ES2072684T3 - Articulos de vidrio o de cuarzo con revestimientos que contienen oxido de cerio absorbentes de los rayos ultravioleta y resistentes a las temperaturas elevadas. - Google Patents
Articulos de vidrio o de cuarzo con revestimientos que contienen oxido de cerio absorbentes de los rayos ultravioleta y resistentes a las temperaturas elevadas.Info
- Publication number
- ES2072684T3 ES2072684T3 ES92120453T ES92120453T ES2072684T3 ES 2072684 T3 ES2072684 T3 ES 2072684T3 ES 92120453 T ES92120453 T ES 92120453T ES 92120453 T ES92120453 T ES 92120453T ES 2072684 T3 ES2072684 T3 ES 2072684T3
- Authority
- ES
- Spain
- Prior art keywords
- degrees
- glass
- cerio
- resistant
- oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000002745 absorbent Effects 0.000 title 1
- 239000002250 absorbent Substances 0.000 title 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 title 1
- 239000011159 matrix material Substances 0.000 abstract 3
- 229910000420 cerium oxide Inorganic materials 0.000 abstract 2
- 239000000084 colloidal system Substances 0.000 abstract 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 229910052809 inorganic oxide Inorganic materials 0.000 abstract 1
- 230000010355 oscillation Effects 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/208—Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/25—Oxides by deposition from the liquid phase
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/23—Mixtures
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/44—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
- C03C2217/45—Inorganic continuous phases
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
- C03C2217/475—Inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/74—UV-absorbing coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/113—Deposition methods from solutions or suspensions by sol-gel processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12993—Surface feature [e.g., rough, mirror]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/256—Heavy metal or aluminum or compound thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31609—Particulate metal or metal compound-containing
- Y10T428/31612—As silicone, silane or siloxane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Composite Materials (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Wood Science & Technology (AREA)
- Surface Treatment Of Glass (AREA)
- Paints Or Removers (AREA)
- Glass Compositions (AREA)
Abstract
SE MUESTRA UN RECUBRIMIENTO ABSORBEDOR DE RADIACION ULTRAVIOLETA QUE COMPRENDE OXIDO DE CERIO EN UNA MATRIZ DE OXIDO INORGANICO FORMADO POR LA HIDROLISIS Y CONDENSACION DE ALCOXISILANO Y/U OTRO OXIDO O ALCOXIDO DE METAL, QUE POSEE UN GROSOR DE RECUBRIMIENTO POR UNIDAD DE ABSORBENCIA MAYOR EN VIRTUD DE SU SUPERIOR CONCENTRACION DE PARTICULAS COLOIDALES EN DICHA MATRIZ, Y UNA TENDENCIA REDUCIDA PARA AGRIETARSE CUANDO SE EXPONE A TEMPERATURAS SUPERIORES A 1000 (GRADOS) C Y/O OSCILACION DE TEMPERATURA ENTRE TEMPERATURA AMBIENTE Y 1000 (GRADOS) C EN VIRTUD DEL CALENTAMIENTO DE UN ARTICULO RECUBIERTO A TEMPERATURA ELEVADA ENTRE 500 (GRADOS) C Y 1100 (GRADOS) C ANTES DEL ENFRIAMIENTO DEL ARTICULO RECUBIERTO. LOS SUSTRATOS DE VIDRIO O CUARZO RECUBIERTOS CON RECUBRIMIENTOS SOLGEL QUE CONTIENEN UNA ALTA CONCENTRACION DE PARTICULAS DE OXIDO DE CERIO COLOIDALES EN UNA MATRIZ DE BASE DE SILICE TIENEN UNA ALTA CAPACIDAD DE ABSORCION DE RADIACION ULTRAVIOLETA EN LA GAMA DE LONGITUD DE ONDA CORTA DE 200 A320 NANOMETROS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/802,914 US5316854A (en) | 1991-12-06 | 1991-12-06 | Glass or quartz articles having high temperature UV absorbing coatings containing ceria |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2072684T3 true ES2072684T3 (es) | 1995-07-16 |
