ES2130132T3 - Procedimiento para la preparacion de un componente catalitico solido para la (co)polimerizacion de etileno. - Google Patents
Procedimiento para la preparacion de un componente catalitico solido para la (co)polimerizacion de etileno.Info
- Publication number
- ES2130132T3 ES2130132T3 ES91201482T ES91201482T ES2130132T3 ES 2130132 T3 ES2130132 T3 ES 2130132T3 ES 91201482 T ES91201482 T ES 91201482T ES 91201482 T ES91201482 T ES 91201482T ES 2130132 T3 ES2130132 T3 ES 2130132T3
- Authority
- ES
- Spain
- Prior art keywords
- polymerization
- ethylene
- ethanol
- procedure
- solid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007787 solid Substances 0.000 title abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 2
- 239000005977 Ethylene Substances 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 230000003197 catalytic effect Effects 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229910021332 silicide Inorganic materials 0.000 abstract 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000011949 solid catalyst Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
UN COMPONENTE CATALIZADOR SOLIDO PARA LA (CO) POLIMERIZACION DE ETILENO, QUE CONSISTE EN UN SOPORTE DE SILICE EN PARTICULAS Y UNA PARTE ACTIVA CATALITICAMENTE CONTENIENDO TITANIO, MAGNESIO, CLORURO Y GRUPOS ALCOXI, SE OBTIENE POR A) PREPARANDO UNA SOLUCION DE CLORURO DE MAGNESIO EN ETANOL; B) IMPREGNANDO SILICE EN PARTICULAS CON DICHA SOLUCION; C) ELIMINANDO EL ETANOL NO ABSORBIDO DE LA SUSPENSION; D) ELIMINANDO EL ETANOL ABSORBIDO DEL SOLIDO; E) INTERACTUANDO EL SOLIDO RESULTANTE CON UN CLORURO DE TITANIO O CLOROALCOXIDO; Y POSIBLEMENTE INTERACTUANDO CON CLORURO DE ALQUILO ALUMINIO. EN UNA REALIZACION PREFERENTE EN LA ETAPA E); SE AÑADE UN HALIDO DE SILICIO PARA MEJORAR LA ACTIVIDAD CATALIZADORA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT02074090A IT1248981B (it) | 1990-06-22 | 1990-06-22 | Procedimento per la preparazione di un componente solido di catalizzatore per la (co)polimerizzazione dell'etilene |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2130132T3 true ES2130132T3 (es) | 1999-07-01 |
Family
ID=11171349
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES91201482T Expired - Lifetime ES2130132T3 (es) | 1990-06-22 | 1991-06-14 | Procedimiento para la preparacion de un componente catalitico solido para la (co)polimerizacion de etileno. |
Country Status (20)
Country | Link |
---|---|
US (1) | US5173465A (es) |
EP (1) | EP0463672B1 (es) |
JP (1) | JP3303240B2 (es) |
CN (1) | CN1038593C (es) |
AT (1) | ATE179720T1 (es) |
BR (1) | BR9102615A (es) |
CA (1) | CA2045188C (es) |
CZ (1) | CZ287448B6 (es) |
DE (1) | DE69131188T2 (es) |
DK (1) | DK0463672T3 (es) |
ES (1) | ES2130132T3 (es) |
FI (1) | FI99206C (es) |
GR (1) | GR3030343T3 (es) |
HU (1) | HU210116B (es) |
IT (1) | IT1248981B (es) |
NO (1) | NO178828C (es) |
RO (1) | RO108794B1 (es) |
RU (1) | RU2054434C1 (es) |
SK (1) | SK282055B6 (es) |
ZA (1) | ZA914541B (es) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1252041B (it) * | 1990-10-11 | 1995-05-29 | Enimont Anic Srl | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene |
IT1251465B (it) * | 1991-07-12 | 1995-05-15 | Enichem Polimeri | Catalizzatore supportato per la (co)polimerizzazione dell'etilene. |
US5583083A (en) * | 1991-12-31 | 1996-12-10 | Neste Oy | Procatalyst composition for homo- and copolymerization of alpha olefins, its preparation and its use |
EP0797596B1 (en) * | 1993-12-16 | 1999-03-03 | Exxon Chemical Patents Inc. | Catalyst for polymerizing olefins |
DE69807367D1 (de) * | 1997-02-17 | 2002-10-02 | Borealis Gmbh Schwechat Mannsw | Träger für Olefinpolymerisationskatalysatoren |
CZ34998A3 (cs) * | 1997-02-17 | 1999-08-11 | Pcd Polymere Gesellschaft M. B. H. | Způsob přípravy pevného nosiče pro katalyzátory polymerace olefinů |
