ES2180347T3 - Procedimiento para la preparacion de acilfosfinas y derivados. - Google Patents

Procedimiento para la preparacion de acilfosfinas y derivados.

Info

Publication number
ES2180347T3
ES2180347T3 ES99973034T ES99973034T ES2180347T3 ES 2180347 T3 ES2180347 T3 ES 2180347T3 ES 99973034 T ES99973034 T ES 99973034T ES 99973034 T ES99973034 T ES 99973034T ES 2180347 T3 ES2180347 T3 ES 2180347T3
Authority
ES
Spain
Prior art keywords
preparation
mono
acilphosphins
derivatives
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99973034T
Other languages
English (en)
Other versions
ES2180347T5 (es
Inventor
David George Leppard
Eugen Eichenberger
Rene Kaeser
Gebhard Hug
Urs Schwendimann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25690294&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2180347(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of ES2180347T3 publication Critical patent/ES2180347T3/es
Application granted granted Critical
Publication of ES2180347T5 publication Critical patent/ES2180347T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5036—Phosphines containing the structure -C(=X)-P or NC-P
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C07F9/5337—Phosphine oxides or thioxides containing the structure -C(=X)-P(=X) or NC-P(=X) (X = O, S, Se)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Saccharide Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Un procedimiento para la preparación de acil-fosfinas de fórmula I **(Fórmula)** en donde n y m son cada uno, independientemente del otro 1 ó 2; R1, si n = 1, es alquilo de C1-C18, alquilo de C2-C18 que está interrumpido por uno o varios átomos de O no secesivos; alquilo de C1-C4 fenilo-sustituido, alquenilo de C2-C8, fenilo, naftilo, difenilo, cicloalquilo de C5-C12 o un anillo heterocíclico conteniendo O, S o N pentagonal o hexagonal, estando los radicales fenilo, naftilo, difenilo, cicloalquilo de C5-C12 o el anillo heterocíclico conteniendo O, S o N pentagonal o hexagonal insustituido o sustituido por uno a cinco halógeno, alquilo de C1-C8, alquiltio de C1-C8 y/o alcoxilo de C1-C8; R1, si n = 2, es alquileno de C1-C18, alquileno de C2-C18 que está interrumpido por uno o varios átomos de O no sucesivos; o R1 es alquileno de C1-C6 que está sustituido por alcoxilo de C1-C4, fenilo, alquilfenilo de C1-C4, fenilalquilo de C1-C4 o alcoxifenilo de C1-C4; o R1 es fenileno o xilileno, cuyos radicales están no sustituidos o sustituidos por uno a tres alquilo de C1-C4 y/o alcoxilo de C1-C4, o R1 es un grupo **(Fórmulas)** R2 es alquilo de C1-C18, cicloalquilo de C3-C12, alquenilo de C2-C18, fenilo, naftilo, difenilo o un anillo heterocíclico conteniendo O, S o N pentagonal o hexagonal, estando los radicales de fenilo, naftilo, difenilo o anillo hete-rocíclico conteniendo O, S o N pentagonal o hexagonal no sustituido o sustituido por uno a cuatro alquilo de C1-C8, alcoxilo de C1-C8, alquiltio de C1-C8 y/o halógeno; R3 es alquilo de C1-C18, alquilo de C2-C18 que está interrumpido por uno o varios átomos de O no sucesivos; alquilo de C1-C4 fenilo-sustituido, alquenilo de C2-C8, fenilo, naftilo, difenilo, cicloalquilo de C5-C12 o un anillo heterocíclico conteniendo O, S o N pentagonal o hexagonal, estando los radicales de fenilo, naftilo, difenilo, cicloalquilo de C5-C12 o el anillo heterocíclico conteniendo O, S o N pentagonal o hexagonal no sustituido o sustituido por uno a cinco halógeno, alquilo de C1-C8, alquiltio de C1-C8 y/o alcoxilo de C1-C8; Q es un enlace simple, CR6R7, -O- o -S-; R4 y R5 son cada uno, independientemente del otro, hidrógeno, alquilo de C1-C4 o alcoxilo de C1-C4; R6 y R7 son cada uno, independientemente del otro, hidrógeno o alquilo de C1-C4.
ES99973034T 1998-11-30 1999-11-20 Procedimiento para la preparacion de acilfosfinas y derivados. Expired - Lifetime ES2180347T5 (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CH2376/98 1998-11-30
CH237698 1998-11-30
CH243498 1998-12-08
CH2434/98 1998-12-08

Publications (2)

Publication Number Publication Date
ES2180347T3 true ES2180347T3 (es) 2003-02-01
ES2180347T5 ES2180347T5 (es) 2007-04-01

Family

ID=25690294

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99973034T Expired - Lifetime ES2180347T5 (es) 1998-11-30 1999-11-20 Procedimiento para la preparacion de acilfosfinas y derivados.

