ES2167314T3 - Catalizadores para eliminar compuestos de azufre de gases tecnicos, procedimiento para su preparacion y su uso. - Google Patents

Catalizadores para eliminar compuestos de azufre de gases tecnicos, procedimiento para su preparacion y su uso.

Info

Publication number
ES2167314T3
ES2167314T3 ES92101510T ES92101510T ES2167314T3 ES 2167314 T3 ES2167314 T3 ES 2167314T3 ES 92101510 T ES92101510 T ES 92101510T ES 92101510 T ES92101510 T ES 92101510T ES 2167314 T3 ES2167314 T3 ES 2167314T3
Authority
ES
Spain
Prior art keywords
catalysts
sulfur compounds
procedure
preparation
technical gases
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92101510T
Other languages
English (en)
Inventor
Otto Dr Immel
Harald Dr Muller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Application granted granted Critical
Publication of ES2167314T3 publication Critical patent/ES2167314T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B01D53/8606—Removing sulfur compounds only one sulfur compound other than sulfur oxides or hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B01D53/8612—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8873—Zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/34—Purifying combustible gases containing carbon monoxide by catalytic conversion of impurities to more readily removable materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Treating Waste Gases (AREA)

Abstract

LA INVENCION TRATA DE CATALIZADORES CUYOS COMPUESTOS DE AZUFRE DE LOS GASES TECNICOS SE PUEDEN SEPARAR PRACTICAMENTE EN SU TOTALIDAD. METODO PARA LA ELABORACION DE ESTOS CATALIZADORES, ASI COMO SU UTILIZACION PARA LA SEPARACION DE LOS COMPUESTOS DE AZUFRE DE GASES TECNICOS.
ES92101510T 1991-02-12 1992-01-30 Catalizadores para eliminar compuestos de azufre de gases tecnicos, procedimiento para su preparacion y su uso. Expired - Lifetime ES2167314T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4104202A DE4104202A1 (de) 1991-02-12 1991-02-12 Katalysatoren zur entfernung von schwefelverbindungen aus technischen gasen, verfahren zu deren herstelllung sowie deren verwendung

Publications (1)

Publication Number Publication Date
ES2167314T3 true ES2167314T3 (es) 2002-05-16

Family

ID=6424871

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92101510T Expired - Lifetime ES2167314T3 (es) 1991-02-12 1992-01-30 Catalizadores para eliminar compuestos de azufre de gases tecnicos, procedimiento para su preparacion y su uso.

Country Status (10)

Country Link
US (2) US5763350A (es)
EP (1) EP0499095B1 (es)
JP (1) JP2923711B2 (es)
KR (1) KR100223127B1 (es)
BR (1) BR9200468A (es)
CA (1) CA2060948A1 (es)
DE (2) DE4104202A1 (es)
ES (1) ES2167314T3 (es)
MX (1) MX9200401A (es)
ZA (1) ZA92975B (es)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL1002524C2 (nl) * 1996-03-04 1997-09-05 Gastec Nv Katalysator voor de selectieve oxidatie van zwavelverbindingen tot elementaire zwavel, werkwijze voor de bereiding van een dergelijke kata- lysator en werkwijze voor de selectieve oxidatie van zwavelverbindingen elementaire zwavel.
FR2747053B1 (fr) * 1996-04-03 1998-10-02 Rhone Poulenc Chimie Utilisation pour l'oxydation directe des composes soufres en soufre et/ou sulfates a basse temperature d'un catalyseur a base de cuivre
WO2004056949A1 (de) * 2002-12-19 2004-07-08 Basf Aktiengesellschaft Verfahren zur entfernung von schwefelverbindungen aus kohlenwasserstoffhaltigen gasen
DE10301434A1 (de) * 2003-01-16 2004-07-29 Bayer Ag Verfahren zur CO-Gas-Entschwefelung
EP1890791A1 (en) 2005-05-23 2008-02-27 Shell Internationale Research Maatschappij B.V. Process for the removal of contaminants
US8802035B2 (en) * 2005-06-21 2014-08-12 Waters Technologies Corporation Apparatus and methods for performing steps of a multi-step process in parallel
US20070031302A1 (en) * 2005-08-08 2007-02-08 Carsten Wittrup Method and apparatus for purifying a gas
KR100685658B1 (ko) * 2005-08-19 2007-02-26 한국과학기술연구원 구리 페라이트 촉매 및 이를 이용한 삼산화황 분해방법
WO2008156524A1 (en) * 2007-06-14 2008-12-24 Exxonmobil Upstream Research Company Process for purification of hydrocarbons
WO2009019238A1 (de) * 2007-08-09 2009-02-12 Basf Se Katalysator und verfahren zur entschwefelung von kohlenwasserstoffhaltigen gasen
US7964114B2 (en) * 2007-12-17 2011-06-21 Sud-Chemie Inc. Iron-based water gas shift catalyst
JP5469169B2 (ja) * 2008-09-01 2014-04-09 ビーエーエスエフ ソシエタス・ヨーロピア 吸着材料、及び炭化水素ガスの脱硫方法
DE102009046741A1 (de) 2008-11-18 2010-05-27 Helmholtz-Zentrum Für Umweltforschung Gmbh - Ufz Verfahren und Vorrichtung zur selektiven Entfernung von Schwefelkohlenstoff aus Strippgasen
EA021535B9 (ru) * 2010-07-05 2016-05-31 Хальдор Топсеэ А/С Способ получения этанола и высших спиртов
KR101048425B1 (ko) 2010-07-28 2011-07-11 조명호 탈황촉매 및 그 제조 방법
DE102011003786A1 (de) * 2011-02-08 2012-08-09 Helmholtz-Zentrum Für Umweltforschung Gmbh - Ufz Verfahren zur selektiven Entschwefelung von Strippgasen
BR112013026811A2 (pt) * 2011-04-18 2017-01-10 Mi Llc sistema e método para regeneração de catalisador
US8703084B2 (en) * 2012-02-17 2014-04-22 Archon Technologies Ltd. Removal of sulfur compounds from a gas stream
KR101403805B1 (ko) * 2012-09-04 2014-06-11 재단법인 포항산업과학연구원 코크 오븐 가스에 함유된 산성가스 제거용 촉매 및 이의 제조방법
CN103864102B (zh) * 2012-12-18 2018-02-06 英威达纺织（英国）有限公司 用于减少安德卢梭法中催化剂中毒的装置和方法
CN104437496B (zh) * 2014-10-30 2017-02-15 沈阳三聚凯特催化剂有限公司 一种脱硫剂的制备方法
US11731080B2 (en) 2018-12-21 2023-08-22 King Fahd University Of Petroleum And Minerals Method of sweetening hydrocarbon gas from hydrogen sulfide
CN113856665A (zh) * 2021-11-02 2021-12-31 浙江工业大学 一种用于脱除有机硫的氧化铝基催化剂的制备方法及其应用

