ES2045739T3 - Procedimiento para la obtencion de plasticos esponjosos rigidos de poliuretano deformables en frio y su empleo para la elaboracion de cielos para automoviles. - Google Patents
Procedimiento para la obtencion de plasticos esponjosos rigidos de poliuretano deformables en frio y su empleo para la elaboracion de cielos para automoviles.Info
- Publication number
- ES2045739T3 ES2045739T3 ES90124859T ES90124859T ES2045739T3 ES 2045739 T3 ES2045739 T3 ES 2045739T3 ES 90124859 T ES90124859 T ES 90124859T ES 90124859 T ES90124859 T ES 90124859T ES 2045739 T3 ES2045739 T3 ES 2045739T3
- Authority
- ES
- Spain
- Prior art keywords
- weight
- spongeous
- skies
- elaboration
- automobiles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
- B60R13/02—Internal Trim mouldings ; Internal Ledges; Wall liners for passenger compartments; Roof liners
- B60R13/0212—Roof or head liners
- B60R13/0225—Roof or head liners self supporting head liners
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1825—Catalysts containing secondary or tertiary amines or salts thereof having hydroxy or primary amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6603—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6607—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
- C08G18/6611—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Laminated Bodies (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
MATERIALES ESPONJOSOS ENDURECIDOS CONFORMABLES EN FRIO SE FORMAN MEDIANTE LA TRANSFORMACION DE UNA MEZCLA DE DIFENILMETADIISOCIADOS Y POLIFENILPOLIMETILOSPOLIISOCIANATOS QUE CONSISTEN EN 1. DE 70 A 90 DE PESO EN % DIFENILMETANO-DIISOCIANATO 2. DE 12 A 30 DE PESO EN %, PREFERENTEMENTE DE 15 A 25 DE PESO EN %, 2''4'' -DIFENILMETADIISOCIANATO Y 3. DE 10 A 30 DE PESO EN %, POLIFENIL-POLIMETIPOLIMETILENOPOLIISOCIANATO CON UNA MEZCLA DE POLIOLES DE 1/ DE 50 A 70 DE PESO EN %, DE UN DIONALES, GRUPO HIDROXILO DE POLIETER MOSTRADO EN UNA CANTIDAD -OH DE 28 HASTA 600, 2/ DE 20 A 35 DE PESO EN %, DE UN DIFUNCIONAL, DEL GRUPO HIDROXILO DE POLIESTERES ACIDOS DE FTALILO MOSTRADOS EN UNA CANTIDAD -OH DE 150 HASTA 440, 3/ DE 2 A 10 DE PESO EN % DE GLICERINA, 4/ DE 4 A 7 DE PESO EN % DE AGUA, 5/ DE 0,1 A 2 DE PESO EN % DE UN ESTABILIZADOR ESPUMOSO DE SILICONA Y 6/ DE 0,3 A 1 DE PESO EN % DE UN TERT.AMINOCATALIZADOR CAPACES DE MONTAJE.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4001249A DE4001249A1 (de) | 1990-01-18 | 1990-01-18 | Verfahren zur herstellung von offenzelligen, kaltverformbaren polyurethan-hartschaumstoffen und deren verwendung zur herstellung von autohimmeln |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2045739T3 true ES2045739T3 (es) | 1994-01-16 |
Family
ID=6398261
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES90124859T Expired - Lifetime ES2045739T3 (es) | 1990-01-18 | 1990-12-20 | Procedimiento para la obtencion de plasticos esponjosos rigidos de poliuretano deformables en frio y su empleo para la elaboracion de cielos para automoviles. |
Country Status (12)
Country | Link |
