ATE331725T1 - Verbrückte metallocenverbindungen als olefinpolymerisationskatalysatoren - Google Patents

Verbrückte metallocenverbindungen als olefinpolymerisationskatalysatoren

Info

Publication number
ATE331725T1
ATE331725T1 AT00990617T AT00990617T ATE331725T1 AT E331725 T1 ATE331725 T1 AT E331725T1 AT 00990617 T AT00990617 T AT 00990617T AT 00990617 T AT00990617 T AT 00990617T AT E331725 T1 ATE331725 T1 AT E331725T1
Authority
AT
Austria
Prior art keywords
olefin polymerization
polymerization catalysts
metallocene compounds
bridged metallocene
bridged
Prior art date
Application number
AT00990617T
Other languages
English (en)
Inventor
Paolo Biagini
Roberto Santi
Giuliana Schimperna
Maria Caldararo
Giampietro Borsotti
Francesco Masi
Original Assignee
Polimeri Europa Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polimeri Europa Spa filed Critical Polimeri Europa Spa
Application granted granted Critical
Publication of ATE331725T1 publication Critical patent/ATE331725T1/de

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/10Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465Indenes; Completely or partially hydrogenated indenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00Systems containing two condensed rings
    • C07C2602/02Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AT00990617T 1999-12-03 2000-11-27 Verbrückte metallocenverbindungen als olefinpolymerisationskatalysatoren ATE331725T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT1999MI002536A IT1314261B1 (it) 1999-12-03 1999-12-03 Composti metallocenici pontati, processo per la loro preparazione eloro uso come catalizzatori per la polimerizzazione di olefine.

Publications (1)

Publication Number Publication Date
ATE331725T1 true ATE331725T1 (de) 2006-07-15

Family

ID=11384070

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00990617T ATE331725T1 (de) 1999-12-03 2000-11-27 Verbrückte metallocenverbindungen als olefinpolymerisationskatalysatoren

Country Status (26)

Country Link
US (1) US6984703B1 (de)
EP (1) EP1250342B1 (de)
JP (1) JP3921601B2 (de)
KR (1) KR20020061625A (de)
CN (1) CN100368417C (de)
AR (1) AR031540A1 (de)
AT (1) ATE331725T1 (de)
AU (1) AU777085B2 (de)
BR (1) BR0016134B1 (de)
CA (1) CA2393175C (de)
CZ (1) CZ20021821A3 (de)
DE (1) DE60029137T2 (de)
ES (1) ES2267602T3 (de)
HR (1) HRP20020461B1 (de)
HU (1) HUP0203804A3 (de)
IT (1) IT1314261B1 (de)
MX (1) MXPA02005494A (de)
MY (1) MY134869A (de)
NO (1) NO333543B1 (de)
PL (1) PL202964B1 (de)
PT (1) PT1250342E (de)
RU (1) RU2238277C2 (de)
SK (1) SK7462002A3 (de)
TW (1) TW593324B (de)
WO (1) WO2001040238A1 (de)
ZA (1) ZA200204342B (de)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7091196B2 (en) 2002-09-26 2006-08-15 Rib-X Pharmaceuticals, Inc. Bifunctional heterocyclic compounds and methods of making and using same
JP5383037B2 (ja) 2004-02-27 2014-01-08 リブ−エックス ファーマシューティカルズ,インコーポレイテッド 大環状化合物およびそれらを製造し使用する方法
EP2215129A2 (de) * 2007-08-27 2010-08-11 Borealis Technology OY Katalysatoren
EP2223944A1 (de) 2009-02-26 2010-09-01 Borealis AG Verfahren zur Herstellung von Semikristallin-Propylenpolymeren
EP2468758B1 (de) 2009-08-18 2017-12-27 LG Chem, Ltd. Neuartige verbindung, katalysatorzusammensetzung damit und verfahren zur herstellung eines zyklischen olefinpolymers damit
JP6036108B2 (ja) * 2012-03-29 2016-11-30 日本ポリエチレン株式会社 エチレン系重合体の製造方法
US10889662B2 (en) * 2014-12-12 2021-01-12 Lg Chem, Ltd. Metallocene-supported catalyst and method of preparing polyolefin using the same
EP3330296B1 (de) 2015-12-04 2020-02-19 LG Chem, Ltd. Verfahren zur herstellung eines geträgerten metallocen-katalysators
CN108383862B (zh) * 2018-02-08 2021-03-30 中国石油天然气股份有限公司 一种茚并[2,1-b]吲哚基稀土金属配合物及其制备方法
US11198747B2 (en) 2018-06-04 2021-12-14 Exxonmobil Chemical Patents Inc. Catalyst systems including two hafnocene catalyst compounds
US11369949B2 (en) 2018-06-04 2022-06-28 Exxonmobil Chemical Patents Inc. Metallocenes with Si—Si bridges
CN115710326B (zh) * 2022-10-27 2024-06-25 万华化学集团股份有限公司 一种氧芴桥连的芳氧基金属络合物催化剂及方法与应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5451649A (en) * 1991-05-09 1995-09-19 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
DE69431222T2 (de) * 1993-06-07 2003-04-17 Mitsui Chemicals, Inc. Übergangsmetallverbindung, und diese enthaltender Polymerisationkatalysator
JPH11503379A (ja) * 1995-04-11 1999-03-26 ダブリュ.エル.ゴア.アンド アソシエイツ,インコーポレイティド 赤外線反射性被覆材
IT1275408B (it) * 1995-05-30 1997-08-05 Spherilene Spa Composti metallocenici bis-indenilici pontanti procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
DE19546501A1 (de) * 1995-12-13 1997-06-19 Hoechst Ag Metallocenverbindung
US5780659A (en) * 1996-03-29 1998-07-14 Phillips Petroleum Company Substituted indenyl unbridged metallocenes

Also Published As

Publication number Publication date
TW593324B (en) 2004-06-21
DE60029137T2 (de) 2007-05-16
PL355486A1 (en) 2004-05-04
ITMI992536A1 (it) 2001-06-03
CA2393175A1 (en) 2001-06-07
HRP20020461B1 (en) 2005-10-31
RU2238277C2 (ru) 2004-10-20
HUP0203804A2 (hu) 2003-03-28
AU777085B2 (en) 2004-09-30
WO2001040238A1 (en) 2001-06-07
DE60029137D1 (de) 2006-08-10
EP1250342B1 (de) 2006-06-28
NO20022611L (no) 2002-08-05
ITMI992536A0 (it) 1999-12-03
HRP20020461A2 (en) 2004-04-30
KR20020061625A (ko) 2002-07-24
JP3921601B2 (ja) 2007-05-30
CA2393175C (en) 2009-01-27
EP1250342A1 (de) 2002-10-23
ES2267602T3 (es) 2007-03-16
PL202964B1 (pl) 2009-08-31
JP2003515540A (ja) 2003-05-07
SK7462002A3 (en) 2003-02-04
NO333543B1 (no) 2013-07-08
NO20022611D0 (no) 2002-05-31
CN1409718A (zh) 2003-04-09
CN100368417C (zh) 2008-02-13
IT1314261B1 (it) 2002-12-06
CZ20021821A3 (cs) 2002-10-16
AR031540A1 (es) 2003-09-24
HUP0203804A3 (en) 2004-06-28
US6984703B1 (en) 2006-01-10
PT1250342E (pt) 2006-11-30
MY134869A (en) 2007-12-31
MXPA02005494A (es) 2004-09-10
ZA200204342B (en) 2003-06-02
BR0016134B1 (pt) 2011-06-14
AU3004301A (en) 2001-06-12
BR0016134A (pt) 2002-08-20

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