ES2169098T3 - Poliisocianatos de baja energia superficial y su uso en composiciones de recubrimiento de uno o dos componentes. - Google Patents

Poliisocianatos de baja energia superficial y su uso en composiciones de recubrimiento de uno o dos componentes.

Info

Publication number
ES2169098T3
ES2169098T3 ES95113753T ES95113753T ES2169098T3 ES 2169098 T3 ES2169098 T3 ES 2169098T3 ES 95113753 T ES95113753 T ES 95113753T ES 95113753 T ES95113753 T ES 95113753T ES 2169098 T3 ES2169098 T3 ES 2169098T3
Authority
ES
Spain
Prior art keywords
groups
alofanate
polyisocianate
sub
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95113753T
Other languages
English (en)
Inventor
Philip E Yeske
Edward P Squiller
William E Slack
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Bayer Corp
Original Assignee
Bayer AG
Bayer Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG, Bayer Corp filed Critical Bayer AG
Application granted granted Critical
Publication of ES2169098T3 publication Critical patent/ES2169098T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/8083—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen
    • C08G18/8087—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen containing halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/30—Only oxygen atoms
    • C07D251/34—Cyanuric or isocyanuric esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5003—Polyethers having heteroatoms other than oxygen having halogens
    • C08G18/5015—Polyethers having heteroatoms other than oxygen having halogens having fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7806—Nitrogen containing -N-C=0 groups
    • C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7837—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing allophanate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8054—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/38

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)

Abstract

LA PRESENTE INVENCION SE REFIERE A UNA MEZCLA DE POLIISOCIANATO I) QUE TIENE UN CONTENIDO NCO DE 5 A 35% EN PESO Y PREPARADO A PARTIR DE UN DIISOCIANATO ORGANICO, II) QUE CONTIENE AL MENOS 1% EN PESO DE GRUPOS DE ISOCIANATO (CALCULADO COMO N{SUB,3},C{SUB,3},O{SUB,3} MW126), III) QUE CONTIENE GRUPOS ALOFANATO EN UNA CANTIDAD TAL QUE HAY MAS EQUIVALENTE DE GRUPOS ALOFANATO QUE GRUPO URETANO Y IV) QUE CONTIENE FLUOR (CALCULADO COMO, F, AW 19) EN UNA CANTIDAD DE 0.001 A 50% EN PESO DONDE LOS PORCENTAJES ANTERIORES SE BASAN EN CONTENIDOS SOLIDOS DE LA MEZCLA DE POLIISOCIANATO, EXCLUYENDO CUALQUIER DIISOCIANATO, Y DONDE EL FLUOR SE INCORPORA REACCIONANDO UN GRUPO ISOCIANATO CON UN COMPUESTO QUE CONTIENE DOS O MAS ATOMOS DE CARBONO, UNO O MAS GRUPOS HIDROXILO Y UNO O MAS ATOMOS DE FLUOR PARA FORMAR GRUPOS URETANOS Y CONVERTIR UNA CANTIDAD SUFICIENTE DE ESTOS GRUPOS URETANOS EN GRUPOS ALOFANATO PARA SATISFACER LAS CONDICIONES DE III) SIEMPRE QUE LA MEZCLA DE POLIISOCIANATO CONTENGA SUFICIENTES GRUPOS DE ALOFANATO PARA ASEGURAR QUE LA MEZCLA DE POLIISOCIANATO PERMANECE ESTABLE Y HOMOGENEA EN ALMACENAMIENTO DURANTE 3 MESES A 25 (GRADOS) C. LA PRESENTE INVENCION TAMBIEN SE DIRIGE A UN PROCESO PARA LA PRODUCCION DE ESTA MEZCLA DE POLIISOCIANATO Y A SU USO, OPCIONALMENTE EN FORMA BLOQUEADA, COMO UN COMPONENTE EN COMPOSICIONES DE REVESTIMIENTO DE UNO O DOS COMPONENTES.
ES95113753T 1994-09-14 1995-09-01 Poliisocianatos de baja energia superficial y su uso en composiciones de recubrimiento de uno o dos componentes. Expired - Lifetime ES2169098T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/306,553 US5576411A (en) 1994-09-14 1994-09-14 Low surface energy polyisocyanates and their use in one-or two component coating compositions

Publications (1)

Publication Number Publication Date
ES2169098T3 true ES2169098T3 (es) 2002-07-01

Family

ID=23185818

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95113753T Expired - Lifetime ES2169098T3 (es) 1994-09-14 1995-09-01 Poliisocianatos de baja energia superficial y su uso en composiciones de recubrimiento de uno o dos componentes.

