ES2176886T3 - Obtencion de polienaldehidos. - Google Patents

Obtencion de polienaldehidos.

Info

Publication number
ES2176886T3
ES2176886T3 ES98121943T ES98121943T ES2176886T3 ES 2176886 T3 ES2176886 T3 ES 2176886T3 ES 98121943 T ES98121943 T ES 98121943T ES 98121943 T ES98121943 T ES 98121943T ES 2176886 T3 ES2176886 T3 ES 2176886T3
Authority
ES
Spain
Prior art keywords
ethylene
procedure
products
new
condensation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98121943T
Other languages
English (en)
Inventor
August Ruttimann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
F Hoffmann La Roche AG
Original Assignee
F Hoffmann La Roche AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by F Hoffmann La Roche AG filed Critical F Hoffmann La Roche AG
Application granted granted Critical
Publication of ES2176886T3 publication Critical patent/ES2176886T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D317/18—Radicals substituted by singly bound oxygen or sulfur atoms
    • C07D317/22—Radicals substituted by singly bound oxygen or sulfur atoms etherified
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/14—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by doubly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C07C45/57—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom
    • C07C45/59—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom in five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/673—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/12—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Abstract

UN PROCEDIMIENTO PARA LA PREPARACION DE ALDEHIDOS DE POLIENO QUE CONSISTE EN QUE SE HACE REACCIONAR UN ACETAL DE POLIEN O,O - ETILENO CON UN 1 - ALCOXI - 1,3 - DIENO EN PRESENCIA DE UN ACIDO DE LEWIS O DE BRONSTED, EL PRODUCTO RESULTANTE DE LA CONDENSACION SE HIDROLIZA Y EL DERIVADO DE POLIENO OBTENIDO EN ESTA ETAPA SE DEGRADA EN CONDICIONES BASICAS O ACIDAS PARA DAR ALCOHOL. OTROS ASPECTOS DE LA INVENCION SON LOS NUEVOS ACETALES DE POLIEN - O,O - ETILENO ASI COMO LOS NUEVOS PRODUCTOS DE CONDENSACION EN ESTE PROCEDIMIENTO. LOS PRODUCTOS FINALES SON PRINCIPALMENTE CAROTENOIDES, QUE SE UTILIZAN P. E. COMO COLORANTES Y PIGMENTOS PARA ALIMENTOS, PRODUCTOS DE ALIMENTACION ANIMAL, ETC.
ES98121943T 1997-11-27 1998-11-19 Obtencion de polienaldehidos. Expired - Lifetime ES2176886T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP97120814 1997-11-27

Publications (1)

Publication Number Publication Date
ES2176886T3 true ES2176886T3 (es) 2002-12-01

Family

ID=8227688

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98121943T Expired - Lifetime ES2176886T3 (es) 1997-11-27 1998-11-19 Obtencion de polienaldehidos.

Country Status (10)

Country Link
US (1) US6153769A (es)
EP (1) EP0919547B1 (es)
JP (1) JP3961136B2 (es)
KR (1) KR100710959B1 (es)
CN (1) CN1115319C (es)
BR (1) BR9804748A (es)
CA (1) CA2254507A1 (es)
DE (1) DE59804303D1 (es)
DK (1) DK0919547T3 (es)
ES (1) ES2176886T3 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090012274A1 (en) * 2007-07-06 2009-01-08 Stephane Biltresse Unsaturated aldehyde surfaces and methods of molecular immobilization
CN102267881B (zh) * 2010-06-02 2013-07-24 绍兴文理学院 番茄红素的中间体及其中间体的制备方法
CN102267879B (zh) * 2010-06-02 2013-07-03 绍兴文理学院 番茄红素的中间体及其中间体的制备方法
CN103172504B (zh) * 2011-12-26 2014-10-08 南京工业大学 2,7-二甲基-2,4,6-辛三烯-1,8-二醛的合成方法
JP6431862B2 (ja) * 2016-03-03 2018-11-28 信越化学工業株式会社 末端共役トリエナール＝アセタール化合物及びこれを用いた末端共役トリエナール化合物の製造方法
CN108059598A (zh) * 2016-11-08 2018-05-22 华东理工大学 由巴豆酸衍生物制备多取代二烯烃的方法
CN107011136B (zh) * 2017-06-01 2023-03-03 云南博淇科技有限公司 一种反-4-癸烯醛的合成方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2573678A (en) * 1951-11-06 Preparation and pyrolysis of satu
US2165962A (en) * 1936-10-29 1939-07-11 Ig Farbenindustrie Ag Production of alkylidene diethers or ether-esters
US2827482A (en) * 1955-07-06 1958-03-18 Hoffmann La Roche Preparation of polyene aldehydes
US2827481A (en) * 1955-07-06 1958-03-18 Hoffmann La Roche Process for the manufacture of polyene aldehydes
DE1031301B (de) * 1956-12-31 1958-06-04 Basf Ag Verfahren zur Herstellung konjugiert-ungesaettigter Aldehyde oder Ketone bzw. ihrer cyclischen Acetale und Ketale
FR2338241A1 (fr) * 1976-01-16 1977-08-12 Rhone Poulenc Ind Procede de preparation d'aldehydes et de cetones aliphatiques alcoxyles
US4861764A (en) * 1986-11-17 1989-08-29 Macro Chem. Corp. Percutaneous absorption enhancers, compositions containing same and method of use
US4832059A (en) * 1987-12-08 1989-05-23 Lorillard, Inc. Citrus-flavored tobacco articles
FR2655342A1 (fr) * 1989-12-01 1991-06-07 Rhone Poulenc Sante Nouveaux intermediaires, leur procede de preparation et leur utilisation pour la synthese des vitamines a et e.
US5266708A (en) * 1989-12-01 1993-11-30 Rhone-Poulenc Nutrition Animale New intermediates, process for their preparation, and their use for the synthesis of vitamins A and E
FR2681784B1 (fr) * 1991-10-01 1995-06-09 Fabre Pierre Cosmetique Composition dermatologique et/ou cosmetologique contenant des retinouides et utilisation de nouveaux retinouides.
FR2698872B1 (fr) * 1992-12-07 1995-01-13 Rhone Poulenc Nutrition Animal Procédé de préparation de la vitamine A et composés intermédiaires utiles pour ce procédé.
DE69424719T2 (de) * 1993-06-24 2000-11-02 Hoffmann La Roche Pigmentierung mit Carotinoiden
US5763651A (en) * 1996-06-17 1998-06-09 Roche Vitamins Inc. Process for manufacturing polyene esters and acids
US5929288A (en) * 1996-06-28 1999-07-27 Roche Vitamins Inc. Process for manufacturing polyene aldehydes

Also Published As

Publication number Publication date
CN1115319C (zh) 2003-07-23
EP0919547A1 (de) 1999-06-02
DE59804303D1 (de) 2002-07-11
US6153769A (en) 2000-11-28
CN1221725A (zh) 1999-07-07
JPH11228477A (ja) 1999-08-24
DK0919547T3 (da) 2002-09-23
CA2254507A1 (en) 1999-05-27
KR100710959B1 (ko) 2007-08-16
BR9804748A (pt) 2000-05-09
KR19990045618A (ko) 1999-06-25
JP3961136B2 (ja) 2007-08-22
EP0919547B1 (de) 2002-06-05

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