US6855655B2 (en) * | 2002-07-15 | 2005-02-15 | Univation Technologies, Llc | Supported polymerization catalyst |
US6982237B2 (en) * | 2002-07-15 | 2006-01-03 | Univation Technologies, Llc | Spray-dried polymerization catalyst and polymerization processes employing same |
US7402546B2 (en) * | 2004-09-23 | 2008-07-22 | Equistar Chemicals, Lp | Magnesium chloride support |
US6967231B1 (en) | 2004-09-23 | 2005-11-22 | Equistar Chemicals, Lp | Olefin polymerization process |
US7326757B2 (en) * | 2005-07-20 | 2008-02-05 | Basf Catalysts Llc | Supported catalyst for olefin polymerization |
CN103145891A (zh) * | 2013-01-30 | 2013-06-12 | 中国石油天然气股份有限公司 | 一种烯烃聚合催化剂及其制备和应用 |
CN104231125B (zh) * | 2013-06-08 | 2016-09-14 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
JP5902210B2 (ja) | 2013-06-08 | 2016-04-13 | 中国石油化工股▲ふん▼有限公司 | 担持型非メタロセン触媒、その製造方法およびその使用 |
CN104231126A (zh) * | 2013-06-08 | 2014-12-24 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
US10717801B2 (en) | 2015-10-12 | 2020-07-21 | Institute Of Chemistry, Chinese Academy Of Sciences | Use of organosilane, in-reactor polyolefin alloy and preparation method thereof |
WO2017063118A1 (zh) | 2015-10-12 | 2017-04-20 | 中国科学院化学研究所 | 烯烃聚合催化剂及其制备方法和烯烃聚合催化剂体系及其应用以及聚烯烃树脂的制备方法 |
WO2017063116A1 (zh) | 2015-10-12 | 2017-04-20 | 中国科学院化学研究所 | 一种有机硅烷的应用以及聚烯烃树脂及其制备方法 |
CN105504113B (zh) * | 2016-01-25 | 2018-01-26 | 山东玉皇盛世化工股份有限公司 | 合成反式‑1,4‑聚异戊二烯的催化剂的制备方法 |
EP3681914B1 (en) * | 2017-09-15 | 2022-04-20 | Basell Poliolefine Italia S.r.l. | Process for the preparation of catalyst components for the polymerization of olefins |
WO2020069847A1 (en) | 2018-10-01 | 2020-04-09 | Basell Poliolefine Italia S.R.L. | Precursors and catalyst components for the polymerization of olefins |
CN113637100A (zh) * | 2021-09-14 | 2021-11-12 | 无锡玖汇科技有限公司 | 一种高氯化镁含量的硅胶复合载体 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1136627B (it) * | 1981-05-21 | 1986-09-03 | Euteco Impianti Spa | Catalizzatore supportato per la polimerizzazione di etilene |
US4477588A (en) * | 1982-12-15 | 1984-10-16 | Phillips Petroleum Company | Polyolefin polymerization process and catalyst |
US4467044A (en) * | 1982-12-20 | 1984-08-21 | Stauffer Chemical Company | Supported catalyst for polymerization of olefins |
US4565797A (en) * | 1984-08-03 | 1986-01-21 | Exxon Research & Engineering Co. | Polymerization catalyst, production and use (P-1010) |
DE3777592D1 (de) * | 1986-12-24 | 1992-04-23 | Basf Ag | Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems. |
DE3711919A1 (de) * | 1987-04-08 | 1988-10-27 | Basf Ag | Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems |
-
1990
- 1990-06-22 IT IT02074090A patent/IT1248981B/it active IP Right Grant
-
1991
- 1991-06-13 ZA ZA914541A patent/ZA914541B/xx unknown
- 1991-06-14 DK DK91201482T patent/DK0463672T3/da active
- 1991-06-14 ES ES91201482T patent/ES2130132T3/es not_active Expired - Lifetime
- 1991-06-14 EP EP91201482A patent/EP0463672B1/en not_active Expired - Lifetime
- 1991-06-14 SK SK1838-91A patent/SK282055B6/sk not_active IP Right Cessation
- 1991-06-14 US US07/715,788 patent/US5173465A/en not_active Expired - Lifetime
- 1991-06-14 CZ CS19911838A patent/CZ287448B6/cs not_active IP Right Cessation
- 1991-06-14 AT AT91201482T patent/ATE179720T1/de not_active IP Right Cessation
- 1991-06-14 DE DE69131188T patent/DE69131188T2/de not_active Expired - Fee Related
- 1991-06-19 NO NO912380A patent/NO178828C/no unknown
- 1991-06-20 FI FI913020A patent/FI99206C/fi active IP Right Grant
- 1991-06-21 CA CA002045188A patent/CA2045188C/en not_active Expired - Fee Related
- 1991-06-21 JP JP17584691A patent/JP3303240B2/ja not_active Expired - Fee Related
- 1991-06-21 RU SU914895714A patent/RU2054434C1/ru not_active IP Right Cessation
- 1991-06-21 HU HU912087A patent/HU210116B/hu not_active IP Right Cessation
