ES2180347T3 - Procedimiento para la preparacion de acilfosfinas y derivados. - Google Patents
Procedimiento para la preparacion de acilfosfinas y derivados.Info
- Publication number
- ES2180347T3 ES2180347T3 ES99973034T ES99973034T ES2180347T3 ES 2180347 T3 ES2180347 T3 ES 2180347T3 ES 99973034 T ES99973034 T ES 99973034T ES 99973034 T ES99973034 T ES 99973034T ES 2180347 T3 ES2180347 T3 ES 2180347T3
- Authority
- ES
- Spain
- Prior art keywords
- preparation
- mono
- acilphosphins
- derivatives
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 4
- 238000002360 preparation method Methods 0.000 title abstract 4
- 150000003568 thioethers Chemical class 0.000 abstract 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 238000002955 isolation Methods 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 150000003003 phosphines Chemical class 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5036—Phosphines containing the structure -C(=X)-P or NC-P
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
- C07F9/5337—Phosphine oxides or thioxides containing the structure -C(=X)-P(=X) or NC-P(=X) (X = O, S, Se)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Saccharide Compounds (AREA)
Abstract
Un procedimiento para la preparación de acil-fosfinas de fórmula I **(Fórmula)** en donde n y m son cada uno, independientemente del otro 1 ó 2; R1, si n = 1, es alquilo de C1-C18, alquilo de C2-C18 que está interrumpido por uno o varios átomos de O no secesivos; alquilo de C1-C4 fenilo-sustituido, alquenilo de C2-C8, fenilo, naftilo, difenilo, cicloalquilo de C5-C12 o un anillo heterocíclico conteniendo O, S o N pentagonal o hexagonal, estando los radicales fenilo, naftilo, difenilo, cicloalquilo de C5-C12 o el anillo heterocíclico conteniendo O, S o N pentagonal o hexagonal insustituido o sustituido por uno a cinco halógeno, alquilo de C1-C8, alquiltio de C1-C8 y/o alcoxilo de C1-C8; R1, si n = 2, es alquileno de C1-C18, alquileno de C2-C18 que está interrumpido por uno o varios átomos de O no sucesivos; o R1 es alquileno de C1-C6 que está sustituido por alcoxilo de C1-C4, fenilo, alquilfenilo de C1-C4, fenilalquilo de C1-C4 o alcoxifenilo de C1-C4; o R1 es fenileno o xilileno, cuyos radicales están no sustituidos o sustituidos por uno a tres alquilo de C1-C4 y/o alcoxilo de C1-C4, o R1 es un grupo **(Fórmulas)** R2 es alquilo de C1-C18, cicloalquilo de C3-C12, alquenilo de C2-C18, fenilo, naftilo, difenilo o un anillo heterocíclico conteniendo O, S o N pentagonal o hexagonal, estando los radicales de fenilo, naftilo, difenilo o anillo hete-rocíclico conteniendo O, S o N pentagonal o hexagonal no sustituido o sustituido por uno a cuatro alquilo de C1-C8, alcoxilo de C1-C8, alquiltio de C1-C8 y/o halógeno; R3 es alquilo de C1-C18, alquilo de C2-C18 que está interrumpido por uno o varios átomos de O no sucesivos; alquilo de C1-C4 fenilo-sustituido, alquenilo de C2-C8, fenilo, naftilo, difenilo, cicloalquilo de C5-C12 o un anillo heterocíclico conteniendo O, S o N pentagonal o hexagonal, estando los radicales de fenilo, naftilo, difenilo, cicloalquilo de C5-C12 o el anillo heterocíclico conteniendo O, S o N pentagonal o hexagonal no sustituido o sustituido por uno a cinco halógeno, alquilo de C1-C8, alquiltio de C1-C8 y/o alcoxilo de C1-C8; Q es un enlace simple, CR6R7, -O- o -S-; R4 y R5 son cada uno, independientemente del otro, hidrógeno, alquilo de C1-C4 o alcoxilo de C1-C4; R6 y R7 son cada uno, independientemente del otro, hidrógeno o alquilo de C1-C4.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH237698 | 1998-11-30 | ||
| CH2376/98 | 1998-11-30 | ||
| CH243498 | 1998-12-08 | ||
| CH2434/98 | 1998-12-08 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2180347T3 true ES2180347T3 (es) | 2003-02-01 |
| ES2180347T5 ES2180347T5 (es) | 2007-04-01 |
Family
ID=25690294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99973034T Expired - Lifetime ES2180347T5 (es) | 1998-11-30 | 1999-11-20 | Procedimiento para la preparacion de acilfosfinas y derivados. |
Country Status (14)
| Country | Link |
|---|---|
| US (3) | US6888031B1 (es) |
| EP (1) | EP1135399B2 (es) |
| JP (1) | JP4265871B2 (es) |
| KR (1) | KR100653117B1 (es) |
| CN (1) | CN1211388C (es) |
| AT (1) | ATE221893T1 (es) |
| AU (1) | AU760237B2 (es) |
| CA (1) | CA2349637C (es) |
| CZ (1) | CZ302512B6 (es) |
| DE (1) | DE69902485T3 (es) |
| ES (1) | ES2180347T5 (es) |
| SK (1) | SK286152B6 (es) |
| TW (1) | TW492972B (es) |
| WO (1) | WO2000032612A1 (es) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1211388C (zh) * | 1998-11-30 | 2005-07-20 | 西巴特殊化学品控股有限公司 | 酰基膦和其衍生物的制备方法 |
| GB2360283B (en) * | 2000-02-08 | 2002-08-21 | Ciba Sc Holding Ag | Monoacylarylphosphines and acylphosphine oxides and sulphides |
| GB2365430B (en) * | 2000-06-08 | 2002-08-28 | Ciba Sc Holding Ag | Acylphosphine photoinitiators and intermediates |
| DK1423757T3 (da) | 2001-08-21 | 2009-08-17 | Ciba Holding Inc | Bathochromiske mono- og bisacylphosphinoxider og -sulfider og deres anvendelse som fotoinitiatorer |
| DE10206117A1 (de) | 2002-02-13 | 2003-08-14 | Basf Ag | Acyl- und Bisacylphosphinderivate |
| DE10244684A1 (de) | 2002-09-24 | 2004-04-01 | Basf Ag | Verfahren zur Herstellung von Acylphosphinoxiden |
| JP4599169B2 (ja) * | 2002-12-04 | 2010-12-15 | チバ ホールディング インコーポレーテッド | シクロオルガニルホスファンおよびジ（アルカリ金属／アルカリ土類金属）オリゴホスファンジイドの合成方法 |
| DE10315671A1 (de) * | 2003-04-04 | 2004-10-14 | Basf Ag | Verfahren zur Herstellung von Acylphosphinoxid-Feststoffen |
| EP1648908B1 (en) * | 2003-07-18 | 2006-10-18 | Ciba SC Holding AG | Process for preparing acylphosphanes and derivatives thereof |
| TW200523265A (en) * | 2003-07-31 | 2005-07-16 | Basf Ag | A process for the preparation of acylphosphines |
| JP5148283B2 (ja) * | 2004-11-23 | 2013-02-20 | チバ ホールディング インコーポレーテッド | アシルホスファン及びその誘導体の製造方法 |
| JP5234912B2 (ja) * | 2005-01-17 | 2013-07-10 | チバ ホールディング インコーポレーテッド | アシルホスファン、並びにこれらの酸化物及び硫化物の製造方法 |
| DE102005005946A1 (de) * | 2005-02-10 | 2006-08-17 | Basf Ag | Verfahren zur Herstellung tertiärer Phosphine |
| CN102203136B (zh) | 2008-11-03 | 2013-11-13 | 巴斯夫欧洲公司 | 光敏引发剂混合物 |
| EP2421903B1 (en) * | 2009-04-20 | 2014-11-19 | ETH Zurich | Polymer nanoparticles |
| CN102875597B (zh) * | 2011-07-11 | 2017-05-03 | 深圳市有为化学技术有限公司 | 芳香酮膦氧杂化型化合物 |
| CN102875598B (zh) * | 2011-07-11 | 2016-09-07 | 深圳市有为化学技术有限公司 | (二苯膦氧基)(均三甲苯基)甲酮和(苯膦氧基)双(均三甲苯基甲酮)的制备方法 |
| CN102675365A (zh) * | 2012-05-16 | 2012-09-19 | 湖北固润科技股份有限公司 | 一种紫外光引发剂xbpo合成方法 |
| GB201213163D0 (en) | 2012-07-24 | 2012-09-05 | Lambson Ltd | Photopolymerisation processes and novel compounds therefor |
| ES2720760T3 (es) | 2012-10-01 | 2019-07-24 | Eth Zuerich | Un procedimiento para la preparación de acilofosfanos |
| US8908090B2 (en) | 2013-03-15 | 2014-12-09 | Freefly Systems, Inc. | Method for enabling manual adjustment of a pointing direction of an actively stabilized camera |
| CN104592298B (zh) * | 2014-12-31 | 2016-07-06 | 湖北固润科技股份有限公司 | 一种酰基膦高效光引发剂及其制备方法 |
| CN105541913B (zh) * | 2015-12-03 | 2017-08-25 | 天津久日新材料股份有限公司 | 一种2,4,6‑三甲基苯甲酰基二苯基氧化膦的制备方法 |
| CN105732709A (zh) * | 2016-03-16 | 2016-07-06 | 三峡大学 | 一种光引发剂2,4,6-三甲基苯甲酰二环己基氧膦，制备方法及其应用 |
| CN105732710A (zh) * | 2016-03-16 | 2016-07-06 | 三峡大学 | 一种光引发剂联苯基四(2,4,6-三甲基苯甲酰基)氧化膦的制备方法及其应用 |
| CN107304220B (zh) * | 2016-04-22 | 2020-03-31 | 江苏英力科技发展有限公司 | 一种“一锅法”合成2,4,6-三甲基苯甲酰基-二苯基氧化膦的方法 |
| EP3296301A1 (en) | 2016-09-19 | 2018-03-21 | ETH Zürich | A versatile process for the preparation of acylphosphines |
| JP6916484B2 (ja) * | 2017-03-28 | 2021-08-11 | 国立大学法人千葉大学 | アシルホスフィンの製造方法 |
| EP3409680B1 (en) | 2017-05-30 | 2021-01-06 | IGM Group B.V. | Synthesis of bis(acyl)phosphines by activation of unreactive metal phosphides |
| EP3539924A1 (en) * | 2018-03-14 | 2019-09-18 | ETH Zurich | Novel vinyl phosphines and photo-initiators obtainable therefrom |
| CN110734461A (zh) * | 2018-07-20 | 2020-01-31 | 深圳市有为化学技术有限公司 | 化合物2,4,6-三甲基苯甲酰基二苯基氧化膦的制备 |
| JP7432616B2 (ja) * | 2018-12-07 | 2024-02-16 | アンチン ライティング オプトエレクトロニクス テクノロジー カンパニー リミテッド | アシルホスフィンオキシド化合物及びその調製方法 |
| CN111138491B (zh) * | 2019-12-31 | 2022-08-05 | 天津久日新材料股份有限公司 | 一种制备光引发剂tpo同时副产氯苄的方法 |
| CN111087425B (zh) | 2020-01-10 | 2022-04-19 | 天津大学 | 一种大粒度苯基双(2,4,6-三甲基苯甲酰基)氧化膦晶型及其结晶方法 |
| CN112279940B (zh) * | 2020-04-17 | 2023-06-27 | 山东科技大学 | 一种酰基膦光引发剂及其制备方法 |
| CN112159429B (zh) * | 2020-10-29 | 2022-06-21 | 天津久日新材料股份有限公司 | 一种双(2,4,6-三甲基苯甲酰基)苯基氧化膦的制备方法 |
| IT202300028218A1 (it) | 2023-12-28 | 2025-06-28 | Igm Resins Italia Srl | Nuova forma solida di bis(2,4,6-trimetilbenzoil)-n-ottilfosfina ossido |
| JP7600464B1 (ja) * | 2024-10-03 | 2024-12-16 | サカタインクス株式会社 | 活性エネルギー線硬化型インクジェット印刷用インク |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2962089D1 (en) | 1978-07-14 | 1982-03-18 | Basf Ag | Light-curable moulding, impregnating and coating compositions and shaped articles prepared therefrom |
| DE2909994A1 (de) | 1979-03-14 | 1980-10-02 | Basf Ag | Acylphosphinoxidverbindungen, ihre herstellung und verwendung |
| DE3020092A1 (de) * | 1980-05-27 | 1981-12-10 | Basf Ag, 6700 Ludwigshafen | Acylphosphinverbindungen und ihre verwendung |
| DE3034697A1 (de) | 1980-09-15 | 1982-05-06 | Basf Ag, 6700 Ludwigshafen | Acylphosphinsulfidverbindungen, ihre herstellung und verwendung |
| DE3443221A1 (de) | 1984-11-27 | 1986-06-05 | ESPE Fabrik pharmazeutischer Präparate GmbH, 8031 Seefeld | Bisacylphosphinoxide, ihre herstellung und verwendung |
| US5218009A (en) * | 1989-08-04 | 1993-06-08 | Ciba-Geigy Corporation | Mono- and di-acylphosphine oxides |
