ES2129041T3 - Catalizadores de combustion parcial de paladio y procedimiento para usarlos. - Google Patents
Catalizadores de combustion parcial de paladio y procedimiento para usarlos.Info
- Publication number
- ES2129041T3 ES2129041T3 ES92905922T ES92905922T ES2129041T3 ES 2129041 T3 ES2129041 T3 ES 2129041T3 ES 92905922 T ES92905922 T ES 92905922T ES 92905922 T ES92905922 T ES 92905922T ES 2129041 T3 ES2129041 T3 ES 2129041T3
- Authority
- ES
- Spain
- Prior art keywords
- catalyst
- temperature
- palladium
- combustion
- support
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
- F01N3/2807—Metal other than sintered metal
- F01N3/281—Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0225—Coating of metal substrates
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/02—Metallic plates or honeycombs, e.g. superposed or rolled-up corrugated or otherwise deformed sheet metal
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/30—Honeycomb supports characterised by their structural details
- F01N2330/32—Honeycomb supports characterised by their structural details characterised by the shape, form or number of corrugations of plates, sheets or foils
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2510/00—Surface coverings
- F01N2510/06—Surface coverings for exhaust purification, e.g. catalytic reaction
- F01N2510/068—Surface coverings for exhaust purification, e.g. catalytic reaction characterised by the distribution of the catalytic coatings
- F01N2510/0682—Surface coverings for exhaust purification, e.g. catalytic reaction characterised by the distribution of the catalytic coatings having a discontinuous, uneven or partially overlapping coating of catalytic material, e.g. higher amount of material upstream than downstream or vice versa
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Toxicology (AREA)
- Catalysts (AREA)
- Gas Burners (AREA)
Abstract
ESTA INVENCION SE REFIERE A UN CATALIZADOR QUE CONTIENE PALADIO EN UN SOPORTE (102) Y A UN PROCESO DE COMBUSTION PARCIAL EN EL QUE EL COMBUSTIBLE SE QUEMA PARCIALMENTE UTILIZANDO ESE CATALIZADOR. EL CATALIZADOR DE PALADIO (106) PUEDE CONTENER TAMBIEN PALADIO MEZCLADO CON METALES SELECCIONADOS DEL GRUPO VIII O IB, SE PUEDE GRADUAR (FIG. 1B) DE MANERA QUE TENGA UNA MAYOR ACTIVIDAD EN EL BORDE ANTERIOR (112) DEL CATALIZADOR O SE PUEDE COLOCAR EN UN SOPORTE QUE CONTENGA ZIRCONIA. CADA UNA DE LAS ELECCIONES DE LOS CATALIZADOR (106) Y SOPORTES (102, 110) ESPECIFICADOS RESUELVE LOS DISTINTOS PROBLEMAS QUE TIENEN QUE VER CON LA ESTABILIDAD A LARGO PLAZO DEL PALADIO COMO CATALIZADOR DE COMBUSTION PARCIAL. LA ESTRUCTURA DEL CATALIZADOR ES ESTABLE CUANDO SE ENCUENTRA EN FUNCIONAMIENTO, TIENE UNA TEMPERATURA DE FUNCIONAMIENTO COMPARATIVAMENTE BAJA, LA OXIDACION EMPIEZA A UNA TEMPERATURA BAJA Y AUN NO SE PRODUCE UN "EMBALAMIENTO" DE LA TEMPERATURA. EL GAS DE COMBUSTION PRODUCIDO POR EL PROCESO CATALITICO TIENE NORMALMENTE UNA TEMPERATURA INFERIOR A LA TEMPERATURA DE AUTOCOMBUSTION Y SE PUEDE UTILIZAR A ESA TEMPERATURA O SE PUEDE ALIMENTAR A OTROS ESTADOS DE COMBUSTION PARA UTILIZARLOS TAMBIEN EN UNA TURBINA DE GAS, UN HORNO, UNA CALDERA O SIMILAR.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US61798190A | 1990-11-26 | 1990-11-26 | |
| US07/617,974 US5250489A (en) | 1990-11-26 | 1990-11-26 | Catalyst structure having integral heat exchange |
| US07/617,975 US5326253A (en) | 1990-11-26 | 1990-11-26 | Partial combustion process and a catalyst structure for use in the process |
| US07/617,979 US5259754A (en) | 1990-11-26 | 1990-11-26 | Partial combustion catalyst of palladium on a zirconia support and a process for using it |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2129041T3 true ES2129041T3 (es) | 1999-06-01 |
