ES2163447T3 - Composicion de catalizador para amoxidacion. - Google Patents
Composicion de catalizador para amoxidacion.Info
- Publication number
- ES2163447T3 ES2163447T3 ES94922381T ES94922381T ES2163447T3 ES 2163447 T3 ES2163447 T3 ES 2163447T3 ES 94922381 T ES94922381 T ES 94922381T ES 94922381 T ES94922381 T ES 94922381T ES 2163447 T3 ES2163447 T3 ES 2163447T3
- Authority
- ES
- Spain
- Prior art keywords
- catalyst
- amoxidation
- composition
- oxide catalyst
- suspension
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title abstract 8
- 239000000203 mixture Substances 0.000 title abstract 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 3
- 239000000725 suspension Substances 0.000 abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- 239000010703 silicon Substances 0.000 abstract 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
SE PRESENTA UNA COMPOSICION PARA UN CATALIZADOR DE AMOXIDACION PARA SU USO EN LA PRODUCCION DE ACRILONITRILO A PARTIR DE PROPILENO, O METACRILONITRILO A PARTIR DE ISOBUTILENO, MEDIANTE AMOXIDACION DEL PROPILENO O DEL ISOBUTILENO, LA COMPOSICION COMPRENDE UN CATALIZADOR DE OXIDO Y UN PORTADOR DE SILICE QUE TIENE EL CATALIZADOR DE OXIDO SOPORTADO SOBRE EL MISMO, EN DONDE EL PORTADOR DE SILICE ESTA PRESENTE EN UNA CANTIDAD DE ENTRE EL 40% Y EL 60% DEL PESO, EN BASE AL PESO TOTAL DEL CATALIZADOR DE OXIDO Y DEL PORTADOR DE SILICIO. EL CATALIZADOR DE OXIDO COMPRENDE OXIDOS DE MOLIBDENO, BISMUTO, HIERRO Y UN COMPONENTE A QUE ES AL MENOS UN ELEMENTO SELECCIONADO ENTRE POTASIO, RUBIDIO Y CESIO, EN DONDE EL BISMUTO, EL HIERRO Y EL COMPONENTE A ESTAN, RESPECTIVAMENTE, PRESENTES EN CANTIDADES DE ENTRE 0.1 Y 6, DE ENTRE 0.1 Y 8 Y DE ENTRE 0.01 Y 5 EN TERMINOS DE PROPORCIONES ATOMICAS CON RELACION A 12 ATOMOS DE MOLIBDENO. EL CATALIZADOR DE AMOXIDACION SE PREPARA SUMINISTRANDO UNA PASTA QUE CONSTA DE UNASUSPENSION COLOIDAL DE SILICE Y FUENTE DE LOS ELEMENTOS METALICOS DE LOS COMPONENTES DEL CATALIZADOR DE OXIDO, Y ROCIANDO LA PASTA, SIGUIENDO CON UNA CALCINACION, EN DONDE LA SUSPENSION COLOIDAL DE SILICE TIENE UN CONTENIDO DE ALUMINIO DE 0.04 O INFERIOR EN TERMINOS DE UNA PROPORCION ATOMICA RELATIVA A 100 ATOMOS DE SILICIO. MEDIANTE EL USO DE LA COMPOSICION DEL CATALIZADOR DE LA INVENCION, PUEDE MEJORARSE SIGNIFICATIVAMENTE LA SELECTIVIDAD PARA EL ACRILONITRILO O METACRILONITRILO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22274593A JP3584940B2 (ja) | 1993-08-17 | 1993-08-17 | アンモ酸化触媒組成物 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2163447T3 true ES2163447T3 (es) | 2002-02-01 |
Family
ID=16787246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94922381T Expired - Lifetime ES2163447T3 (es) | 1993-08-17 | 1994-08-16 | Composicion de catalizador para amoxidacion. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5780664A (es) |
| EP (1) | EP0714697B1 (es) |
| JP (1) | JP3584940B2 (es) |
| KR (1) | KR100196369B1 (es) |
| CN (1) | CN1081084C (es) |
| DE (1) | DE69429180T2 (es) |
| ES (1) | ES2163447T3 (es) |
| TW (1) | TW328055B (es) |
| WO (1) | WO1995005241A1 (es) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5840648A (en) * | 1997-09-02 | 1998-11-24 | The Standard Oil Company | Catalyst for the manufacture of acrylonitrile and hydrogen cyanide |
