ES2350011T3 - Método y aparato para eliminar partículas de sulfuros de metal de una corriente líquida. - Google Patents
Método y aparato para eliminar partículas de sulfuros de metal de una corriente líquida. Download PDFInfo
- Publication number
- ES2350011T3 ES2350011T3 ES07726879T ES07726879T ES2350011T3 ES 2350011 T3 ES2350011 T3 ES 2350011T3 ES 07726879 T ES07726879 T ES 07726879T ES 07726879 T ES07726879 T ES 07726879T ES 2350011 T3 ES2350011 T3 ES 2350011T3
- Authority
- ES
- Spain
- Prior art keywords
- membrane
- sulfide particles
- metal sulfide
- metal
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052976 metal sulfide Inorganic materials 0.000 title claims abstract description 116
- 239000002245 particle Substances 0.000 title claims abstract description 99
- 239000007788 liquid Substances 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims abstract description 47
- 239000012528 membrane Substances 0.000 claims abstract description 105
- 239000002904 solvent Substances 0.000 claims abstract description 65
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 33
- 229910052751 metal Inorganic materials 0.000 claims description 25
- 239000007789 gas Substances 0.000 claims description 24
- 239000002184 metal Substances 0.000 claims description 24
- 238000000926 separation method Methods 0.000 claims description 20
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 19
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 15
- 230000001172 regenerating effect Effects 0.000 claims description 13
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 9
- 238000004140 cleaning Methods 0.000 claims description 7
- -1 polytetrafluoroethylene Polymers 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 239000011148 porous material Substances 0.000 claims description 5
- 239000004697 Polyetherimide Substances 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 230000033001 locomotion Effects 0.000 claims description 4
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 4
- 229920001601 polyetherimide Polymers 0.000 claims description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 4
- 238000000108 ultra-filtration Methods 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229910010293 ceramic material Inorganic materials 0.000 claims description 2
- 238000001728 nano-filtration Methods 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 230000035699 permeability Effects 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 238000001223 reverse osmosis Methods 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 229920002301 cellulose acetate Polymers 0.000 claims 1
- 239000003365 glass fiber Substances 0.000 claims 1
- 229940087654 iron carbonyl Drugs 0.000 claims 1
- 230000008929 regeneration Effects 0.000 claims 1
- 238000011069 regeneration method Methods 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 description 16
- 238000003786 synthesis reaction Methods 0.000 description 16
- 239000000356 contaminant Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 5
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005201 scrubbing Methods 0.000 description 3
- 150000003464 sulfur compounds Chemical class 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 229920002312 polyamide-imide Polymers 0.000 description 2
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 2
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 150000001983 dialkylethers Chemical class 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- OCHIDBMJEFPMFG-UHFFFAOYSA-N dithiiran-3-one Chemical compound O=C1SS1 OCHIDBMJEFPMFG-UHFFFAOYSA-N 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- XUWHAWMETYGRKB-UHFFFAOYSA-N piperidin-2-one Chemical class O=C1CCCCN1 XUWHAWMETYGRKB-UHFFFAOYSA-N 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/30—Polyalkenyl halides
- B01D71/32—Polyalkenyl halides containing fluorine atoms
- B01D71/34—Polyvinylidene fluoride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/145—Ultrafiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
