DE69330780D1 - Verfahren zur Polymerisierung von Alpha-Olefinen mittels Metalloceneverbindungen mit Liganden des Typs Fluorenyl - Google Patents

Verfahren zur Polymerisierung von Alpha-Olefinen mittels Metalloceneverbindungen mit Liganden des Typs Fluorenyl

Info

Publication number
DE69330780D1
DE69330780D1 DE69330780T DE69330780T DE69330780D1 DE 69330780 D1 DE69330780 D1 DE 69330780D1 DE 69330780 T DE69330780 T DE 69330780T DE 69330780 T DE69330780 T DE 69330780T DE 69330780 D1 DE69330780 D1 DE 69330780D1
Authority
DE
Germany
Prior art keywords
olefins
ligands
alpha
polymerization
metallocene compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69330780T
Other languages
English (en)
Other versions
DE69330780T2 (de
Inventor
Luigi Resconi
Robert Lawrence Jones
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Basell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Technology Co BV filed Critical Basell Technology Co BV
Publication of DE69330780D1 publication Critical patent/DE69330780D1/de
Application granted granted Critical
Publication of DE69330780T2 publication Critical patent/DE69330780T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69330780T 1992-12-30 1993-12-23 Verfahren zur Polymerisierung von Alpha-Olefinen mittels Metalloceneverbindungen mit Liganden des Typs Fluorenyl Expired - Fee Related DE69330780T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI922988A IT1256259B (it) 1992-12-30 1992-12-30 Composti mettallocenici aventi leganti di tipo fluorenilico

Publications (2)

Publication Number Publication Date
DE69330780D1 true DE69330780D1 (de) 2001-10-25
DE69330780T2 DE69330780T2 (de) 2002-07-04

Family

ID=11364558

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69330780T Expired - Fee Related DE69330780T2 (de) 1992-12-30 1993-12-23 Verfahren zur Polymerisierung von Alpha-Olefinen mittels Metalloceneverbindungen mit Liganden des Typs Fluorenyl

Country Status (9)

Country Link
EP (1) EP0604908B1 (de)
JP (1) JPH06256369A (de)
KR (1) KR940014423A (de)
CA (1) CA2112598A1 (de)
DE (1) DE69330780T2 (de)
ES (1) ES2162802T3 (de)
FI (1) FI935913A (de)
IT (1) IT1256259B (de)
RU (1) RU2169152C2 (de)