Family
ID=25185072
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES92120453T Expired - Lifetime ES2072684T3 (es) | 1991-12-06 | 1992-12-01 | Articulos de vidrio o de cuarzo con revestimientos que contienen oxido de cerio absorbentes de los rayos ultravioleta y resistentes a las temperaturas elevadas. |
Country Status (7)
Country | Link |
---|---|
US (1) | US5316854A (es) |
EP (1) | EP0545347B1 (es) |
JP (1) | JPH08720B2 (es) |
DE (1) | DE69201634T2 (es) |
ES (1) | ES2072684T3 (es) |
HU (2) | HUH3786A (es) |
TW (1) | TW270108B (es) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6180248B1 (en) | 1987-12-16 | 2001-01-30 | Ppg Industries Ohio, Inc. | Siloxane organic hybrid polymers |
US5480722A (en) * | 1992-07-03 | 1996-01-02 | Asahi Glass Company Ltd. | Ultraviolet ray absorbent glass and method for preparing the same |
US5817160A (en) * | 1992-12-16 | 1998-10-06 | The Center For Innovative Technology | UV absorbing glass |
AU687883B2 (en) * | 1993-10-01 | 1998-03-05 | Kao Corporation | Ultraviolet shielding composite fine particles, method for producing the same, and cosmetics |
JP3368953B2 (ja) * | 1993-11-12 | 2003-01-20 | 旭硝子株式会社 | 紫外線吸収着色ガラス |
MY115988A (en) * | 1994-10-26 | 2003-10-31 | Asahi Glass Co Ltd | Glass having low solar radiation and ultraviolet ray transmittance |
US5789476A (en) * | 1995-03-03 | 1998-08-04 | Seiko Epson Corporation | Film-forming coating solution and synthetic resin lens |
US5668072A (en) * | 1996-05-09 | 1997-09-16 | Equity Enterprises | High emissivity coating |
IL120022A (en) * | 1997-01-16 | 2003-02-12 | Yissum Res Dev Co | Sunscreens for protection from sun radiation |
US7192986B2 (en) * | 1997-03-12 | 2007-03-20 | Catalysts & Chemicals Industries Co., Ltd. | Inorganic compound sol modified by organic compound |
JP4144204B2 (ja) * | 2001-09-20 | 2008-09-03 | 日産自動車株式会社 | 光吸収膜およびその製造方法 |
FR2835246B1 (fr) * | 2002-01-29 | 2004-03-19 | Centre Nat Rech Scient | Polymere a base d'oxyde de titane |
DE10215941A1 (de) | 2002-04-11 | 2003-10-23 | Bayer Ag | Anorganische UV-Absorber enthaltene Bindemittel |
US6875515B2 (en) * | 2002-05-10 | 2005-04-05 | General Electric Company | Fused quartz article having controlled devitrification |
MXPA06010676A (es) * | 2004-03-19 | 2007-02-21 | Doerken Ewald Ag | Microrevestimiento comprendiendo siloxanos. |
KR100855809B1 (ko) | 2004-06-22 | 2008-09-01 | 에보니크 데구사 게엠베하 | 금속 산화물 졸, 이를 사용하여 생성된 층 및 성형품 |
DE102004030093A1 (de) * | 2004-06-22 | 2006-01-12 | Degussa Ag | Metalloxid-Sol, damit hergestellte Schicht und Formkörper |
FR2881844B1 (fr) * | 2005-02-09 | 2007-04-13 | Saint Gobain | Structure diffusante a proprietes d'absorption dans l'ultraviolet |
US7659001B2 (en) * | 2005-09-20 | 2010-02-09 | Guardian Industries Corp. | Coating with infrared and ultraviolet blocking characteristics |
US7771103B2 (en) * | 2005-09-20 | 2010-08-10 | Guardian Industries Corp. | Optical diffuser with IR and/or UV blocking coating |
JP4994640B2 (ja) * | 2005-11-07 | 2012-08-08 | 岩瀬コスファ株式会社 | 紫外線吸収性複合粉体 |
WO2007068685A1 (en) * | 2005-12-13 | 2007-06-21 | Bluestar Silicones France | Silicon resin coating composition containing redispersible powder of mineral particle dispersions stabilized with a polymer |
