ES2707301T3 - Sistema de polimerización para la copolimerización de CO2 y epóxidos y método relacionado - Google Patents

Sistema de polimerización para la copolimerización de CO2 y epóxidos y método relacionado Download PDF

Info

Publication number
ES2707301T3
ES2707301T3 ES13793633T ES13793633T ES2707301T3 ES 2707301 T3 ES2707301 T3 ES 2707301T3 ES 13793633 T ES13793633 T ES 13793633T ES 13793633 T ES13793633 T ES 13793633T ES 2707301 T3 ES2707301 T3 ES 2707301T3
Authority
ES
Spain
Prior art keywords
optionally substituted
group
groups
aliphatic
certain embodiments
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES13793633T
Other languages
English (en)
Spanish (es)
Inventor
Jay Farmer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saudi Aramco Technologies Co
Original Assignee
Saudi Aramco Technologies Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Aramco Technologies Co filed Critical Saudi Aramco Technologies Co
Application granted granted Critical
Publication of ES2707301T3 publication Critical patent/ES2707301T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/32—General preparatory processes using carbon dioxide
    • C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2217—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44—Polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/02—Aliphatic polycarbonates
    • C08G64/0208—Aliphatic polycarbonates saturated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/02—Aliphatic polycarbonates
    • C08G64/0208—Aliphatic polycarbonates saturated
    • C08G64/0216—Aliphatic polycarbonates saturated containing a chain-terminating or -crosslinking agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/266—Metallic elements not covered by group C08G65/2648 - C08G65/2645, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/025—Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/184—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine mixed aromatic/aliphatic ring systems, e.g. indoline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
ES13793633T 2012-05-24 2013-05-24 Sistema de polimerización para la copolimerización de CO2 y epóxidos y método relacionado Active ES2707301T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261651254P 2012-05-24 2012-05-24
PCT/US2013/042712 WO2013177546A2 (en) 2012-05-24 2013-05-24 Polycarbonate polyol compositions and methods

Publications (1)

Publication Number Publication Date
ES2707301T3 true ES2707301T3 (es) 2019-04-03

Family

ID=49624541

Family Applications (2)

Application Number Title Priority Date Filing Date
ES13793633T Active ES2707301T3 (es) 2012-05-24 2013-05-24 Sistema de polimerización para la copolimerización de CO2 y epóxidos y método relacionado
ES18214217T Active ES2974014T3 (es) 2012-05-24 2013-05-24 Sistema de polimerización para la copolimerización de CO2 y epóxidos y método relacionado

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES18214217T Active ES2974014T3 (es) 2012-05-24 2013-05-24 Sistema de polimerización para la copolimerización de CO2 y epóxidos y método relacionado

Country Status (7)