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3518208A (en) * 1966-04-26 1970-06-30 Girdler Suedchemie Katalysator Catalyst for the water gas shift reaction
FR1541573A (fr) * 1966-10-24 1968-10-04 Shell Int Research Procédé pour l'élimination de l'oxygène et de l'oxysulfure de carbone des gaz
NL6615007A (es) * 1966-10-24 1968-04-25
US3536755A (en) * 1966-10-26 1970-10-27 Dobres Amalie B Process for producing acetic acid by catalytic oxidation of propylene
DE1667590B2 (de) * 1967-08-03 1975-12-04 Laboratorium Fuer Adsorptionstechnik Gmbh, 6000 Frankfurt Verfahren zur katalytischer! Hydrolyse von Kohlenoxysulfid zu Schwefelwasserstoff
SU566624A1 (ru) * 1975-03-19 1977-07-30 Среднеазиатский Научно-Исследовательский Институт Нефтеперерабатывающей Промышленности Катализатор дл сероочистки углеводородного газа
JPS5527102A (en) * 1978-07-15 1980-02-27 Osaka Sekiyu Kagaku Kk Removal of carbonyl sulfide with active alumina
DE3020975A1 (de) * 1980-06-03 1981-12-10 Krupp-Koppers Gmbh, 4300 Essen Verfahren zur katalytischen behandlung von partialoxidationsrohgas
US4332781A (en) * 1980-12-29 1982-06-01 Shell Oil Company Removal of hydrogen sulfide and carbonyl sulfide from gas-streams
JPS58193738A (ja) * 1982-05-06 1983-11-11 Mitsubishi Heavy Ind Ltd 水素富化ガス製造用触媒
DE3228481A1 (de) * 1982-07-30 1984-02-02 VEG-Gasinstituut N.V., 7300 Apeldoorn Reaktionsmasse, verfahren zu ihrer herstellung und deren verwendung
DE3740439A1 (de) * 1987-11-28 1989-06-08 Veg Gasinstituut Nv Verfahren zur entfernung von schwefelwasserstoff aus gasen

Also Published As

Publication number Publication date
US5985227A (en) 1999-11-16
EP0499095B1 (de) 2001-11-14
KR100223127B1 (ko) 1999-10-15
MX9200401A (es) 1992-08-01
JPH0568884A (ja) 1993-03-23
BR9200468A (pt) 1992-10-20
EP0499095A1 (de) 1992-08-19
CA2060948A1 (en) 1992-08-13
JP2923711B2 (ja) 1999-07-26
US5763350A (en) 1998-06-09
DE59209928D1 (de) 2001-12-20
DE4104202A1 (de) 1992-08-13
ZA92975B (en) 1994-10-06
KR920016140A (ko) 1992-09-24

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