ES2115094T3 - Epoxidacion de olefinas a traves de ciertos complejos de manganeso. - Google Patents

Epoxidacion de olefinas a traves de ciertos complejos de manganeso.

Info

Publication number
ES2115094T3
ES2115094T3 ES94104709T ES94104709T ES2115094T3 ES 2115094 T3 ES2115094 T3 ES 2115094T3 ES 94104709 T ES94104709 T ES 94104709T ES 94104709 T ES94104709 T ES 94104709T ES 2115094 T3 ES2115094 T3 ES 2115094T3
Authority
ES
Spain
Prior art keywords
olefins
manganese
epoxidation
manganese complexes
certain manganese
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94104709T
Other languages
English (en)
Inventor
Sharon H Jureller
Judith L Kerschner
Robert Humphreys
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Starch and Chemical Investment Holding Corp
Original Assignee
National Starch and Chemical Investment Holding Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Starch and Chemical Investment Holding Corp filed Critical National Starch and Chemical Investment Holding Corp
Application granted granted Critical
Publication of ES2115094T3 publication Critical patent/ES2115094T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/38—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/06—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the liquid phase
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

SE PRESENTA UN METODO PARA EPOXIDAR OLEFINAS SEGUN EL CUAL SE PONEN EN CONTACTO UNA OLEFINA Y UN AGENTE DE OXIGENACION EN PRESENCIA DE UN CATALIZADOR DE UN COMPLEJO DE MANGANESO QUE TIENE AL MENOS UN ATOMO DE MANGANESO COORDINADO CON UN LIGANDO QUE CONTIENE NITROGENO DE TAL MODO QUE LA RELACION ENTRE EL ATOMO DE MANGANESO Y EL ATOMO DE NITROGENO COORDINADO SEA DE 1:3 Y SE AISLA DESPUES EL PRODUCTO EPOXIDO RESULTANTE. SE PRESENTAN TAMBIEN LAS COMPOSICIONES CATALIZADORAS FORMADAS DE LA ADSORCION DEL CATALIZADOR DEL COMPLEJO DE MANGANESO EN UN SOPORTE INSOLUBLE SOLVENTE.
ES94104709T 1993-03-30 1994-03-24 Epoxidacion de olefinas a traves de ciertos complejos de manganeso. Expired - Lifetime ES2115094T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/040,316 US5329024A (en) 1993-03-30 1993-03-30 Epoxidation of olefins via certain manganese complexes

Publications (1)

Publication Number Publication Date
ES2115094T3 true ES2115094T3 (es) 1998-06-16

Family

ID=21910336

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94104709T Expired - Lifetime ES2115094T3 (es) 1993-03-30 1994-03-24 Epoxidacion de olefinas a traves de ciertos complejos de manganeso.

Country Status (7)

Country Link
US (2) US5329024A (es)
EP (1) EP0618202B1 (es)
JP (1) JP2764005B2 (es)
KR (1) KR970002230B1 (es)
CA (1) CA2120268C (es)
DE (1) DE69408884T2 (es)
ES (1) ES2115094T3 (es)

