ES2044545T3 - Procedimiento y catalizador para la deshidrogenacion o la deshidrociclizacion de hidrocarburos. - Google Patents

Procedimiento y catalizador para la deshidrogenacion o la deshidrociclizacion de hidrocarburos.

Info

Publication number
ES2044545T3
ES2044545T3 ES90900189T ES90900189T ES2044545T3 ES 2044545 T3 ES2044545 T3 ES 2044545T3 ES 90900189 T ES90900189 T ES 90900189T ES 90900189 T ES90900189 T ES 90900189T ES 2044545 T3 ES2044545 T3 ES 2044545T3
Authority
ES
Spain
Prior art keywords
catalyst
hydrocarbons
dehydrocyclization
dehydrogenation
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90900189T
Other languages
English (en)
Inventor
Heinz Dr Ing Zimmermann
Frederik Versluis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Linde GmbH
Engelhard Netherlands BV
Original Assignee
Linde GmbH
Engelhard de Meern BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Linde GmbH, Engelhard de Meern BV filed Critical Linde GmbH
Application granted granted Critical
Publication of ES2044545T3 publication Critical patent/ES2044545T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C07C5/412—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C07C5/322—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCESO Y CATALIZADOR PARA LA DESHIDRATACION Y DEHIDROCICLACION DE HIDROCARBUROS. EL CATALIZADOR CONSISTE EN UN OXIDO DE ALUMINIO U OXIDO DE CROMO APOYADO CON PROMOTORES FORMADOS DE COMPUESTOS DE METALES ALCALI Y/O METALES DE TIERRA ALCALINA Y COMPUESTOS DE METALES DE LOS SUBGRUPOS TERCERO Y CUARTO DEL SISTEMA PERIODICO. LA FORMACION DE COQUE Y LAS REACCIONES LATERALES PUEDEN SUPRIMIRSE SUSTANCIALMENTE MEDIANTE EL USO DE ESOS CATALIZADORES BAJO CONDICIONES DE OPERACION ESPECIALES Y EN REACTORES ESPECIALES.
ES90900189T 1988-12-12 1989-12-12 Procedimiento y catalizador para la deshidrogenacion o la deshidrociclizacion de hidrocarburos. Expired - Lifetime ES2044545T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3841800A DE3841800A1 (de) 1988-12-12 1988-12-12 Verfahren und katalysator zur dehydrierung oder dehydrozyklisierung von kohlenwasserstoffen

Publications (1)

Publication Number Publication Date
ES2044545T3 true ES2044545T3 (es) 1994-01-01

Family

ID=6368983

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90900189T Expired - Lifetime ES2044545T3 (es) 1988-12-12 1989-12-12 Procedimiento y catalizador para la deshidrogenacion o la deshidrociclizacion de hidrocarburos.

Country Status (11)

