ES2172178T3 - Procedimiento de preparacion de poliorgano-siloxanos (pos) con funciones tioles, los pos susceptibles de obtenerse por este procedimiento y su utilizacion principalmente en el campo de los materiales de caucho. - Google Patents

Procedimiento de preparacion de poliorgano-siloxanos (pos) con funciones tioles, los pos susceptibles de obtenerse por este procedimiento y su utilizacion principalmente en el campo de los materiales de caucho.

Info

Publication number
ES2172178T3
ES2172178T3 ES98937614T ES98937614T ES2172178T3 ES 2172178 T3 ES2172178 T3 ES 2172178T3 ES 98937614 T ES98937614 T ES 98937614T ES 98937614 T ES98937614 T ES 98937614T ES 2172178 T3 ES2172178 T3 ES 2172178T3
Authority
ES
Spain
Prior art keywords
sub
pos
radicals
procedure
sio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98937614T
Other languages
English (en)
Inventor
Pierre Barruel
Yves Bomal
Nathalie Guennouni
Gerard Mignani
Christian Priou
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhodia Chimie SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26233685&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2172178(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Rhodia Chimie SAS filed Critical Rhodia Chimie SAS
Application granted granted Critical
Publication of ES2172178T3 publication Critical patent/ES2172178T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C08G77/392—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Silicon Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paper (AREA)

Abstract

La invención se refiere a procedimiento para la preparación de poliorganosiloxanos (POS) multifuncionalizados que comprenden grupos siloxilos funcionales alcoxilos y grupos siloxilos que comprenden cada uno una función SH, que consiste en introducir la función SH mediante la reacción de H{sub,2}S en un POS precursor de fórmula: A-{(}RXSiO{{sub,a}-{(}RYSiO{{sub,b}-B en la que R es en particular un radical alquilo C{sub,1}-C{sub,6}, X es un radical alcoxilo C{sub,1}-C{sub,15}, Y es un grupo hidrocarburo C{sub,2}-C{sub,30} que incluye una instauración etilénica del que se deriva la fucionalidad SH, a es un número de 1 a 150 , b es un número de 1 a 150, el número a + b de 2 a 300 y A y B son grupos terminales que están respectivamente seleccionados en particular entre los radicales {(}R{{sub,3}SiO- tomados solos o en mezcla con los radicales {(}R{{sub,2}XSiO- y/o {(}R{{sub,2}SiO- y/o {(}X{{sub,3}SiO- y los radicales -Si{(}R{{sub,3} tomados solos o en mezcla con los radicales -SiX{(}R{{sub,2}y/o Si{(}X{{sub,2}R, y/o -Si{(}X{{sub,3}. Los POS multifuncionalizados resultantes se utilizan en particular como agente acoplador para la carga blanca - elastómero en las composiciones de elastómero natural o sintética que comprenden una carga blanca, en particular una sustancia silícea, como carga de refuerzo para la fabricación de artículos hechos en elastómero.
ES98937614T 1997-07-11 1998-07-10 Procedimiento de preparacion de poliorgano-siloxanos (pos) con funciones tioles, los pos susceptibles de obtenerse por este procedimiento y su utilizacion principalmente en el campo de los materiales de caucho. Expired - Lifetime ES2172178T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9709116 1997-07-11
FR9801513 1998-02-04

Publications (1)

Publication Number Publication Date
ES2172178T3 true ES2172178T3 (es) 2002-09-16

Family

ID=26233685

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98937614T Expired - Lifetime ES2172178T3 (es) 1997-07-11 1998-07-10 Procedimiento de preparacion de poliorgano-siloxanos (pos) con funciones tioles, los pos susceptibles de obtenerse por este procedimiento y su utilizacion principalmente en el campo de los materiales de caucho.