| CN1108865C (zh) * | 1997-09-03 | 2003-05-21 | 中国石油化工集团公司 | 生产丙烯腈的催化剂 |
| US6143928A (en) * | 1998-08-10 | 2000-11-07 | Saudi Basic Industries Corporation | Catalysts for low temperature selective oxidation of propylene, methods of making and using the same |
| US6017846A (en) * | 1999-01-11 | 2000-01-25 | Saudi Basic Industries Corporation | Highly active and selective catalysts for the production of unsaturated nitriles, methods of making and using the same |
| RU2159666C1 (ru) * | 1999-11-24 | 2000-11-27 | Дыкман Аркадий Самуилович | Способ очистки промышленных газовых выбросов |
| US6458742B1 (en) * | 2000-08-17 | 2002-10-01 | The Standard Oil Company | Catalyst for the manufacture of acrylonitrile |
| JP4159759B2 (ja) * | 2001-04-13 | 2008-10-01 | ダイヤニトリックス株式会社 | モリブデン−ビスマス−鉄含有複合酸化物流動層触媒の製法 |
| JP4030740B2 (ja) | 2001-10-11 | 2008-01-09 | ダイヤニトリックス株式会社 | アンモ酸化用触媒の製造方法 |
| US7792758B2 (en) * | 2002-11-18 | 2010-09-07 | Microsoft Corporation | Substitution groups/inheritance for extensibility in authorization policy |
| US7071140B2 (en) * | 2002-12-02 | 2006-07-04 | The Standard Oil Company | Catalyst for the manufacture of acrylonitrile |
| US7348291B2 (en) * | 2002-12-02 | 2008-03-25 | Ineos Usa Llc | Catalyst for the manufacture of acrylonitrile |
| JP4242197B2 (ja) * | 2003-04-18 | 2009-03-18 | ダイヤニトリックス株式会社 | アクリロニトリル合成用触媒 |
| JP4588533B2 (ja) * | 2005-05-24 | 2010-12-01 | ダイヤニトリックス株式会社 | アクリロニトリル合成用触媒 |
| JP5387297B2 (ja) | 2009-09-30 | 2014-01-15 | 住友化学株式会社 | 複合酸化物触媒の製造方法 |
| US8420566B2 (en) * | 2010-03-23 | 2013-04-16 | Ineos Usa Llc | High efficiency ammoxidation process and mixed metal oxide catalysts |
| US8455388B2 (en) | 2010-03-23 | 2013-06-04 | Ineos Usa Llc | Attrition resistant mixed metal oxide ammoxidation catalysts |
| US8258073B2 (en) * | 2010-03-23 | 2012-09-04 | Ineos Usa Llc | Process for preparing improved mixed metal oxide ammoxidation catalysts |
| US8153546B2 (en) | 2010-03-23 | 2012-04-10 | Ineos Usa Llc | Mixed metal oxide ammoxidation catalysts |
| CN102371156B (zh) * | 2010-08-23 | 2013-06-05 | 中国石油化工股份有限公司 | 氨氧化制不饱和腈流化床催化剂及其制备方法 |
| EP3744418A1 (en) | 2016-01-09 | 2020-12-02 | Ascend Performance Materials Operations LLC | Catalyst compositions and process for direct production of hydrogen cyanide in an acrylonitrile reactor feed stream |
| US20180318803A1 (en) * | 2016-01-25 | 2018-11-08 | Asahi Kasei Kabushiki Kaisha | Catalyst for fluidized bed ammoxidation reaction, and method for producing acrylonitrile |
| WO2019187786A1 (ja) | 2018-03-28 | 2019-10-03 | 旭化成株式会社 | アクリロニトリルの製造方法 |
| CN108816242A (zh) * | 2018-06-11 | 2018-11-16 | 福州大学 | 一种低温丙烯气相环氧化催化剂及其制备方法 |
| CN108816243A (zh) * | 2018-06-11 | 2018-11-16 | 福州大学 | 一种常压下的丙烯气相环氧化催化剂及其制备方法 |
| CN109847744B (zh) * | 2018-12-26 | 2022-02-15 | 万华化学集团股份有限公司 | 氨氧化催化剂，及其制备方法和制备间苯二甲腈的方法 |
| CN113996288B (zh) * | 2021-11-03 | 2023-10-10 | 中国五环工程有限公司 | 一种合成甲基丙烯腈的氨氧化催化剂及其制备方法 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA975382A (en) * | 1971-02-04 | 1975-09-30 | Arthur F. Miller | Process for the manufacture of acrylonitrile and methacrylonitrile |
| US3746657A (en) * | 1971-06-28 | 1973-07-17 | Standard Oil Co | Catalyst manufacturing process |
| US4139552A (en) * | 1974-01-04 | 1979-02-13 | The Standard Oil Company | Production of unsaturated nitriles |
