ES2026510T3 - Pigmento nacarado resistente al agua y procedimiento para su produccion. - Google Patents

Pigmento nacarado resistente al agua y procedimiento para su produccion.

Info

Publication number
ES2026510T3
ES2026510T3 ES198787116542T ES87116542T ES2026510T3 ES 2026510 T3 ES2026510 T3 ES 2026510T3 ES 198787116542 T ES198787116542 T ES 198787116542T ES 87116542 T ES87116542 T ES 87116542T ES 2026510 T3 ES2026510 T3 ES 2026510T3
Authority
ES
Spain
Prior art keywords
procedure
production
water resistant
pearling
pigment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES198787116542T
Other languages
English (en)
Inventor
Katsuhisa Nitta
Takaji Watanabe
Isao Suzuki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Merck Patent GmbH
Original Assignee
Merck Patent GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Merck Patent GmbH filed Critical Merck Patent GmbH
Application granted granted Critical
Publication of ES2026510T3 publication Critical patent/ES2026510T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/36—Pearl essence, e.g. coatings containing platelet-like pigments for pearl lustre
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/20—Particle morphology extending in two dimensions, e.g. plate-like
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/10—Interference pigments characterized by the core material
    • C09C2200/102—Interference pigments characterized by the core material the core consisting of glass or silicate material like mica or clays, e.g. kaolin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/30—Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
    • C09C2200/301—Thickness of the core
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/40—Interference pigments comprising an outermost surface coating
    • C09C2200/401—Inorganic protective coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/40—Interference pigments comprising an outermost surface coating
    • C09C2200/402—Organic protective coating
    • C09C2200/407—Organosilicon materials, e.g. silanes, silicones
    • C09C2200/408—Organosilicon materials, e.g. silanes, silicones comprising additional functional groups, e.g. –NH2, -C=C- or -SO3

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

SE PREPARAN PIGMENTOS MARCADOS RESISTENTES AL AGUA POR UN PROCEDIMIENTO QUE IMPLICA HIDROLIZAR UN COMPUESTO DE ZIRCONILO EN MEDIO ACUOSO EN PRESENCIA DE UN HIPOFOSFITO, FORMANDO ASI OXIDO DE ZIRCONIO HIDRATADO Y DEPOSITANDOLO SOBRE LA SUPERFICIE DEL PIGMENTO BASE DE LAMINILLAS DE MICA RECUBIERTAS CON OXIDO METALICO.
ES198787116542T 1986-11-21 1987-11-10 Pigmento nacarado resistente al agua y procedimiento para su produccion. Expired - Lifetime ES2026510T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61276687A JPH0643565B2 (ja) 1986-11-21 1986-11-21 耐水性真珠光沢顔料およびその製造法

Publications (1)

Publication Number Publication Date
ES2026510T3 true ES2026510T3 (es) 1992-05-01

Family

ID=17572920

Family Applications (1)

Application Number Title Priority Date Filing Date
ES198787116542T Expired - Lifetime ES2026510T3 (es) 1986-11-21 1987-11-10 Pigmento nacarado resistente al agua y procedimiento para su produccion.

Country Status (12)

Country Link
US (1) US4828623A (es)
EP (1) EP0268918B1 (es)
JP (1) JPH0643565B2 (es)
KR (1) KR960005432B1 (es)
BR (1) BR8706283A (es)
CA (1) CA1281152C (es)
DE (1) DE3774245D1 (es)
ES (1) ES2026510T3 (es)
FI (1) FI86881C (es)
MX (1) MX168811B (es)
YU (1) YU45467B (es)
ZA (1) ZA878718B (es)