- B01D65/02—Membrane cleaning or sterilisation ; Membrane regeneration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0088—Physical treatment with compounds, e.g. swelling, coating or impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
- B01D2321/20—By influencing the flow
- B01D2321/2033—By influencing the flow dynamically
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/12—Adsorbents being present on the surface of the membranes or in the pores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/30—Chemical resistance
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
- Industrial Gases (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06111226 | 2006-03-16 | ||
| EP06111226 | 2006-03-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2350011T3 true ES2350011T3 (es) | 2011-01-14 |
Family
ID=36218324
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES07726879T Active ES2350011T3 (es) | 2006-03-16 | 2007-03-14 | Método y aparato para eliminar partículas de sulfuros de metal de una corriente líquida. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US8123946B2 (enExample) |
| EP (1) | EP1993711B1 (enExample) |
| JP (1) | JP2009530072A (enExample) |
| CN (1) | CN101389397B (enExample) |
| AT (1) | ATE479491T1 (enExample) |
| AU (1) | AU2007224417B2 (enExample) |
| CA (1) | CA2640061A1 (enExample) |
| DE (1) | DE602007008848D1 (enExample) |
| EA (1) | EA012480B1 (enExample) |
| ES (1) | ES2350011T3 (enExample) |
| WO (1) | WO2007104769A1 (enExample) |
| ZA (1) | ZA200805744B (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012057176A1 (ja) * | 2010-10-29 | 2012-05-03 | 東レ株式会社 | 水処理方法および造水方法 |
| EP2900354B1 (en) * | 2012-09-26 | 2019-04-03 | Dow Silicones Corporation | Method of separating a gas using at least one membrane in contact with an organosilicon fluid |
| RU2016101227A (ru) * | 2013-06-19 | 2017-07-24 | ЭфПиИННОВЕЙШНЗ | Способ получения биометанола на целлюлозных заводах |
| JP7609855B2 (ja) * | 2019-09-25 | 2025-01-07 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 噴射器堆積物を低減するためのプロセス |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3899312A (en) * | 1969-08-21 | 1975-08-12 | Linde Ag | Extraction of odorizing sulfur compounds from natural gas and reodorization therewith |
| DE2610982C3 (de) * | 1976-03-16 | 1982-12-30 | Veba Oel AG, 4660 Gelsenkirchen-Buer | Verfahren zum Reinigen von Druckgasen aus der Spaltung schwermetallhaltiger Brennstoffe |
| US4370236A (en) * | 1980-12-16 | 1983-01-25 | Phillips Petroleum Company | Purification of hydrocarbon streams |
| DE3148520A1 (de) * | 1981-12-08 | 1983-07-21 | Linde Ag, 6200 Wiesbaden | "verfahren zur entfernung von sauren gasen aus gasgemischen" |
| US5190662A (en) * | 1991-07-29 | 1993-03-02 | Conoco Inc. | Removal of iron sulfide particles from alkanolamine solutions |
| DE4324347A1 (de) * | 1992-07-23 | 1994-01-27 | Noritake Co Ltd | Monolithischer Keramikfilter |
| DE19507584C2 (de) | 1995-03-04 | 1997-06-12 | Geesthacht Gkss Forschung | Strahlenchemisch modifizierte Silikonkompositmembran für die Ultrafiltration |
| JPH09262565A (ja) * | 1996-03-29 | 1997-10-07 | Ishikawajima Harima Heavy Ind Co Ltd | 臭素を含む難燃性樹脂廃棄物の処理方法 |
| GB9702742D0 (en) * | 1997-02-11 | 1997-04-02 | Ici Plc | Gas absorption |
| JP3512342B2 (ja) * | 1998-08-18 | 2004-03-29 | 株式会社クボタ | 分離膜の洗浄方法 |
| JP3848789B2 (ja) * | 1998-09-09 | 2006-11-22 | 三菱重工業株式会社 | 灰溶融炉排ガス処理用スクラバ排水の排水処理装置 |
| EP1255803A1 (en) * | 2000-02-17 | 2002-11-13 | Shell Internationale Researchmaatschappij B.V. | Process for purifying a liquid hydrocarbon fuel |
| DE10021790B4 (de) * | 2000-05-10 | 2004-07-08 | Raschig Gmbh | Verfahren zur Herstellung von ω-Aminoalkansulfonsäuren und deren Verwendung als Biopuffer |
| DE10023661B4 (de) * | 2000-05-13 | 2007-07-26 | Lurgi Ag | Verfahren zum Reinigen einer beladenen Waschflüssigkeit, die aus einer Anlage zur Gasentschwefelung kommt |
