MX9706977A - Utilizacion del grupo platino en motores diesel. - Google Patents

Utilizacion del grupo platino en motores diesel.

Info

Publication number
MX9706977A
MX9706977A MX9706977A MX9706977A MX9706977A MX 9706977 A MX9706977 A MX 9706977A MX 9706977 A MX9706977 A MX 9706977A MX 9706977 A MX9706977 A MX 9706977A MX 9706977 A MX9706977 A MX 9706977A
Authority
MX
Mexico
Prior art keywords
catalyst
fuel
platinum group
metal
combustion
Prior art date
Application number
MX9706977A
Other languages
English (en)
Inventor
James M Valentine
Jeremy D Peter-Hoblyn
Original Assignee
Platinum Plus Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Platinum Plus Inc filed Critical Platinum Plus Inc
Publication of MX9706977A publication Critical patent/MX9706977A/es

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/944—Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0033—Iridium compounds
    • C—CHEMISTRY; METALLURGY
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    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/006—Palladium compounds
    • C—CHEMISTRY; METALLURGY
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    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
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    • C07F15/0086—Platinum compounds
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    • C10L1/00—Liquid carbonaceous fuels
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    • C10L1/00—Liquid carbonaceous fuels
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    • C10L1/14—Organic compounds
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    • C10L1/00—Liquid carbonaceous fuels
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    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
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    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
    • C10L1/328—Oil emulsions containing water or any other hydrophilic phase
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    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
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    • C10L10/06—Use of additives to fuels or fires for particular purposes for facilitating soot removal
    • C—CHEMISTRY; METALLURGY
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    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
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Abstract

La invencion proporciona un método que emplea un aditivo de combustible para mejorar la operacion de un catalizador de oxidacion de paso sobre largos períodos de tiempo con actividad catalítica continua y sin la indeseable conversion de SO2 a SO3. Un soporte de catalizador de paso se cataliza continuamente de manera selectiva mediante la combustion de un combustible que contiene una composicion metálica del grupo platino que se quema para liberar el metal catalizador en forma activa. La efectividad del proceso se atribuye a una combustion mejorada en el motor mediante el catalizador y el tratamiento del oxidante catalítico con el metal catalítico activo liberado durante la combustion de tal manera que, en el sistema de descarga, la fraccion orgánica soluble de las partículas y los niveles de hidrocarburos no quemados gaseosos y el monoxido de carbono se reducen significativamente. Los catalizadores condicionados por la presente invencion provocan una mínima conversion de SO2 a SO3. Las composiciones metálicas del grupo platino solubles o dispersable en el combustible diesel y se añaden en cantidades efectivas para proporcionar concentraciones del metal en el combustible de menos de 1 parte por millon (ppm).
MX9706977A 1995-03-14 1996-03-14 Utilizacion del grupo platino en motores diesel. MX9706977A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/403,365 US5501714A (en) 1988-12-28 1995-03-14 Operation of diesel engines with reduced particulate emission by utilization of platinum group metal fuel additive and pass-through catalytic oxidizer
PCT/US1996/003602 WO1996028524A1 (en) 1995-03-14 1996-03-14 Utilization of platinum group in diesel engines

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MX9706977A true MX9706977A (es) 1997-11-29

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MX9706977A MX9706977A (es) 1995-03-14 1996-03-14 Utilizacion del grupo platino en motores diesel.

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US (1) US5501714A (es)
EP (1) EP0815185B1 (es)
JP (1) JPH11502242A (es)
KR (1) KR100469501B1 (es)
CN (1) CN1087768C (es)
AT (1) ATE362504T1 (es)
CA (1) CA2214216C (es)
DE (1) DE69637083T2 (es)
ES (1) ES2283000T3 (es)
MX (1) MX9706977A (es)
TW (1) TW329456B (es)
WO (1) WO1996028524A1 (es)
ZA (1) ZA961657B (es)

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WO1996028524A1 (en) 1996-09-19
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US5501714A (en) 1996-03-26
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CA2214216A1 (en) 1996-09-19
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