MX2008012426A (es) * | 2006-03-30 | 2008-12-18 | Rhodia | Superficies modificadas y metodo para modificar una superficie. |
US7744951B2 (en) * | 2006-04-13 | 2010-06-29 | Guardian Industries Corp. | Coated glass substrate with infrared and ultraviolet blocking characteristics |
US7989068B2 (en) * | 2007-11-06 | 2011-08-02 | Rhodia Operations | Articles having an interface between a polymer surface and a modified glass surface |
US8709545B2 (en) * | 2009-01-30 | 2014-04-29 | The Boeing Company | Hybrid coatings and associated methods of application |
US10450221B2 (en) | 2011-02-24 | 2019-10-22 | Owens-Brockway Glass Container Inc. | Hybrid sol-gel coated glass containers |
US8940397B2 (en) | 2011-02-28 | 2015-01-27 | Momentive Performance Materials Inc. | Weatherable and abrasion resistant coating systems for polymeric substrates |
CN103484060B (zh) * | 2013-08-12 | 2016-09-21 | 曹坚林 | 一种新型的无机紫外线吸收剂及其制备方法 |
CN104068832A (zh) * | 2014-06-20 | 2014-10-01 | 京东方科技集团股份有限公司 | 一种体表温度计及可佩戴显示装置 |
US11104814B2 (en) * | 2016-02-15 | 2021-08-31 | Momentive Performance Materials Inc. | Primer formulations with improved photostability |
TR201617722A2 (tr) * | 2016-12-02 | 2017-02-21 | Tuerkiye Sise Ve Cam Fabrikalari Anonim Sirketi | Anorgani̇k nanoparti̇küller i̇çeren saydam uv koruyucu sert kaplama ve kaplamali cam |
CN110621629B (zh) * | 2017-05-04 | 2022-07-29 | 旭硝子欧洲玻璃公司 | 经涂覆的基板 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4028085A (en) * | 1976-02-03 | 1977-06-07 | Owens-Illinois, Inc. | Method for manufacturing silicate glasses from alkoxides |
US4528212A (en) * | 1982-07-22 | 1985-07-09 | International Business Machines Corporation | Coated ceramic substrates for mounting integrated circuits |
JPS6291442A (ja) * | 1985-06-21 | 1987-04-25 | Natl Inst For Res In Inorg Mater | セリウム酸化物含有アルミノけい酸塩ガラスの製造法 |
IL84025A0 (en) * | 1986-10-03 | 1988-02-29 | Ppg Industries Inc | Organosiloxane/metal oxide coating compositions and their production |
JPS6428243A (en) * | 1987-07-22 | 1989-01-30 | Seiko Epson Corp | Cerium-doped quartz glass and production thereof |
JP2515137B2 (ja) * | 1988-06-02 | 1996-07-10 | 多木化学株式会社 | 紫外線吸収方法 |
JPH02274781A (ja) * | 1989-04-17 | 1990-11-08 | Seiko Epson Corp | コーティング用組成物 |
US5035745A (en) * | 1990-06-29 | 1991-07-30 | Ppg Industries, Inc. | Ion-exchanged abrasion resistant coatings |
-
1991
- 1991-12-06 US US07/802,914 patent/US5316854A/en not_active Expired - Fee Related
-
1992
- 1992-11-26 TW TW81109481A patent/TW270108B/zh active
- 1992-12-01 DE DE69201634T patent/DE69201634T2/de not_active Expired - Fee Related
- 1992-12-01 ES ES92120453T patent/ES2072684T3/es not_active Expired - Lifetime
- 1992-12-01 EP EP19920120453 patent/EP0545347B1/en not_active Expired - Lifetime
- 1992-12-04 HU HU9203852D patent/HUH3786A/hu unknown
- 1992-12-04 HU HU929203852A patent/HU9203852D0/hu unknown
- 1992-12-04 JP JP32537792A patent/JPH08720B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69201634D1 (de) | 1995-04-13 |
JPH08720B2 (ja) | 1996-01-10 |
DE69201634T2 (de) | 1995-10-19 |
JPH0664938A (ja) | 1994-03-08 |
US5316854A (en) | 1994-05-31 |
HUH3786A (en) | 1996-07-29 |
EP0545347B1 (en) | 1995-03-08 |
TW270108B (es) | 1996-02-11 |
HU9203852D0 (en) | 1993-03-29 |
EP0545347A1 (en) | 1993-06-09 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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