ES2039667T3 - Procedimiento de recuperacion de galio contenido en soluciones acuosas muy basicas por extraccion liquido-liquido. - Google Patents
Procedimiento de recuperacion de galio contenido en soluciones acuosas muy basicas por extraccion liquido-liquido.Info
- Publication number
- ES2039667T3 ES2039667T3 ES198888402275T ES88402275T ES2039667T3 ES 2039667 T3 ES2039667 T3 ES 2039667T3 ES 198888402275 T ES198888402275 T ES 198888402275T ES 88402275 T ES88402275 T ES 88402275T ES 2039667 T3 ES2039667 T3 ES 2039667T3
- Authority
- ES
- Spain
- Prior art keywords
- liquid
- galium
- extraction
- contained
- recovery procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 241001101998 Galium Species 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 4
- 238000000622 liquid--liquid extraction Methods 0.000 title abstract 2
- 238000011084 recovery Methods 0.000 title abstract 2
- 238000000638 solvent extraction Methods 0.000 title abstract 2
- 239000007864 aqueous solution Substances 0.000 title 1
- 239000007788 liquid Substances 0.000 abstract 4
- 239000002253 acid Substances 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 238000000605 extraction Methods 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003637 basic solution Substances 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- 239000012074 organic phase Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910001388 sodium aluminate Inorganic materials 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/46—Purification of aluminium oxide, aluminium hydroxide or aluminates
- C01F7/47—Purification of aluminium oxide, aluminium hydroxide or aluminates of aluminates, e.g. removal of compounds of Si, Fe, Ga or of organic compounds from Bayer process liquors
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G15/00—Compounds of gallium, indium or thallium
- C01G15/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/36—Heterocyclic compounds
- C22B3/362—Heterocyclic compounds of a single type
- C22B3/364—Quinoline
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
LA PRESENTE INVENCION SE REFIERE A UN PROCEDIMIENTO DE RECUPERACION DE GALIO POR EXTRACCION LIQUIDO - LIQUIDO. ESTE PROCEDIMIENTO CONSISTE EN EXTRAER, EN UN APARATO DE EXTRACCION LIQUIDO - LIQUIDO 1, EL GALIO CONTENIDO EN UNA SOLUCION BASICA DE ALUMINATO DE SODIO (LICOR DE BAYER) POR MEDIO DE UN AGENTE EXTRACTANTE CONOCIDO BAJO LA APELACION COMERCIAL KELEX, SOLUBILIZADO EN UN DISLOVENTE ORGANICO. LA FASE ORGANICA QUE CONTIENE EL GALIO SE SOMETE A UNA EXTRACCION LIQUIDO - LIQUIDO 2 POR MEDIO DE UNA SOLUCION ACIDA CONCENTRADA PARA EXTRAER SIMULTANEAMENTE EL GALIO, ALUMINIO Y SODIO. ESTA SOLUCION ACIDA QUE CONTIENE EL GALIO SE TRATA EN 3 CON UN AGENTE EXTRACTANTE PARA EXTRAER EL GALIO, DESPUES SE RECICLA AL MENOS PARCIALMENTE EN EL EXTRACTOR 2 PARA DISMINUIR LA CONSUMACION EN ACIDO DEL PROCEDIMIENTO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8713024A FR2620695B1 (fr) | 1987-09-21 | 1987-09-21 | Procede de recuperation de gallium par extraction liquide-liquide |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2039667T3 true ES2039667T3 (es) | 1993-10-01 |
Family
ID=9355078
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES198888402275T Expired - Lifetime ES2039667T3 (es) | 1987-09-21 | 1988-09-09 | Procedimiento de recuperacion de galio contenido en soluciones acuosas muy basicas por extraccion liquido-liquido. |
Country Status (11)
Country | Link |
---|---|
US (1) | US4844808A (es) |
EP (1) | EP0309312B1 (es) |
JP (1) | JPH01165729A (es) |