| DE10336677B4 (de) | 2003-08-09 | 2007-10-31 | Lurgi Ag | Verfahren und Vorrichtung zur Reinigung von Industriegasen |
| JP2005272795A (ja) * | 2003-11-10 | 2005-10-06 | Fuji Photo Film Co Ltd | ドープ型金属硫化物蛍光体ナノ粒子、その分散液及びそれらの製造方法 |
| JP4445758B2 (ja) * | 2004-01-22 | 2010-04-07 | 出光興産株式会社 | 難分解性物質を含有する汚染水の処理方法 |
-
2007
- 2007-03-14 CN CN2007800067476A patent/CN101389397B/zh not_active Expired - Fee Related
- 2007-03-14 CA CA002640061A patent/CA2640061A1/en not_active Abandoned
- 2007-03-14 EA EA200801987A patent/EA012480B1/ru unknown
- 2007-03-14 US US12/282,530 patent/US8123946B2/en not_active Expired - Fee Related
- 2007-03-14 AU AU2007224417A patent/AU2007224417B2/en not_active Ceased
- 2007-03-14 WO PCT/EP2007/052383 patent/WO2007104769A1/en not_active Ceased
- 2007-03-14 EP EP07726879A patent/EP1993711B1/en not_active Not-in-force
- 2007-03-14 DE DE602007008848T patent/DE602007008848D1/de active Active
- 2007-03-14 ES ES07726879T patent/ES2350011T3/es active Active
- 2007-03-14 AT AT07726879T patent/ATE479491T1/de not_active IP Right Cessation
- 2007-03-14 JP JP2008558812A patent/JP2009530072A/ja active Pending
-
2008
- 2008-07-01 ZA ZA200805744A patent/ZA200805744B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN101389397B (zh) | 2012-09-19 |
| AU2007224417A1 (en) | 2007-09-20 |
| JP2009530072A (ja) | 2009-08-27 |
| EP1993711A1 (en) | 2008-11-26 |
| DE602007008848D1 (de) | 2010-10-14 |
| US20090065432A1 (en) | 2009-03-12 |
| AU2007224417B2 (en) | 2010-04-01 |
| CA2640061A1 (en) | 2007-09-20 |
| WO2007104769A1 (en) | 2007-09-20 |
| EP1993711B1 (en) | 2010-09-01 |
| CN101389397A (zh) | 2009-03-18 |
| ATE479491T1 (de) | 2010-09-15 |
| ZA200805744B (en) | 2009-08-26 |
| EA012480B1 (ru) | 2009-10-30 |
| EA200801987A1 (ru) | 2009-02-27 |
| US8123946B2 (en) | 2012-02-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Yeo et al. | Conventional processes and membrane technology for carbon dioxide removal from natural gas: A review | |
| JP6977112B2 (ja) | 酸性ガスをガス流から除去する統合システム及び方法 | |
| Chuah et al. | CO2 absorption using membrane contactors: Recent progress and future perspective | |
| Yu et al. | CO2 capture using a superhydrophobic ceramic membrane contactor | |
| Hong et al. | Hydrogen purification using a SAPO-34 membrane | |
| US7572318B2 (en) | High-temperature membrane for CO2 and/or H2S separation | |
| CN103635248B (zh) | Co2的沸石膜分离回收系统 | |
| Mansourizadeh et al. | CO2 stripping from water through porous PVDF hollow fiber membrane contactor | |
| ES2350011T3 (es) | Método y aparato para eliminar partículas de sulfuros de metal de una corriente líquida. | |
| Grosso et al. | Polymeric and mixed matrix polyimide membranes | |
| Shi et al. | SiC–C composite as a highly stable and easily regenerable photothermal material for practical water evaporation | |
| KR101354680B1 (ko) | 실리콘 분리막을 이용한 이산화탄소 분리장치 | |
| Tang et al. | Long-term stability of polytetrafluoroethylene (PTFE) hollow fiber membranes for CO2 capture | |
| Yu et al. | High performance fluoride MFI membranes for efficient CO2/H2 separation | |
| CN101801506A (zh) | 由含h2s、co2及hcn和/或cos的气体生产纯化气体的方法 | |
| MXPA03007910A (es) | Aparato y metodo para separar gases. | |
| BR112020006088B1 (pt) | Métodos e sistema de processamento de gás para produzir uma corrente de gás hidrogênio purificada | |
| EP4019119A1 (en) | Membrane assembly for gas separation, method for producing the membrane assembly and method of separating gases | |
| EP2712326A1 (en) | Particle doped hollow-fiber contactor | |
| Bhalani et al. | Hydrogen separation membranes: a material perspective | |
| Ryi et al. | Fabrication and characterization of metal porous membrane made of Ni powder for hydrogen separation | |
| Kim et al. | The preparation and characterization of hydrotalcite thin films | |
| Lie | Synthesis, performance and regeneration of carbon membranes for biogas upgrading-a future energy carrier | |
| JP2011231181A (ja) | メタンガス精製装置 | |
| Sircar et al. | Nanoporous carbon membranes for gas separation |