Family
ID=27505143
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES92905922T Expired - Lifetime ES2129041T3 (es) | 1990-11-26 | 1991-11-26 | Catalizadores de combustion parcial de paladio y procedimiento para usarlos. |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0559844B1 (es) |
| JP (1) | JP3191013B2 (es) |
| KR (1) | KR100261782B1 (es) |
| AT (1) | ATE176605T1 (es) |
| AU (1) | AU1335792A (es) |
| DE (1) | DE69130894T2 (es) |
| ES (1) | ES2129041T3 (es) |
| RU (1) | RU2153631C2 (es) |
| WO (1) | WO1992009848A1 (es) |
Families Citing this family (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5474441A (en) * | 1989-08-22 | 1995-12-12 | Engelhard Corporation | Catalyst configuration for catalytic combustion systems |
| EP0605251A1 (en) * | 1992-12-28 | 1994-07-06 | Kabushiki Kaisha Riken | Exhaust gas cleaner |
| JPH08507599A (ja) * | 1993-03-01 | 1996-08-13 | エンゲルハード・コーポレーシヨン | 分離体物体を含む改善された接触的燃焼システム |
| AU6268094A (en) * | 1993-03-04 | 1994-09-26 | Engelhard Corporation | Improved substrate configuration for catalytic combustion system |
| EP0645171B1 (en) * | 1993-09-21 | 1997-11-26 | National Science Council | Palladium-alloy catalyst for thermal decomposition of NO |
| FR2742680B1 (fr) * | 1995-12-22 | 1998-01-16 | Inst Francais Du Petrole | Catalyseur de combustion et procede de combustion utilisant un tel catalyseur |
| FR2743008B1 (fr) * | 1995-12-28 | 1998-01-30 | Inst Francais Du Petrole | Procede de combustion catalytique a plusieurs zones catalytiques successives |
| FR2743616B1 (fr) | 1996-01-15 | 1998-02-27 | Inst Francais Du Petrole | Systeme de combustion catalytique a injection etagee de combustible |
| FR2743511B1 (fr) | 1996-01-15 | 1998-02-27 | Inst Francais Du Petrole | Procede de combustion catalytique a injection etagee de combustible |
| US20010026838A1 (en) | 1996-06-21 | 2001-10-04 | Engelhard Corporation | Monolithic catalysts and related process for manufacture |
| SE518816C2 (sv) * | 1997-10-20 | 2002-11-26 | Kanthal Ab | Förfarande för avgasrening jämte gasbrännare |
| WO1999055459A1 (en) | 1998-04-28 | 1999-11-04 | Engelhard Corporation | Monolithic catalysts and related process for manufacture |
| JP4226143B2 (ja) * | 1998-06-05 | 2009-02-18 | パナソニック株式会社 | 触媒燃焼装置及びその燃焼制御方法 |
| US6174159B1 (en) | 1999-03-18 | 2001-01-16 | Precision Combustion, Inc. | Method and apparatus for a catalytic firebox reactor |
| US6375910B1 (en) | 1999-04-02 | 2002-04-23 | Engelhard Corporation | Multi-zoned catalytic trap and methods of making and using the same |
| JP4350250B2 (ja) * | 2000-01-27 | 2009-10-21 | 株式会社キャタラー | 排気ガス浄化用触媒 |
| US6727097B2 (en) | 2000-06-15 | 2004-04-27 | Engelhard Corporation | Method and apparatus for accelerated catalyst poisoning and deactivation |
| US6586254B1 (en) | 2000-06-15 | 2003-07-01 | Engelhard Corporation | Method and apparatus for accelerated catalyst poisoning and deactivation |
| US6540843B1 (en) * | 2000-09-12 | 2003-04-01 | Honeywell International Inc. | Method of preparing a catalyst layer over a metallic surface of a recuperator |
| DE10110465B4 (de) * | 2001-03-05 | 2005-12-08 | Vodafone Pilotentwicklung Gmbh | Reaktor |
| US7276212B2 (en) | 2001-10-01 | 2007-10-02 | Engelhard Corporation | Exhaust articles for internal combustion engines |
| US6948928B2 (en) * | 2001-10-18 | 2005-09-27 | Catacel Corporation | Catalytic combustor for a gas turbine |
| US20040001781A1 (en) | 2002-06-27 | 2004-01-01 | Engelhard Corporation | Multi-zone catalytic converter |
| DE10329162A1 (de) * | 2003-06-27 | 2005-01-13 | Alstom Technology Ltd | Katalytischer Reaktor und zugehöriges Betriebsverfahren |