Families Citing this family (64)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5223034A (en) * 1988-05-19 1993-06-29 Merck Patent Gesellschaft Mit Beschrankter Haftung Weather-resistant, pearlescent pigment and process for producing the same in the presence of hypophosphite
JPH0819350B2 (ja) * 1988-05-19 1996-02-28 メルク・ジヤパン株式会社 耐候性真珠光沢顔料およびその製造法
JPH0832119B2 (ja) * 1988-05-27 1996-03-27 松下電器産業株式会社 音場可変装置
CA1329867C (en) * 1988-07-20 1994-05-31 Hiroshi Ito Pigment
JP2508816B2 (ja) * 1988-09-19 1996-06-19 トヨタ自動車株式会社 顔料の製造方法
JP2533838B2 (ja) * 1989-02-06 1996-09-11 大阪シーリング印刷株式会社 感熱記録ラベル
JPH0376763A (ja) * 1989-08-21 1991-04-02 Merck Japan Kk 紫外線および赤外線に対し防御効果を有する顔料
DE4207723A1 (de) * 1992-03-11 1993-09-16 Merck Patent Gmbh Oberflaechenmodifizierte pigmente
EP0632821B1 (en) * 1992-03-26 1997-01-15 MERCK PATENT GmbH Platelet-like colored pigments and process for producing the same
US5273576A (en) * 1992-10-19 1993-12-28 Mearl Corporation Intensely colored pearlescent pigments
US5266107A (en) * 1992-12-21 1993-11-30 Merck Patent Gesellschaft Mit Beschrankter Haftung Pearlscent pigment and process for producing the same
DE4321005A1 (de) * 1993-06-24 1995-01-05 Merck Patent Gmbh Perlglanzpigment für Wasserlacksysteme
DE4323914A1 (de) 1993-07-16 1995-01-19 Merck Patent Gmbh Perlglanzpigment-Zubereitung
US5433779A (en) * 1993-12-06 1995-07-18 The Mearl Corporation Rutile titanium dioxide coated micaceous pigments formed without tin
US5527848A (en) * 1994-12-14 1996-06-18 Basf Corporation Pacification of optically variable pigments for use in waterborne coating compositions
US5693134A (en) 1994-12-29 1997-12-02 Merck Patent Gesellschaft Mit Beschrankter Haftung Gray interference pigment and process for producing the same
JP3643144B2 (ja) * 1995-08-04 2005-04-27 メルク株式会社 新規な真珠光沢顔料およびその製造方法
US5759255A (en) * 1996-02-07 1998-06-02 Engelhard Corporation Pearlescent pigment for exterior use
DE19639783A1 (de) * 1996-09-27 1998-04-02 Merck Patent Gmbh Modifizierte Perlglanzpigmente für Wasserlacksysteme
US5951750A (en) * 1997-06-19 1999-09-14 Engelhard Corporation Anti-yellowing polyolefin compositions containing pearlescent pigment to prevent yellowing and method therefore
US6107244A (en) * 1997-10-15 2000-08-22 Nashua Corporation Verification methods employing thermally--imageable substrates
DE19820112A1 (de) 1998-05-06 1999-11-11 Eckart Standard Bronzepulver Mit reaktiven Orientierungshilfsmitteln beschichtete Effektpigmente
JP4557193B2 (ja) 1999-10-05 2010-10-06 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング 高配向性薄片状顔料およびその製造方法
JP4278813B2 (ja) 2000-02-10 2009-06-17 メルク株式会社 新規な表面変性パール顔料及びその製造方法
US6533858B1 (en) 2000-10-10 2003-03-18 Engelhard Corporation Effect pigments with improved colorant adhesion
KR100337000B1 (ko) * 2000-10-14 2002-05-17 장길완 합성운모에 금속산화물을 코팅하여 펄 광택성 안료를제조하는 방법
DE10054980C2 (de) 2000-11-06 2003-02-06 Merck Patent Gmbh Stabilisierung von Perlglanzpigmenten
DE10054981A1 (de) 2000-11-06 2002-05-16 Merck Patent Gmbh Nachbeschichtung von Perlglanzpigmenten mit hydrophoben Kupplungsreagenzien
JP2004520472A (ja) * 2001-02-15 2004-07-08 メルク　パテント　ゲゼルシャフト　ミット　ベシュレンクテル　ハフトング 薄片状顔料
JP2003003089A (ja) * 2001-06-26 2003-01-08 Kao Corp 被覆粉体
KR100485632B1 (ko) * 2001-12-31 2005-04-27 한국조폐공사 이색성을 갖는 착색 진주안료 및 이의 제조방법
JP4334204B2 (ja) 2002-11-21 2009-09-30 メルク株式会社 高輝度高彩度虹彩顔料およびその製造方法
CN100519669C (zh) 2004-07-01 2009-07-29 温州泰珠集团有限公司 改性珠光颜料及其制备方法
DE102004035769A1 (de) 2004-07-27 2006-03-23 Merck Patent Gmbh Mehrschichtige Interferenzpigmente
DE602005026820D1 (de) 2004-08-23 2011-04-21 Basf Se Verfahren zur herstellung von blättchenförmigen pi0)
CN100420721C (zh) * 2004-09-24 2008-09-24 林一中 供外部使用的珠光颜料
DE102004049203A1 (de) 2004-10-08 2006-04-20 Merck Patent Gmbh Effektpigmente auf Basis dünner SiO2-Plättchen
DE102004056330A1 (de) 2004-11-22 2006-06-01 Eckart Gmbh & Co.Kg Trockentoner, Verfahren zu dessen Herstellung und Verwendung desselben
DE102005001997A1 (de) 2005-01-17 2006-07-20 Merck Patent Gmbh Effektpigmente mit starkem Farbtop
DE102005002124A1 (de) 2005-01-17 2006-07-27 Merck Patent Gmbh Farbstarke rote Effektpigmente
US7819966B2 (en) 2005-08-05 2010-10-26 Eckart Gmbh Surface-coated pearlescent pigments, process for preparing them, and their use
DE102005037612A1 (de) * 2005-08-05 2007-02-08 Eckart Gmbh & Co. Kg Oberflächenbelegte Perlglanzpigmente, Verfahren zu deren Herstellung und deren Verwendung
DE102006002264A1 (de) * 2006-01-17 2007-07-19 BSH Bosch und Siemens Hausgeräte GmbH Pyrolysefester Beschichtungslack
DE102006009131A1 (de) 2006-02-24 2007-09-06 Eckart Gmbh & Co.Kg Mit anorganisch/organischen Mischschichten beschichtete Perlglanzpigmente und Verfahren zu deren Herstellung
CN101517011B (zh) * 2006-07-21 2013-01-16 巴斯福公司 含铁氧体的合成云母基珠光颜料
EP2089478B1 (en) * 2006-12-05 2016-01-27 Basf Se Surface-modified (effect) pigments
US20100203093A1 (en) 2007-07-12 2010-08-12 Ciba Corporation Interference pigments on the basis of perlite flakes
CN102015914B (zh) 2008-05-09 2013-09-25 巴斯夫欧洲公司 涂有金属氧化物/氢氧化物层和丙烯酸类共聚物的珠光颜料
DE102008050924A1 (de) 2008-10-10 2010-04-15 Merck Patent Gmbh Pigmente
FR2937043B1 (fr) * 2008-10-15 2012-03-30 Marine Products Pigment nacre en tant qu'agent antifouling
DE102010009239A1 (de) 2009-03-20 2010-09-23 Merck Patent Gmbh Wässrige Beschichtungszusammensetzung
DE102009016089A1 (de) 2009-03-20 2010-09-23 Merck Patent Gmbh Beschichtungszusammensetzung
WO2011051122A1 (en) 2009-10-28 2011-05-05 Basf Se Pigments with improved sparkling effect
WO2011095447A2 (en) 2010-02-04 2011-08-11 Basf Se Pigment compositions with improved sparkling effect
CN103249782B (zh) 2010-12-09 2015-05-20 默克专利股份有限公司 亮黑色颜料
CN103249783B (zh) 2010-12-09 2015-04-15 默克专利股份有限公司 磁性颜料
JP5912565B2 (ja) * 2012-01-23 2016-04-27 サカタインクス株式会社 ラミネート缶用印刷インキ組成物
CN102876091A (zh) * 2012-10-11 2013-01-16 浙江瑞成珠光颜料有限公司 一种抗黄变珠光颜料的制备方法
EP3596169B1 (en) 2017-03-17 2022-09-14 Merck Patent GmbH Interference pigments
TW202045631A (zh) 2019-03-15 2020-12-16 德商麥克專利有限公司 帶藍色之深黑色效果顏料
DE102019006869A1 (de) 2019-10-02 2021-04-08 Merck Patent Gmbh Interferenzpigmente
WO2021185693A1 (en) 2020-03-16 2021-09-23 Merck Patent Gmbh Use of colored effect pigments for enhancing the infrared absorption capacity of colored polymers
WO2022244766A1 (ja) * 2021-05-17 2022-11-24 日本板硝子株式会社 酸化ジルコニウムを含む被膜を有する光揮性顔料
WO2023152073A1 (en) 2022-02-09 2023-08-17 Merck Patent Gmbh Metal effect pigments with surface-treatments, preparing method and use of same