---|---|
US (1) | US5219893A (es) |
EP (1) | EP0437787B1 (es) |
JP (1) | JP3013108B2 (es) |
KR (1) | KR0178401B1 (es) |
BR (1) | BR9100208A (es) |
CA (1) | CA2032737C (es) |
CZ (1) | CZ280163B6 (es) |
DE (2) | DE4001249A1 (es) |
ES (1) | ES2045739T3 (es) |
HU (1) | HU209720B (es) |
RU (1) | RU2031098C1 (es) |
ZA (1) | ZA91343B (es) |
Families Citing this family (49)
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US5216041A (en) * | 1990-12-27 | 1993-06-01 | Basf Corporation | Energy absorbing, water blown, rigid polyurethane foam |
TW256842B (es) † | 1991-12-17 | 1995-09-11 | Takeda Pharm Industry Co Ltd | |
DE4333795C2 (de) * | 1993-10-04 | 2003-04-10 | Basf Ag | Verfahren zur Herstellung von thermoplastisch verformbaren Polyurethan-Hartschaumstoffen und hierfür verwendbare Mischungen aus Polyhydroxylverbindungen |
DE19501198A1 (de) * | 1995-01-17 | 1996-07-18 | Bayer Ag | Verwendung eines Folienverbundkörpers als selbsttragendes Bauteil im Automobilbereich |
DE69838755T3 (de) * | 1997-04-02 | 2012-05-24 | Sanyo Chemical Industries, Ltd. | Polyurethanschaum, verfahren zur herstellung und zusammensetzung zur herstellung von schäumen |
EP1012198B2 (en) * | 1997-09-11 | 2005-09-14 | Kao Corporation | Low viscosity polyester polyols and polyurethane foams prepared therefrom |
ES2157725B1 (es) * | 1998-06-19 | 2002-05-01 | Antolin Grupo Ing Sa | Procedimiento e instalacion para fabricar elementos para la industria del automovil y/o de la construccionn y producto resultante. |
DE19847804C1 (de) * | 1998-10-16 | 2000-05-11 | Johnson Controls Headliner | Verfahren zur Herstellung einer Dachversteifung für Fahrzeuge und Dachversteifung |
US6586487B1 (en) | 2000-07-12 | 2003-07-01 | Bayer Corporation | Low-density, water blown polyurethane foams for energy-absorbing applications |
JP2002155125A (ja) * | 2000-11-20 | 2002-05-28 | Sumika Bayer Urethane Kk | ポリウレタン変性ポリイソシアヌレートフォームの製造方法 |
KR100412228B1 (ko) * | 2001-02-01 | 2003-12-24 | 한림인텍 주식회사 | 열간 성형이 용이한 연속기포 경질 폴리우레탄 발포체 및그 발포체를 이용한 자동차 마감재 |
CN1249115C (zh) * | 2001-02-06 | 2006-04-05 | 东洋品质第一股份有限公司 | 低透气性挠性聚氨酯泡沫块及其生产方法 |
US20060175575A1 (en) * | 2001-06-15 | 2006-08-10 | Kaplan Warren A | Method for preparing phthalate polyester polyol-based dimensionally stable spray polyurethane foam |
WO2002102866A2 (en) * | 2001-06-15 | 2002-12-27 | Stepan Company | Phthalate polyester polyol-based compositions and high dimensionally stable all water-blown spray polyurethane foam derived therefrom |
DE10161745A1 (de) * | 2001-12-15 | 2003-07-10 | Arvinmeritor Gmbh | Verbundbauteil für Fahrzeugkarosserien |
DE60333284D1 (de) | 2002-05-24 | 2010-08-19 | Tempur World Inc | Gesundheitskissen |
US6833390B2 (en) * | 2002-07-22 | 2004-12-21 | Bayer Polymers Llc | Process for preparing closed-cell water-blown rigid polyurethane foams having improved mechanical properties |
US20060035994A1 (en) * | 2004-05-17 | 2006-02-16 | Kaplan Warren A | Method for preparing phthalate polyester polyol-based dimensionally stable spray polyurethane foam |
