ES2132513T3 - Procedimiento para preparar una zeolita y modificada. - Google Patents
Procedimiento para preparar una zeolita y modificada.Info
- Publication number
- ES2132513T3 ES2132513T3 ES95200302T ES95200302T ES2132513T3 ES 2132513 T3 ES2132513 T3 ES 2132513T3 ES 95200302 T ES95200302 T ES 95200302T ES 95200302 T ES95200302 T ES 95200302T ES 2132513 T3 ES2132513 T3 ES 2132513T3
- Authority
- ES
- Spain
- Prior art keywords
- zeolite
- prepare
- exchange
- procedure
- modified zeolite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/36—Steaming
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
LA INVENCION SE REFIERE A UN PROCESO PARA PREPARAR UNA ZEOLITA Y MODIFICADO, EN EL CUAL A LA ZEOLITA NAY SE EXPONE PRIMERO A UN INTERCAMBIO DE AMONIO, A LA ZEOLITA RESULTANTE DEL INTERCAMBIO DE AMONIO SE EXPONE A UN INTERCAMBIO DE ALUMINIO, A LA ZEOLITA EXPUESTO AL INTERCAMBIO DE ALUMINIO SE EXPONE A CALCINACION MEDIANTE VAPOR, Y SE INCORPORA UN COMPONENTE FOSFOROSO EN LA ZEOLITA CALCINADO CON VAPOR. TAMBIEN SE PRESENTA LA ZEOLITA Y QUE SE OBTIENE MEDIANTE EL PROCESO Y UN CATALIZADOR FCC QUE COMPRENDE DICHA ZEOLITA Y. EL CATALIZADOR FCC QUE COMPRENDE A LA ZEOLITA Y QUE CONTIENE FOSFORO Y QUE HA SIDO INTERCAMBIADO CON ALUMINIO DE ACUERDO CON LA INVENCION MUESTRA MENOS PRODUCCION DE COQUE, Y UNA SELECTIVIDAD MEJORADA A LAS OLEFINAS C3 EN COMPARACION CON LOS CATALIZADORES FCC QUE COMPRENDEN ZEOLITAS QUE O BIEN NO HAN SIDO INTERCAMBIADOS CON ALUMINIO O NO COMPRENDEN FOSFORO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR9400475A BR9400475A (pt) | 1994-02-09 | 1994-02-09 | Processo de preparação de zeólita modificada e zeólita modificada |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2132513T3 true ES2132513T3 (es) | 1999-08-16 |
Family
ID=4058277
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES95200302T Expired - Lifetime ES2132513T3 (es) | 1994-02-09 | 1995-02-08 | Procedimiento para preparar una zeolita y modificada. |
Country Status (8)
Country | Link |
---|---|
US (1) | US5576258A (es) |
EP (1) | EP0667185B1 (es) |
JP (1) | JPH08508970A (es) |
CN (1) | CN1070731C (es) |
BR (1) | BR9400475A (es) |
DE (1) | DE69510245T2 (es) |
ES (1) | ES2132513T3 (es) |
WO (1) | WO1995021693A1 (es) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6482313B1 (en) * | 1994-10-03 | 2002-11-19 | Exxonmobil Research And Engineering Company | FCC process incorporating crystalline microporous oxide catalysts having increased Lewis acidity |
US6673734B1 (en) * | 1994-10-03 | 2004-01-06 | Exxonmobil Research And Engineering Company | Crystalline microporous oxide catalysts having increased Lewis acidity and methods for the preparation thereof |
CN1055063C (zh) * | 1996-09-27 | 2000-08-02 | 中国石油化工总公司 | 一种改性y沸石及其制备方法 |
US6379646B1 (en) * | 1997-06-17 | 2002-04-30 | Chevron U.S.A. Inc. | Crystalline phosphorus-containing molecular sieves |
FR2778343B1 (fr) | 1998-05-06 | 2000-06-16 | Inst Francais Du Petrole | Catalyseur a base de zeolithe y non globalement desaluminee, de bore et/ou de silicium et procede d'hydrocraquage |
