HRP20020461B1 - Bridged metallocene compounds as olefin-polymerization catalysts - Google Patents

Bridged metallocene compounds as olefin-polymerization catalysts

Info

Publication number
HRP20020461B1
HRP20020461B1 HR20020461A HRP20020461A HRP20020461B1 HR P20020461 B1 HRP20020461 B1 HR P20020461B1 HR 20020461 A HR20020461 A HR 20020461A HR P20020461 A HRP20020461 A HR P20020461A HR P20020461 B1 HRP20020461 B1 HR P20020461B1
Authority
HR
Croatia
Prior art keywords
olefin
polymerization catalysts
metallocene compounds
bridged metallocene
bridged
Prior art date
Application number
HR20020461A
Inventor
Biagini Paolo
Santi Roberto
Schimperna Giuliana
Caldararo Maria
Borsotti Giampietro
Masi Francesco
Original Assignee
Polimeri Europa S.P.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polimeri Europa S.P.A. filed Critical Polimeri Europa S.P.A.
Publication of HRP20020461A2 publication Critical patent/HRP20020461A2/en
Publication of HRP20020461B1 publication Critical patent/HRP20020461B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465—Indenes; Completely or partially hydrogenated indenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
HR20020461A 1999-12-03 2002-05-24 Bridged metallocene compounds as olefin-polymerization catalysts HRP20020461B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT1999MI002536A IT1314261B1 (en) 1999-12-03 1999-12-03 METALLOCENIC COMPOUNDS BRIDGE, PROCESS FOR THEIR PREPARATION AND THEIR USE AS CATALYSTS FOR THE POLYMERIZATION OF OLEFINS.
PCT/EP2000/011824 WO2001040238A1 (en) 1999-12-03 2000-11-27 Bridged metallocene compounds as olefin-polymerization catalysts

Publications (2)

Publication Number Publication Date
HRP20020461A2 HRP20020461A2 (en) 2004-04-30
HRP20020461B1 true HRP20020461B1 (en) 2005-10-31

Family

ID=11384070

Family Applications (1)

Application Number Title Priority Date Filing Date
HR20020461A HRP20020461B1 (en) 1999-12-03 2002-05-24 Bridged metallocene compounds as olefin-polymerization catalysts

Country Status (26)

Country Link
US (1) US6984703B1 (en)
EP (1) EP1250342B1 (en)
JP (1) JP3921601B2 (en)
KR (1) KR20020061625A (en)
CN (1) CN100368417C (en)
AR (1) AR031540A1 (en)
AT (1) ATE331725T1 (en)
AU (1) AU777085B2 (en)
BR (1) BR0016134B1 (en)
CA (1) CA2393175C (en)
CZ (1) CZ20021821A3 (en)
DE (1) DE60029137T2 (en)
ES (1) ES2267602T3 (en)
HR (1) HRP20020461B1 (en)
HU (1) HUP0203804A3 (en)
IT (1) IT1314261B1 (en)
MX (1) MXPA02005494A (en)
MY (1) MY134869A (en)
NO (1) NO333543B1 (en)
PL (1) PL202964B1 (en)
PT (1) PT1250342E (en)
RU (1) RU2238277C2 (en)
SK (1) SK7462002A3 (en)
TW (1) TW593324B (en)
WO (1) WO2001040238A1 (en)
ZA (1) ZA200204342B (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW200420573A (en) 2002-09-26 2004-10-16 Rib X Pharmaceuticals Inc Bifunctional heterocyclic compounds and methods of making and using same
US8202843B2 (en) 2004-02-27 2012-06-19 Rib-X Pharmaceuticals, Inc. Macrocyclic compounds and methods of making and using the same
CN101815727B (en) * 2007-08-27 2013-05-15 保瑞利斯科技公司 Catalysts
EP2223944A1 (en) 2009-02-26 2010-09-01 Borealis AG Process for producing semicrystalline propylene polymers
WO2011021805A2 (en) 2009-08-18 2011-02-24 주식회사 엘지화학 Novel compound, catalyst composition comprising same, and method for preparing a cyclic olefin polymer using same
JP6036108B2 (en) * 2012-03-29 2016-11-30 日本ポリエチレン株式会社 Process for producing ethylene polymer
WO2016093678A1 (en) * 2014-12-12 2016-06-16 주식회사 엘지화학 Supported metallocene catalyst and polyolefin preparation method using same
CN108026199B (en) * 2015-12-04 2020-08-11 Lg化学株式会社 Method for preparing supported hybrid metallocene catalyst and supported hybrid metallocene catalyst prepared by using same
CN108383862B (en) * 2018-02-08 2021-03-30 中国石油天然气股份有限公司 Indeno [2,1-b ] indolyl rare earth metal complex and preparation method thereof
US11198747B2 (en) 2018-06-04 2021-12-14 Exxonmobil Chemical Patents Inc. Catalyst systems including two hafnocene catalyst compounds
US11369949B2 (en) 2018-06-04 2022-06-28 Exxonmobil Chemical Patents Inc. Metallocenes with Si—Si bridges
CN115710326B (en) * 2022-10-27 2024-06-25 万华化学集团股份有限公司 Fluorene-bridged aryloxy metal complex catalyst, method and application