| RU2091385C1 (ru) | 1991-09-23 | 1997-09-27 | Циба-Гейги АГ | Бисацилфосфиноксиды, состав и способ нанесения покрытий |
| ZA941879B (en) | 1993-03-18 | 1994-09-19 | Ciba Geigy | Curing compositions containing bisacylphosphine oxide photoinitiators |
| TW381106B (en) * | 1994-09-02 | 2000-02-01 | Ciba Sc Holding Ag | Alkoxyphenyl-substituted bisacylphosphine oxides |
| MX9701734A (es) * | 1994-09-08 | 1997-06-28 | Ciba Sc Holding Ag | Novedosos oxidos de acilfosfina. |
| TW323274B (es) * | 1994-10-13 | 1997-12-21 | Ciba Sc Holding Ag | |
| CN1211388C (zh) * | 1998-11-30 | 2005-07-20 | 西巴特殊化学品控股有限公司 | 酰基膦和其衍生物的制备方法 |
| GB2360283B (en) * | 2000-02-08 | 2002-08-21 | Ciba Sc Holding Ag | Monoacylarylphosphines and acylphosphine oxides and sulphides |
-
1999
- 1999-11-20 CN CNB998137138A patent/CN1211388C/zh not_active Expired - Lifetime
- 1999-11-20 SK SK727-2001A patent/SK286152B6/sk not_active IP Right Cessation
- 1999-11-20 DE DE69902485T patent/DE69902485T3/de not_active Expired - Lifetime
- 1999-11-20 AU AU13845/00A patent/AU760237B2/en not_active Expired
- 1999-11-20 WO PCT/EP1999/008968 patent/WO2000032612A1/en not_active Ceased
- 1999-11-20 CA CA002349637A patent/CA2349637C/en not_active Expired - Lifetime
- 1999-11-20 JP JP2000585253A patent/JP4265871B2/ja not_active Expired - Lifetime
- 1999-11-20 ES ES99973034T patent/ES2180347T5/es not_active Expired - Lifetime
- 1999-11-20 US US09/856,769 patent/US6888031B1/en not_active Expired - Lifetime
- 1999-11-20 EP EP99973034A patent/EP1135399B2/en not_active Expired - Lifetime
- 1999-11-20 KR KR1020017006727A patent/KR100653117B1/ko not_active Expired - Lifetime
- 1999-11-20 AT AT99973034T patent/ATE221893T1/de active
- 1999-11-20 CZ CZ20011875A patent/CZ302512B6/cs not_active IP Right Cessation
- 1999-11-29 TW TW088120769A patent/TW492972B/zh not_active IP Right Cessation
-
2004
- 2004-05-17 US US10/847,095 patent/US7094931B2/en not_active Expired - Lifetime
-
2006
- 2006-02-06 US US11/348,042 patent/US7214830B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1135399B1 (en) | 2002-08-07 |
| DE69902485D1 (de) | 2002-09-12 |
| ES2180347T5 (es) | 2007-04-01 |
| KR100653117B1 (ko) | 2006-12-21 |
| WO2000032612A1 (en) | 2000-06-08 |
| SK7272001A3 (en) | 2001-12-03 |
| US7094931B2 (en) | 2006-08-22 |
| US20040248855A1 (en) | 2004-12-09 |
| AU760237B2 (en) | 2003-05-08 |
| AU1384500A (en) | 2000-06-19 |
| JP2002531460A (ja) | 2002-09-24 |
| CZ302512B6 (cs) | 2011-06-29 |
| TW492972B (en) | 2002-07-01 |
| EP1135399B2 (en) | 2006-08-09 |
| CZ20011875A3 (cs) | 2001-09-12 |
| JP4265871B2 (ja) | 2009-05-20 |
| EP1135399A1 (en) | 2001-09-26 |
| CA2349637A1 (en) | 2000-06-08 |
| ATE221893T1 (de) | 2002-08-15 |
| US7214830B2 (en) | 2007-05-08 |
| KR20010093124A (ko) | 2001-10-27 |
| SK286152B6 (sk) | 2008-04-07 |
| CN1328564A (zh) | 2001-12-26 |
| DE69902485T3 (de) | 2007-03-15 |
| CA2349637C (en) | 2008-12-23 |
| DE69902485T2 (de) | 2003-05-08 |
| US6888031B1 (en) | 2005-05-03 |
| US20060128959A1 (en) | 2006-06-15 |
| CN1211388C (zh) | 2005-07-20 |
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