CN (1) | CN1020757C (es) |
AU (1) | AU621833B2 (es) |
BR (1) | BR8804856A (es) |
CA (1) | CA1321076C (es) |
DE (1) | DE3878120T2 (es) |
ES (1) | ES2039667T3 (es) |
FR (1) | FR2620695B1 (es) |
IE (1) | IE61666B1 (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4965054A (en) * | 1989-08-01 | 1990-10-23 | Henkel Corporation | Process of extraction of gallium from aqueous solutions thereof |
US5221525A (en) * | 1991-04-26 | 1993-06-22 | N. A. Degerstrom, Inc. | Solvent extraction of gallium from acidic solutions containing phosphorus |
ES2187311B2 (es) * | 1999-07-05 | 2005-03-01 | Universidad De Cantabria | Metodo para la extraccion y concentracion simultaneas de compuestos de fases liquidas utilizando membranas microporosas. |
WO2003083147A1 (en) * | 2002-03-28 | 2003-10-09 | Council Of Scientific And Industrial Research | Process for recovery of gallium |
CN103320611B (zh) * | 2013-06-09 | 2014-09-17 | 中南大学 | 一种从含镓和锗的高酸浸出液中选择性萃取镓和锗的方法 |
DE102016210451A1 (de) * | 2016-06-13 | 2017-12-14 | Freiberger Compound Materials Gmbh | Verfahren und Vorrichtung zur Ga-Rückgewinnung |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2277897A1 (fr) * | 1974-07-12 | 1976-02-06 | Rhone Poulenc Ind | Procede de recuperation du gallium de solutions tres basiques par extraction liquide/liquide |
US3971843A (en) * | 1974-07-12 | 1976-07-27 | Rhone-Poulenc Industries | Process for liquid/liquid extraction of gallium |
FR2365641A2 (fr) * | 1976-09-27 | 1978-04-21 | Rhone Poulenc Ind | Procede de recuperation du gallium de solutions tres basiques par extraction liquide/liquide |
US4169130A (en) * | 1977-07-13 | 1979-09-25 | Rhone-Poulenc Industries | Liquid/liquid extraction of gallium values from highly basic aqueous solutions thereof |
FR2411894A1 (fr) * | 1977-12-15 | 1979-07-13 | Rhone Poulenc Ind | Procede d'extraction du gallium |
FR2495601A1 (fr) * | 1980-12-05 | 1982-06-11 | Rhone Poulenc Ind | Procede de purification de solutions de gallium |
FR2495600A1 (fr) * | 1980-12-05 | 1982-06-11 | Rhone Poulenc Ind | Procede de purification d'une solution de gallium par extraction liquide-liquide a l'aide de sels d'ammonium quaternaires |
FR2532295A1 (fr) * | 1982-08-26 | 1984-03-02 | Rhone Poulenc Spec Chim | Procede d'extraction du gallium a l'aide d'hydroxyquinoleines substituees et de sulfates ou sulfonates substitues |
FR2532296B1 (fr) * | 1982-08-26 | 1985-06-07 | Rhone Poulenc Spec Chim | Procede d'extraction du gallium a l'aide d'hydroxyquinoleines substituees et de composes organophosphores |
JPS59219422A (ja) * | 1983-05-28 | 1984-12-10 | Unitika Ltd | ガリウムの回収方法 |
JPS604132A (ja) * | 1983-06-21 | 1985-01-10 | Nisshin Flour Milling Co Ltd | 新規なα−アミラ−ゼ阻害物質 |
JPS6048451A (ja) * | 1983-08-26 | 1985-03-16 | Sanyo Electric Co Ltd | 太陽熱集熱器 |
CH655710A5 (de) * | 1983-11-17 | 1986-05-15 | Sulzer Ag | Verfahren zur fluessig-fluessig-extraktion von gallium aus natriumaluminatloesung mit hilfe eines organischen extraktionsmittels. |
JPS60245736A (ja) * | 1984-05-18 | 1985-12-05 | Unitika Ltd | ガリウムの回収方法 |
JPS6152085A (ja) * | 1984-08-22 | 1986-03-14 | Nec Corp | 動画像の符号化装置 |
JPS6242851A (ja) * | 1985-08-21 | 1987-02-24 | Hitachi Ltd | 印字ヘツド |
FR2614887B1 (fr) * | 1987-05-06 | 1990-11-30 | Rhone Poulenc Chimie | Procede de recuperation de gallium par extraction liquide-liquide |
-
1987
- 1987-09-21 FR FR8713024A patent/FR2620695B1/fr not_active Expired - Lifetime
-
1988
- 1988-04-25 IE IE123788A patent/IE61666B1/en not_active IP Right Cessation
- 1988-09-09 DE DE8888402275T patent/DE3878120T2/de not_active Expired - Fee Related
