ES2036640T3 - Componente de catalizador solido para la copolimerizacion de olefinas, y procedimiento para copolimerizar olefinas usando dicho componente de catalizador solido. - Google Patents
Componente de catalizador solido para la copolimerizacion de olefinas, y procedimiento para copolimerizar olefinas usando dicho componente de catalizador solido.Info
- Publication number
- ES2036640T3 ES2036640T3 ES198888114678T ES88114678T ES2036640T3 ES 2036640 T3 ES2036640 T3 ES 2036640T3 ES 198888114678 T ES198888114678 T ES 198888114678T ES 88114678 T ES88114678 T ES 88114678T ES 2036640 T3 ES2036640 T3 ES 2036640T3
- Authority
- ES
- Spain
- Prior art keywords
- catalyst component
- solid catalyst
- copolymerization
- olefins
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
UN COMPONENTE DE CATALIZADOR SOLIDO PARA COPOLIMERIZACION DE OLEFINA QUE CONTIENE COMPUESTO DE TITANIO TRIVALENTE QUE SE OBTIENE POR REDUCCION DE UN COMPUESTO DE TITANIO REPRESENTADO POR LA FORMULA TI(OR1)NX4-M, (DONDE R1 ES UN HIDRATO DE CARBONO DE 1 A 20 ATOMOS DE CARBONO, X ES UN ATOMO DE HALOGENO, Y N ES UN NUMERO TAL QUE 0 < N <= 4) CON UN COMPUESTO ORGANOMAGNESICO EN PRESENCIA DE UN SOPORTE POROSO CON UN VOLUMEN DE PORO DE AL MENOS 0.2 ML/G (PARA UN RADIO DE PORO DE 50 A 50000 AMSTRONS) O EN LA PRESENCIA DE UN COMPUESTO DE ORGANOSILICIO CON AL MENOS UN ENLACE SI - O Y EL SOPORTE POROSO PARA OBTENER UN PRODUCTO SOLIDO, TRATANDO EL PRODUCTO SOLIDO CON UNA MEZCLA DE UN COMPUESTO DE ETER Y TETRACLORURO DE TITANIO, UN SISTEMA CATALIZADOR PARA COPOLIMERIZACION DE OLEFINA CON EL COMPONENTE DE CATALIZADOR SOLIDO ARRIBA MENCIONADO Y UN COMPUESTO DE ORGANOALUMINIO, ASI COMO UN PROCESO PARA COPOLIMERIZACION DE OLEFINAS UTILIZANDO DICHO SISTEMA CATALIZADOR.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62227032A JPH0780968B2 (ja) | 1987-09-09 | 1987-09-09 | オレフィン重合体の製造法 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2036640T3 true ES2036640T3 (es) | 1993-06-01 |
Family
ID=16854452
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES198888114678T Expired - Lifetime ES2036640T3 (es) | 1987-09-09 | 1988-09-08 | Componente de catalizador solido para la copolimerizacion de olefinas, y procedimiento para copolimerizar olefinas usando dicho componente de catalizador solido. |
Country Status (10)
Country | Link |
---|---|
US (1) | US4916099A (es) |
EP (1) | EP0306939B1 (es) |
JP (1) | JPH0780968B2 (es) |
KR (1) | KR950012332B1 (es) |
CN (1) | CN1031844A (es) |
CA (1) | CA1325004C (es) |
DE (1) | DE3876550T2 (es) |
ES (1) | ES2036640T3 (es) |
HU (1) | HU208707B (es) |
NO (1) | NO172544C (es) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5145821A (en) * | 1990-05-09 | 1992-09-08 | Quantum Chemical Corporation | Silica supported polymerization catalyst system |
US5034365A (en) * | 1990-05-09 | 1991-07-23 | Quantum Chemical Corporation | Silica supported polymerization catalyst |
US5143883A (en) * | 1987-09-21 | 1992-09-01 | Quantum Chemical Corporation | Modified silica based catalyst |
EP0356518A4 (de) * | 1988-02-23 | 1990-06-26 | Inst Khim Fiz An Sssr | Verfahren zur herstellung von 1-butan und/oder hexenen. |
SG42868A1 (en) * | 1989-05-08 | 1997-10-17 | Sumitomo Chemical Co | Process for producing solid catalyst for use in polymerization of olefins |
US5037789A (en) * | 1990-03-23 | 1991-08-06 | Quantum Chemical Corporation | Non-supported catalyst |
US5232998A (en) * | 1990-05-09 | 1993-08-03 | Quantum Chemical Corporation | Olefin polymerization using silica supported catalyst |