FR2780311B1 (fr) * | 1998-06-25 | 2000-08-11 | Inst Francais Du Petrole | Catalyseur d'hydrocraquage comprenant une zeolithe y non globalement desaluminee, un element du groupe vb, et un element promoteur choisi dans le groupe forme par le bore, le phosphore et le silicium |
ATE277867T1 (de) * | 1999-03-03 | 2004-10-15 | Pq Holding Inc | Verfahren zur herstellung eines modifizierten zeolith |
CN1091399C (zh) * | 1999-06-04 | 2002-09-25 | 中国石油化工集团公司 | 一种y型沸石的改性方法 |
CN1112247C (zh) * | 1999-11-17 | 2003-06-25 | 中国石化集团齐鲁石油化工公司 | 含小晶粒y型分子筛的催化剂的制备 |
JP2000202281A (ja) * | 2000-04-20 | 2000-07-25 | Air Water Inc | 選択的窒素吸着剤およびそれを用いた空気分離方法 |
CN1288225C (zh) * | 2000-08-31 | 2006-12-06 | 埃克森美孚研究工程公司 | 结合路易斯酸性增加的晶态微孔氧化物催化剂的fcc方法 |
WO2004108273A1 (en) * | 2003-06-06 | 2004-12-16 | Zeochem Ag | Method for sulfur compounds removal from contaminated gas and liquid streams |
CN1332758C (zh) * | 2004-02-27 | 2007-08-22 | 中国石油化工股份有限公司 | 一种含磷和无定形氧化硅的rey分子筛、制备方法及其应用 |
EP2082801A1 (en) | 2008-01-25 | 2009-07-29 | Total Petrochemicals Research Feluy | Process for obtaining modified molecular sieves |
JP5587297B2 (ja) | 2008-05-20 | 2014-09-10 | 中国石油化工股▲ふん▼有限公司 | 含酸劣質原油改質触媒、その製造方法、およびその応用 |
US20100144514A1 (en) * | 2008-12-09 | 2010-06-10 | Nicholas Christopher P | Process for Making Catalyst for Olefin Upgrading |
US20100144513A1 (en) * | 2008-12-09 | 2010-06-10 | Nicholas Christopher P | Catalyst for Olefin Upgrading |
FR2940265B1 (fr) * | 2008-12-22 | 2011-06-10 | Total Raffinage Marketing | Zeolithes y modifiees, leur procede de fabrication et leur utilisation |
JP5919586B2 (ja) * | 2010-01-20 | 2016-05-18 | Jxエネルギー株式会社 | 炭化水素製造用触媒および炭化水素の製造方法 |
EP2527036A4 (en) * | 2010-01-20 | 2014-03-05 | Jx Nippon Oil & Energy Corp | CATALYST FOR USE IN THE PRODUCTION OF MONOCYCLIC AROMATIC HYDROCARBONS AND METHOD FOR THE PRODUCTION OF MONOCYCLIC AROMATIC HYDROCARBONS |
JP5528969B2 (ja) * | 2010-09-29 | 2014-06-25 | 水澤化学工業株式会社 | 除湿剤 |
CA2854610C (en) * | 2011-11-04 | 2020-03-31 | Basf Corporation | Phosphorus modified cracking catalysts with enhanced activity and hydrothermal stability |
CN102887731B (zh) * | 2012-09-25 | 2014-11-05 | 李成哲 | 肥料用含钾矿石及其制备方法与应用 |
WO2014097350A1 (ja) * | 2012-12-19 | 2014-06-26 | 昭和電工株式会社 | 炭化水素接触分解用触媒の製造方法、芳香族炭化水素および/または炭素数4以下のオレフィンの製造方法、および炭化水素接触分解用触媒 |
WO2014129585A1 (ja) | 2013-02-21 | 2014-08-28 | Jx日鉱日石エネルギー株式会社 | 単環芳香族炭化水素の製造方法 |
CN104628010B (zh) * | 2013-11-08 | 2017-01-04 | 中国石油天然气股份有限公司 | 一种y型沸石的改性处理方法 |
KR20180075687A (ko) | 2015-11-24 | 2018-07-04 | 바스프 코포레이션 | 부틸렌 수율을 증가시키기 위한 유동 접촉 분해 촉매 |
CN111099616B (zh) * | 2018-10-29 | 2022-07-12 | 中国石油化工股份有限公司 | 一种改性y型分子筛及其制备方法和应用 |
CN110980756B (zh) * | 2019-11-22 | 2021-06-08 | 中触媒新材料股份有限公司 | 一种以磷改性y型分子筛为原料制备ssz-39分子筛的方法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE635482A (es) * | 1962-07-27 | |||
US3252889A (en) * | 1963-07-16 | 1966-05-24 | Gulf Research Development Co | Cracking catalyst and process of cracking |
US3455842A (en) * | 1964-02-20 | 1969-07-15 | Air Prod & Chem | Cracking catalyst comprising aluminum zeolite |
US3293192A (en) * | 1965-08-23 | 1966-12-20 | Grace W R & Co | Zeolite z-14us and method of preparation thereof |
US3506400A (en) * | 1966-05-25 | 1970-04-14 | Exxon Research Engineering Co | High silica crystalline zeolites and process for their preparation |
