ES2555781T3 - Aceites vegetales epoxidados como plastificantes de PVC - Google Patents
Aceites vegetales epoxidados como plastificantes de PVC Download PDFInfo
- Publication number
- ES2555781T3 ES2555781T3 ES08021385.3T ES08021385T ES2555781T3 ES 2555781 T3 ES2555781 T3 ES 2555781T3 ES 08021385 T ES08021385 T ES 08021385T ES 2555781 T3 ES2555781 T3 ES 2555781T3
- Authority
- ES
- Spain
- Prior art keywords
- vegetable oils
- epoxied
- pvc plasticizers
- plasticizer composition
- plasticizers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 235000015112 vegetable and seed oil Nutrition 0.000 title abstract 2
- 239000008158 vegetable oil Substances 0.000 title abstract 2
- 239000008037 PVC plasticizer Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000004014 plasticizer Substances 0.000 abstract 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 abstract 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 abstract 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 abstract 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000005642 Oleic acid Substances 0.000 abstract 1
- 230000021736 acetylation Effects 0.000 abstract 1
- 238000006640 acetylation reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000006735 epoxidation reaction Methods 0.000 abstract 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 abstract 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 1
- 238000005809 transesterification reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/38—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D303/40—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by ester radicals
- C07D303/42—Acyclic compounds having a chain of seven or more carbon atoms, e.g. epoxidised fats
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/027—Polycondensates containing more than one epoxy group per molecule obtained by epoxidation of unsaturated precursor, e.g. polymer or monomer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
- C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
- C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1515—Three-membered rings
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/006—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by oxidation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Emergency Medicine (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Composición de plastificante que puede obtenerse mediante transesterificación parcial de aceites vegetales con etanol, acetilación y epoxidación, en la que dicha composición de plastificante presenta una mezcla de los compuestos:**Fórmula** en los que cada R se selecciona aleatoriamente de ácido oleico, linoleico y linolénico epoxidados.
Description
Claims (1)
-
imagen1
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BRPI0705621-4A BRPI0705621B1 (pt) | 2007-12-10 | 2007-12-10 | Composição plastificte de pvc |
BRPI0705621 | 2007-12-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2555781T3 true ES2555781T3 (es) | 2016-01-08 |
Family
ID=40344406
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES15002306T Active ES2726175T3 (es) | 2007-12-10 | 2008-12-09 | Composición de plastificante adecuada para composiciones de PVC |
ES08021385.3T Active ES2555781T3 (es) | 2007-12-10 | 2008-12-09 | Aceites vegetales epoxidados como plastificantes de PVC |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES15002306T Active ES2726175T3 (es) | 2007-12-10 | 2008-12-09 | Composición de plastificante adecuada para composiciones de PVC |
Country Status (9)
Country | Link |
---|---|
US (3) | US20090149586A1 (es) |
EP (2) | EP2070977B1 (es) |
BR (1) | BRPI0705621B1 (es) |
CY (1) | CY1116883T1 (es) |
DK (2) | DK2070977T3 (es) |
ES (2) | ES2726175T3 (es) |
PT (2) | PT2070977E (es) |
SI (1) | SI2070977T1 (es) |