Country Status (14)

Country Link
US (3) US6888031B1 (es)
EP (1) EP1135399B2 (es)
JP (1) JP4265871B2 (es)
KR (1) KR100653117B1 (es)
CN (1) CN1211388C (es)
AT (1) ATE221893T1 (es)
AU (1) AU760237B2 (es)
CA (1) CA2349637C (es)
CZ (1) CZ302512B6 (es)
DE (1) DE69902485T3 (es)
ES (1) ES2180347T5 (es)
SK (1) SK286152B6 (es)
TW (1) TW492972B (es)
WO (1) WO2000032612A1 (es)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000032612A1 (en) * 1998-11-30 2000-06-08 Ciba Specialty Chemicals Holding Inc. Process for preparing acylphosphines and derivatives
GB2360283B (en) * 2000-02-08 2002-08-21 Ciba Sc Holding Ag Monoacylarylphosphines and acylphosphine oxides and sulphides
GB2365430B (en) * 2000-06-08 2002-08-28 Ciba Sc Holding Ag Acylphosphine photoinitiators and intermediates
CA2454914A1 (en) * 2001-08-21 2003-03-06 Ciba Specialty Chemicals Holding Inc. Bathochromic mono- and bis-acylphosphine oxides and sulfides and their use as photoinitiators
DE10206117A1 (de) 2002-02-13 2003-08-14 Basf Ag Acyl- und Bisacylphosphinderivate
DE10244684A1 (de) 2002-09-24 2004-04-01 Basf Ag Verfahren zur Herstellung von Acylphosphinoxiden
ATE435230T1 (de) * 2002-12-04 2009-07-15 Ciba Holding Inc Verfahren zur synthese von cycloorganylphosphanen und von di(alkali/erdalkalimetall)oligophosphandiiden
DE10315671A1 (de) * 2003-04-04 2004-10-14 Basf Ag Verfahren zur Herstellung von Acylphosphinoxid-Feststoffen
JP4949025B2 (ja) 2003-07-18 2012-06-06 チバ ホールディング インコーポレーテッド アシルホスファンおよびそれらの誘導体の製造方法
TW200523265A (en) * 2003-07-31 2005-07-16 Basf Ag A process for the preparation of acylphosphines
US7687657B2 (en) * 2004-11-23 2010-03-30 Ciba Speciality Chemicals Corporation Process for preparing acylphosphanes and derivatives thereof
EP1838721B1 (en) * 2005-01-17 2011-12-21 Basf Se Process for preparing acylphosphanes and their oxides and sulphides
DE102005005946A1 (de) * 2005-02-10 2006-08-17 Basf Ag Verfahren zur Herstellung tertiärer Phosphine
US8507726B2 (en) 2008-11-03 2013-08-13 Basf Se Photoinitiator mixtures
US9181358B2 (en) * 2009-04-20 2015-11-10 Eth Zuerich Polymer nanoparticles
CN102875598B (zh) * 2011-07-11 2016-09-07 深圳市有为化学技术有限公司 (二苯膦氧基)(均三甲苯基)甲酮和(苯膦氧基)双(均三甲苯基甲酮)的制备方法
CN102875597B (zh) * 2011-07-11 2017-05-03 深圳市有为化学技术有限公司 芳香酮膦氧杂化型化合物
CN102675365A (zh) * 2012-05-16 2012-09-19 湖北固润科技股份有限公司 一种紫外光引发剂xbpo合成方法
GB201213163D0 (en) 2012-07-24 2012-09-05 Lambson Ltd Photopolymerisation processes and novel compounds therefor
WO2014053455A1 (en) 2012-10-01 2014-04-10 ETH Zürich A process for the preparation of acylphosphanes
US20140267778A1 (en) 2013-03-15 2014-09-18 Freefly Systems, Inc. Apparatuses and methods for controlling a gimbal and other displacement systems
CN104592298B (zh) * 2014-12-31 2016-07-06 湖北固润科技股份有限公司 一种酰基膦高效光引发剂及其制备方法
CN105541913B (zh) * 2015-12-03 2017-08-25 天津久日新材料股份有限公司 一种2,4,6‑三甲基苯甲酰基二苯基氧化膦的制备方法
CN105732710A (zh) * 2016-03-16 2016-07-06 三峡大学 一种光引发剂联苯基四(2,4,6-三甲基苯甲酰基)氧化膦的制备方法及其应用
CN105732709A (zh) * 2016-03-16 2016-07-06 三峡大学 一种光引发剂2,4,6-三甲基苯甲酰二环己基氧膦，制备方法及其应用
CN107304220B (zh) * 2016-04-22 2020-03-31 江苏英力科技发展有限公司 一种“一锅法”合成2,4,6-三甲基苯甲酰基-二苯基氧化膦的方法
EP3296301A1 (en) 2016-09-19 2018-03-21 ETH Zürich A versatile process for the preparation of acylphosphines
JP6916484B2 (ja) * 2017-03-28 2021-08-11 国立大学法人千葉大学 アシルホスフィンの製造方法
EP3409680B1 (en) 2017-05-30 2021-01-06 IGM Group B.V. Synthesis of bis(acyl)phosphines by activation of unreactive metal phosphides
EP3539924A1 (en) 2018-03-14 2019-09-18 ETH Zurich Novel vinyl phosphines and photo-initiators obtainable therefrom
CN110734461A (zh) * 2018-07-20 2020-01-31 深圳市有为化学技术有限公司 化合物2,4,6-三甲基苯甲酰基二苯基氧化膦的制备
WO2020113585A1 (zh) * 2018-12-07 2020-06-11 安庆莱霆光电科技有限公司 酰基膦氧类化合物及其制备方法
CN111138491B (zh) * 2019-12-31 2022-08-05 天津久日新材料股份有限公司 一种制备光引发剂tpo同时副产氯苄的方法
CN111087425B (zh) 2020-01-10 2022-04-19 天津大学 一种大粒度苯基双(2,4,6-三甲基苯甲酰基)氧化膦晶型及其结晶方法
CN112279940B (zh) * 2020-04-17 2023-06-27 山东科技大学 一种酰基膦光引发剂及其制备方法
CN112159429B (zh) * 2020-10-29 2022-06-21 天津久日新材料股份有限公司 一种双(2,4,6-三甲基苯甲酰基)苯基氧化膦的制备方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2909994A1 (de) 1979-03-14 1980-10-02 Basf Ag Acylphosphinoxidverbindungen, ihre herstellung und verwendung
DE2962089D1 (en) 1978-07-14 1982-03-18 Basf Ag Light-curable moulding, impregnating and coating compositions and shaped articles prepared therefrom
DE3020092A1 (de) 1980-05-27 1981-12-10 Basf Ag, 6700 Ludwigshafen Acylphosphinverbindungen und ihre verwendung
DE3034697A1 (de) 1980-09-15 1982-05-06 Basf Ag, 6700 Ludwigshafen Acylphosphinsulfidverbindungen, ihre herstellung und verwendung
DE3443221A1 (de) 1984-11-27 1986-06-05 ESPE Fabrik pharmazeutischer Präparate GmbH, 8031 Seefeld Bisacylphosphinoxide, ihre herstellung und verwendung
US5218009A (en) * 1989-08-04 1993-06-08 Ciba-Geigy Corporation Mono- and di-acylphosphine oxides
RU2091385C1 (ru) 1991-09-23 1997-09-27 Циба-Гейги АГ Бисацилфосфиноксиды, состав и способ нанесения покрытий
ZA941879B (en) 1993-03-18 1994-09-19 Ciba Geigy Curing compositions containing bisacylphosphine oxide photoinitiators
TW381106B (en) * 1994-09-02 2000-02-01 Ciba Sc Holding Ag Alkoxyphenyl-substituted bisacylphosphine oxides
CA2197787A1 (en) * 1994-09-08 1996-03-14 David George Leppard Novel acylphosphine oxides
TW323274B (es) * 1994-10-13 1997-12-21 Ciba Sc Holding Ag
WO2000032612A1 (en) * 1998-11-30 2000-06-08 Ciba Specialty Chemicals Holding Inc. Process for preparing acylphosphines and derivatives
GB2360283B (en) * 2000-02-08 2002-08-21 Ciba Sc Holding Ag Monoacylarylphosphines and acylphosphine oxides and sulphides