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3087828A (en) * 1961-06-28 1963-04-30 Du Pont Nacreous pigment compositions
FR1326901A (fr) * 1961-06-28 1963-05-10 Du Pont Nouvelles compositions de pigments
US3832208A (en) * 1972-03-09 1974-08-27 Du Pont Nacreous pigments treated with methacrylatochromic chloride for improved humidity resistance
DE2244298C3 (de) * 1972-09-09 1975-06-19 Merck Patent Gmbh, 6100 Darmstadt Perlglanzpigmente und Verfahren zu ihrer Herstellung
DE3137809A1 (de) * 1981-09-23 1983-03-31 Merck Patent Gmbh, 6100 Darmstadt "perlglanzpigmente, ihre herstellung und ihre verwendung"
DE3151343A1 (de) * 1981-12-24 1983-07-07 Merck Patent Gmbh, 6100 Darmstadt Perlglanzpigmente mit verbesserter lichtbestaendigkeit, ihre herstellung und ihre verwendung
DE3221045A1 (de) * 1982-06-04 1983-12-08 Merck Patent Gmbh, 6100 Darmstadt Perlglanzpigmente, verfahren zu ihrer herstellung und ihrer verwendung
US4505755A (en) * 1982-12-28 1985-03-19 Onahama Sakai Kagaku Kabushiki Kaisha Method of producing surface-treated barium sulfate

Also Published As

Publication number Publication date
EP0268918B1 (en) 1991-10-30
KR880006331A (ko) 1988-07-22
MX168811B (es) 1993-06-09
ZA878718B (en) 1988-08-31
FI86881C (fi) 1992-10-26
BR8706283A (pt) 1988-06-28
JPH0643565B2 (ja) 1994-06-08
US4828623A (en) 1989-05-09
JPS63130673A (ja) 1988-06-02
DE3774245D1 (de) 1991-12-05
CA1281152C (en) 1991-03-12
FI875144A (fi) 1988-05-22
YU45467B (en) 1992-05-28
FI86881B (fi) 1992-07-15
KR960005432B1 (en) 1996-04-25
YU208887A (en) 1989-04-30
FI875144A0 (fi) 1987-11-20
EP0268918A1 (en) 1988-06-01

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