Country Link
US (2) US9388277B2 (enExample)
EP (2) EP3486269B1 (enExample)
JP (2) JP6527080B2 (enExample)
KR (1) KR102159100B1 (enExample)
CN (1) CN104487485B (enExample)
ES (2) ES2707301T3 (enExample)
WO (1) WO2013177546A2 (enExample)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103333330A (zh) 2008-09-08 2013-10-02 诺沃梅尔公司 聚碳酸酯多元醇组合物和方法
US9388277B2 (en) 2012-05-24 2016-07-12 Novomer, Inc. Polycarbonate polyol compositions and methods
ES2761880T3 (es) 2012-08-24 2020-05-21 Saudi Aramco Tech Co Complejos metálicos
EP2940056B1 (en) * 2012-12-26 2024-04-24 Mitsubishi Chemical Corporation Polycarbonate diol and polyurethane using same
CN105518053B (zh) 2013-05-01 2017-07-21 诺沃梅尔公司 脂族聚碳酸酯组合物和方法
WO2016203408A1 (en) * 2015-06-15 2016-12-22 King Abdullah University Of Science And Technology Use of additives to fine-tune the composition of carbonate units in the polymer formed by copolymerization of co2 with epoxide: application to the synthesis of polycarbonate-based block copolymers and of telechelics
CN106957415B (zh) * 2015-09-16 2019-07-12 武汉理工大学 一种用于二氧化碳、环氧丙烷和丙交酯三元共聚的复合催化剂及其制备方法
MX2019014529A (es) * 2017-06-13 2020-08-31 Elementis Specialties Inc Sistema de revestimiento.
WO2019126221A1 (en) 2017-12-22 2019-06-27 Saudi Aramco Technologies Company Catalysts for polycarbonate production
CN109988296B (zh) 2018-01-02 2021-09-10 财团法人工业技术研究院 聚碳酸酯多元醇的制法及聚碳酸酯多元醇组合物
JP7114939B2 (ja) * 2018-03-02 2022-08-09 三菱ケミカル株式会社 触媒組成物、ポリアルキレンカーボネートの製造方法
JP7114938B2 (ja) * 2018-03-02 2022-08-09 三菱ケミカル株式会社 触媒組成物、ポリアルキレンカーボネートの製造方法
WO2019204553A1 (en) 2018-04-18 2019-10-24 Saudi Aramco Technologies Company End-group isomerization of poly(alkylene carbonate) polymers
US11180609B2 (en) 2018-08-02 2021-11-23 Saudi Aramco Technologies Company Sustainable polymer compositions and methods
GB201814526D0 (en) * 2018-09-06 2018-10-24 Econic Tech Ltd Methods for forming polycarbonate ether polyols and high molecular weight polyether carbonates
MA53727A (fr) 2018-09-24 2021-12-29 Saudi Aramco Tech Co Copolymères séquencés de polycarbonate et procédés associés
EP3656797A1 (de) * 2018-11-22 2020-05-27 Covestro Deutschland AG Verfahren zur herstellung von polyoxymethylen-polyalkylenoxid-blockcopolymeren
CN111378106B (zh) * 2020-03-30 2021-06-01 杭州普力材料科技有限公司 一种预加热液相法管道化连续化生产聚碳酸酯-聚醚多元醇的方法
CN113234216A (zh) * 2021-06-02 2021-08-10 冯明文 一种基于ppc的改善降解塑料及其生产工艺
JP2024525422A (ja) 2021-06-23 2024-07-12 サウジ アラムコ テクノロジーズ カンパニー ポリオール組成物及び方法
CN113444222A (zh) * 2021-07-21 2021-09-28 中国科学院长春应用化学研究所 一种抗菌聚氨酯、其制备方法及应用
CN115028845B (zh) * 2022-05-11 2023-05-12 烟台大学 一种锌配位聚合物催化剂及其制备方法和应用

