ES2579907R1 - Células solares mesoscópicas sensibilizadas con perovskita de alto rendimiento - Google Patents

Células solares mesoscópicas sensibilizadas con perovskita de alto rendimiento Download PDF

Info

Publication number
ES2579907R1
ES2579907R1 ES201590118A ES201590118A ES2579907R1 ES 2579907 R1 ES2579907 R1 ES 2579907R1 ES 201590118 A ES201590118 A ES 201590118A ES 201590118 A ES201590118 A ES 201590118A ES 2579907 R1 ES2579907 R1 ES 2579907R1
Authority
ES
Spain
Prior art keywords
perovskita
high performance
solar cells
organic
cells sensitized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES201590118A
Other languages
English (en)
Other versions
ES2579907B1 (es
ES2579907A2 (es
Inventor
Julian Alexander BURSCHKA
Mohammad Khaja Nazeeruddin
Michael Graetzel
Shahzada Ahmad
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Abengoa Research SL
Original Assignee
Abengoa Research SL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from EP20130382181 external-priority patent/EP2804232A1/en
Application filed by Abengoa Research SL filed Critical Abengoa Research SL
Publication of ES2579907A2 publication Critical patent/ES2579907A2/es
Publication of ES2579907R1 publication Critical patent/ES2579907R1/es
Application granted granted Critical
Publication of ES2579907B1 publication Critical patent/ES2579907B1/es
Withdrawn - After Issue legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G21/00—Compounds of lead
    • C01G21/16—Halides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2059—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution
    • H01G9/2063—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution comprising a mixture of two or more dyes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/02—Lithium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06—Cobalt compounds
    • C07F15/065—Cobalt compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/24—Lead compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/0029—Processes of manufacture
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/10—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising heterojunctions between organic semiconductors and inorganic semiconductors
    • H10K30/15—Sensitised wide-bandgap semiconductor devices, e.g. dye-sensitised TiO2
    • H10K30/151—Sensitised wide-bandgap semiconductor devices, e.g. dye-sensitised TiO2 the wide bandgap semiconductor comprising titanium oxide, e.g. TiO2
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/50—Organic perovskites; Hybrid organic-inorganic perovskites [HOIP], e.g. CH3NH3PbI3
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2102/00—Constructional details relating to the organic devices covered by this subclass
    • H10K2102/10—Transparent electrodes, e.g. using graphene
    • H10K2102/101—Transparent electrodes, e.g. using graphene comprising transparent conductive oxides [TCO]
    • H10K2102/102—Transparent electrodes, e.g. using graphene comprising transparent conductive oxides [TCO] comprising tin oxides, e.g. fluorine-doped SnO2
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/50—Photovoltaic [PV] devices
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/542—Dye sensitized solar cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Power Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Photovoltaic Devices (AREA)
  • Hybrid Cells (AREA)

Abstract

La presente invención se refiere a un método para producir una célula solar que comprende las etapas de: proporcionar un colector de corriente y una capa nanoporosa; aplicar y/o depositar una película que comprende una o más sales de metal divalente o trivalente sobre dicha capa nanoporosa; exponer y/o poner en contacto la película obtenida en la etapa anterior con una disolución que comprende una o más sales de amonio orgánico en un disolvente, obteniendo de ese modo una capa que comprende una perovskita orgánica-inorgánica; y proporcionar un contraelectrodo. La invención también se refiere a la perovskita orgánica-inorgánica que se obtiene en el método y a la célula solar resultante.
ES201590118A 2013-05-06 2014-05-05 Células solares mesoscópicas sensibilizadas con perovskita de alto rendimiento Withdrawn - After Issue ES2579907B1 (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP13166720 2013-05-06
EP13166720 2013-05-06
EP20130382181 EP2804232A1 (en) 2013-05-16 2013-05-16 High performance perovskite-sensitized mesoscopic solar cells
EP13382181 2013-05-16
PCT/EP2014/059124 WO2014180789A1 (en) 2013-05-06 2014-05-05 High performance perovskite-sensitized mesoscopic solar cells

Publications (3)