KR100609285B1 (ko) | 2004-05-28 | 2006-08-08 | 화신산업 (주) | 우레탄을 이용한 자동차 내장제 및 제조방법 |
DE102004062540A1 (de) * | 2004-12-24 | 2006-07-06 | Bayer Materialscience Ag | Polyurethan-Hartschaumstoffe, ein Verfahren zu ihrer Herstellung sowie ihre Verwendung |
US7469437B2 (en) | 2005-06-24 | 2008-12-30 | Tempur-Pedic Management, Inc. | Reticulated material body support and method |
US8656537B2 (en) | 2006-04-20 | 2014-02-25 | Dan Foam Aps | Multi-component pillow and method of manufacturing and assembling same |
US20080227879A1 (en) * | 2007-03-15 | 2008-09-18 | Bayer Materialscience Llc | Water-blown polyurethane foams and a process for their production |
ES2621176T5 (es) * | 2008-02-20 | 2020-06-26 | Basf Se | Espumas rígidas de poliuretano plásticamente deformables con permeabilidad al aire mejorada y su empleo para la producción de techos de automóviles |
EP2159240A2 (de) | 2008-09-01 | 2010-03-03 | Basf Se | Plastisch verformbare Polyurethanschaumstoffe |
US20100151227A1 (en) * | 2008-12-17 | 2010-06-17 | International Automative Components Group North America, Inc. | Interior panel component for use with a vehicle and method for making |
CN102317049A (zh) | 2009-02-13 | 2012-01-11 | 陶氏环球技术有限责任公司 | 用于制备多个成形泡沫体制品的方法 |
KR101752514B1 (ko) * | 2009-06-05 | 2017-06-29 | 바스프 에스이 | 소성 변형성 강성 폴리우레탄 발포체, 접착제 및 피복재를 함유하는 복합 부품 |
DE102009048000A1 (de) * | 2009-10-01 | 2011-09-15 | Bayer Materialscience Ag | Verbundwerkstoff aus offenzelligem Hartschaum |
CN102399435B (zh) * | 2010-09-11 | 2013-05-29 | 烟台正海汽车内饰件有限公司 | 一种轿车顶棚专用聚氨酯大泡块及其生产方法 |
WO2012110585A1 (de) * | 2011-02-17 | 2012-08-23 | Basf Se | Verfahren zur herstellung von polyesteretherolen |
CN102391640B (zh) * | 2011-09-29 | 2013-03-27 | 烟台正海汽车内饰件有限公司 | 一种汽车顶棚专用一步湿法pu板 |
EP2597107A1 (de) | 2011-11-28 | 2013-05-29 | Basf Se | Verbundteile enthaltend plastisch verformbaren Polyurethanhartschaumstoff, Klebstoff und Abdeckmaterial |
US9272489B2 (en) | 2011-11-28 | 2016-03-01 | Basf Se | Composite parts comprising plastically deformable rigid polyurethane foam, adhesive and covering material |
EP2700669A1 (de) | 2012-08-21 | 2014-02-26 | Basf Se | Plastisch verformbarer Polyurethan-Polyamid-Hartschaumstoff |
US9562131B2 (en) | 2012-08-21 | 2017-02-07 | Basf Se | Thermoformable rigid polyurethane-polyamide foam |
JP2014104603A (ja) * | 2012-11-26 | 2014-06-09 | Inoac Corp | 積層体とその製造方法 |
EP2784100B1 (de) * | 2013-03-25 | 2015-09-23 | Bayer MaterialScience AG | Polyurethan-Hartschaumstoffe mit gleichmäßiger Zellgrößenverteilung und homogener Offenzelligkeit |
JP6231186B2 (ja) | 2013-03-25 | 2017-11-15 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag | 音響吸収性が高い硬質ポリウレタンフォーム |
MX370742B (es) | 2013-05-29 | 2019-12-20 | Dow Quim Mexicana S A De C V | Una formulacion para preparar una espuma de poliuretano. |
JP6218306B2 (ja) * | 2013-05-31 | 2017-10-25 | アキレス株式会社 | ポリウレタンフォーム |
JP6235247B2 (ja) * | 2013-06-20 | 2017-11-22 | アキレス株式会社 | ポリウレタンフォーム |
CN106414533B (zh) * | 2014-05-29 | 2020-03-13 | 陶氏化学墨西哥股份公司 | 用于生产聚氨酯泡沫的调配物 |