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5451649A (en) 1991-05-09 1995-09-19 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
NL9201970A (en) * 1992-11-11 1994-06-01 Dsm Nv Indenyl compounds and catalyst components for the polymerization of olefins.
CA2125246C (en) * 1993-06-07 2001-07-03 Junichi Imuta Transition metal compound and olefin polymerization catalyst using the same
ATE213994T1 (en) * 1995-04-11 2002-03-15 Gore & Ass INFRARED LIGHT REFLECTIVE COVERS
IT1275408B (en) * 1995-05-30 1997-08-05 Spherilene Spa BIS-INDENYL METALLOCENIC COMPOUNDS PONTANTS PROCEDURE FOR THEIR PREPARATION AND THEIR USE IN CATALYSTS FOR THE POLYMERIZATION OF OLEFINS
DE19546501A1 (en) * 1995-12-13 1997-06-19 Hoechst Ag Metallocene compound
US5780659A (en) * 1996-03-29 1998-07-14 Phillips Petroleum Company Substituted indenyl unbridged metallocenes

Also Published As

Publication number Publication date
SK7462002A3 (en) 2003-02-04
CA2393175C (en) 2009-01-27
JP3921601B2 (en) 2007-05-30
PL355486A1 (en) 2004-05-04
PT1250342E (en) 2006-11-30
ZA200204342B (en) 2003-06-02
BR0016134A (en) 2002-08-20
EP1250342B1 (en) 2006-06-28
HUP0203804A2 (en) 2003-03-28
NO20022611L (en) 2002-08-05
CA2393175A1 (en) 2001-06-07
CN100368417C (en) 2008-02-13
US6984703B1 (en) 2006-01-10
JP2003515540A (en) 2003-05-07
ITMI992536A1 (en) 2001-06-03
BR0016134B1 (en) 2011-06-14
EP1250342A1 (en) 2002-10-23
AU777085B2 (en) 2004-09-30
ATE331725T1 (en) 2006-07-15
ITMI992536A0 (en) 1999-12-03
HUP0203804A3 (en) 2004-06-28
RU2238277C2 (en) 2004-10-20
DE60029137D1 (en) 2006-08-10
HRP20020461A2 (en) 2004-04-30
KR20020061625A (en) 2002-07-24
PL202964B1 (en) 2009-08-31
DE60029137T2 (en) 2007-05-16
CN1409718A (en) 2003-04-09
MXPA02005494A (en) 2004-09-10
MY134869A (en) 2007-12-31
ES2267602T3 (en) 2007-03-16
NO333543B1 (en) 2013-07-08
NO20022611D0 (en) 2002-05-31
AR031540A1 (en) 2003-09-24
CZ20021821A3 (en) 2002-10-16
AU3004301A (en) 2001-06-12
IT1314261B1 (en) 2002-12-06
TW593324B (en) 2004-06-21
WO2001040238A1 (en) 2001-06-07

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