Publication Number Publication Date
ES2579907A2 ES2579907A2 (es) 2016-08-17
ES2579907R1 true ES2579907R1 (es) 2017-01-12
ES2579907B1 ES2579907B1 (es) 2017-10-24

Family

ID=50639546

Family Applications (1)

Application Number Title Priority Date Filing Date
ES201590118A Withdrawn - After Issue ES2579907B1 (es) 2013-05-06 2014-05-05 Células solares mesoscópicas sensibilizadas con perovskita de alto rendimiento

Country Status (6)

Country Link
US (1) US20160086739A1 (es)
CN (1) CN105474421A (es)
BR (1) BR112015028097A2 (es)
ES (1) ES2579907B1 (es)
MX (1) MX2015015395A (es)
WO (1) WO2014180789A1 (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3396729B1 (en) 2014-05-28 2019-10-09 Alliance for Sustainable Energy, LLC Methods for producing and using perovskite materials and devices therefrom
US9324562B1 (en) 2014-11-12 2016-04-26 Alliance For Sustainable Energy, Llc Metal halide solid-state surface treatment for nanocrystal materials
EP3248229B1 (en) * 2015-01-21 2021-10-27 Commonwealth Scientific and Industrial Research Organisation Process of forming a photoactive layer of a perovskite photoactive device
JP6745214B2 (ja) * 2015-01-29 2020-08-26 積水化学工業株式会社 太陽電池及び太陽電池の製造方法
US9701696B2 (en) 2015-02-27 2017-07-11 Alliance For Sustainable Energy, Llc Methods for producing single crystal mixed halide perovskites
JP6657572B2 (ja) * 2015-03-06 2020-03-04 株式会社リコー 光電変換素子
JP6486737B2 (ja) * 2015-03-19 2019-03-20 株式会社東芝 光電変換素子
JP6572015B2 (ja) * 2015-06-25 2019-09-04 株式会社日本マイクロニクス 二次電池の製造方法
GB201513366D0 (en) * 2015-07-29 2015-09-09 Univ Ulster Photovoltaic device
EP3157025A1 (en) 2015-10-15 2017-04-19 g2e glass2energy SA Porphyrin-based sensitizer for dye-sensitized solar cell
KR101994429B1 (ko) * 2015-10-27 2019-06-28 주식회사 엘지화학 태양전지의 광흡수체 제조 방법
CN105789398B (zh) * 2016-04-11 2017-07-21 郑州大学 以ZnO纳米墙网络作为电子注入层的钙钛矿LED及制备方法
EP3279960A1 (en) 2016-08-02 2018-02-07 Aalto University Foundation Method for inkjet printing an organic-inorganic perovskite
CN106486602B (zh) * 2016-10-27 2019-01-11 北京科技大学 一种引入廉价添加剂制备高质量钙钛矿薄膜的方法
CN107359252A (zh) * 2017-06-07 2017-11-17 常州市瑞泰物资有限公司 一种晶体均一型钙钛矿薄膜的制备方法
CN109244250B (zh) * 2017-07-11 2023-09-22 松下控股株式会社 太阳能电池模块
CN109904319B (zh) * 2019-01-29 2022-11-18 安徽大学 大尺寸钙钛矿扁平晶体、钙钛矿层制备方法及太阳能电池
JP6675505B2 (ja) * 2019-02-15 2020-04-01 株式会社東芝 光電変換素子の製造方法
WO2020213196A1 (ja) * 2019-04-16 2020-10-22 パナソニックＩｐマネジメント株式会社 太陽電池
CN114072930A (zh) * 2019-08-27 2022-02-18 松下知识产权经营株式会社 太阳能电池
CN112599673B (zh) * 2020-12-14 2024-03-01 苏州科技大学 利用氧化铁薄膜构筑的钙钛矿太阳能电池及其制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH674596A5 (es) 1988-02-12 1990-06-15 Sulzer Ag
FR2694451B1 (fr) 1992-07-29 1994-09-30 Asulab Sa Cellule photovoltaïque.
EP1160888A1 (en) 2000-05-29 2001-12-05 Sony International (Europe) GmbH Hole transporting agents and photoelectric conversion device comprising the same
EP1837929A1 (en) 2006-03-23 2007-09-26 Ecole Polytechnique Fédérale de Lausanne (EPFL) Liquid Charge Transporting Material
KR100839371B1 (ko) * 2006-11-17 2008-06-19 삼성에스디아이 주식회사 염료감응 태양전지
US9595678B2 (en) 2010-07-23 2017-03-14 Basf Se Dye solar cell with improved stability
CN104106118B (zh) 2011-12-08 2018-06-22 洛桑联邦理工学院 包括阻挡层的半导体电极

