ES2165190T3 - Foto-polimerizacion de cloruro de vinilo utilizando catalizadores metalocenos. - Google Patents

Foto-polimerizacion de cloruro de vinilo utilizando catalizadores metalocenos.

Info

Publication number
ES2165190T3
ES2165190T3 ES98942972T ES98942972T ES2165190T3 ES 2165190 T3 ES2165190 T3 ES 2165190T3 ES 98942972 T ES98942972 T ES 98942972T ES 98942972 T ES98942972 T ES 98942972T ES 2165190 T3 ES2165190 T3 ES 2165190T3
Authority
ES
Spain
Prior art keywords
vinyl chloride
catalyst
polymerization
photo
moles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98942972T
Other languages
English (en)
Inventor
Sandor M Nagy
Ramesh Krishnamurti
Mary K Cocoman
Walter M Opalinski
Thomas F Smolka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oxy Vinyls LP
Original Assignee
Oxy Vinyls LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oxy Vinyls LP filed Critical Oxy Vinyls LP
Application granted granted Critical
Publication of ES2165190T3 publication Critical patent/ES2165190T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F114/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F114/02—Monomers containing chlorine
    • C08F114/04—Monomers containing two carbon atoms
    • C08F114/06—Vinyl chloride

Abstract

Un método para fabricar poli(cloruro de vinilo) terminado en alquilo que comprende la polimerización de monómero cloruro de vinilo en presencia de luz procedente de una fuente de luz en la región UVo la región visible del espectro a por lo menos 1W por 100 ml de volumen de reacción, un catalizador metaloceno, aproximadamente 1 a 2000 moles de un co-catalizador que contiene aluminio y grupo alquilo por mol de dicho catalizador, y hasta aproximadamente 500 moles de una base Lewis por mol de aluminio en dicho co-catalizador, con la particularidad de que dicho grupo alquilo en el co-catalizador mencionado que contiene aluminio se transfiere al poli(cloruro de vinilo).
ES98942972T 1997-10-30 1998-10-23 Foto-polimerizacion de cloruro de vinilo utilizando catalizadores metalocenos. Expired - Lifetime ES2165190T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/961,516 US6025407A (en) 1997-10-30 1997-10-30 Photo-polymerization of vinyl chloride using metallocene catalysts

Publications (1)

Publication Number Publication Date
ES2165190T3 true ES2165190T3 (es) 2002-03-01

Family

ID=25504578

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98942972T Expired - Lifetime ES2165190T3 (es) 1997-10-30 1998-10-23 Foto-polimerizacion de cloruro de vinilo utilizando catalizadores metalocenos.

Country Status (9)

Country Link
US (1) US6025407A (es)
EP (1) EP1025137B1 (es)
JP (1) JP2001521950A (es)
AU (1) AU740714B2 (es)
BR (1) BR9813298A (es)
CO (1) CO5050393A1 (es)
DE (1) DE69801838T2 (es)
ES (1) ES2165190T3 (es)
WO (1) WO1999023124A1 (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1046642B1 (de) * 1999-04-22 2004-06-30 Basell Polyolefine GmbH Verfahren zur Herstellung von silylverbrückten Fluorenyl-Cyclopentadienyl-Liganden und silylverbrückten Fluorenyl-Cyclopentadienyl-Metallocenen
US6303718B1 (en) 1999-09-17 2001-10-16 Bayer Aktiengesellschaft Composition based on fluorine-containing metal complexes
DE19932409A1 (de) * 1999-07-14 2001-01-18 Bayer Ag Zusammensetzung auf Basis von fluorhaltigen Metallkomplexen
US6399722B1 (en) * 1999-12-01 2002-06-04 Univation Technologies, Llc Solution feed of multiple catalysts
JP4742410B2 (ja) * 2000-09-06 2011-08-10 東ソー株式会社 塩化ビニル系重合体の製造方法
US6410764B1 (en) 2001-01-18 2002-06-25 Equistar Chemicals, L.P. Method for preparation of boratabenzene derivatives
DE60322365D1 (de) * 2002-04-12 2008-09-04 Dow Global Technologies Inc Azaborolylkomplexe mit metallen der gruppe 4, katalysatoren und verfahren zur olefinepolymerisation
GB0220681D0 (en) * 2002-09-05 2002-10-16 Borealis Tech Oy Process
WO2013181345A2 (en) * 2012-05-30 2013-12-05 The University Of Toledo Synthesis of polymeric ionic liquids using a photochemical polymerization process
EP2450728A1 (en) 2010-11-05 2012-05-09 British Telecommunications Public Limited Company Optical fibre tray
DE102011102673A1 (de) 2011-05-28 2012-11-29 Sebastian De Nardo Zweistufiges Verfahren zur Herstellung von hochmolekularen Polyolefinen