JP2682305B2 (ja) * | 1991-10-29 | 1997-11-26 | 住友化学工業株式会社 | オレフィン重合体の製造方法 |
US5939348A (en) * | 1991-11-06 | 1999-08-17 | Mobil Oil Corporation | Catalyst for the manufacture of polythylene with a narrow molecular weight distribution |
US5336652A (en) * | 1991-11-06 | 1994-08-09 | Mobil Oil Corporation | High activity polyethylene catalysts prepared with alkoxysilane reagents |
US6291384B1 (en) * | 1991-11-06 | 2001-09-18 | Mobil Oil Corporation | High activity catalyst prepared with alkoxysilanes |
US5470812A (en) * | 1991-11-06 | 1995-11-28 | Mobil Oil Corporation | High activity polyethylene catalysts prepared with alkoxysilane reagents |
US5514634A (en) * | 1991-11-06 | 1996-05-07 | Mobil Oil Corporation | High activity polyethylene catalysts |
US5416051A (en) * | 1992-03-24 | 1995-05-16 | Exxon Research & Engineering Co. | Pillared metakandite clay compositions as sorbents, catalysts and ceramic and refractory precursors |
FR2689133A1 (fr) * | 1992-03-27 | 1993-10-01 | Atochem Elf Sa | Catalyseur de polymérisation des oléfines, son procédé d'obtention. |
DE69330044T2 (de) * | 1992-10-28 | 2001-07-19 | Mitsubishi Chem Corp | Katalysatorbestandteil für Olefinpolymerisation |
US5258345A (en) * | 1992-11-20 | 1993-11-02 | Mobil Oil Corporation | High-activity polyethylene catalysts |
AU6031294A (en) * | 1993-01-29 | 1994-08-15 | Quantum Chemical Corporation | Four component polymerization catalyst |
US5424263A (en) * | 1993-04-23 | 1995-06-13 | Quantum Chemical Corporation | Supported polymerization catalyst |
JP3670010B2 (ja) * | 1993-11-18 | 2005-07-13 | モービル・オイル・コーポレーション | 触媒組成物の製造方法 |
US5608018A (en) * | 1993-12-08 | 1997-03-04 | Sumitomo Chemical Company, Limited | α-olefin polymerization catalyst system and process for producing α-olefin catalyst |
EP0768322A1 (en) * | 1995-10-16 | 1997-04-16 | Sumitomo Chemical Company, Limited | Method for preparing catalyst component for olefin polymerization, catalyst for olefin polymerization and process for producing olefin polymer with the catalyst |
KR100436359B1 (ko) * | 1999-02-04 | 2004-06-18 | 삼성아토피나주식회사 | 기체상 에틸렌중합체 및 에틸렌/알파-올레핀 공중합체의 제조방법 |
KR100436360B1 (ko) * | 1999-02-04 | 2004-06-18 | 삼성아토피나주식회사 | 에틸렌 중합 및 에틸렌/알파-올레핀 공중합용 담지촉매의 제조방법 |
EP1219644A1 (en) | 2000-12-27 | 2002-07-03 | Sumitomo Chemical Company, Limited | Process for producing solid product, solid catalyst component, and catalyst for olefin polymerization, and process for producing olefin polymer |
JP4983408B2 (ja) * | 2000-12-27 | 2012-07-25 | 住友化学株式会社 | ポリプロピレン系樹脂組成物 |
JP4951837B2 (ja) * | 2001-09-28 | 2012-06-13 | 住友化学株式会社 | オレフィン重合用固体触媒成分、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
WO2003055921A1 (en) * | 2001-12-24 | 2003-07-10 | Basell Poliolefine Italia S.P.A. | Ziegler natta catalyst for the polymerization of olefins |
RU2005135113A (ru) * | 2003-04-15 | 2006-05-10 | Базелль Полиолефине Итали с.р.л. (IT) | Каталитические системы типа циглера-натта и способ их получения |
JP2006523742A (ja) * | 2003-04-15 | 2006-10-19 | バーゼル、ポリオレフィン、イタリア、ソシエタ、ア、レスポンサビリタ、リミタータ | チーグラ−ナッタ型の触媒組成物及びその製造方法 |
EP1481994A1 (en) * | 2003-05-28 | 2004-12-01 | Borealis Technology Oy | Novel polymerisation catalyst |
KR100771273B1 (ko) * | 2005-12-20 | 2007-10-29 | 삼성토탈 주식회사 | 분자량 분포가 좁은 폴리올레핀 제조용 촉매 및 그를사용한 폴리올레핀 제조방법 |
KR101236596B1 (ko) * | 2010-12-24 | 2013-02-22 | 삼성토탈 주식회사 | 에틸렌 기상중합용 고체촉매의 제조방법 및 그에 의해 제조되는 촉매를 이용한 에틸렌 중합 또는 공중합 방법 |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES448189A1 (es) * | 1975-05-27 | 1977-07-01 | Dow Chemical Co | Procedimiento para polimerizar una alfa-olefina. |