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
HYOJOONG LEE ET AL, "Efficient CdSe Quantum Dot-Sensitized Solar Cells Prepared by an Improved Successive Ionic Layer Adsorption and Reaction Process", NANO LETTERS, vol. 9, no. 12, doi:10.1021/nl902438d, ISSN 1530-6984, pages 4221 - 4227. Resumen. *
IM, J.-H.; CHUNG, J.; KIM, S.-J.; PARK, N.-G., "Synthesis, structure, and photovoltaic property of a nanocrystalline 2H perovskite-type novel sensitizer (CH3CH2NH3)PbI3", NANOSCALE RES. LETT., vol. 7, page 7PP. Resumen. *
LIOZ ETGAR ET AL, "Mesoscopic CH 3 NH 3 PbI 3 /TiO 2 Heterojunction Solar Cells", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 134, no. 42, doi:10.1021/ja307789s, ISSN 0002-7863, pages 17396 - 17399. Resumen, figs. Apartado: "Results and discussion". *

Also Published As

Publication number Publication date
ES2579907B1 (es) 2017-10-24
ES2579907A2 (es) 2016-08-17
CN105474421A (zh) 2016-04-06
US20160086739A1 (en) 2016-03-24
WO2014180789A1 (en) 2014-11-13
BR112015028097A2 (pt) 2017-07-25
MX2015015395A (es) 2016-08-04

Similar Documents

Publication Publication Date Title
ES2579907R1 (es) Células solares mesoscópicas sensibilizadas con perovskita de alto rendimiento
CL2016000712A1 (es) Metalización de celdas solares con hojas metálicas
MX2019013856A (es) Metodo de formulacion de materiales de celdas solares de perovskita.
TW201613040A (en) Integration of embedded thin film capacitors in package substrates
WO2015028886A3 (en) Nano-gap electrode and methods for manufacturing same
WO2015006046A3 (en) Providing otdoa prs assistance data
AR085468A1 (es) Metodo y aparato para un inserto funcional con una capa de energia
BR112014016332A2 (pt) Barreira de difusão de película fina
ES2551459T3 (es) Método para producir un parche de ropinirol supersaturado
WO2016100303A3 (en) Photolithography based fabrication of 3d structures
AR096550A1 (es) Pala de rotor para una instalación de energía eólica e instalación de energía eólica
JP2014241304A5 (ja) 二次電池及びその製造方法
WO2015013631A3 (en) Electrochromic films and related methods thereof
WO2014130026A8 (en) Optical design techniques for providing favorable fabrication characteristics
BR112018001991A2 (pt) célula solar
WO2015047503A3 (en) Coatings for aircraft window surfaces to produce electricity for mission-critical systems on military aircraft
GB2509851A (en) Organic electronic device and method of manufacture
JP2013526041A5 (es)
BR112014018505A8 (pt) Técnicas para aperfeiçoar o gerenciamento de economia de energia
JP2013188968A5 (es)
BR112016011057A8 (pt) método e sistema
MX359718B (es) Sistemas y metodos para mejorar la fidelidad del espectro optico en elementos informaticos integrados.
AR095247A1 (es) Celdas de memoria magnética de acceso aleatorio con revestimientos aislantes
ES2527644A2 (es) SISTEMAS Y MÉTODOS PARA FORMAR CÉLULAS SOLARES CON PELÍCULAS DE CuInSe2 y Cu(In,Ga)Se2
CL2015003256A1 (es) Método para producir una célula solar sensibilizada con perovskita orgánica-inorgánica preparada por deposición secuencial de los componentes; un método para producir una capa de perovskita; una célula solar; y una capa de perovskita.

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 2579907

Country of ref document: ES

Kind code of ref document: B1

Effective date: 20171024

FA2A Application withdrawn

Effective date: 20180320