ES2162802T3 - Procedimiento para la polimerizacion de alfa-olefinas utilizando compuestos de metaloceno que tienen ligandos de tipo fluorenilico. - Google Patents

Procedimiento para la polimerizacion de alfa-olefinas utilizando compuestos de metaloceno que tienen ligandos de tipo fluorenilico.

Info

Publication number
ES2162802T3
ES2162802T3 ES93120798T ES93120798T ES2162802T3 ES 2162802 T3 ES2162802 T3 ES 2162802T3 ES 93120798 T ES93120798 T ES 93120798T ES 93120798 T ES93120798 T ES 93120798T ES 2162802 T3 ES2162802 T3 ES 2162802T3
Authority
ES
Spain
Prior art keywords
polymerization
fluorenilic
alfa
olefins
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93120798T
Other languages
English (en)
Inventor
Luigi Resconi
Robert Lawrence Jones
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Basell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Technology Co BV filed Critical Basell Technology Co BV
Application granted granted Critical
Publication of ES2162802T3 publication Critical patent/ES2162802T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

SE DESCRIBEN METALOCENOS CONTENIENDO FLUORENILO, DE PUENTE, Y QUE TIENEN LA FORMULA (I), EN LA QUE SUSTITUYENTES SON, POR EJEMPLO, GRUPOS DE ATOMOS DE HIDROGENO O ALQUILOS, M ES TI, ZR O HF, SUSTITUYENTES R2 SON, POR EJEMPLO, GRUPOS HALOGENOS O ALQUILOS, EL GRUPO DE PUENTE R3 ES, POR EJEMPLO, UN RADICAL DIVALENTE DIALQUILSILANDIILO. ESTOS METALOCENOS SON UTILES COMO COMPONENTES CATALIZADORES PARA LA POLIMERIZACION DE OLEOFINAS Y, ESPECIALMENTE, PARA LA PREPARACION DE POLIPROPILENO ATACTICO DE GRAN PESO MOLECULAR.
ES93120798T 1992-12-30 1993-12-23 Procedimiento para la polimerizacion de alfa-olefinas utilizando compuestos de metaloceno que tienen ligandos de tipo fluorenilico. Expired - Lifetime ES2162802T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI922988A IT1256259B (it) 1992-12-30 1992-12-30 Composti mettallocenici aventi leganti di tipo fluorenilico

Publications (1)

Publication Number Publication Date
ES2162802T3 true ES2162802T3 (es) 2002-01-16

Family

ID=11364558

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93120798T Expired - Lifetime ES2162802T3 (es) 1992-12-30 1993-12-23 Procedimiento para la polimerizacion de alfa-olefinas utilizando compuestos de metaloceno que tienen ligandos de tipo fluorenilico.

Country Status (9)

Country Link
EP (1) EP0604908B1 (es)
JP (1) JPH06256369A (es)
KR (1) KR940014423A (es)
CA (1) CA2112598A1 (es)
DE (1) DE69330780T2 (es)
ES (1) ES2162802T3 (es)
FI (1) FI935913A (es)
IT (1) IT1256259B (es)
RU (1) RU2169152C2 (es)

Families Citing this family (41)