Country Status (26)

Country Link
US (1) US6372843B1 (es)
EP (1) EP0996660B1 (es)
JP (1) JP3437957B2 (es)
KR (1) KR20010021753A (es)
CN (1) CN1268150A (es)
AR (1) AR016766A1 (es)
AT (1) ATE215578T1 (es)
AU (1) AU732312B2 (es)
BG (1) BG104066A (es)
BR (1) BR9815506A (es)
CA (1) CA2296039A1 (es)
DE (1) DE69804622T2 (es)
DK (1) DK0996660T3 (es)
ES (1) ES2172178T3 (es)
GE (1) GEP20022805B (es)
ID (1) ID24121A (es)
IL (1) IL133910A0 (es)
MA (1) MA24603A1 (es)
NO (1) NO20000133L (es)
NZ (1) NZ502226A (es)
PL (1) PL337949A1 (es)
PT (1) PT996660E (es)
SK (1) SK202000A3 (es)
TR (1) TR200000843T2 (es)
TW (1) TW502047B (es)
WO (1) WO1999002580A1 (es)

Families Citing this family (29)

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Publication number Priority date Publication date Assignee Title
EP0921179A1 (en) * 1997-12-05 1999-06-09 Fina Research S.A. Production of olefins
US6140445A (en) 1998-04-17 2000-10-31 Crompton Corporation Silane functional oligomer
DE19905820A1 (de) * 1998-10-27 2000-05-04 Degussa Schwefelfunktionelle Polyorganosilane
US6207783B1 (en) 1999-03-11 2001-03-27 Crompton Corporation Silicone oligomers with higher alkoxy groups
DE10044989A1 (de) 2000-09-11 2002-03-21 Bayer Ag Flüssige schwefelhaltige Oligosiloxane und ihre Verwendung in Kautschukmischungen
DE10132941A1 (de) * 2001-07-06 2003-01-23 Degussa Oligomere Organosilane, Verfahren zu deren Herstellung und deren Verwendung
DE10132942A1 (de) * 2001-07-06 2003-01-23 Degussa Siloxan-Oligomere, Verfahren zu deren Herstellung und deren Verwendung
FR2849045B1 (fr) * 2002-12-19 2005-01-21 Rhodia Chimie Sa Oligomeres polyorganosiloxane portant des fonctions thiols ou episulfures et leurs procedes de preparation
WO2004056918A1 (fr) * 2002-12-19 2004-07-08 Societe De Technologie Michelin Composition de caoutchouc pour pneumatique comportant un oligomere polyorganosiloxane a titre d’agent de couplage
KR20070003883A (ko) 2004-02-09 2007-01-05 후소 야쿠힝 고교 가부시끼가이샤 핵산 검출방법 및 그 이용
DE102004061014A1 (de) * 2004-12-18 2006-06-29 Degussa Ag Kautschukmischungen
BRPI0606640A2 (pt) * 2005-03-24 2009-07-14 Bridgestone Corp mistura de borracha reforçada com sìlica com baixa emissão de compostos orgánicos voláteis (voc)
FR2886304B1 (fr) * 2005-05-26 2007-08-10 Michelin Soc Tech Composition de caoutchouc pour pneumatique comportant un systeme de couplage organosilicique
FR2886305B1 (fr) * 2005-05-26 2007-08-10 Michelin Soc Tech Composition de caoutchouc pour pneumatique comportant un agent de couplage organosilicique et un agent de recouvrement de charge inorganique
FR2886306B1 (fr) * 2005-05-26 2007-07-06 Michelin Soc Tech Composition de caoutchouc pour pneumatique comportant un agent de couplage organosiloxane
US7915368B2 (en) * 2007-05-23 2011-03-29 Bridgestone Corporation Method for making alkoxy-modified silsesquioxanes
US8501895B2 (en) * 2007-05-23 2013-08-06 Bridgestone Corporation Method for making alkoxy-modified silsesquioxanes and amino alkoxy-modified silsesquioxanes
US8962746B2 (en) * 2007-12-27 2015-02-24 Bridgestone Corporation Methods of making blocked-mercapto alkoxy-modified silsesquioxane compounds
US8794282B2 (en) 2007-12-31 2014-08-05 Bridgestone Corporation Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber
US8513371B2 (en) * 2007-12-31 2013-08-20 Bridgestone Corporation Amino alkoxy-modified silsesquioxanes and method of preparation
US8642691B2 (en) 2009-12-28 2014-02-04 Bridgestone Corporation Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber
EP2354145A1 (de) 2010-02-03 2011-08-10 Schill + Seilacher "Struktol" GmbH Verwendung von Polyorganosiloxanen bei der Verarbeitung und Vulkanisation von Kautschuk
US10532020B2 (en) 2012-08-22 2020-01-14 Revlon Consumer Products Corporation Nail coatings having enhanced adhesion
JP6070103B2 (ja) * 2012-11-21 2017-02-01 横浜ゴム株式会社 タイヤトレッド用ゴム組成物および空気入りタイヤ
CN105324103B (zh) 2013-04-22 2018-07-20 指甲创意设计股份有限公司 具有增强的粘附力的指甲涂料
WO2015100449A2 (en) * 2013-12-27 2015-07-02 Bridgestone Corporation Vulcanizates and tire components prepared from compositions including mercapto-functional siloxanes
EP3240822B1 (en) * 2014-12-30 2023-07-26 Bridgestone Corporation Terminal-functionalized polymer and related methods
CN107406689A (zh) 2014-12-31 2017-11-28 株式会社普利司通 用于将钢合金粘附到橡胶的氨基烷氧基改性倍半硅氧烷粘合剂
CN106496567B (zh) * 2016-12-05 2019-05-03 山东大学 一种用于可逆加成-断裂链转移自由基聚合的有机硅三硫酯及其制备方法与应用