Country Status (6)

Country Link
US (1) US5576411A (es)
EP (1) EP0702041B1 (es)
JP (1) JPH08104728A (es)
CA (1) CA2156244C (es)
DE (1) DE69524508T2 (es)
ES (1) ES2169098T3 (es)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19534624A1 (de) * 1995-09-18 1997-03-20 Bayer Ag Allophanatgruppen aufweisende Polyisocyanate auf Basis Diphenylmethandiisocyanat mit überwiegend oder vollständig blockierten Isocyanatgruppen
US5747629A (en) * 1996-12-16 1998-05-05 Bayer Corporation Low surface energy polyisocyanates and their use in one-or two-component coating compositions
DE19731864A1 (de) * 1997-07-24 1999-01-28 Bayer Ag Wäßrige PUR-Dispersionen mit verbesserten Eigenschaften
US6028158A (en) * 1997-12-31 2000-02-22 Bayer Corporation Freeze-stable allophanate-modified toluene diisocyanate trimers
US5955609A (en) * 1997-12-31 1999-09-21 Bayer Corporation Trimer catalyst system for aliphatic and aromatic isocyanates
US6228472B1 (en) 1998-12-21 2001-05-08 Basf Corporation Process for synthesis of allophanate compounds and compositions including the product thereof
US6214470B1 (en) 1998-12-21 2001-04-10 Basf Corporation Cathodic electrocoat composition
DE19910810C2 (de) * 1999-03-11 2001-06-28 Bayer Ag Hydrophilierbare Blockcopolymere, Verfahren zu ihrer Herstellung und deren Verwendung
DE19910811C2 (de) * 1999-03-11 2002-11-14 Sunyx Surface Nanotechnologies Hydrophilierbare Blockcopolymere
ITMI991303A1 (it) 1999-06-11 2000-12-11 Ausimont Spa Oligouretani fluorurati
US6362302B1 (en) 1999-11-29 2002-03-26 Carl E. Boddie Method and compositions for spray molding polyurethane three dimensional objects
IT1317725B1 (it) 2000-01-17 2003-07-15 Ausimont Spa Composizioni per coatings a base di (per)fluoropolieteri.
DE10046473A1 (de) 2000-09-20 2002-03-28 Bayer Ag Fluorhaltige blockierte Isocyanate
JP4678466B2 (ja) * 2001-08-09 2011-04-27 Ｄｉｃ株式会社 エネルギー線硬化型樹脂組成物
US20060223970A1 (en) * 2005-03-31 2006-10-05 Bayer Materialscience Llc Low surface energy polyisocyanates and their use in one- or two-component coating compositions
US20060223969A1 (en) * 2005-03-31 2006-10-05 Bayer Materialscience Llc Low surface energy polyisocyanates and their use in one- or two-component coating compositions
US20070032624A1 (en) * 2005-08-05 2007-02-08 Bayer Materialscience Llc Low surface energy polyisocyanates and their use in one- or two-component coating compositions
US20070032623A1 (en) * 2005-08-05 2007-02-08 Bayer Material Science Llc Low surface energy polyisocyanates and their use in one-or two-component coating compositions
US20070032626A1 (en) * 2005-08-05 2007-02-08 Bayer Materialscience Llc Low surface energy polyisocyanates and their use in two-component coating compositions
US20070032625A1 (en) * 2005-08-05 2007-02-08 Bayer Materialscience Llc Low surface energy polyisocyanates and their use in one-or two-component coating compositions
US7759447B2 (en) * 2005-11-17 2010-07-20 Bayer Materialscience Llc Low surface energy, ethylenically unsaturated polyisocyanate addition compounds and their use in coating compositions
US20070112162A1 (en) * 2005-11-17 2007-05-17 Bayer Materialscience Llc Low surface energy, ethylenically unsaturated polyisocyanate addition compounds and their use in coating compositions
US20070112161A1 (en) * 2005-11-17 2007-05-17 Bayer Materialscience Llc Low surface energy, ethylenically unsaturated polyisocyanate addition compounds and their use in coating compositions
US20070112164A1 (en) * 2005-11-17 2007-05-17 Bayer Materialscience Llc Low surface energy, ethylenically unsaturated polyisocyanate addition compounds and their use in coating compositions
WO2008065732A1 (fr) * 2006-11-27 2008-06-05 Nippon Polyurethane Industry Co., Ltd. Procédé de production d'un mélange à base d'isocyanate modifié contenant une liaison allophanate et une liaison isocyanurate
US20090131581A1 (en) * 2007-11-19 2009-05-21 Wylie Amy S Aqueous, stain-resistant coating compositions
US8415471B2 (en) * 2007-11-29 2013-04-09 Baver MaterialScience LLC Flexible cycloaliphatic diisocyanate trimers
JP2009227927A (ja) * 2008-03-25 2009-10-08 Nippon Polyurethane Ind Co Ltd ポリイソシアネート及び二液型コーティング剤
US8544987B2 (en) * 2010-08-20 2013-10-01 Xerox Corporation Thermally stable oleophobic low adhesion coating for inkjet printhead front face
PL238515B1 (pl) 2016-01-26 2021-08-30 Politechnika Rzeszowska Im Ignacego Lukasiewicza Blokowane poliizocyjaniany, ich zastosowanie oraz poliuretanowe lakiery proszkowe
PL238230B1 (pl) 2016-09-20 2021-07-26 Politechnika Rzeszowska Im Ignacego Lukasiewicza Blokowane poliizocyjaniany, sposób ich wytwarzania i zastosowanie
JP7159613B2 (ja) * 2018-05-17 2022-10-25 東ソー株式会社 ポリイソシアネート組成物およびそれを用いた塗料組成物