US3609103A (en) * | 1967-07-31 | 1971-09-28 | Exxon Research Engineering Co | Hydrocarbon conversion catalysts containing dispersed clay |
US3591488A (en) * | 1969-06-11 | 1971-07-06 | Exxon Research Engineering Co | High silica crystalline zeolites and processes for their preparation |
US3676330A (en) * | 1969-12-15 | 1972-07-11 | Mobil Oil Corp | Zeolite-containing catalyst, synthesis and use thereof |
US3743594A (en) * | 1971-05-14 | 1973-07-03 | Chevron Res | Hydrodesulfurization of naphtha with a group viii metal component combined with synthetic layered crystalline aluminosilicate |
US4218307A (en) * | 1975-04-24 | 1980-08-19 | W. R. Grace & Co. | Hydrocarbon cracking catalyst |
US4224188A (en) * | 1978-03-13 | 1980-09-23 | Filtrol Corporation | Aluminum faujasites, catalyst containing same and process of producing same |
US4357265A (en) * | 1980-10-28 | 1982-11-02 | W. R. Grace & Co. | Catalytic cracking catalyst |
US4454241A (en) * | 1982-05-24 | 1984-06-12 | Exxon Research And Engineering Co. | Phosphorus-containing catalyst |
SE8602341D0 (sv) * | 1986-05-22 | 1986-05-22 | Eka Nobel Ab | Sett att framstella en modifierad zeolit y |
US4839319A (en) * | 1986-07-11 | 1989-06-13 | Exxon Research And Engineering Company | Hydrocarbon cracking catalysts and processes for utilizing the same |
CA1297861C (en) * | 1986-07-11 | 1992-03-24 | William L. Schuette | Hydrocarbon cracking catalysts and processes utilizing the same |
JPH07106317B2 (ja) * | 1987-02-13 | 1995-11-15 | 触媒化成工業株式会社 | 炭化水素油の接触分解用触媒組成物の製造方法 |
CA2015335A1 (en) * | 1989-05-12 | 1990-11-12 | Terry G. Roberie | Catalytic compositions |
IT1250435B (it) * | 1991-07-01 | 1995-04-07 | Mini Ricerca Scient Tecnolog | Catalizzatore per l'alchilazione di composti aromatici e processo impiegante lo stesso |
US5378670A (en) * | 1993-04-16 | 1995-01-03 | W. R. Grace & Co.-Conn. | Phosphorus zeolites/molecular sieves |
-
1994
- 1994-02-09 BR BR9400475A patent/BR9400475A/pt not_active IP Right Cessation
-
1995
- 1995-02-08 US US08/385,251 patent/US5576258A/en not_active Expired - Lifetime
- 1995-02-08 JP JP7520865A patent/JPH08508970A/ja active Pending
- 1995-02-08 ES ES95200302T patent/ES2132513T3/es not_active Expired - Lifetime
- 1995-02-08 DE DE69510245T patent/DE69510245T2/de not_active Expired - Lifetime
- 1995-02-08 WO PCT/BR1995/000009 patent/WO1995021693A1/en active Application Filing
- 1995-02-08 CN CN95190006A patent/CN1070731C/zh not_active Expired - Lifetime
- 1995-02-08 EP EP95200302A patent/EP0667185B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69510245T2 (de) | 1999-12-16 |
CN1070731C (zh) | 2001-09-12 |
US5576258A (en) | 1996-11-19 |
EP0667185B1 (en) | 1999-06-16 |
CN1122111A (zh) | 1996-05-08 |
BR9400475A (pt) | 1995-09-19 |
JPH08508970A (ja) | 1996-09-24 |
DE69510245D1 (de) | 1999-07-22 |
EP0667185A1 (en) | 1995-08-16 |
WO1995021693A1 (en) | 1995-08-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FA2A | Application withdrawn |
Effective date: 19970406 |
|
FG2A | Definitive protection |
Ref document number: 667185 Country of ref document: ES |