TR (1) | TR201906236T4 (es) |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009102877A1 (en) | 2008-02-15 | 2009-08-20 | Union Carbide Chemicals & Plastics Technology Llc (Formerly Union Carbide Chemicals & Plastics Technology Corporation) | A replacement plasticizer system for phthalate-plasticized formulations |
US8552098B2 (en) | 2009-09-30 | 2013-10-08 | Dow Global Technologies Llc | Purified acetylated derivatives of castor oil and compositions including same |
TW201116618A (en) | 2009-09-30 | 2011-05-16 | Dow Global Technologies Inc | Acetylated glyceride of 12-hydroxystearic acid and blends with epoxidized fatty acid esters |
JP5757952B2 (ja) | 2009-09-30 | 2015-08-05 | ダウ グローバル テクノロジーズ エルエルシー | エポキシ化脂肪酸エステル可塑剤を有する熱安定化ポリマー組成物 |
US8802988B2 (en) | 2009-09-30 | 2014-08-12 | Dow Global Technologies Llc | Acetylated derivatives of castor oil and their blends with epoxidized fatty acid esters |
CA2775993C (en) * | 2009-09-30 | 2017-07-18 | Dow Global Technologies Llc | Acetylated glycerin esters and their blends with epoxidized fatty acid esters |
US8703849B2 (en) | 2010-01-22 | 2014-04-22 | Archer Daniels Midland Company | Processes for making high purity renewable source-based plasticizers and products made therefrom |
CN102985481A (zh) | 2010-05-10 | 2013-03-20 | 陶氏环球技术有限责任公司 | 由源自可再生资源的增塑剂制备的挠性pvc组合物 |
TW201209168A (en) | 2010-07-28 | 2012-03-01 | Dow Global Technologies Llc | Plasticizers made from oil extracted from microorganisms and polar polymeric compositions comprising the same |
US9034965B2 (en) * | 2010-08-06 | 2015-05-19 | Arkema Inc. | Epoxidized composition and methods for making the same |
KR20140000238A (ko) * | 2010-11-05 | 2014-01-02 | 다우 글로벌 테크놀로지스 엘엘씨 | 개선된 전기 특성을 갖는 가소제 시스템 |
WO2013003225A2 (en) * | 2011-06-29 | 2013-01-03 | Dow Global Technologies Llc | Vegetable-oil derived plasticizer |
EP2812389B1 (en) | 2012-02-08 | 2017-10-04 | Dow Global Technologies LLC | Plasticizer compositions and methods for making plasticizer compositions |
BR112014027887B1 (pt) | 2012-06-22 | 2021-01-05 | Dow Global Technologies Llc | composição polimérica e condutor revestido |
US10100172B2 (en) | 2012-06-26 | 2018-10-16 | Dow Global Technologies Llc | Plasticizers and plasticized polymeric compositions |
EP2909261B1 (en) | 2012-10-18 | 2019-04-03 | Dow Global Technologies LLC | Epoxidized fatty acid alkyl ester plasticizers and methods for making epoxidized fatty acid alkyl ester plasticizers |
JP6192733B2 (ja) | 2012-11-12 | 2017-09-06 | ダウ グローバル テクノロジーズ エルエルシー | エポキシ化脂肪酸アルキルエステル可塑剤およびエポキシ化脂肪酸アルキルエステル可塑剤を作製するための方法 |
CN104781328B (zh) | 2012-11-12 | 2017-12-05 | 陶氏环球技术有限公司 | 制造环氧化脂肪酸烷基酯的方法 |
EP2738774A1 (en) | 2012-11-30 | 2014-06-04 | Borealis AG | A cable construction |
US9586918B2 (en) * | 2013-02-25 | 2017-03-07 | Arkema Inc. | Unsaturated fatty acid ester-based compositions useful as plastic additives |
US10398625B2 (en) | 2013-03-13 | 2019-09-03 | Fenwal, Inc. | Medical containers with terephthalate plasticizer for storing red blood cell products |
EP3016938A4 (en) * | 2013-07-01 | 2017-05-24 | Polymer Additives, Inc. | Biobased epoxidized fatty acid ester plasticizers |
US11160728B2 (en) | 2014-02-20 | 2021-11-02 | Fresenius Kabi Deutschland Gmbh | Medical containers and system components with non-DEHP plasticizers for storing red blood cell products, plasma and platelets |
US10407559B2 (en) * | 2014-03-27 | 2019-09-10 | New Japan Chemical Co., Ltd. | Plasticizer for vinyl chloride resin containing non-phthalate ester and vinyl chloride resin composition containing such plasticizer |
EP2924063A1 (de) * | 2014-03-28 | 2015-09-30 | LANXESS Deutschland GmbH | Weichmacherzusammensetzung |
EP3143094A4 (en) | 2014-05-13 | 2018-04-04 | Magink Comércio De Imagem Gráfica Ltda - ME | Dispersion of homopolymer of vinyl chloride |
SI24879A (sl) | 2014-11-06 | 2016-05-31 | Eurel D.O.O. | Postopek za izdelavo oplaščenih vodilnih cevi, ki ne bodo vsebovale ftalatov, in oplaščene vodilne cevi narejene po tem postopku |
KR101899655B1 (ko) * | 2015-10-27 | 2018-09-17 | 주식회사 엘지화학 | 가소제 조성물, 수지 조성물 및 이들의 제조 방법 |