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US377993A (en) 1888-02-14 Calvin e
US4477643A (en) * 1984-04-20 1984-10-16 The United States Of America As Represented By The Secretary Of The Navy Fluorinated polyurethanes
US4606737A (en) * 1984-06-26 1986-08-19 Minnesota Mining And Manufacturing Company Fluorochemical allophanate compositions and fibrous substrates treated therewith
US4701480A (en) 1985-09-23 1987-10-20 Mobay Corporation Stable, aqueous dispersions of polyurethane-ureas
GB8809864D0 (en) * 1988-04-26 1988-06-02 Ici Plc Polyurethanes
US5124427A (en) * 1991-01-22 1992-06-23 Miles Inc. Polyisocyanates containing allophanate and isocyanurate groups, a process for their production and their use in two-component coating compositions
US5194487A (en) 1991-01-22 1993-03-16 Miles Inc. Two-component aqueous polyurethane dispersions with reduced solvent content and coatings prepared therefrom with improved gloss
US5208334A (en) * 1991-07-22 1993-05-04 Miles Inc. Process for the production of polyisocyanates containing allophanate and isocyanurate groups
US5235018A (en) * 1991-07-22 1993-08-10 Miles Inc. Polyisocyanates containing allophanate and isocyanurate groups, a process for their production and their use in two-component coating compositions
US5200489A (en) 1992-02-27 1993-04-06 Miles Inc. Water dispersible polyisocyanates
DE4136768A1 (de) * 1991-11-08 1993-05-13 Bayer Ag Die verwendung von polyisocyanatloesungen zur impraegnierung von mineralischen substanzen
DE69324784T2 (de) * 1992-12-30 1999-10-21 Ici Plc Verfahren zur Herstellung von Hartschaumstoffen
US5283311A (en) * 1992-12-30 1994-02-01 Basf Corporation Fatty prepolymers and fatty-modified polyisocyanates as internal mold release agents
US5294662A (en) * 1993-04-15 1994-03-15 Minnesota Mining And Manufacturing Company Aqueous fluorochemical compositions and coatings therefrom

Also Published As

Publication number Publication date
JPH08104728A (ja) 1996-04-23
DE69524508T2 (de) 2002-05-29
CA2156244C (en) 2008-04-29
US5576411A (en) 1996-11-19
DE69524508D1 (de) 2002-01-24
EP0702041B1 (en) 2001-12-12
CA2156244A1 (en) 1996-03-15
MX9503659A (es) 1997-07-31
EP0702041A1 (en) 1996-03-20

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