ES2159942T3 - Latex de poliuretano, procedimientos para su preparacion y polimeros preparados con ellos. - Google Patents
Latex de poliuretano, procedimientos para su preparacion y polimeros preparados con ellos.Info
- Publication number
- ES2159942T3 ES2159942T3 ES98911679T ES98911679T ES2159942T3 ES 2159942 T3 ES2159942 T3 ES 2159942T3 ES 98911679 T ES98911679 T ES 98911679T ES 98911679 T ES98911679 T ES 98911679T ES 2159942 T3 ES2159942 T3 ES 2159942T3
- Authority
- ES
- Spain
- Prior art keywords
- prepolymer
- component
- ethylene
- latex
- procedures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
- C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
- C08G18/0866—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being an aqueous medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Un procedimiento para preparar un látex de poliuretano estable que comprende mezclar un prepolímero de poliuretano con agua, un tensioactivo, y un extendedor de cadena bajo condiciones suficientes para dispersar el producto de reacción del prepolímero y el extendedor de cadena para formar un látex, en el que: (i) el prepolímero se prepara a partir de una formulación de prepolímero que incluye un componente de poliisocianato y componente de poliol, (ii) desde 5 hasta 40 por ciento del peso del componente de poliol es óxido de etileno en forma de óxido de etileno aplicado como remate terminal sobre un polioxialquilén poliol de óxido de propileno u oxialquileno superior, y (iii) no más del 45 por ciento del peso del componente de poliolesóxido de etileno.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US4160097P | 1997-03-17 | 1997-03-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2159942T3 true ES2159942T3 (es) | 2001-10-16 |
Family
ID=21917398
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES98911679T Expired - Lifetime ES2159942T3 (es) | 1997-03-17 | 1998-03-16 | Latex de poliuretano, procedimientos para su preparacion y polimeros preparados con ellos. |
Country Status (21)
Country | Link |
---|---|
US (2) | US20020010262A1 (es) |
EP (1) | EP0971966B1 (es) |
JP (1) | JP4128631B2 (es) |
KR (1) | KR100507015B1 (es) |
CN (1) | CN1129619C (es) |
AR (1) | AR012082A1 (es) |
AT (1) | ATE204886T1 (es) |
AU (1) | AU750396B2 (es) |
BR (1) | BR9807257A (es) |
CA (1) | CA2281584A1 (es) |
CO (1) | CO4870712A1 (es) |
DE (1) | DE69801494T2 (es) |
ES (1) | ES2159942T3 (es) |
HU (1) | HUP0001800A3 (es) |
ID (1) | ID23444A (es) |
NO (1) | NO994496L (es) |
PL (1) | PL335694A1 (es) |
TR (1) | TR199902163T2 (es) |
TW (1) | TW464659B (es) |
WO (1) | WO1998041554A1 (es) |
ZA (1) | ZA982198B (es) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6087440A (en) * | 1999-02-16 | 2000-07-11 | The Dow Chemical Company | Continuous process for preparing a polyurethane latex |
NO20001904L (no) | 1999-04-14 | 2000-10-16 | Dow Chemical Co | Polyuretanfilmer fremstilt ved elektrolytisk utfelling fra polyuretandispersjoner |
NO20001903L (no) | 1999-04-14 | 2000-10-16 | Dow Chemical Co | Polyuretan-filmer fremstilt fra polyuretan-dispersjoner |