Family Cites Families (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4581470A (en) * 1983-09-27 1986-04-08 Union Carbide Corporation Novel polyols and uses thereof
GB8529890D0 (en) 1985-12-04 1986-01-15 Watson P Garbage collection in computer system
US5637739A (en) 1990-03-21 1997-06-10 Research Corporation Technologies, Inc. Chiral catalysts and catalytic epoxidation catalyzed thereby
IL110787A0 (en) * 1993-08-27 1994-11-11 Sandoz Ag Biodegradable polymer, its preparation and pharmaceutical composition containing it
US5665890A (en) 1995-03-14 1997-09-09 President And Fellows Of Harvard College Stereoselective ring opening reactions
AU3813997A (en) 1996-07-26 1998-02-20 Princeton University Catalytic oxygenation of hydrocarbons by metalloporphyrin and metallosalen complexes
TW420693B (en) 1997-04-25 2001-02-01 Mitsui Chemicals Inc Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers
US6130340A (en) 1998-01-13 2000-10-10 President And Fellows Of Harvard College Asymmetric cycloaddition reactions
US6521561B1 (en) 1998-05-01 2003-02-18 President And Fellows Of Harvard College Main-group metal based asymmetric catalysts and applications thereof
KR100342659B1 (en) 2000-12-15 2002-07-04 Rstech Co Ltd Chiral polymer salene catalyst and process for preparing chiral compounds from racemic epoxide using the same
DE60200346T2 (de) 2001-06-27 2005-03-24 Rs Tech Corp. Neuer chiraler salen-katalysator und verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung des neuen katalysators
US6639087B2 (en) 2001-08-22 2003-10-28 Rhodia Pharma Solutions Inc. Kinetic resolution method
US6870004B1 (en) 2001-08-24 2005-03-22 Northwestern University Metal-ligand complexes and related methods of chemical CO2 fixation
DE10235316A1 (de) 2002-08-01 2004-02-12 Basf Ag Katalysator und Verfahren zur Carbonylierung von Oxiranen
US7304172B2 (en) 2004-10-08 2007-12-04 Cornell Research Foundation, Inc. Polycarbonates made using highly selective catalysts
ATE435882T1 (de) * 2004-12-10 2009-07-15 Basf Se Herstellung und verwendung von ultrahochmolekularen polycarbonaten
KR100724550B1 (ko) 2004-12-16 2007-06-04 주식회사 엘지화학 이중 금속 아연 착화합물과 이를 촉매로 사용한폴리카보네이트의 제조 방법
WO2006099162A2 (en) 2005-03-14 2006-09-21 Georgia Tech Research Corporation Polymeric salen compounds and methods thereof
JP2008081518A (ja) * 2006-09-25 2008-04-10 Tokyo Univ Of Science アルキレンオキシドと二酸化炭素の共重合体の製造方法、及び共重合体
WO2008094222A2 (en) 2006-10-06 2008-08-07 Trustees Of Princeton Porphyrin catalysts and methods of use thereof
CN100494248C (zh) 2007-03-21 2009-06-03 大连理工大学 用于合成聚碳酸酯的双功能催化剂
GB0708016D0 (en) 2007-04-25 2007-06-06 Univ Newcastle Synthesis of cyclic carbonates
EP2147037B1 (en) 2007-05-04 2014-08-20 SK Innovation Co. Ltd. A process for producing polycarbonates and a coordination complex used therefor
EP2157116A4 (en) 2007-06-08 2010-11-03 Univ Tokyo STEREOSELECTIVE ALTERNATIVE EPOXY-CARBON DIOXIDE COPOLYMER
EP2096132A1 (en) 2008-02-26 2009-09-02 Total Petrochemicals Research Feluy Monomers issued from renewable resources and process for polymerising them
EP2258745B1 (en) * 2008-03-25 2014-07-16 Asahi Glass Company, Limited Hydroxy compound, process for production thereof, and prepolymer and polyurethane each comprising the hydroxy compound
US20110087001A1 (en) 2008-05-09 2011-04-14 Cornell University Polymers of ethylene oxide and carbon dioxide
US7858729B2 (en) 2008-05-29 2010-12-28 Novomer, Inc. Methods of controlling molecular weight distribution of polymers and compositions thereof
EP2307477A4 (en) 2008-07-30 2014-12-10 Sk Innovation Co Ltd NOVEL COORDINATION COMPLEXES AND METHOD FOR THE PRODUCTION OF POLYCARBONATES BY COPOLYMERIZATION OF CARBON DIOXIDE AND EPOXYDIDE THEREOF AS A CATALYST
KR102128706B1 (ko) 2008-08-22 2020-07-02 사우디 아람코 테크놀로지스 컴퍼니 촉매 및 중합체 합성방법
CN103333330A (zh) 2008-09-08 2013-10-02 诺沃梅尔公司 聚碳酸酯多元醇组合物和方法
BRPI0919237B1 (pt) 2008-09-17 2019-08-13 Novomer Inc método de remoção de um catalisador de um produto de uma reação de polimerização de policarbonato alifático e método de purificação de um produto de reação de polimerização de policarbonato alifático
CA2639870A1 (en) 2008-09-29 2010-03-29 Nova Chemicals Corporation Trimerization
WO2010062703A1 (en) 2008-11-01 2010-06-03 Novomer, Inc. Polycarbonate block copolymers
CN101412809B (zh) 2008-11-28 2011-04-27 大连理工大学 用于合成聚碳酸酯的单活性点催化剂
US8575245B2 (en) 2008-12-23 2013-11-05 Novomer, Inc. Tunable polymer compositions
JP5782027B2 (ja) 2009-07-05 2015-09-24 ノボマー， インコーポレイテッド 構造的に精密なポリ（プロピレンカーボネート）組成物
EP2289971A1 (en) * 2009-08-27 2011-03-02 Total Petrochemicals Research Feluy Ring opening polymerisation of cyclic carbonates with organic catalyst systems
KR101503745B1 (ko) 2010-02-25 2015-03-19 에스케이이노베이션 주식회사 나이트레이트 음이온의 이산화탄소/에폭사이드 공중합 촉매 시스템
KR101715657B1 (ko) * 2010-04-06 2017-03-14 에스케이이노베이션 주식회사 이산화탄소／에폭사이드 공중합의 분자량 및 사슬 모양 정밀 제어 및 이를 통한 저분자량의 폴리(알킬렌 카보네이트)의 제조
WO2011163133A1 (en) 2010-06-20 2011-12-29 Novomer, Inc. Aliphatic polycarbonates
WO2011163250A1 (en) 2010-06-21 2011-12-29 Ndsu Research Foundation Aqueous polyurethane dispersions
CN103153278B (zh) 2010-08-27 2016-01-20 诺沃梅尔公司 聚合物组合物和方法
EP2616513B1 (en) 2010-09-14 2019-11-06 Saudi Aramco Technologies Company Catalysts and methods for polymer synthesis
EP2643374B1 (en) 2010-11-23 2019-09-18 Saudi Aramco Technologies Company Polycarbonate polyol compositions
KR101942034B1 (ko) 2011-01-06 2019-01-25 사우디 아람코 테크놀로지스 컴퍼니 고분자 조성물 및 방법
KR102055540B1 (ko) 2011-05-09 2019-12-13 사우디 아람코 테크놀로지스 컴퍼니 고분자 조성물 및 방법
JP2014524965A (ja) 2011-07-25 2014-09-25 ノボマー， インコーポレイテッド ポリウレタンに使用するための脂肪族ポリカーボネート
GB201115565D0 (en) 2011-09-08 2011-10-26 Imp Innovations Ltd Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent
ES2963032T3 (es) 2011-12-20 2024-03-25 Saudi Aramco Tech Co Métodos para la síntesis de polímeros
US9388277B2 (en) * 2012-05-24 2016-07-12 Novomer, Inc. Polycarbonate polyol compositions and methods

