes to make the same |
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Also Published As
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| CN104822713A (zh) | 2015-08-05 |
| KR20150063094A (ko) | 2015-06-08 |
| IN2015DN02921A (en:Method) | 2015-09-18 |
| US9303107B2 (en) | 2016-04-05 |
| AR092728A1 (es) | 2015-04-29 |
| CN104822713B (zh) | 2018-05-18 |
| EP2900704A1 (en) | 2015-08-05 |
| EP2900704B1 (en) | 2020-07-29 |
| JP2015530459A (ja) | 2015-10-15 |
| KR102037561B1 (ko) | 2019-10-28 |
| US8916667B2 (en) | 2014-12-23 |
| US20150112039A1 (en) | 2015-04-23 |
| WO2014051682A1 (en) | 2014-04-03 |
| BR112015006812A2 (pt) | 2017-07-04 |
| BR112015006812B1 (pt) | 2021-03-23 |
| JP6279584B2 (ja) | 2018-02-14 |
| US20140094583A1 (en) | 2014-04-03 |
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