NO20001902L (no) * | 1999-04-14 | 2000-10-16 | Dow Chemical Co | Polyuretanfilmer og dispersjoner for fremstilling derav |
CA2427836C (en) | 2000-11-02 | 2009-12-29 | Dow Global Technologies Inc. | Process for preparing aqueous dispersions of hybrid polyurethane particles |
KR100798188B1 (ko) * | 2002-04-16 | 2008-01-24 | 도요 세이칸 가부시키가이샤 | 커버용 밀봉재 및 이를 사용한 커버의 제조방법 |
JP4103500B2 (ja) * | 2002-08-26 | 2008-06-18 | カシオ計算機株式会社 | 表示装置及び表示パネルの駆動方法 |
US7179845B2 (en) * | 2003-01-10 | 2007-02-20 | Fomo Products, Inc. | Elastomeric latex foams |
EP1602675B1 (en) * | 2003-02-17 | 2014-09-10 | NHK Spring Co., Ltd. | Flexible polyurethane foam |
DE10322266A1 (de) * | 2003-05-16 | 2004-12-02 | Basf Ag | Selbstemulgierende wäßrige Polyurethandispersion |
JP4783553B2 (ja) * | 2004-02-18 | 2011-09-28 | 三井化学ポリウレタン株式会社 | ポリウレタン水性分散系の製造方法 |
DE102004017436A1 (de) * | 2004-04-08 | 2005-10-27 | Bayer Materialscience Ag | Verfahren zur kontinuierlichen Herstellung einer wässrigen Polyurethandispersion |
FR2879616B1 (fr) * | 2004-12-21 | 2007-05-25 | Rhodia Chimie Sa | Composition polyisacyanate a proprietes anti-chocs ameliorees |
US20060199007A1 (en) * | 2005-03-01 | 2006-09-07 | Sivapackia Ganapathiappan | Urethane polymer containing latex particles |
BRPI0617075A2 (pt) * | 2005-09-02 | 2011-07-12 | Dow Global Technologies Inc | dispersão de poliuretano aquosa, uso de uma dispersão de poliuretano e dispersão de poliuretano isenta de solvente |
US20090105411A1 (en) * | 2006-05-16 | 2009-04-23 | Bedri Erdem | Aqueous non-ionic hydrophilic polyurethane dispersions, and a continuous process of making the same |
BRPI0719471B1 (pt) * | 2006-12-19 | 2018-07-03 | Dow Global Technologies Inc. | Dispositivo para produzir dispersões e método para produzir uma dispersão polimérica, emulsão ou látex |
US20100260687A1 (en) * | 2007-09-24 | 2010-10-14 | Yu Wei H | Personal care compositions including polyurethane dispersions |
KR101931401B1 (ko) | 2011-07-22 | 2019-03-13 | 다우 글로벌 테크놀로지스 엘엘씨 | 시멘트가 적용되고 외피를 갖는 세라믹 허니콤 구조체의 제조 방법 |
WO2013035461A1 (ja) * | 2011-09-08 | 2013-03-14 | Dic株式会社 | ポリウレタンフィルム及びそれを用いて得たフィルム加工品 |
US20180298253A1 (en) * | 2015-10-26 | 2018-10-18 | Dow Global Technologies Llc | Polyurethane adhesive composition |
WO2024047166A1 (en) * | 2022-09-01 | 2024-03-07 | Polyu Gmbh | Aqueous polyurethane dispersion, and its manufacturing method and use |
Family Cites Families (57)
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US2968575A (en) * | 1953-06-30 | 1961-01-17 | Du Pont | Stable polyurethane latex and process of making same |
US3148173A (en) * | 1959-01-26 | 1964-09-08 | Wyandotte Chemicals Corp | Polyurethane-ureas containing urealinked nu-(2-hydroxypropyl) alkylene diamines |
US3210302A (en) | 1960-12-19 | 1965-10-05 | Glidden Co | Emulsifiable composition of polyurethanes with metal-salt driers, anionic emulsifiers, and pigments |
US3178310A (en) | 1962-03-01 | 1965-04-13 | Du Pont | Aqueous polyurethane coating emulsions |
US3360599A (en) | 1963-11-06 | 1967-12-26 | Shell Oil Co | Preparation of coherent block copolymer films of high tensile strength and extensibility |