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE508768A (es) * 1951-01-26
US3364190A (en) * 1964-04-27 1968-01-16 Standard Oil Co Process for polymerizing propylene to syndiotactic polypropylene
NL139324B (nl) * 1968-03-28 1973-07-16 Pechiney Saint Gobain Werkwijze voor het polymeriseren of copolymeriseren van vinylchloride bij aanwezigheid van een ziegler-katalysator.
US3886130A (en) * 1970-01-21 1975-05-27 Ceskoslovenska Akademie Ved Catalyzed production of heat stable fiber-forming vinyl chloride
JPS5148795B2 (es) * 1974-05-18 1976-12-22
US5089536A (en) * 1982-11-22 1992-02-18 Minnesota Mining And Manufacturing Company Energy polmerizable compositions containing organometallic initiators
US4662211A (en) * 1985-12-16 1987-05-05 K. J. Law Engineers, Inc. Measuring friction characteristics of vehicle travel surfaces
PL147864B1 (en) * 1985-12-16 1989-08-31 Wojskowa Akad Tech A method of liquid crystal compounds with a terminal izotiocyanate group getting
US4927797A (en) * 1987-04-09 1990-05-22 Fina Technology, Inc. Catalyst system for the polymerization of olefins
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5243002A (en) * 1988-07-15 1993-09-07 Fina Technology, Inc. Process and catalyst for producing syndiotactic polymers
US5223467A (en) * 1988-07-15 1993-06-29 Fina Technology, Inc. Process and catalyst for producing syndiotactic polymers
US5225500A (en) * 1988-07-15 1993-07-06 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
ES2086397T5 (es) * 1989-10-30 2005-07-16 Fina Technology, Inc. Adicion de alkiloaluminio para un catalizador metaloceno mejorado.
US5432139A (en) * 1992-03-04 1995-07-11 Fina Technology, Inc. Catalyst formulation and polymerization process
DE59308118D1 (de) * 1992-12-01 1998-03-12 Merck Patent Gmbh Koordinations-katalysatorsysteme
JPH07208736A (ja) * 1994-10-11 1995-08-11 Hitachi Home Tec Ltd 温風暖房器
JPH08208736A (ja) * 1994-11-28 1996-08-13 Chisso Corp 塩化ビニル系樹脂の製造方法
US5677405A (en) * 1995-05-24 1997-10-14 The B.F. Goodrich Company Homopolymers and copolymers of cationically polymerizable monomers and method of their preparation
US5670595A (en) * 1995-08-28 1997-09-23 Exxon Chemical Patents Inc. Diene modified polymers
US5807800A (en) * 1997-02-11 1998-09-15 Fina Technology, Inc. Process for producing stereospecific polymers
US5756611A (en) * 1997-02-21 1998-05-26 Lyondell Petrochemical Company α-olefin polymerization catalysts

Also Published As

Publication number Publication date
AU740714B2 (en) 2001-11-15
JP2001521950A (ja) 2001-11-13
BR9813298A (pt) 2000-08-29
AU9092498A (en) 1999-05-24
DE69801838T2 (de) 2002-04-11
WO1999023124A1 (en) 1999-05-14
EP1025137B1 (en) 2001-09-26
EP1025137A1 (en) 2000-08-09
CO5050393A1 (es) 2001-06-27
DE69801838D1 (de) 2001-10-31
US6025407A (en) 2000-02-15

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