Country Link
US (1) US5378350A (es)
EP (1) EP0448584B1 (es)
JP (1) JP2794335B2 (es)
KR (1) KR0169117B1 (es)
AR (1) AR247192A1 (es)
CA (1) CA2005244A1 (es)
DE (2) DE3841800A1 (es)
ES (1) ES2044545T3 (es)
RU (1) RU1836140C (es)
UA (1) UA18586A1 (es)
WO (1) WO1990006907A1 (es)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991006366A1 (en) * 1989-10-31 1991-05-16 Dow Benelux N.V. Supported catalyst, method for the preparation thereof, and use thereof for the dehydrogenation of hydrocarbons
US5382733A (en) * 1992-03-27 1995-01-17 Mitsubishi Kasei Corporation Process for preparing naphthalene or derivative thereof
US5376613A (en) * 1993-05-04 1994-12-27 The Dow Chemical Company Dehydrogenation catalyst and process for preparing same
CN1042529C (zh) * 1994-08-17 1999-03-17 江苏丹化集团公司 裂解碳五芳构化工艺及其反应器
DE19654391A1 (de) * 1996-12-27 1998-07-02 Basf Ag Katalysator zur selektiven Herstellung von Propylen aus Propan
IT1293497B1 (it) * 1997-07-29 1999-03-01 Snam Progetti Procedimento per ottenere olefine leggere mediante deidrogenazione delle corrispondenti paraffine
EP0947247A1 (en) * 1998-03-27 1999-10-06 Engelhard Corporation Dehydrogenation catalyst
US6472577B1 (en) * 1998-12-17 2002-10-29 Uop Llc Process for increasing the yield and selectivity of a dehydrogenation process using side-by-side reaction zones
JP2003520126A (ja) * 2000-01-24 2003-07-02 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー ゲル触媒およびこれを接触脱水素工程で用いる方法
US6696388B2 (en) 2000-01-24 2004-02-24 E. I. Du Pont De Nemours And Company Gel catalysts and process for preparing thereof
US6475950B2 (en) 2000-03-16 2002-11-05 E. I. Du Pont De Nemours And Company Catalytic dehydrogenation processes and chromium catalysts for use therein
US8680357B1 (en) 2002-01-14 2014-03-25 Clariant Corporation Dehydrogenation catalyst
US8063261B2 (en) * 2002-01-14 2011-11-22 Sud-Chemie Inc. Multi-layered dehydrogenation catalyst system and process of use
US20040092391A1 (en) * 2002-11-08 2004-05-13 Andrzej Rokicki Fluid bed catalyst for dehydrogenation of hydrocarbons
US7776778B2 (en) 2003-01-31 2010-08-17 Sergey Dmitrievich Kusch Hydrocarbon conversion catalyst and methods for making and using it
RU2231516C1 (ru) * 2003-01-31 2004-06-27 Кущ Сергей Дмитриевич Способ дегидрирования и дегидроциклизации углеводородов
US20050075243A1 (en) * 2003-10-07 2005-04-07 Sud-Chemie, Inc. Catalyst for dehydrogenation of hydrocarbons
US20070038559A1 (en) * 2005-07-28 2007-02-15 Searete Llc, A Limited Liability Corporation Of The State Of Delaware Rating notification for virtual world environment
US20070249793A1 (en) * 2006-04-19 2007-10-25 Vanderbilt Jeffrey J Simplified process to prepare polyolefins from saturated hydrocarbons
KR100931792B1 (ko) 2007-05-25 2009-12-11 주식회사 엘지화학 탄화수소 수증기 열분해용 촉매, 그의 제조방법 및 이를이용한 올레핀의 제조방법
JP2009167171A (ja) * 2008-01-11 2009-07-30 Rohm & Haas Co プロパンをプロペンに転化するための担持触媒およびその転化のためのプロセスにおけるその使用
US8101541B2 (en) * 2008-07-14 2012-01-24 Sud-Chemie Inc. Catalyst for dehydrogenation of hydrocarbons
CN103769079B (zh) * 2012-10-24 2016-11-16 中国石油化工股份有限公司 一种低碳烷烃脱氢催化剂及其制备方法和应用
KR101425375B1 (ko) 2013-01-08 2014-07-31 한국과학기술연구원 탈수소고리화 반응을 이용한 탄소재료의 후처리 방법, 이를 통하여 후처리 된 탄소재료 및 이를 포함하는 고분자복합재료
US9415378B2 (en) 2013-12-02 2016-08-16 Saudi Basic Industries Corporation Dehydrogenation catalyst, its use and method of preparation
DE102014203960A1 (de) 2014-03-05 2015-09-10 Evonik Degussa Gmbh Verfahren zur Herstellung von Aldehyden aus Alkanen und Synthesegas
KR101758226B1 (ko) 2015-07-10 2017-07-17 한국화학연구원 탄화수소의 탈수소화를 통해 올레핀을 제조하기 위한 촉매 및 그 제조방법
CN106563440A (zh) * 2016-11-14 2017-04-19 中海油天津化工研究设计院有限公司 一种控制晶粒分布的低碳烷烃脱氢催化剂及其制备方法
EA201991803A1 (ru) * 2017-02-02 2019-12-30 Клариант Корпорейшн Материалы хромового катализатора, полученные из источников, не содержащих хром(vi), а также способы их получения и применение
KR102234966B1 (ko) * 2017-06-07 2021-03-31 에스케이가스 주식회사 안정성, 전환율 및 선택도가 향상된 올레핀 제조용 촉매 및 그 제조방법
JP6925961B2 (ja) * 2017-12-27 2021-08-25 株式会社クボタ オレフィン製造用熱分解管
CN115055178A (zh) * 2022-07-08 2022-09-16 润和科华催化剂(上海)有限公司 一种低碳烷烃铬系脱氢催化剂及其制备方法和应用

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA620993A (en) * 1961-05-30 A. E. Moy John Catalytic reforming of petroleum hydrocarbons
GB483417A (en) * 1936-09-30 1938-04-20 Universal Oil Prod Co Process for conversion of aliphatic hydrocarbons
DE767855C (de) * 1938-09-15 1954-03-08 Bataafsche Petroleum Verfahren zur katalytischen UEberfuehrung aliphatischer Kohlenwasserstoffe in cyclische Verbindungen
US2249337A (en) * 1938-09-15 1941-07-15 Shell Dev Process for the treatment of hydrocarbons
US2374404A (en) * 1940-01-08 1945-04-24 Universal Oil Prod Co Catalytic conversion of hydrocarbons
US2311979A (en) * 1940-03-15 1943-02-23 Universal Oil Prod Co Process for dehydrogenation of hydrocarbons
US2371087A (en) * 1942-03-27 1945-03-06 Universal Oil Prod Co Catalytic dehydrogenation process
US2437532A (en) * 1942-12-24 1948-03-09 Union Oil Co Process for the catalytic reforming of hydrocarbons
US2380035A (en) * 1943-05-28 1945-07-10 Skelly Oil Co Process for the production of aromatic hydrocarbons
US2668142A (en) * 1952-02-06 1954-02-02 Standard Oil Co Reforming process and catalysts
BE581979A (es) * 1958-08-27
FR2270938A1 (en) * 1974-01-25 1975-12-12 Inst Cercetare Si Proiectare T Chromium oxide/alumina hydrocarbon conversion catalysts - contg titanium dioxide for increased selectivity and activity
US4151071A (en) * 1977-07-26 1979-04-24 Phillips Petroleum Company Dehydrocyclization process
US4347123A (en) * 1980-05-05 1982-08-31 Exxon Research & Engineering Co. Reforming with multimetallic catalysts
US4788364A (en) * 1987-12-22 1988-11-29 Mobil Oil Corporation Conversion of paraffins to gasoline

Also Published As

Publication number Publication date
EP0448584B1 (de) 1993-08-04
AR247192A1 (es) 1994-11-30
JPH05502436A (ja) 1993-04-28
DE3841800A1 (de) 1990-06-13
UA18586A1 (uk) 1997-12-25
KR0169117B1 (ko) 1999-03-20
DE58905191D1 (de) 1993-09-09
EP0448584A1 (de) 1991-10-02
RU1836140C (ru) 1993-08-23
WO1990006907A1 (de) 1990-06-28
JP2794335B2 (ja) 1998-09-03
KR910700215A (ko) 1991-03-14
CA2005244A1 (en) 1990-06-12
US5378350A (en) 1995-01-03

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