| US4192776A (en) * | 1973-12-19 | 1980-03-11 | The Standard Oil Company | Catalysts and process for the ammoxidation of olefins |
| JPS5412913B2 (es) * | 1974-03-23 | 1979-05-26 | ||
| US4162234A (en) * | 1974-07-22 | 1979-07-24 | The Standard Oil Company | Oxidation catalysts |
| JPS5412913A (en) * | 1977-06-27 | 1979-01-31 | Silver Seiko | Printer |
| JPS582232B2 (ja) * | 1977-12-31 | 1983-01-14 | 旭化成株式会社 | アクリロニトリルの製造方法 |
| JPS5510534A (en) * | 1978-07-08 | 1980-01-25 | Fuji Electric Co Ltd | Photo-acoustic analyzer |
| JPS5556839A (en) * | 1978-10-20 | 1980-04-26 | Ube Ind Ltd | Acrylonitrile preparing catalyst using fludized bed reactor |
| JPS5916817B2 (ja) * | 1979-04-18 | 1984-04-18 | 宇部興産株式会社 | アクリロニトリル製造用触媒 |
| JPS5867349A (ja) * | 1981-10-20 | 1983-04-21 | Asahi Chem Ind Co Ltd | 触媒組成物 |
| JPS5872550A (ja) * | 1981-10-26 | 1983-04-30 | Asahi Chem Ind Co Ltd | メタクリロニトリルの製造方法 |
| JPS59204164A (ja) * | 1983-05-06 | 1984-11-19 | Asahi Chem Ind Co Ltd | 不飽和ニトリルの製法 |
| JPS60127216A (ja) * | 1983-12-10 | 1985-07-06 | Nitto Chem Ind Co Ltd | 低アルカリ低アルミナ含量の水性シリカゾルの製造法 |
| JPS61158810A (ja) * | 1984-12-28 | 1986-07-18 | Shokubai Kasei Kogyo Kk | 高純度シリカゾルの製造法 |
| EP0265964A3 (en) * | 1986-10-31 | 1989-05-31 | Mitsubishi Gas Chemical Company, Inc. | Process for preparing alpha,beta-unsaturated aliphatic monocarboxylic acids or esters thereof |
| JP2508713B2 (ja) * | 1987-05-15 | 1996-06-19 | 日産化学工業株式会社 | 高純度大粒子径シリカゾルの製造法 |
| JP2520279B2 (ja) * | 1988-03-03 | 1996-07-31 | 日東化学工業株式会社 | アクリロニトリルの製造方法 |
| JP2701065B2 (ja) * | 1989-03-23 | 1998-01-21 | 日東化学工業株式会社 | モリブデン―ビスマス含有複合酸化物触媒の製法 |
| US5093299A (en) * | 1990-01-09 | 1992-03-03 | The Standard Oil Company | Catalyst for process for the manufacture of acrylonitrile and methacrylonitrile |
| DK0464289T3 (da) * | 1990-07-02 | 1995-04-03 | Nalco Chemical Co | Fremstilling af silicasoler |
| JP3225549B2 (ja) * | 1991-09-25 | 2001-11-05 | 日産化学工業株式会社 | 高純度の水性シリカゾルの製造法 |
-
1993
- 1993-08-16 US US08/583,028 patent/US5780664A/en not_active Expired - Lifetime
- 1993-08-17 JP JP22274593A patent/JP3584940B2/ja not_active Expired - Lifetime
-
1994
- 1994-08-16 TW TW083107509A patent/TW328055B/zh not_active IP Right Cessation
- 1994-08-16 KR KR1019960700748A patent/KR100196369B1/ko not_active IP Right Cessation
- 1994-08-16 WO PCT/JP1994/001356 patent/WO1995005241A1/ja active IP Right Grant
- 1994-08-16 CN CN94193133A patent/CN1081084C/zh not_active Expired - Lifetime
- 1994-08-16 DE DE69429180T patent/DE69429180T2/de not_active Expired - Lifetime
- 1994-08-16 EP EP94922381A patent/EP0714697B1/en not_active Expired - Lifetime
- 1994-08-16 ES ES94922381T patent/ES2163447T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0714697A4 (en) | 1998-01-07 |
| US5780664A (en) | 1998-07-14 |
| EP0714697A1 (en) | 1996-06-05 |
| WO1995005241A1 (en) | 1995-02-23 |
| JP3584940B2 (ja) | 2004-11-04 |
| CN1129408A (zh) | 1996-08-21 |
| CN1081084C (zh) | 2002-03-20 |
| JPH0751570A (ja) | 1995-02-28 |
| DE69429180D1 (de) | 2002-01-03 |
| EP0714697B1 (en) | 2001-11-21 |
| KR100196369B1 (ko) | 1999-06-15 |
| KR960703673A (ko) | 1996-08-31 |
| DE69429180T2 (de) | 2002-08-29 |
| TW328055B (en) | 1998-03-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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