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DE19523891C1 (de) * 1995-06-30 1996-11-21 Hoechst Ag Chirale Mangan-triazanonankomplexe und Verfahren zu ihrer Herstellung
DE19523890C1 (de) * 1995-06-30 1996-11-28 Hoechst Ag Verfahren zur Herstellung von chiralen Epoxiden mit chiralen Mangantriazanonankomplexen als Oxidationskatalysatoren
FR2741340B1 (fr) * 1995-11-16 1997-12-26 Elf Aquitaine Procede d'oxydation de substrats organiques en presence de complexes metalliques de ligands tetra-, penta- et hexacoordinants et catalyseurs d'oxydation les contenant
US20080125344A1 (en) * 2006-11-28 2008-05-29 Daryle Hadley Busch Bleach compositions
ZA981883B (en) * 1997-03-07 1998-09-01 Univ Kansas Catalysts and methods for catalytic oxidation
US20030017941A1 (en) 1997-03-07 2003-01-23 The Procter & Gamble Company Catalysts and methods for catalytic oxidation
US6218351B1 (en) 1998-03-06 2001-04-17 The Procter & Gamble Compnay Bleach compositions
US6387862B2 (en) 1997-03-07 2002-05-14 The Procter & Gamble Company Bleach compositions
TR199902673T2 (en) * 1997-03-07 2000-04-21 The Procter & Gamble Company A�art�c� bile�imler.
MA24733A1 (fr) 1997-03-07 1999-10-01 Procter & Gamble Compositions de blanchiment contenant un catalyseur metallique de blanchiment et activateurs de blanchiment et/ou acides percarboxyliques organiques
US5998606A (en) * 1997-11-10 1999-12-07 Grandics; Peter Mn(IV)-mediated crosslinking and functionalization of chromatography media
EP0970951A1 (en) * 1998-07-09 2000-01-12 K.U. Leuven Research & Development A manganese oxidation catalyst, a method for its preparation and use thereof for catalytic epoxidation, catalytic cis-dihydroxylation and combined expoxidation-cis-dihydroxylation of olefins
US20030008770A1 (en) * 2001-06-28 2003-01-09 Council Of Scientific & Industrial Research Encapsulated oxo-bridged organometallic cluster catalyst and a process for the preparation thereof
US20050192195A1 (en) * 2002-08-27 2005-09-01 Busch Daryle H. Catalysts and methods for catalytic oxidation
US20040048763A1 (en) * 2002-08-27 2004-03-11 The Procter & Gamble Co. Bleach compositions
DE10343252A1 (de) * 2003-09-17 2005-04-21 Basf Ag Verfahren zur Herstellung von Bisepoxiden und Dithiolen
US6884898B1 (en) * 2003-12-08 2005-04-26 Arco Chemical Technology, L.P. Propylene oxide process
WO2005095370A1 (en) * 2004-03-31 2005-10-13 Council Of Scientific & Industrial Research An improved catalytic process for the preparation of epoxides from alkenes
PT2402087E (pt) 2005-05-27 2013-07-22 Catexel Ltd Sais pré-formados de catalisador de metal de transição
US7368410B2 (en) * 2005-08-03 2008-05-06 Saudi Basic Industries Corporation Zeolite catalyst and method of preparing and use of zeolite catalyst
WO2007042192A2 (en) * 2005-10-12 2007-04-19 Unilever Plc Bleaching of substrates
US7976582B2 (en) * 2007-01-16 2011-07-12 Conopco, Inc. Bleaching of substrates
ES2336746B1 (es) * 2008-04-10 2011-01-25 Universitat De Girona Catalizadores de manganeso y su uso para la epoxidacion selectiva de olefinas.
EP2149570A1 (en) * 2008-08-01 2010-02-03 Hexion Specialty Chemicals Research Belgium S.A. Process for the manufacture of epichlorohydrin using hydrogen peroxide and a manganese komplex
EP2149569A1 (en) * 2008-08-01 2010-02-03 Hexion Specialty Chemicals Research Belgium S.A. Process for the manufacture of a 1,2-Epoxide
KR101708955B1 (ko) 2009-06-05 2017-02-21 솔베이(소시에떼아노님) 산화전분의 제조 방법, 산화전분 및 그 용도
EP2273006A1 (en) 2009-06-17 2011-01-12 Unilever PLC Bleaching of substrates