- 1991-06-21 BR BR919102615A patent/BR9102615A/pt not_active IP Right Cessation
- 1991-06-21 RO RO147870A patent/RO108794B1/ro unknown
- 1991-06-22 CN CN91104207A patent/CN1038593C/zh not_active Expired - Fee Related
-
1999
- 1999-05-27 GR GR990401432T patent/GR3030343T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
DE69131188D1 (de) | 1999-06-10 |
ATE179720T1 (de) | 1999-05-15 |
HU210116B (en) | 1995-02-28 |
HUT57797A (en) | 1991-12-30 |
IT9020740A1 (it) | 1991-12-22 |
IT1248981B (it) | 1995-02-11 |
RO108794B1 (ro) | 1994-08-30 |
NO178828C (no) | 1996-06-12 |
GR3030343T3 (en) | 1999-09-30 |
FI99206B (fi) | 1997-07-15 |
SK282055B6 (sk) | 2001-10-08 |
FI913020A (fi) | 1991-12-23 |
DK0463672T3 (da) | 1999-11-01 |
EP0463672B1 (en) | 1999-05-06 |
BR9102615A (pt) | 1992-01-21 |
CN1057467A (zh) | 1992-01-01 |
CA2045188A1 (en) | 1991-12-23 |
NO178828B (no) | 1996-03-04 |
CS183891A3 (en) | 1992-02-19 |
CZ287448B6 (cs) | 2000-11-15 |
JP3303240B2 (ja) | 2002-07-15 |
FI913020A0 (fi) | 1991-06-20 |
NO912380D0 (no) | 1991-06-19 |
RU2054434C1 (ru) | 1996-02-20 |
IT9020740A0 (es) | 1990-06-22 |
ZA914541B (en) | 1992-03-25 |
EP0463672A2 (en) | 1992-01-02 |
NO912380L (no) | 1991-12-23 |
CN1038593C (zh) | 1998-06-03 |
CA2045188C (en) | 2002-12-10 |
JPH04226108A (ja) | 1992-08-14 |
EP0463672A3 (en) | 1992-11-19 |
US5173465A (en) | 1992-12-22 |
FI99206C (fi) | 1997-10-27 |
DE69131188T2 (de) | 1999-08-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ES2130132T3 (es) | Procedimiento para la preparacion de un componente catalitico solido para la (co)polimerizacion de etileno. | |
BR8907158A (pt) | Processo para utilizar trietilaluminio no preparo de um suporte de alumoxana destinado a um catalisador de metaloceno ativo | |
BR9508869A (pt) | Componente de catalisador suportado processo para preparar um componente de catalisador suportado composição de catalisador suportador e processo de polimerização de olefine | |
ES2041053T3 (es) | Catalizadores para la polimerizacion de olefinas. | |
MY110349A (en) | Process for the gas-phase polymerization of olefins | |
FI895646A0 (fi) | Foerfarande foer framstaellning av en kiselgelburen metallocenalumoxankatalysator. | |
IT1227258B (it) | Componenti e catalizzatori per la polimerizzazione di olefine | |
KR900018152A (ko) | 올레핀 중합용 성분 및 촉매 | |
CA2050815A1 (en) | Solid component of catalyst for the (co)polymerization of ethylene | |
ITMI910813A1 (it) | Componenti e catalizzatori per la polimerizzazione di olefine | |
ES2088455T3 (es) | Catalizador soportado para la polimerizacion de etileno y la copolimerizacion de etileno con alfa-olefinas, su preparacion y su uso. | |
KR910002879A (ko) | 유기실란 화합물 | |
ES2083468T3 (es) | Metodo para la preparacion de un componente catalizador para la polimerizacion de olefinas, componente catalizador de polimerizacion producido por el metodo y el uso del mismo. | |
BR0012220A (pt) | Complexos de alcóxidos de magnésio/titânio catalisadores de polimerização feitos destes, e seu uso | |
NO171859C (no) | Fremgangsmaate for fremstilling av en katalysator for kopolymerisasjon av etylen og anvendelse av katalysatoren | |
NO179332C (no) | Fremgangsmåte for fremstilling av en fast katalysatorbestanddel for anvendelse ved (ko)polymerisasjon av etylen | |
FI935551A0 (fi) | Foerfarande foer framstaellning av eten(ko)polymerer med bred molmassafoerdelning | |
RU93054514A (ru) | Способ получения гомополимеров и сополимеров этилена | |
YU46479B (sh) | Postupak za dobijanje katalitičkog kompleksa | |
EP0417724A2 (en) | Coordination polymerization of styrene monomer | |
KR950701550A (ko) | 올레핀 중합 촉매계(olefin polymerization catalyst system) | |
IT1243720B (it) | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e procedimento per la sua preparazione. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
Ref document number: 463672 Country of ref document: ES |