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US5504169A (en) * 1989-09-13 1996-04-02 Exxon Chemical Patents Inc. Process for producing amorphous poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5571880A (en) * 1991-05-09 1996-11-05 Phillips Petroleum Company Organometallic fluorenyl compounds and use thereof in an alpha-olefin polymerization process
US5631335A (en) * 1991-05-09 1997-05-20 Phillips Petroleum Company Process of polymerizing olefins using diphenylsilyl or dimethyl tin bridged 1-methyl fluorenyl metallocenes
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5710224A (en) * 1991-07-23 1998-01-20 Phillips Petroleum Company Method for producing polymer of ethylene
IT1273420B (it) 1994-04-06 1997-07-08 Spherilene Srl Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
IT1273662B (it) * 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propiline'
US5770755A (en) * 1994-11-15 1998-06-23 Phillips Petroleum Company Process to prepare polymeric metallocenes
AU4527196A (en) * 1994-12-21 1996-07-10 Exxon Chemical Patents Inc. A method of preparing high purity racemic metallocene alkyls and use thereof
IT1272924B (it) * 1995-01-23 1997-07-01 Spherilene Srl Procedimento per la preparazione di composti ciclopentadienilici e composti cosi' ottenibili
IT1275857B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Copolimeri atattici del propilene con l'etilene
IT1275856B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
IT1275408B (it) 1995-05-30 1997-08-05 Spherilene Spa Composti metallocenici bis-indenilici pontanti procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
AT403376B (de) * 1995-07-03 1998-01-26 Danubia Petrochem Polymere Metallocene mit silylsubstituierten brücken und deren einsatz für die olefinpolymerisation
IT1282683B1 (it) * 1996-02-23 1998-03-31 Montell North America Inc Mescole di bitume e di polimeri olefinici atti alla modifica dei bitumi
US6329541B1 (en) 1997-01-08 2001-12-11 Phillips Petroleum Company Organo omega-alkenyl cyclopentacarbyl silane-bridged metallocene compounds
US5856547A (en) * 1997-01-08 1999-01-05 Phillips Petroleum Company Organo omega-alkenyl cyclopentacarbyl silane compounds
US5854363A (en) * 1997-01-08 1998-12-29 Phillips Petroleum Company (Omega-alkenyl) (cyclopentacarbyl) metallocene compounds
US6265512B1 (en) 1997-10-23 2001-07-24 3M Innovative Company Elastic polypropylenes and catalysts for their manufacture
AU1870999A (en) 1997-11-12 1999-05-31 Montell Technology Company B.V. Metallocenes and catalysts for olefin-polymerisation
KR19990067851A (ko) 1998-01-14 1999-08-25 고오사이 아끼오 올레핀 중합체, 올레핀 중합 촉매 및 올레핀 중합체의 제조 방법
DE69903388T2 (de) * 1998-01-14 2003-06-18 Basell Polyolefine Gmbh Verfahren zur herstellung von metallocenen
JP4592848B2 (ja) * 1998-10-21 2010-12-08 三井化学株式会社 軟質透明性シンジオタクティックポリプロピレン組成物
BR0105938A (pt) 2000-03-22 2002-03-26 Basell Technology Co Bv Composições termoplásticas de polìmeros de propileno isotáticos e de polìmeros de propileno flexìveis dotados de isotaticidade reduzida, e processo para a preparação das mesmas
FR2813079B1 (fr) * 2000-08-18 2003-07-25 Atofina Ligands avec au moins un substituant fluorosilicone pour la preparation de metallocenes
ATE388957T1 (de) 2002-01-08 2008-03-15 Basell Polyolefine Gmbh Herstellung von siliziumverbrückten metallocenverbindungen
US7943716B2 (en) 2004-03-12 2011-05-17 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
EP1735355B1 (en) 2004-03-12 2010-09-29 Basell Polyolefine GmbH Process for polymerizing 1-hexene or higher alpha-olefins
ATE445650T1 (de) 2004-05-04 2009-10-15 Basell Polyolefine Gmbh Verfahren zur herstellung von ataktischen 1- butenpolymeren
AU2005263671A1 (en) 2004-07-22 2006-01-26 Basell Polyolefine Gmbh Process for producing fractionable 1-butene polymers
PL1769030T3 (pl) 2004-07-22 2008-08-29 Basell Polyolefine Gmbh Kompozycja polimerów 1-butenu
DE602007003743D1 (de) 2006-08-30 2010-01-21 Basell Polyolefine Gmbh 1-buten-propylen-copolymer-zusammensetzungen
KR101374142B1 (ko) 2006-08-30 2014-03-17 바젤 폴리올레핀 게엠베하 1-부텐 프로필렌 공중합체 조성물
KR101154507B1 (ko) 2009-07-31 2012-06-13 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하여 제조된 올레핀계 중합체
US8691916B2 (en) 2012-05-07 2014-04-08 Dow Global Technologies Llc Retortable easy opening seals for film extrusion
ES2770021T3 (es) * 2014-04-17 2020-06-30 Borealis Ag Sistema catalítico mejorado para producir copolímeros de polietileno en un proceso de polimerización en solución a alta temperatura
KR101666170B1 (ko) 2014-06-18 2016-10-13 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 폴리올레핀의 제조방법
KR102363189B1 (ko) 2018-01-11 2022-02-15 주식회사 엘지화학 혼성 담지 메탈로센 촉매를 이용한 폴리올레핀의 제조 방법
WO2019139355A1 (ko) * 2018-01-11 2019-07-18 주식회사 엘지화학 혼성 담지 메탈로센 촉매를 이용한 폴리올레핀의 제조방법
CN113880881B (zh) * 2021-10-20 2023-11-17 中化泉州石化有限公司 一种刚性有机膦配体的合成及其在乙烯齐聚中的应用
CN115109189B (zh) * 2022-06-15 2024-01-30 宁夏清研高分子新材料有限公司 一种环烯烃共聚物材料的制备方法、催化剂体系及其应用

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JPH01249782A (ja) * 1988-03-30 1989-10-05 Mitsubishi Metal Corp 高活性触媒用有機珪素化合物のカリウム塩とその製法
CA2067525C (en) * 1991-05-09 1998-09-15 Helmut G. Alt Organometallic fluorenyl compounds, preparation and use
US5436305A (en) * 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
US5191132A (en) * 1991-05-09 1993-03-02 Phillips Petroleum Company Cyclopentadiene type compounds and method for making
NL9101502A (nl) * 1991-09-06 1993-04-01 Dsm Nv Werkwijze voor het bereiden van een gebrugde metalloceenverbinding alsmede een katalysatorcomponent en een werkwijze voor de polymerisatie van een olefinen.

Also Published As

Publication number Publication date
DE69330780T2 (de) 2002-07-04
IT1256259B (it) 1995-11-29
RU2169152C2 (ru) 2001-06-20
FI935913A (fi) 1994-07-01
EP0604908A2 (en) 1994-07-06
EP0604908A3 (en) 1994-08-24
ITMI922988A0 (it) 1992-12-30
DE69330780D1 (de) 2001-10-25
CA2112598A1 (en) 1994-07-01
ITMI922988A1 (it) 1994-06-30
KR940014423A (ko) 1994-07-18
EP0604908B1 (en) 2001-09-19
FI935913A0 (fi) 1993-12-29
JPH06256369A (ja) 1994-09-13

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