CN106519081B (zh) * | 2016-09-22 | 2018-06-26 | 深圳立山环保材料有限公司 | 一种环氧类增塑剂及其制备方法 |
CN108863987B (zh) * | 2018-07-25 | 2020-10-30 | 浙江工业大学 | 一种利用表面活性剂强化油脂环氧化的生产方法 |
CN110804029B (zh) * | 2019-11-08 | 2022-04-29 | 浙江工业大学 | 一种环氧类增塑剂及其制备方法 |
CN115151602A (zh) * | 2020-01-30 | 2022-10-04 | 嘉吉公司 | 增塑剂组合物和制备增塑剂组合物的方法 |
CN111234421B (zh) * | 2020-03-31 | 2021-11-02 | 安徽和佳医疗用品科技有限公司 | 一种具有抑菌功能的pvc手套及其制备方法 |
CN113817226B (zh) * | 2021-10-12 | 2022-05-10 | 南京工业大学 | 一种高分子复合材料添加剂及其应用 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE957756C (de) * | 1953-07-15 | 1957-01-17 | Rohm &. Haas Company, Philadelphia, Pa. (V. St. A.) | Verfahren zur Verbesserung der Weichmachereigenschaften von ep oxydierten Estern ungesättigter Pflanzenöl-Fettsäuren |
US2895966A (en) * | 1954-04-12 | 1959-07-21 | Waldo C Ault | Monoglyceride diacetates |
US3281382A (en) * | 1956-08-27 | 1966-10-25 | Swift & Co | Halogenated polymers containing complex epoxy fatty esters |
US3070608A (en) * | 1958-07-07 | 1962-12-25 | Swift & Co | Selective alcoholysis of epoxy fatty acid esters |
US3377304A (en) * | 1959-04-22 | 1968-04-09 | Swift & Co | High oxirane fatty esters |
GB934689A (en) * | 1959-04-22 | 1963-08-21 | Swift & Co | Epoxy fatty acid esters and polyvinyl resin compositions containing them |
DE2652328A1 (de) | 1976-11-17 | 1978-05-18 | Neynaber Chemie Gmbh | Bleiverbindungen enthaltende stabilisator-gleitmittel-kombination fuer formmassen auf basis von polyvinylchlorid |
US4605694A (en) | 1985-10-31 | 1986-08-12 | Hercules Incorporated | Plasticizing compositions for polyvinylchloride |
US5886072A (en) | 1993-05-24 | 1999-03-23 | Teknor Apex Company | Flame retardant composition |
US5430108A (en) | 1994-01-14 | 1995-07-04 | Exxon Chemical Patents Inc. | Polyol ester PVC plasticizers |
US6797753B2 (en) | 2000-06-20 | 2004-09-28 | Battelle Memorial Institute | Plasticizers derived from vegetable oils |
DE10104815A1 (de) * | 2001-02-01 | 2002-08-08 | Cognis Deutschland Gmbh | Verfahren zur Herstellung von epoxidierten Glyceridacetaten |
EP2470596B1 (en) * | 2009-09-30 | 2013-07-17 | Dow Global Technologies LLC | Acetylated polyglycerine fatty acid ester and a pvc insulator plasticised therewith |
-
2007
- 2007-12-10 BR BRPI0705621-4A patent/BRPI0705621B1/pt active IP Right Grant
-
2008
- 2008-12-09 US US12/331,092 patent/US20090149586A1/en not_active Abandoned
- 2008-12-09 TR TR2019/06236T patent/TR201906236T4/tr unknown
- 2008-12-09 SI SI200831529T patent/SI2070977T1/sl unknown
- 2008-12-09 EP EP08021385.3A patent/EP2070977B1/en active Active
- 2008-12-09 PT PT80213853T patent/PT2070977E/pt unknown
- 2008-12-09 DK DK08021385.3T patent/DK2070977T3/da active
- 2008-12-09 EP EP15002306.7A patent/EP2960282B1/en active Active
- 2008-12-09 PT PT15002306T patent/PT2960282T/pt unknown
- 2008-12-09 ES ES15002306T patent/ES2726175T3/es active Active
- 2008-12-09 ES ES08021385.3T patent/ES2555781T3/es active Active
- 2008-12-09 DK DK15002306.7T patent/DK2960282T3/da active
-
2014
- 2014-01-06 US US14/148,312 patent/US9303140B2/en active Active
- 2014-03-24 US US14/223,090 patent/US9388292B2/en active Active
-
2015
- 2015-10-07 CY CY20151100898T patent/CY1116883T1/el unknown
Also Published As
Publication number | Publication date |
---|---|
EP2960282B1 (en) | 2019-02-13 |
US20090149586A1 (en) | 2009-06-11 |
US20140221538A1 (en) | 2014-08-07 |
CY1116883T1 (el) | 2017-04-05 |
US20140316038A1 (en) | 2014-10-23 |
BRPI0705621B1 (pt) | 2019-04-09 |
EP2960282A1 (en) | 2015-12-30 |
DK2070977T3 (da) | 2015-10-05 |
ES2726175T3 (es) | 2019-10-02 |
EP2070977A2 (en) | 2009-06-17 |
US9303140B2 (en) | 2016-04-05 |
PT2070977E (pt) | 2016-01-15 |
DK2960282T3 (da) | 2019-05-13 |
BRPI0705621A2 (pt) | 2009-08-18 |
EP2070977B1 (en) | 2015-09-23 |
EP2070977A3 (en) | 2010-12-15 |
PT2960282T (pt) | 2019-05-27 |
TR201906236T4 (tr) | 2019-05-21 |
US9388292B2 (en) | 2016-07-12 |
SI2070977T1 (sl) | 2015-12-31 |
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