GB1111043A (en) * | 1964-04-27 | 1968-04-24 | Wyandotte Chemicals Corp | Aqueous polyurethane dispersions |
US3294724A (en) | 1964-11-23 | 1966-12-27 | Wyandotte Chemicals Corp | Film-forming urethane latices, and preparation by chain extending a prepolymer of anorganic dhsocyanate and a polymeric diol with a piperazine compound |
US3410817A (en) * | 1965-04-29 | 1968-11-12 | Wyandotte Chemicals Corp | Polyurethane latices |
NL127262C (es) | 1965-08-24 | Wyandotte Chemicals Corp | ||
US3488272A (en) | 1966-12-27 | 1970-01-06 | Wyandotte Chemicals Corp | Electrolytic deposition of urethane films onto metal or other conductive surfaces |
US3503917A (en) | 1967-03-09 | 1970-03-31 | Burke Oliver W Jun | Aqueous latices of high polymer compositions and processes for producing same |
NL136660C (es) | 1968-02-05 | |||
US3826768A (en) * | 1968-11-08 | 1974-07-30 | Asahi Chemical Ind | Process for preparing polyurethane compositions |
GB1243604A (en) | 1969-01-21 | 1971-08-25 | Jefferson Chem Co Inc | Elastomeric latex and method of preparation thereof |
JPS5118255B2 (es) | 1972-08-22 | 1976-06-08 | ||
SU523643A3 (ru) | 1973-03-09 | 1976-07-30 | Байер Аг, (Фирма) | Способ получени полиуретанмочевины в высокодисперсном виде |
DE2314512C3 (de) | 1973-03-23 | 1980-10-09 | Bayer Ag, 5090 Leverkusen | Thermoplastische, nichtionische, in Wasser despergierbare im wesentlichen lineare Polyurethanelastomere |
US3919173A (en) | 1973-11-23 | 1975-11-11 | Contech Inc | Moisture curable polyurethane systems |
US4046729A (en) | 1975-06-02 | 1977-09-06 | Ppg Industries, Inc. | Water-reduced urethane coating compositions |
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US3997592A (en) | 1975-11-24 | 1976-12-14 | E. I. Du Pont De Nemours And Company | Preparation of aqueous dispersions of blocked aromatic polyisocyanates |
US4147679A (en) | 1976-06-02 | 1979-04-03 | Ppg Industries, Inc. | Water-reduced urethane coating compositions |
US4119602A (en) | 1977-04-07 | 1978-10-10 | W. R. Grace & Co. | Aqueous urethane codispersions |
US4123403A (en) | 1977-06-27 | 1978-10-31 | The Dow Chemical Company | Continuous process for preparing aqueous polymer microsuspensions |
DE2843790A1 (de) | 1978-10-06 | 1980-04-17 | Bayer Ag | Verfahren zur herstellung von waessrigen dispersionen oder loesungen von polyurethan-polyharnstoffen, die nach diesem verfahren erhaeltlichen dispersionen oder loesungen, sowie ihre verwendung |
JPS5552359A (en) | 1978-10-12 | 1980-04-16 | Nippon Oil & Fats Co Ltd | Resin composition for cationic electrodeposition coating |
US4374209A (en) | 1980-10-01 | 1983-02-15 | Interchem International S.A. | Polymer-modified polyols useful in polyurethane manufacture |
DE3112117A1 (de) | 1981-03-27 | 1982-10-07 | Bayer Ag, 5090 Leverkusen | Verwendung von in wasser dispergierbaren polyisocyanat-zubereitungen als zusatzmittel fuer waessrige klebstoffe |
DE3210051A1 (de) | 1982-03-19 | 1983-09-29 | Basf Farben + Fasern Ag, 2000 Hamburg | Wasserverduennbares ueberzugsmittel zur herstellung der basisschicht eines mehrschichtueberzuges |
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DE3231062A1 (de) | 1982-08-20 | 1984-02-23 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von beschichtungsmassen, waessrige dispersionen von pu-reaktiv-systemen und ihre verwendung zur beschichtung |
US4431763A (en) | 1982-08-31 | 1984-02-14 | Minnesota Mining And Manufacturing Company | Flexible solvent barrier coating |
US4444976A (en) | 1982-12-20 | 1984-04-24 | The Goodyear Tire & Rubber Company | Sag resistant two component adhesive and sealant |
US4540633A (en) | 1983-04-20 | 1985-09-10 | Textron, Inc. | Water dispersible polyurethane adhesive compositions and adhesive layer formed therefrom |
US4501852A (en) | 1983-06-20 | 1985-02-26 | Mobay Chemical Corporation | Stable, aqueous dispersions of polyurethane-ureas |
NL8401785A (nl) | 1984-06-04 | 1986-01-02 | Polyvinyl Chemie Holland | Werkwijze voor de bereiding van een waterige dispersie van urethan-acrylaat entcopolymeren, alsmede aldus verkregen stabiele waterige dispersie. |
US4742095A (en) | 1985-07-25 | 1988-05-03 | Mobay Corporation | Continuous process for the production of aqueous polyurethane-urea dispersions |
DE3701547A1 (de) | 1987-01-21 | 1988-08-04 | Basf Lacke & Farben | Polyetherurethan, verfahren zu seiner herstellung, verlaufshilfsmittel und verwendung des polyetherurethans |
GB8721533D0 (en) | 1987-09-14 | 1987-10-21 | Polyvinyl Chemical Ind | Aqueous dispersions |
JP2757418B2 (ja) | 1989-02-01 | 1998-05-25 | 東洋紡績株式会社 | 袋用基材 |
US5071904A (en) | 1989-05-30 | 1991-12-10 | Ppg Industries, Inc. | Waterborne coating compositions for automotive applications |
US5037864A (en) | 1989-07-11 | 1991-08-06 | The Dow Chemical Company | Semi-continuous process for the preparation of polyurethane-urea aqueous dispersions |
JP3094109B2 (ja) | 1990-08-22 | 2000-10-03 | 関西ペイント株式会社 | 水性塗料及びそれを用いる塗装法 |
US5494960A (en) | 1990-12-10 | 1996-02-27 | H.B. Fuller Licensing & Financing, Inc. | Aqueous polyurethane dispersions and adhesives based thereon |
US5185200A (en) | 1991-03-28 | 1993-02-09 | Miles Inc. | Aqueous polyisocyanate dispersions with reduced isocyanate contents and their use for the production of fiberglass mats |
JPH055094A (ja) | 1991-04-19 | 1993-01-14 | Fukoku Co Ltd | 制電材料 |
DE4211787C1 (de) | 1992-04-08 | 1993-11-04 | Schott Glaswerke | Verfahren und vorrichtung zur herstellung eines filters in form eines keramischen wabenkoerper-monolithen |
US5589563A (en) | 1992-04-24 | 1996-12-31 | The Polymer Technology Group | Surface-modifying endgroups for biomedical polymers |
EP0746579B1 (en) | 1993-09-24 | 1998-08-05 | H.B. Fuller Licensing & Financing, Inc. | Aqueous anionic polyurethane dispersions |
GB9418688D0 (en) | 1994-09-16 | 1994-11-02 | Smith & Nephew | Elastomeric articles |
CA2175403C (en) | 1995-05-05 | 2008-09-02 | Stephen D. Seneker | Aqueous polyurethane dispersions based on polyether polyols of low monol content |
US5569706A (en) * | 1995-06-02 | 1996-10-29 | Bayer Corporation | Aqueous polyurea dispersions with improved hardness and solvent resistance |
US5539021A (en) | 1995-06-05 | 1996-07-23 | The Dow Chemical Company | Process for preparing high internal phase ratio emulsions and latexes derived thereof |
JPH09165425A (ja) | 1995-12-18 | 1997-06-24 | Toyo Ink Mfg Co Ltd | 水性ウレタン化合物の製造方法 |
US5576382A (en) | 1996-05-05 | 1996-11-19 | Arco Chemical Technology, L.P. | Aqueous polyurethane dispersions based on polyether polyols of low monol content |
GB9618504D0 (en) | 1996-09-05 | 1996-10-16 | Lrc Products | Thin walled elastic articles |
DE19708451A1 (de) | 1997-03-03 | 1998-09-10 | Basf Ag | Verfahren zum Herstellen von dünnwandigen elastischen Formkörpern |
-
1998
- 1998-03-16 AU AU65581/98A patent/AU750396B2/en not_active Ceased
- 1998-03-16 ZA ZA9802198A patent/ZA982198B/xx unknown
- 1998-03-16 CO CO98014585A patent/CO4870712A1/es unknown
- 1998-03-16 DE DE69801494T patent/DE69801494T2/de not_active Expired - Lifetime
- 1998-03-16 KR KR10-1999-7008313A patent/KR100507015B1/ko not_active IP Right Cessation
- 1998-03-16 PL PL98335694A patent/PL335694A1/xx unknown
- 1998-03-16 WO PCT/US1998/005113 patent/WO1998041554A1/en active IP Right Grant
- 1998-03-16 ES ES98911679T patent/ES2159942T3/es not_active Expired - Lifetime
- 1998-03-16 JP JP54067398A patent/JP4128631B2/ja not_active Expired - Fee Related
- 1998-03-16 ID IDW991016A patent/ID23444A/id unknown
- 1998-03-16 AR ARP980101181A patent/AR012082A1/es unknown
- 1998-03-16 CN CN98803376A patent/CN1129619C/zh not_active Expired - Fee Related
- 1998-03-16 TR TR1999/02163T patent/TR199902163T2/xx unknown
- 1998-03-16 CA CA002281584A patent/CA2281584A1/en not_active Abandoned
- 1998-03-16 HU HU0001800A patent/HUP0001800A3/hu unknown
- 1998-03-16 BR BR9807257-9A patent/BR9807257A/pt unknown
- 1998-03-16 AT AT98911679T patent/ATE204886T1/de active
- 1998-03-16 EP EP98911679A patent/EP0971966B1/en not_active Expired - Lifetime
- 1998-03-17 TW TW087103917A patent/TW464659B/zh not_active IP Right Cessation
-
1999
- 1999-09-16 NO NO994496A patent/NO994496L/no unknown
-
2001
- 2001-08-17 US US09/932,131 patent/US20020010262A1/en not_active Abandoned
-
2002
- 2002-04-30 US US10/135,726 patent/US6720385B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
AR012082A1 (es) | 2000-09-27 |
CN1129619C (zh) | 2003-12-03 |
CA2281584A1 (en) | 1998-09-24 |
EP0971966B1 (en) | 2001-08-29 |
JP2001516384A (ja) | 2001-09-25 |
WO1998041554A1 (en) | 1998-09-24 |
PL335694A1 (en) | 2000-05-08 |
EP0971966A1 (en) | 2000-01-19 |
US20020010262A1 (en) | 2002-01-24 |
NO994496D0 (no) | 1999-09-16 |
US6720385B2 (en) | 2004-04-13 |
US20020165314A1 (en) | 2002-11-07 |
HUP0001800A3 (en) | 2000-12-28 |
NO994496L (no) | 1999-09-16 |
TR199902163T2 (xx) | 2000-04-21 |
JP4128631B2 (ja) | 2008-07-30 |
KR100507015B1 (ko) | 2005-08-09 |
ZA982198B (en) | 1999-12-17 |
ID23444A (id) | 2000-04-20 |
HUP0001800A2 (hu) | 2000-10-28 |
BR9807257A (pt) | 2000-05-02 |
AU750396B2 (en) | 2002-07-18 |
DE69801494D1 (de) | 2001-10-04 |
DE69801494T2 (de) | 2002-04-18 |
CN1250454A (zh) | 2000-04-12 |
CO4870712A1 (es) | 1999-12-27 |
AU6558198A (en) | 1998-10-12 |
TW464659B (en) | 2001-11-21 |
ATE204886T1 (de) | 2001-09-15 |
KR20000076219A (ko) | 2000-12-26 |
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