| DE10349876A1 (de) | 2003-10-25 | 2005-05-25 | Daimlerchrysler Ag | Brennkraftmaschine mit Abgasreinigungsanlage und Verfahren zur Reinigung des Abgases einer Brennkraftmaschine |
| US7374729B2 (en) | 2004-03-30 | 2008-05-20 | Basf Catalysts Llc | Exhaust gas treatment catalyst |
| US7795172B2 (en) | 2004-06-22 | 2010-09-14 | Basf Corporation | Layered exhaust treatment catalyst |
| RU2372556C2 (ru) * | 2008-01-24 | 2009-11-10 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Способ сжигания углеводородных топлив (варианты) и катализаторы для его осуществления |
| US8038954B2 (en) | 2008-02-14 | 2011-10-18 | Basf Corporation | CSF with low platinum/palladium ratios |
| EP2141139A1 (en) * | 2008-07-03 | 2010-01-06 | L'AIR LIQUIDE, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Ceramic foams with gradients of composition in heterogeneous catalytic |
| EP2141140A1 (en) * | 2008-07-03 | 2010-01-06 | L'AIR LIQUIDE, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Ceramic foams with gradient of porosity and gradient of catalytic active(s) phase(s) |
| FR2941999B1 (fr) * | 2009-02-12 | 2011-04-08 | Peugeot Citroen Automobiles Sa | Catalyseur pour le traitement des gaz d'echappement d'un moteur a combustion et procede d'obtention d'un tel catalyseur |
| RU2406954C1 (ru) * | 2009-07-16 | 2010-12-20 | Шелудяков Евгений Павлович | Каталитический генератор тепла |
| GB0922194D0 (en) * | 2009-12-21 | 2010-02-03 | Johnson Matthey Plc | Improvements in emission control |
| DE102011101616A1 (de) | 2011-05-14 | 2012-11-15 | Howaldtswerke-Deutsche Werft Gmbh | Verfahren zur Verbrennung eines Brennstoff-Sauerstoff-Gemisches und Vorrichtung zur Durchführung dieses Verfahrens |
| US8585807B2 (en) * | 2011-09-30 | 2013-11-19 | Uchicago Argonne, Llc | Low-cost method for fabricating palladium and palladium-alloy thin films on porous supports |
| JP5966637B2 (ja) | 2012-06-07 | 2016-08-10 | 株式会社Ihi | マイクロリアクタ |
| RU2491118C1 (ru) * | 2012-06-28 | 2013-08-27 | ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ БЮДЖЕТНОЕ УЧРЕЖДЕНИЕ НАУКИ ИНСТИТУТ ОРГАНИЧЕСКОЙ ХИМИИ им. Н.Д. ЗЕЛИНСКОГО РОССИЙСКОЙ АКАДЕМИИ НАУК (ИОХ РАН) | Способ приготовления катализатора для получения синтез-газа, катализатор, приготовленный по этому способу, и способ получения синтез-газа с его использованием |
| RU2514382C1 (ru) * | 2012-10-09 | 2014-04-27 | Гребнев Вениамин Владимирович | Способ изготовления рений- и рутенийсодержащих каталитических нейтрализаторов двигателей внутреннего сгорания (двс) |
| RU2493912C1 (ru) * | 2012-10-16 | 2013-09-27 | ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ БЮДЖЕТНОЕ УЧРЕЖДЕНИЕ НАУКИ ИНСТИТУТ ОРГАНИЧЕСКОЙ ХИМИИ им. Н.Д. ЗЕЛИНСКОГО РОССИЙСКОЙ АКАДЕМИИ НАУК (ИОХ РАН) | Способ приготовления катализатора для получения синтез-газа |
| GB201315892D0 (en) * | 2013-07-31 | 2013-10-23 | Johnson Matthey Plc | Zoned diesel oxidation catalyst |
| UA123263C2 (uk) * | 2015-03-05 | 2021-03-10 | Шелл Інтернаціонале Рісерч Маатшаппідж Б.В. | Каталізатор окислення метану, процес його отримання та спосіб його застосування |
| GB2542654B (en) * | 2015-06-28 | 2019-12-04 | Johnson Matthey Plc | Catalytic wall-flow filter having a membrane |
| RU2619104C1 (ru) * | 2015-12-24 | 2017-05-12 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" | Способ приготовления катализатора для получения синтез газа из метана, катализатор, приготовленный по этому способу, и способ получения синтез газа из метана с его использованием |
| RU2621689C1 (ru) * | 2015-12-24 | 2017-06-07 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" | Катализатор и способ получения синтез-газа из метана с его использованием |
| DK3507008T3 (da) | 2016-08-31 | 2021-11-22 | Shell Int Research | Fremgangsmåde til fremstilling af en methanoxideringskatalysator |