FR2400040A2 (fr) * | 1977-08-09 | 1979-03-09 | Charbonnages Ste Chimique | Procede controle de polymerisation ionique de l'ethylene sous haute pression |
US4302565A (en) * | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization |
DE3027885A1 (de) * | 1979-07-24 | 1981-02-12 | Mitsubishi Petrochemical Co | Polymerisation von ethylen |
JPS5618607A (en) * | 1979-07-24 | 1981-02-21 | Mitsubishi Petrochem Co Ltd | Polymerization of ethylene |
FR2472581A1 (fr) * | 1979-12-28 | 1981-07-03 | Charbonnages Ste Chimique | Catalyseurs de polymerisation de l'ethylene comprenant des composes de plusieurs metaux de transition, et procede de polymerisation utilisant lesdits catalyseurs. |
JPS5787405A (en) * | 1980-11-21 | 1982-05-31 | Asahi Chem Ind Co Ltd | Preparation of ethylene copolymer |
DE3100736A1 (de) * | 1981-01-13 | 1982-08-26 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von traegerkatalysatoren fuer die polymerisation von (alpha)-olefinen |
US4335016A (en) * | 1981-02-23 | 1982-06-15 | Chemplex Company | Catalyst and method |
JPS57153007A (en) * | 1981-03-19 | 1982-09-21 | Mitsubishi Chem Ind Ltd | Production of polyolefin |
JPH0247484B2 (ja) * | 1981-05-20 | 1990-10-19 | Mitsubishi Petrochemical Co | Echirenkyojugotainoseizohoho |
EP0095855B1 (en) * | 1982-05-28 | 1987-04-08 | Ube Industries, Ltd. | Process for polymerizing ethylene |
JPS58208303A (ja) * | 1982-05-28 | 1983-12-05 | Ube Ind Ltd | エチレンの重合法 |
CA1263370A (en) * | 1985-03-25 | 1989-11-28 | Masaaki Katao | CATALYST AND PROCESS FOR PRODUCING .alpha.-OLEFIN POLYMERS USING THE SAME |
JPS61296007A (ja) * | 1985-06-25 | 1986-12-26 | Sumitomo Chem Co Ltd | オレフイン重合体の製造法 |
US4670413A (en) * | 1985-12-06 | 1987-06-02 | Mobil Oil Corporation | Catalyst composition for polymerizing alpha-olefins |
JPS62256802A (ja) * | 1986-04-28 | 1987-11-09 | Sumitomo Chem Co Ltd | α−オレフイン重合体の製造法 |
JPS62267305A (ja) * | 1986-05-15 | 1987-11-20 | Sumitomo Chem Co Ltd | オレフイン重合体の製造法 |
JP2688380B2 (ja) * | 1990-06-04 | 1997-12-10 | 富士写真フイルム株式会社 | 写真フイルムユニット及びフイルムプロセサ |
-
1987
- 1987-09-09 JP JP62227032A patent/JPH0780968B2/ja not_active Expired - Lifetime
-
1988
- 1988-08-29 US US07/237,324 patent/US4916099A/en not_active Expired - Fee Related
- 1988-09-06 CA CA000576580A patent/CA1325004C/en not_active Expired - Fee Related
- 1988-09-07 NO NO883981A patent/NO172544C/no unknown
- 1988-09-08 ES ES198888114678T patent/ES2036640T3/es not_active Expired - Lifetime
- 1988-09-08 KR KR1019880011607A patent/KR950012332B1/ko active IP Right Grant
- 1988-09-08 EP EP88114678A patent/EP0306939B1/en not_active Expired - Lifetime
- 1988-09-08 CN CN88106619A patent/CN1031844A/zh active Pending
- 1988-09-08 DE DE8888114678T patent/DE3876550T2/de not_active Expired - Fee Related
- 1988-09-09 HU HU884652A patent/HU208707B/hu not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0306939B1 (en) | 1992-12-09 |
HU208707B (en) | 1993-12-28 |
JPH0780968B2 (ja) | 1995-08-30 |
US4916099A (en) | 1990-04-10 |
CA1325004C (en) | 1993-12-07 |
EP0306939A1 (en) | 1989-03-15 |
KR890005156A (ko) | 1989-05-13 |
NO172544B (no) | 1993-04-26 |
DE3876550D1 (de) | 1993-01-21 |
DE3876550T2 (de) | 1993-06-24 |
CN1031844A (zh) | 1989-03-22 |
NO883981L (no) | 1989-03-10 |
HUT52121A (en) | 1990-06-28 |
KR950012332B1 (ko) | 1995-10-17 |
JPS6469610A (en) | 1989-03-15 |
NO172544C (no) | 1993-08-04 |
NO883981D0 (no) | 1988-09-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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