CN102510774B (zh) 2009-09-18 2014-07-23 科莱恩金融(Bvi)有限公司 制备桥联的三氮杂环壬烷的锰络合物的方法
EP2343288A1 (en) 2009-11-27 2011-07-13 Momentive Specialty Chemicals Research Belgium S.A. Process for the manufacture of propylene oxide
DE102009057220A1 (de) 2009-12-05 2011-06-09 Clariant International Ltd. Nicht hygroskopische Übergangsmetallkomplexe, Verfahren zu ihrer Herstellung und ihre Verwendung
DE102009057222A1 (de) 2009-12-05 2011-06-09 Clariant International Ltd. Bleichkatalysator-Compounds, Verfahren zu ihrer Herstellung und ihre Verwendung
EP2357180A1 (en) * 2010-02-02 2011-08-17 Momentive Specialty Chemicals Research Belgium S.A. Manufacture of epoxyethyl ethers or glycidyl ethers
EP2354130A1 (en) 2010-02-02 2011-08-10 Momentive Specialty Chemicals Research Belgium Manufacture of an epoxyethyl carboxylate or glycidyl carboxylate
EP2354131A1 (en) * 2010-02-02 2011-08-10 Momentive Specialty Chemicals Research Belgium Process for the manufacture of a 1,2-epoxide and a device for carrying out said process
EP2354129A1 (en) * 2010-02-02 2011-08-10 Momentive Specialty Chemicals Research Belgium S.A. Epoxidation process
KR101735087B1 (ko) 2010-03-03 2017-05-24 카텍셀 리미티드 표백 촉매 제조방법
EP2377614A1 (en) * 2010-04-16 2011-10-19 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Bleaching of substrates
EP2409962A1 (en) * 2010-07-21 2012-01-25 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House A one-pot method for the oxidation of unsaturated organic compounds
EP2537836A1 (en) * 2011-06-22 2012-12-26 Momentive Specialty Chemicals Research Belgium S.A. Apparatus and methods to preserve catalyst activity in an epoxidation process
ES2683005T3 (es) 2011-09-08 2018-09-24 Catexel Technologies Limited Catalizadores
US9024076B2 (en) 2011-10-24 2015-05-05 Northwestern University Alkane Oxidation
JP2015529628A (ja) 2012-01-31 2015-10-08 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ エポキシドの製造方法
US8614342B2 (en) 2012-01-31 2013-12-24 Basf Se Process for preparing epoxycarboxylic esters
US9943839B2 (en) 2014-07-15 2018-04-17 Northwestern University Catalyst composition and process for preparing olefin oxides
JP6707553B2 (ja) 2015-02-17 2020-06-10 エボニック オペレーションズ ゲーエムベーハー 過酸化水素を用いたオレフィンのエポキシ化方法
EP3059230A1 (en) 2015-02-17 2016-08-24 Evonik Degussa GmbH Method for the epoxidation of propene with hydrogen peroxide
EP3059228A1 (en) 2015-02-17 2016-08-24 Evonik Degussa GmbH Method for the epoxidation of allyl chloride with hydrogen peroxide
TW201700464A (zh) 2015-02-17 2017-01-01 贏創德固賽有限責任公司 使用過氧化氫之使烯烴環氧化方法
EP3059229A1 (en) 2015-02-17 2016-08-24 Evonik Degussa GmbH Method for the epoxidation of an olefin with hydrogen peroxide
DE102015016402A1 (de) * 2015-12-18 2017-06-22 Weylchem Wiesbaden Gmbh Feinteilige Bleichkatalysatoren, Verfahren zu deren Herstellung und deren Verwendung
KR20180089958A (ko) 2017-02-02 2018-08-10 유진초저온(주) Lng 냉열을 이용한 진공 동결 건조 시스템
KR101961161B1 (ko) * 2017-11-17 2019-03-22 롯데케미칼 주식회사 망간 촉매를 사용한 고리형 올레핀 공중합체의 에폭시화 방법
JP7327758B2 (ja) * 2019-10-29 2023-08-16 株式会社ダイセル エポキシ化合物の製造方法
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Also Published As

Publication number Publication date
JPH06321924A (ja) 1994-11-22
US5329024A (en) 1994-07-12
JP2764005B2 (ja) 1998-06-11
KR940021542A (ko) 1994-10-19
KR970002230B1 (ko) 1997-02-26
DE69408884D1 (de) 1998-04-16
EP0618202A1 (en) 1994-10-05
CA2120268C (en) 1997-11-25
CA2120268A1 (en) 1994-10-01
DE69408884T2 (de) 1998-06-25
US5516738A (en) 1996-05-14
EP0618202B1 (en) 1998-03-11

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