| KR102379498B1 (ko) | 2016-08-31 | 2022-03-28 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | 메탄 산화 촉매, 이를 제조하는 공정 및 이를 사용하는 방법 |
| RU2638831C1 (ru) * | 2016-09-30 | 2017-12-18 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) | Способ приготовления катализатора для получения синтез-газа из метана, катализатор, приготовленный по этому способу, и способ получения синтез-газа из метана с его использованием |
| JP6865664B2 (ja) * | 2017-09-25 | 2021-04-28 | 株式会社キャタラー | 排ガス浄化用酸化触媒装置 |
| JP2019058876A (ja) | 2017-09-27 | 2019-04-18 | イビデン株式会社 | ハニカム触媒 |
| JP6684257B2 (ja) | 2017-09-27 | 2020-04-22 | イビデン株式会社 | 排ガス浄化用ハニカム触媒 |
| JP6698602B2 (ja) | 2017-09-27 | 2020-05-27 | イビデン株式会社 | 排ガス浄化用ハニカム触媒 |
| JP2019058875A (ja) * | 2017-09-27 | 2019-04-18 | イビデン株式会社 | ハニカム触媒 |
| CN107855123B (zh) * | 2017-11-23 | 2020-04-10 | 中国科学技术大学 | 一种Pd/SiO2@Al2O3纳米晶材料及其制备方法、应用 |
| EP3778011B1 (en) * | 2018-03-28 | 2026-03-04 | Mitsui Kinzoku Company, Limited | Exhaust gas purification catalyst |
| CN114258322A (zh) | 2019-08-20 | 2022-03-29 | 国际壳牌研究有限公司 | 甲烷氧化催化剂及其制备和使用方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4270896A (en) * | 1975-08-26 | 1981-06-02 | Engelhard Minerals & Chemicals Corporation | Catalyst system |
| SE7802205L (sv) * | 1977-03-04 | 1978-09-05 | Johnson Matthey Co Ltd | Forbettringar i och avseende katalys |
| US4603547A (en) * | 1980-10-10 | 1986-08-05 | Williams Research Corporation | Catalytic relight coating for gas turbine combustion chamber and method of application |
| EP0198948A3 (en) * | 1985-04-11 | 1988-09-21 | Nippon Shokubai Kagaku Kogyo Co., Ltd | Catalytic combustor for combustion of lower hydrocarbon fuel |
| US4598063A (en) * | 1985-08-09 | 1986-07-01 | Retallick William B | Spiral catalyst support and method of making it |
| DE3665216D1 (en) * | 1985-11-21 | 1989-09-28 | Werner Fiala | Process for raising the temperature of catalysts and device for performing the process |
| US4870824A (en) * | 1987-08-24 | 1989-10-03 | Westinghouse Electric Corp. | Passively cooled catalytic combustor for a stationary combustion turbine |
| KR920005089B1 (ko) * | 1988-07-06 | 1992-06-26 | 우스이 고꾸사이 산교 가부시끼가이샤 | 배기가스 정화용 촉매를 담지하기 위한 금속제 담지모체(擔持母體)와 그의 제조방법 |
| US4893465A (en) * | 1988-08-22 | 1990-01-16 | Engelhard Corporation | Process conditions for operation of ignition catalyst for natural gas combustion |
| US5047381A (en) * | 1988-11-21 | 1991-09-10 | General Electric Company | Laminated substrate for catalytic combustor reactor bed |
-
1991
- 1991-11-26 KR KR1019930701566A patent/KR100261782B1/ko not_active Expired - Lifetime
- 1991-11-26 WO PCT/US1991/008918 patent/WO1992009848A1/en not_active Ceased
- 1991-11-26 EP EP92905922A patent/EP0559844B1/en not_active Expired - Lifetime
- 1991-11-26 AU AU13357/92A patent/AU1335792A/en not_active Abandoned
- 1991-11-26 RU RU93039971/04A patent/RU2153631C2/ru not_active IP Right Cessation
- 1991-11-26 ES ES92905922T patent/ES2129041T3/es not_active Expired - Lifetime
- 1991-11-26 DE DE69130894T patent/DE69130894T2/de not_active Expired - Lifetime
- 1991-11-26 JP JP50566892A patent/JP3191013B2/ja not_active Expired - Lifetime
- 1991-11-26 AT AT92905922T patent/ATE176605T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| RU2153631C2 (ru) | 2000-07-27 |
| JP3191013B2 (ja) | 2001-07-23 |
| JPH06506290A (ja) | 1994-07-14 |
| ATE176605T1 (de) | 1999-02-15 |
| EP0559844B1 (en) | 1999-02-10 |
| AU1335792A (en) | 1992-06-25 |
| EP0559844A1 (en) | 1993-09-15 |
| WO1992009848A1 (en) | 1992-06-11 |
| DE69130894D1 (de) | 1999-03-25 |
| DE69130894T2 (de) | 1999-09-02 |
| EP0559844A4 (en) | 1993-11-03 |
| KR100261782B1 (ko) | 2000-07-15 |
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