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US2960492A (en) * 1954-12-07 1960-11-15 Morton Maurice Sulfur-containing organosiloxane polymers, and processes for making the same
GB1310379A (en) * 1970-12-10 1973-03-21 Ppg Industries Inc Tire tread
US4082790A (en) * 1974-12-11 1978-04-04 Dow Corning Corporation Method of preparing mercaptans
DD299187B5 (de) * 1990-07-13 1996-05-15 Huels Silicone Gmbh Verfahren zur Herstellung von schwefelhaltigen Organosiliciumverbindungen
US5366772A (en) * 1993-07-28 1994-11-22 Xerox Corporation Fuser member
FR2727119B1 (fr) * 1994-11-18 1997-01-03 Rhone Poulenc Chimie Polyorganosiloxanes fonctionnalises et l'un de leurs procedes de preparation
FR2727118B1 (fr) * 1994-11-18 1997-01-03 Rhone Poulenc Chimie Polyorganosiloxanes fonctionnalises et l'un de leurs procedes de preparation

Also Published As

Publication number Publication date
KR20010021753A (ko) 2001-03-15
NO20000133L (no) 2000-03-10
BR9815506A (pt) 2000-10-31
AU732312B2 (en) 2001-04-12
PT996660E (pt) 2002-08-30
BG104066A (en) 2001-01-31
MA24603A1 (fr) 1999-04-01
EP0996660B1 (fr) 2002-04-03
NO20000133D0 (no) 2000-01-10
PL337949A1 (en) 2000-09-11
TR200000843T2 (tr) 2000-10-23
AR016766A1 (es) 2001-08-01
NZ502226A (en) 2001-12-21
ATE215578T1 (de) 2002-04-15
WO1999002580A1 (fr) 1999-01-21
JP3437957B2 (ja) 2003-08-18
DE69804622T2 (de) 2002-09-12
IL133910A0 (en) 2001-04-30
CA2296039A1 (fr) 1999-01-21
CN1268150A (zh) 2000-09-27
SK202000A3 (en) 2000-08-14
GEP20022805B (en) 2002-09-25
DE69804622D1 (de) 2002-05-08
ID24121A (id) 2000-07-06
AU8634798A (en) 1999-02-08
DK0996660T3 (da) 2002-07-01
JP2001512146A (ja) 2001-08-21
EP0996660A1 (fr) 2000-05-03
TW502047B (en) 2002-09-11
US6372843B1 (en) 2002-04-16

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