US11447079B2 (en) | 2018-01-05 | 2022-09-20 | Kasai Kogyo Co., Ltd. | Vehicle interior component and method for manufacturing vehicle interior component |
CN110317311A (zh) * | 2018-03-28 | 2019-10-11 | 科思创德国股份有限公司 | 低气味的硬质聚氨酯泡沫 |
EP3553105A1 (en) * | 2018-04-10 | 2019-10-16 | Covestro Deutschland AG | A rigid polyurethane foam with low odor |
EP3774964A1 (en) * | 2018-03-28 | 2021-02-17 | Covestro Intellectual Property GmbH & Co. KG | A rigid polyurethane foam with low odor |
CN114536879A (zh) * | 2022-03-17 | 2022-05-27 | 无锡吉兴汽车声学部件科技有限公司 | 一种微纳胶体纤维混凝结构及其加工方法 |
CN114474883A (zh) * | 2022-03-17 | 2022-05-13 | 无锡吉兴汽车声学部件科技有限公司 | 一种内外饰件热压凝胶收边与插接结构及其加工方法 |
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DE3806476A1 (de) * | 1988-03-01 | 1989-09-14 | Bayer Ag | Verfahren zur herstellung von kalthaertenden polyurethan-weichformschaumstoffen mit hervorragenden daempfungseigenschaften |
US4929646A (en) * | 1988-04-26 | 1990-05-29 | The Dow Chemical Company | Polyurethane foam prepared using high functionality cell openers |
US4863976A (en) * | 1988-04-26 | 1989-09-05 | Dow Chemical Company | Polyurethane foam prepared using high functionalilty cell openers |
DE4007330A1 (de) * | 1990-03-08 | 1991-09-12 | Bayer Ag | Verfahren zur herstellung von im wesentlichen geschlossenzelligen urethan-, harnstoff- und biuretgruppen aufweisenden hartschaumstoffen und deren verwendung |
-
1990
- 1990-01-18 DE DE4001249A patent/DE4001249A1/de not_active Withdrawn
- 1990-12-19 CA CA002032737A patent/CA2032737C/en not_active Expired - Lifetime
- 1990-12-20 EP EP90124859A patent/EP0437787B1/de not_active Expired - Lifetime
- 1990-12-20 ES ES90124859T patent/ES2045739T3/es not_active Expired - Lifetime
- 1990-12-20 DE DE90124859T patent/DE59003353D1/de not_active Expired - Fee Related
-
1991
- 1991-01-11 US US07/640,457 patent/US5219893A/en not_active Expired - Lifetime
- 1991-01-16 JP JP3015021A patent/JP3013108B2/ja not_active Expired - Fee Related
- 1991-01-17 HU HU91152A patent/HU209720B/hu not_active IP Right Cessation
- 1991-01-17 BR BR919100208A patent/BR9100208A/pt not_active IP Right Cessation
- 1991-01-17 CZ CS91101A patent/CZ280163B6/cs not_active IP Right Cessation
- 1991-01-17 ZA ZA91343A patent/ZA91343B/xx unknown
- 1991-01-17 KR KR1019910000683A patent/KR0178401B1/ko not_active IP Right Cessation
- 1991-01-17 RU SU914894234A patent/RU2031098C1/ru not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0437787A1 (de) | 1991-07-24 |
HU910152D0 (en) | 1991-08-28 |
CA2032737C (en) | 1999-07-13 |
DE59003353D1 (de) | 1993-12-09 |
CA2032737A1 (en) | 1991-07-19 |
ZA91343B (en) | 1991-10-30 |
DE4001249A1 (de) | 1991-07-25 |
RU2031098C1 (ru) | 1995-03-20 |
HUT59710A (en) | 1992-06-29 |
JPH04211416A (ja) | 1992-08-03 |
CS9100101A2 (en) | 1991-08-13 |
BR9100208A (pt) | 1991-10-22 |
EP0437787B1 (de) | 1993-11-03 |
US5219893A (en) | 1993-06-15 |
CZ280163B6 (cs) | 1995-11-15 |
JP3013108B2 (ja) | 2000-02-28 |
HU209720B (en) | 1994-10-28 |
KR910014431A (ko) | 1991-08-31 |
KR0178401B1 (ko) | 1999-05-15 |
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