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US5504169A (en) * 1989-09-13 1996-04-02 Exxon Chemical Patents Inc. Process for producing amorphous poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5631335A (en) * 1991-05-09 1997-05-20 Phillips Petroleum Company Process of polymerizing olefins using diphenylsilyl or dimethyl tin bridged 1-methyl fluorenyl metallocenes
US5571880A (en) * 1991-05-09 1996-11-05 Phillips Petroleum Company Organometallic fluorenyl compounds and use thereof in an alpha-olefin polymerization process
US5710224A (en) * 1991-07-23 1998-01-20 Phillips Petroleum Company Method for producing polymer of ethylene
IT1273420B (it) 1994-04-06 1997-07-08 Spherilene Srl Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
IT1273662B (it) * 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propiline'
US5770755A (en) * 1994-11-15 1998-06-23 Phillips Petroleum Company Process to prepare polymeric metallocenes
AU4527196A (en) * 1994-12-21 1996-07-10 Exxon Chemical Patents Inc. A method of preparing high purity racemic metallocene alkyls and use thereof
IT1272924B (it) * 1995-01-23 1997-07-01 Spherilene Srl Procedimento per la preparazione di composti ciclopentadienilici e composti cosi' ottenibili
IT1275856B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
IT1275857B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Copolimeri atattici del propilene con l'etilene
IT1275408B (it) 1995-05-30 1997-08-05 Spherilene Spa Composti metallocenici bis-indenilici pontanti procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
AT403376B (de) * 1995-07-03 1998-01-26 Danubia Petrochem Polymere Metallocene mit silylsubstituierten brücken und deren einsatz für die olefinpolymerisation
IT1282683B1 (it) * 1996-02-23 1998-03-31 Montell North America Inc Mescole di bitume e di polimeri olefinici atti alla modifica dei bitumi
US6329541B1 (en) 1997-01-08 2001-12-11 Phillips Petroleum Company Organo omega-alkenyl cyclopentacarbyl silane-bridged metallocene compounds
US5854363A (en) * 1997-01-08 1998-12-29 Phillips Petroleum Company (Omega-alkenyl) (cyclopentacarbyl) metallocene compounds
US5856547A (en) * 1997-01-08 1999-01-05 Phillips Petroleum Company Organo omega-alkenyl cyclopentacarbyl silane compounds
US6265512B1 (en) 1997-10-23 2001-07-24 3M Innovative Company Elastic polypropylenes and catalysts for their manufacture
DE69810894T2 (de) 1997-11-12 2003-11-13 Basell Polyolefine Gmbh Metallocene und katalysatoren zur olefinpolymerisation
US6288192B1 (en) 1998-01-14 2001-09-11 Sumitomo Chemical Company, Ltd. Olefin polymer, olefin polymerization catalyst and process for producing olefin polymer
CN1243763C (zh) * 1998-01-14 2006-03-01 蒙特尔技术有限公司 茂金属化合物的制备方法
JP4592848B2 (ja) * 1998-10-21 2010-12-08 三井化学株式会社 軟質透明性シンジオタクティックポリプロピレン組成物
ES2223832T3 (es) 2000-03-22 2005-03-01 Basell Polyolefine Gmbh Procedimiento para la preparacion de composiciones termoplasticas de propileno isotactico y polipropileno flexible de isotacticidad inferior.
FR2813079B1 (fr) * 2000-08-18 2003-07-25 Atofina Ligands avec au moins un substituant fluorosilicone pour la preparation de metallocenes
DE60225595T2 (de) * 2002-01-08 2009-04-16 Basell Polyolefine Gmbh Herstellung von siliziumverbrückten metallocenverbindungen
US7943716B2 (en) 2004-03-12 2011-05-17 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
DE602005023844D1 (de) * 2004-03-12 2010-11-11 Basell Polyolefine Gmbh Verfahren zur polymerisation von 1-hexen oder höheren alpha-olefinen
ATE445650T1 (de) 2004-05-04 2009-10-15 Basell Polyolefine Gmbh Verfahren zur herstellung von ataktischen 1- butenpolymeren
BRPI0513108A (pt) 2004-07-22 2008-04-29 Basell Polyolefine Gmbh processo para produzir polìmeros de buteno-1 fracionáveis
ATE388994T1 (de) 2004-07-22 2008-03-15 Basell Polyolefine Gmbh 1-butenpolymerzusammensetzung
KR101374142B1 (ko) 2006-08-30 2014-03-17 바젤 폴리올레핀 게엠베하 1-부텐 프로필렌 공중합체 조성물
US8097682B2 (en) 2006-08-30 2012-01-17 Basell Polyolefine Gmbh 1-butene propylene copolymer compositions
KR101154507B1 (ko) 2009-07-31 2012-06-13 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하여 제조된 올레핀계 중합체
US8691916B2 (en) 2012-05-07 2014-04-08 Dow Global Technologies Llc Retortable easy opening seals for film extrusion
EP3131934B1 (de) * 2014-04-17 2020-01-22 Borealis AG Verbessertes katalysatorsystem zur herstellung von polyethylencopolymeren in einem hochtemperaturlösungspolymerisierungsverfahren
KR101666170B1 (ko) 2014-06-18 2016-10-13 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 폴리올레핀의 제조방법
KR102363189B1 (ko) * 2018-01-11 2022-02-15 주식회사 엘지화학 혼성 담지 메탈로센 촉매를 이용한 폴리올레핀의 제조 방법
WO2019139355A1 (ko) * 2018-01-11 2019-07-18 주식회사 엘지화학 혼성 담지 메탈로센 촉매를 이용한 폴리올레핀의 제조방법
CN113880881B (zh) * 2021-10-20 2023-11-17 中化泉州石化有限公司 一种刚性有机膦配体的合成及其在乙烯齐聚中的应用
CN115109189B (zh) * 2022-06-15 2024-01-30 宁夏清研高分子新材料有限公司 一种环烯烃共聚物材料的制备方法、催化剂体系及其应用

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JPH01249782A (ja) * 1988-03-30 1989-10-05 Mitsubishi Metal Corp 高活性触媒用有機珪素化合物のカリウム塩とその製法
US5191132A (en) * 1991-05-09 1993-03-02 Phillips Petroleum Company Cyclopentadiene type compounds and method for making
US5436305A (en) * 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
CA2067525C (en) * 1991-05-09 1998-09-15 Helmut G. Alt Organometallic fluorenyl compounds, preparation and use
NL9101502A (nl) * 1991-09-06 1993-04-01 Dsm Nv Werkwijze voor het bereiden van een gebrugde metalloceenverbinding alsmede een katalysatorcomponent en een werkwijze voor de polymerisatie van een olefinen.

Also Published As

Publication number Publication date
EP0604908A2 (de) 1994-07-06
ITMI922988A1 (it) 1994-06-30
JPH06256369A (ja) 1994-09-13
ES2162802T3 (es) 2002-01-16
KR940014423A (ko) 1994-07-18
EP0604908B1 (de) 2001-09-19
RU2169152C2 (ru) 2001-06-20
CA2112598A1 (en) 1994-07-01
DE69330780T2 (de) 2002-07-04
ITMI922988A0 (it) 1992-12-30
FI935913A (fi) 1994-07-01
IT1256259B (it) 1995-11-29
EP0604908A3 (en) 1994-08-24
FI935913A0 (fi) 1993-12-29

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee