ES2137489T3 - Proceso para la isomerizacion de olefinas lineales en isoolefinas. - Google Patents
Proceso para la isomerizacion de olefinas lineales en isoolefinas.Info
- Publication number
- ES2137489T3 ES2137489T3 ES95905464T ES95905464T ES2137489T3 ES 2137489 T3 ES2137489 T3 ES 2137489T3 ES 95905464 T ES95905464 T ES 95905464T ES 95905464 T ES95905464 T ES 95905464T ES 2137489 T3 ES2137489 T3 ES 2137489T3
- Authority
- ES
- Spain
- Prior art keywords
- coke
- catalyst
- enough
- temperature
- isomerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000006317 isomerization reaction Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 4
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical class [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- 230000001737 promoting effect Effects 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 238000006471 dimerization reaction Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 230000008929 regeneration Effects 0.000 abstract 1
- 238000011069 regeneration method Methods 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/736—Chitin; Chitosan; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
- A61P17/02—Drugs for dermatological disorders for treating wounds, ulcers, burns, scars, keloids, or the like
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/90—Regeneration or reactivation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2767—Changing the number of side-chains
- C07C5/277—Catalytic processes
- C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0024—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid beta-D-Glucans; (beta-1,3)-D-Glucans, e.g. paramylon, coriolan, sclerotan, pachyman, callose, scleroglucan, schizophyllan, laminaran, lentinan or curdlan; (beta-1,6)-D-Glucans, e.g. pustulan; (beta-1,4)-D-Glucans; (beta-1,3)(beta-1,4)-D-Glucans, e.g. lichenan; Derivatives thereof
- C08B37/0027—2-Acetamido-2-deoxy-beta-glucans; Derivatives thereof
- C08B37/003—Chitin, i.e. 2-acetamido-2-deoxy-(beta-1,4)-D-glucan or N-acetyl-beta-1,4-D-glucosamine; Chitosan, i.e. deacetylated product of chitin or (beta-1,4)-D-glucosamine; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Materials Engineering (AREA)
- Dermatology (AREA)
- Medicinal Chemistry (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Polymers & Plastics (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Pharmacology & Pharmacy (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
ESTA INVENCION SE REFIERE A UN PROCESO EN EL CUAL UNA OLEFINA LINEAL SE CONVIERTE BAJO CONDICIONES DE ISOMERIZACION EN SU CORRESPONDIENTE ISOOLEFINA RAMIFICADA CON METILO MEDIANTE EL CONTACTO A UNA TEMPERATURA DE ENTRE 200 Y 650 GRADOS CENTIGRADOS COMO UN CATALIZADOR DE ISOMERIZACION QUE COMPRENDE (I) AL MENOS UNO ZEOLITO QUE TIENE SOLAMENTE EN UNA DIMENSION UNA ESTRUCTURA DE POROS QUE TIENE UN TAMAÑO DE PORO LO SUFICIENTEMENTE PEQUEÑO PARA RETARDAR LA DIMERIZACION DEL SUBPRODUCTO Y LA FORMACION DE COQUE Y LO SUFICIENTE MENTE GRANDE PARA PERMITIR LA ENTRADA DE LA OLEFINA LINEAL Y PARA PERMITIR LA FORMACION DE ISOOLEFINA RAMIFICADA CON METILO, (II) UN AMALGAMADOR DE ALUMINA Y (III) HASTA ALREDEDOR DEL 15% DE SU PESO DE UN METAL PROMOTOR DE LA OXIDACION DEL COQUE. DESPUES DE UN PERIODO DE FUNCIONAMIENTO, CUANDO SE HA DEPOSITADO SUFICIENTE COQUE SOBRE EL CATALIZADOR EN UNA CANTIDAD PARA REDUCIR SIGNIFICATIVAMENTE LA ACTIVIDAD DEL CATALIZADOR, EL CATALIZADOR ES DESPOSEIDO DEL HIDROCARBONO Y SEPONE EN CONTACTO ENTONCES A TEMPERATURA ELEVADA CON UN GAS QUE CONTENGA OXIGENO DURANTE UN TIEMPO SUFICIENTE PARA QUEMAR EL COQUE, POR EJEMPLO, PARA REGENERAR EL CATALIZADOR A UNA TEMPERATURA INFERIOR DE ALREDEDOR DE 565 GRADOS CENTIGRADOS. DESPUES DE LA REGENERACION, SE CONTINUA EL PROCESO DE ISOMERIZACION. EL USO DE PALADIO Y/O PLATINO COMO METAL PROMOTOR DE LA OXIDACION DEL COQUE ES PARTICULARMENTE DESEABLE.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/175,010 US5648585A (en) | 1993-12-29 | 1993-12-29 | Process for isomerizing linear olefins to isoolefins |
| PCT/US1994/014863 WO1995018084A1 (en) | 1993-12-29 | 1994-12-23 | Process for isomerizing linear olefins to isoolefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2137489T3 true ES2137489T3 (es) | 1999-12-16 |
Family
ID=22638463
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES95905464T Expired - Lifetime ES2137489T3 (es) | 1993-12-29 | 1994-12-23 | Proceso para la isomerizacion de olefinas lineales en isoolefinas. |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US5648585A (es) |
| EP (1) | EP0737176B1 (es) |
| JP (1) | JP3935202B2 (es) |
| KR (1) | KR100350180B1 (es) |
| CN (2) | CN1046929C (es) |
| AT (1) | ATE182870T1 (es) |
| AU (1) | AU697265B2 (es) |
| BR (1) | BR9408464A (es) |
| CA (1) | CA2180276C (es) |
| DE (1) | DE69419941T2 (es) |
| ES (1) | ES2137489T3 (es) |
| FI (1) | FI115969B (es) |
| MY (1) | MY111811A (es) |
| NO (2) | NO313742B1 (es) |
| RU (1) | RU2140410C1 (es) |
| SG (1) | SG52393A1 (es) |
| TW (1) | TW267998B (es) |
| WO (1) | WO1995018084A1 (es) |
| ZA (1) | ZA9410399B (es) |
Families Citing this family (80)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6342191B1 (en) | 1994-12-07 | 2002-01-29 | Apyron Technologies, Inc. | Anchored catalyst system and method of making and using thereof |
| EP1001921B1 (en) | 1997-07-21 | 2003-05-07 | The Procter & Gamble Company | Improved processes for making alkylbenzenesulfonate surfactants and products thereof |
| TR200000796T2 (tr) | 1997-07-21 | 2000-07-21 | The Procter & Gamble Company | Kristalinitesi kesintiye uğramış yüzey aktif madde karışımları içeren deterjan kompozisyonları |
| WO1999005241A1 (en) | 1997-07-21 | 1999-02-04 | The Procter & Gamble Company | Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof |
| PH11998001775B1 (en) * | 1997-07-21 | 2004-02-11 | Procter & Gamble | Improved alkyl aryl sulfonate surfactants |
| KR100391190B1 (ko) | 1997-07-21 | 2003-07-12 | 더 프록터 앤드 갬블 캄파니 | 개선된 알킬벤젠설포네이트 계면활성제 |
| HUP0003855A3 (en) | 1997-08-08 | 2001-11-28 | Procter & Gamble | Improved processes for making surfactants via adsorptive separation and products thereof |
| EP1022326A1 (en) | 1999-01-20 | 2000-07-26 | The Procter & Gamble Company | Hard surface cleaning compositions comprising modified alkylbenzene sulfonates |
| US6774099B1 (en) | 1999-01-20 | 2004-08-10 | The Procter & Gamble Company | Dishwashing detergent compositions containing mixtures or crystallinity-disrupted surfactants |
| EP1022325A3 (en) | 1999-01-20 | 2003-01-02 | The Procter & Gamble Company | Hard surface cleaning compositions comprising modified alkylbenzene sulfonates |
| CZ20012570A3 (cs) | 1999-01-20 | 2002-07-17 | The Procter & Gamble Company | Prostředky na mytí nádobí obsahující alkylbenzensulfonátové tenzidy |
| US6383273B1 (en) | 1999-08-12 | 2002-05-07 | Apyron Technologies, Incorporated | Compositions containing a biocidal compound or an adsorbent and/or catalyst compound and methods of making and using therefor |
| US7202205B1 (en) | 1999-09-01 | 2007-04-10 | Daniel Stedman Connor | Processes for making surfactants via adsorptive separation and products thereof |
| US6472441B1 (en) | 2000-07-24 | 2002-10-29 | Chevron U.S.A. Inc. | Methods for optimizing Fischer-Tropsch synthesis of hydrocarbons in the distillate fuel and/or lube base oil ranges |
| US7022637B2 (en) * | 2001-01-29 | 2006-04-04 | Bp Corporation North America Inc. | Selective methylation catalyst, method of catalyst manufacture and methylation process |
| JP2002263501A (ja) * | 2001-03-05 | 2002-09-17 | Toyota Motor Corp | 一酸化炭素選択酸化触媒およびその製造方法 |
| DE10161665A1 (de) * | 2001-12-14 | 2003-06-26 | Lurgi Ag | Verfahren zur thermischen Entkokung eines Zeolith-Katalysators |
| US20040176655A1 (en) * | 2003-02-05 | 2004-09-09 | Ayoub Paul Marie | Methods of preparing branched alkyl aromatic hydrocarbons |
| US7055602B2 (en) * | 2003-03-11 | 2006-06-06 | Shell Oil Company | Method and composition for enhanced hydrocarbons recovery |
| FI118517B (fi) * | 2003-03-14 | 2007-12-14 | Neste Oil Oyj | Menetelmä katalyyttien regeneroimiseksi |
| US6987078B2 (en) * | 2003-10-03 | 2006-01-17 | Fina Technology, Inc. | Alkylation and catalyst regenerative process |
| US7335802B2 (en) * | 2003-10-15 | 2008-02-26 | Shell Oil Company | Methods of preparing branched aliphatic alcohols |
| US7235507B2 (en) * | 2004-08-14 | 2007-06-26 | Sud-Chemie Inc. | Catalyst for purifying diesel engine exhaust emissions |
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| WO2022099016A1 (en) | 2020-11-05 | 2022-05-12 | Lyondell Chemical Technology, L.P. | Olefin isomerization with small crystallite zeolite catalyst |
| WO2022098965A1 (en) | 2020-11-05 | 2022-05-12 | Lyondell Chemical Technology, L.P. | Method of improving olefin isomerization |
| CN119998332A (zh) * | 2022-06-29 | 2025-05-13 | 陶氏环球技术有限责任公司 | 减少烷氧基醚从纤维素醚中释放的方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1017878B (it) * | 1974-08-02 | 1977-08-10 | Snam Progetti | Processo per la isomerizzazione di alcheni |
| EP0032543A1 (de) * | 1980-01-10 | 1981-07-29 | Chemische Werke Hüls Ag | Verfahren zur Isomerisierung von n-Alkenen |
| US4392003A (en) * | 1980-06-12 | 1983-07-05 | The British Petroleum Company Limited | Isobutene by dehydroisomerization of normal butane |
| FR2506297B1 (fr) * | 1981-05-21 | 1986-05-02 | Inst Francais Du Petrole | Procede d'isomerisation d'olefines |
| US4503282A (en) * | 1982-09-24 | 1985-03-05 | Standard Oil Company (Indiana) | Process to convert linear alkenes selectively using high concentrations of AMS-1B crystalline borosilicate catalyst |
| US4719189A (en) * | 1984-04-26 | 1988-01-12 | Mobil Oil Corporation | Reactivation of noble metal-containing zeolite catalyst materials |
| US4795623A (en) * | 1986-08-05 | 1989-01-03 | Shell Oil Company | Time effective method for preparing ferrierite |
| US4689312A (en) * | 1986-03-25 | 1987-08-25 | Mobil Oil Corporation | Procedure for regenerating platinum containing zeolite catalyst compositions |
| US4942027A (en) * | 1986-08-05 | 1990-07-17 | Shell Oil Company | Method for preparing ferrierite |
| US4855529A (en) * | 1988-04-25 | 1989-08-08 | Shell Oil Company | Isomerization process with preliminary normal paraffin and mono-methyl paraffin feed capture step |
| US5057635A (en) * | 1990-02-08 | 1991-10-15 | Uop | Process for isomerizing olefins in gasoline streams |
| GB9024342D0 (en) * | 1990-11-08 | 1990-12-19 | British Petroleum Co Plc | Process for the preparation of branched olefins |
| GB9103989D0 (en) * | 1991-02-26 | 1991-04-10 | Shell Int Research | Process for the conversion of a feedstock comprising linear olefins |
| SG67315A1 (en) * | 1991-06-05 | 1999-09-21 | Lyondell Petrochem | Process for isomerizing linear olefins to isoolefins |
| CN1032059C (zh) * | 1991-06-05 | 1996-06-19 | 莱昂德尔石油化学公司 | 将直链烯烃异构成异烯烃的方法 |
| US5227569A (en) * | 1991-08-19 | 1993-07-13 | Texaco Inc. | Skeletal isomerization of n-butylenes to isobutylene on boron-beta zeolites |
| DE4139552C2 (de) * | 1991-11-30 | 1996-05-30 | Chemtec Leuna Ges Fuer Chemie | Verfahren zur Skelettisomerisierung von n-Alkenen |
| US5221776A (en) * | 1992-05-11 | 1993-06-22 | Amoco Corporation | selective isomerization of olefinic hydrocarbons |
| US5393717A (en) * | 1993-05-18 | 1995-02-28 | Mobil Oil Corp. | Regeneration of noble metal containing zeolite catalysts via partial removal of carbonaceous deposits |
| US5489726A (en) * | 1994-04-26 | 1996-02-06 | Mobil Oil Corporation | Highly selective N-olefin isomerization process using multiple parallel reactors |
-
1993
- 1993-12-29 US US08/175,010 patent/US5648585A/en not_active Expired - Lifetime
-
1994
- 1994-12-23 AU AU14070/95A patent/AU697265B2/en not_active Expired
- 1994-12-23 WO PCT/US1994/014863 patent/WO1995018084A1/en not_active Ceased
- 1994-12-23 EP EP95905464A patent/EP0737176B1/en not_active Expired - Lifetime
- 1994-12-23 BR BRPI9408464-5A patent/BR9408464A/pt not_active IP Right Cessation
- 1994-12-23 AT AT95905464T patent/ATE182870T1/de active
- 1994-12-23 SG SG1996003910A patent/SG52393A1/en unknown
- 1994-12-23 CN CN94195040A patent/CN1046929C/zh not_active Expired - Lifetime
- 1994-12-23 KR KR1019960703568A patent/KR100350180B1/ko not_active Expired - Lifetime
- 1994-12-23 JP JP51815495A patent/JP3935202B2/ja not_active Expired - Lifetime
- 1994-12-23 RU RU96116838A patent/RU2140410C1/ru active
- 1994-12-23 DE DE69419941T patent/DE69419941T2/de not_active Expired - Lifetime
- 1994-12-23 CN CNB991052129A patent/CN1145529C/zh not_active Expired - Lifetime
- 1994-12-23 CA CA002180276A patent/CA2180276C/en not_active Expired - Lifetime
- 1994-12-23 ES ES95905464T patent/ES2137489T3/es not_active Expired - Lifetime
- 1994-12-24 TW TW083112448A patent/TW267998B/zh not_active IP Right Cessation
- 1994-12-29 MY MYPI94003555A patent/MY111811A/en unknown
- 1994-12-29 ZA ZA9410399A patent/ZA9410399B/xx unknown
-
1996
- 1996-06-28 NO NO19962770A patent/NO313742B1/no not_active IP Right Cessation
- 1996-06-28 FI FI962683A patent/FI115969B/fi not_active IP Right Cessation
-
2002
- 2002-09-04 NO NO20024215A patent/NO332081B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CA2180276A1 (en) | 1995-07-06 |
| WO1995018084A1 (en) | 1995-07-06 |
| NO20024215D0 (no) | 2002-09-04 |
| NO332081B1 (no) | 2012-06-18 |
| ATE182870T1 (de) | 1999-08-15 |
| AU697265B2 (en) | 1998-10-01 |
| NO962770D0 (no) | 1996-06-28 |
| MY111811A (en) | 2001-01-31 |
| ZA9410399B (en) | 1995-09-11 |
| JP3935202B2 (ja) | 2007-06-20 |
| NO962770L (no) | 1996-06-28 |
| EP0737176A1 (en) | 1996-10-16 |
| AU1407095A (en) | 1995-07-17 |
| JPH09509406A (ja) | 1997-09-22 |
| EP0737176B1 (en) | 1999-08-04 |
| RU2140410C1 (ru) | 1999-10-27 |
| FI962683A0 (fi) | 1996-06-28 |
| CN1046929C (zh) | 1999-12-01 |
| NO313742B1 (no) | 2002-11-25 |
| KR100350180B1 (ko) | 2002-12-06 |
| DE69419941D1 (de) | 1999-09-09 |
| CN1145529C (zh) | 2004-04-14 |
| NO20024215L (no) | 1996-06-28 |
| US5648585A (en) | 1997-07-15 |
| DE69419941T2 (de) | 2000-04-20 |
| CA2180276C (en) | 2006-02-21 |
| FI115969B (fi) | 2005-08-31 |
| SG52393A1 (en) | 1998-09-28 |
| BR9408464A (pt) | 1997-08-26 |
| TW267998B (es) | 1996-01-11 |
| CN1236671A (zh) | 1999-12-01 |
| FI962683A7 (fi) | 1996-08-28 |
| CN1143356A (zh) | 1997-02-19 |
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