Also Published As

Publication number Publication date
EP1135399B2 (en) 2006-08-09
DE69902485D1 (de) 2002-09-12
TW492972B (en) 2002-07-01
CZ302512B6 (cs) 2011-06-29
DE69902485T2 (de) 2003-05-08
AU1384500A (en) 2000-06-19
DE69902485T3 (de) 2007-03-15
US7214830B2 (en) 2007-05-08
JP2002531460A (ja) 2002-09-24
ATE221893T1 (de) 2002-08-15
CZ20011875A3 (cs) 2001-09-12
KR20010093124A (ko) 2001-10-27
EP1135399B1 (en) 2002-08-07
SK7272001A3 (en) 2001-12-03
AU760237B2 (en) 2003-05-08
JP4265871B2 (ja) 2009-05-20
EP1135399A1 (en) 2001-09-26
KR100653117B1 (ko) 2006-12-21
US20040248855A1 (en) 2004-12-09
WO2000032612A1 (en) 2000-06-08
US7094931B2 (en) 2006-08-22
US20060128959A1 (en) 2006-06-15
US6888031B1 (en) 2005-05-03
CA2349637C (en) 2008-12-23
CA2349637A1 (en) 2000-06-08
SK286152B6 (sk) 2008-04-07
CN1211388C (zh) 2005-07-20
CN1328564A (zh) 2001-12-26
ES2180347T5 (es) 2007-04-01

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