Also Published As

Publication number Publication date
US9388277B2 (en) 2016-07-12
CN104487485B (zh) 2018-04-20
ES2974014T3 (es) 2024-06-25
US20150152221A1 (en) 2015-06-04
KR20150003414A (ko) 2015-01-08
WO2013177546A3 (en) 2014-04-17
US9850345B2 (en) 2017-12-26
EP3486269A1 (en) 2019-05-22
EP2855558A4 (en) 2015-12-16
EP2855558B1 (en) 2018-12-26
EP3486269B1 (en) 2023-12-20
US20170051106A1 (en) 2017-02-23
JP2019094510A (ja) 2019-06-20
CN104487485A (zh) 2015-04-01
EP2855558A2 (en) 2015-04-08
WO2013177546A2 (en) 2013-11-28
KR102159100B1 (ko) 2020-09-23
JP6527080B2 (ja) 2019-06-05
JP2015517607A (ja) 2015-06-22

Similar Documents

Publication Publication Date Title
ES2707301T3 (es) Sistema de polimerización para la copolimerización de CO2 y epóxidos y método relacionado
ES2645064T5 (es) Composiciones de policarbonato poliol y métodos
JP2012502143A5 (enExample)
HK40039127A (en) Polycarbonate polyol compositions and methods
HK1247224B (en) Polycarbonate polyol compositions and methods
BRPI0919323B1 (pt) Métodos e composições de poliol polocarbonato
HK1158235A (en) Polycarbonate polyol compositions and methods
HK1158235B (en) Polycarbonate polyol compositions and methods