- 1988-09-09 EP EP88402275A patent/EP0309312B1/fr not_active Expired - Lifetime
- 1988-09-09 ES ES198888402275T patent/ES2039667T3/es not_active Expired - Lifetime
- 1988-09-20 JP JP63233875A patent/JPH01165729A/ja active Granted
- 1988-09-20 CN CN88106935A patent/CN1020757C/zh not_active Expired - Fee Related
- 1988-09-20 CA CA000577918A patent/CA1321076C/fr not_active Expired - Fee Related
- 1988-09-20 AU AU22437/88A patent/AU621833B2/en not_active Ceased
- 1988-09-20 BR BR8804856A patent/BR8804856A/pt unknown
- 1988-09-21 US US07/247,484 patent/US4844808A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
AU621833B2 (en) | 1992-03-26 |
FR2620695A1 (fr) | 1989-03-24 |
US4844808A (en) | 1989-07-04 |
IE881237L (en) | 1989-03-21 |
BR8804856A (pt) | 1989-04-25 |
DE3878120D1 (de) | 1993-03-18 |
AU2243788A (en) | 1989-03-23 |
CN1032554A (zh) | 1989-04-26 |
CA1321076C (fr) | 1993-08-10 |
JPH0375617B2 (es) | 1991-12-02 |
DE3878120T2 (de) | 1993-06-09 |
FR2620695B1 (fr) | 1990-01-05 |
EP0309312A1 (fr) | 1989-03-29 |
EP0309312B1 (fr) | 1993-02-03 |
JPH01165729A (ja) | 1989-06-29 |
IE61666B1 (en) | 1994-11-16 |
CN1020757C (zh) | 1993-05-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE3061208D1 (en) | Process for treating mixtures of rare earth oxides and gallium oxides | |
ES439330A1 (es) | Procedimiento para recuperar galio presente en soluciones acuosas. | |
FR2411894A1 (fr) | Procede d'extraction du gallium | |
GB1209498A (en) | Process for drying methacrylic acid | |
GB1210446A (en) | Continuous process for the purification of phosphoric acid | |
ES2039667T3 (es) | Procedimiento de recuperacion de galio contenido en soluciones acuosas muy basicas por extraccion liquido-liquido. | |
EG14374A (en) | Procede de recuperation de l'uranium contenu dans un acide phosphorique impur | |
ES2040857T3 (es) | Neutralizacion de acido sulfurico que contiene iones hierro. | |
ES2051238B1 (es) | Procedimiento de aprovechamiento del alpechin para la obtencion de acidos, fenoles, alcoholes y derivados mediante extraccion en contracorriente. | |
ES2043864T3 (es) | Procedimiento de recuperacion de galio por extraccion liquido-liquido. | |
GB991613A (en) | Process for the recovery of gallium | |
PE20010861A1 (es) | Proceso para extraer indices de cobre a partir de minerales que contienen cobre | |
GB1322444A (en) | Process for separating methacrolein from a gaseous mixture cont aining it | |
ES426753A1 (es) | Procedimiento para la purificacion de acido fosforico. | |
GB1023889A (en) | Continuous process for extracting anhydrous hydrofluoric acid from its aqueous solutions | |
GB464370A (en) | Improvements in and relating to processes for the purification of crude phosphoric acid | |
ES2077996T3 (es) | Procedimiento para la purificacion y la recuperacion de acido ortofosforico por extraccion liquido-liquido. | |
ES2058763T3 (es) | Procedimiento para purificar acidos sulfonicos de parafina. | |
IE40576L (en) | Purified phosphoric acid | |
GB1077172A (en) | Purification of solutions by liquid-liquid extraction | |
ES2034688T3 (es) | Procedimiento de recuperacion de galio. | |
GB1072238A (en) | Process for the preparation of pivalolactone | |
GB1101579A (en) | Process for the separation of isopropylphenols | |
SU440369A1 (ru) | Способ выделени серной кислоты из смеси ароматических сульфокислот и серной кислоты | |
GB966634A (en) | Extraction of trimethylol alkanes |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
Ref document number: 309312 Country of ref document: ES |