EP4152094A1 - Pellicle frame, pellicle, pellicle-attached exposure original plate, method for manufacturing semiconductor, method for manufacturing liquid crystal display plate, and exposure method - Google Patents

Pellicle frame, pellicle, pellicle-attached exposure original plate, method for manufacturing semiconductor, method for manufacturing liquid crystal display plate, and exposure method Download PDF

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Publication number
EP4152094A1
EP4152094A1 EP21805081.3A EP21805081A EP4152094A1 EP 4152094 A1 EP4152094 A1 EP 4152094A1 EP 21805081 A EP21805081 A EP 21805081A EP 4152094 A1 EP4152094 A1 EP 4152094A1
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EP
European Patent Office
Prior art keywords
pellicle
exposure
resin
porous film
frame
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP21805081.3A
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German (de)
English (en)
French (fr)
Inventor
Yu Yanase
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shin Etsu Chemical Co Ltd
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Shin Etsu Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shin Etsu Chemical Co Ltd filed Critical Shin Etsu Chemical Co Ltd
Publication of EP4152094A1 publication Critical patent/EP4152094A1/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F1/00Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
    • G03F1/62Pellicles, e.g. pellicle assemblies, e.g. having membrane on support frame; Preparation thereof
    • G03F1/64Pellicles, e.g. pellicle assemblies, e.g. having membrane on support frame; Preparation thereof characterised by the frames, e.g. structure or material, including bonding means therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/42Auxiliary equipment or operation thereof
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F1/00Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
    • G03F1/22Masks or mask blanks for imaging by radiation of 100nm or shorter wavelength, e.g. X-ray masks, extreme ultraviolet [EUV] masks; Preparation thereof
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/70008Production of exposure light, i.e. light sources
    • G03F7/70033Production of exposure light, i.e. light sources by plasma extreme ultraviolet [EUV] sources
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/708Construction of apparatus, e.g. environment aspects, hygiene aspects or materials
    • G03F7/70908Hygiene, e.g. preventing apparatus pollution, mitigating effect of pollution or removing pollutants from apparatus
    • G03F7/70916Pollution mitigation, i.e. mitigating effect of contamination or debris, e.g. foil traps
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/708Construction of apparatus, e.g. environment aspects, hygiene aspects or materials
    • G03F7/70983Optical system protection, e.g. pellicles or removable covers for protection of mask
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/10Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces

Definitions

  • This invention relates to a pellicle frame, pellicle, pellicle-covered exposure original, method for manufacturing semiconductor device, method for manufacturing liquid crystal (LC) display panel, and exposure method.
  • LC liquid crystal
  • the exposure light source becomes shorter in wavelength. Specifically, the exposure light source makes a transition from g-line (436 nm) and i-line (365 nm) of mercury lamps to KrF excimer laser (248 nm) and ArF excimer laser (193 nm).
  • EUV extreme ultraviolet
  • the pellicle is basically constructed such that a pellicle membrane having a high transmittance to radiation used in the exposure is extended on the upper end surface of a pellicle frame made of aluminum or titanium, and a gas-tight gasket is formed on the lower end surface of the pellicle frame.
  • a pressure-sensitive adhesive (PSA) layer is generally used as the gas-tight gasket.
  • a protective sheet is attached to the PSA layer for protection purpose.
  • the pellicle membrane is made of nitrocellulose, cellulose acetate, and fluoro-polymers which are fully transmissive to radiation used in the exposure such as g-line (436 nm) or i-line (365 nm) of mercury lamps, KrF excimer laser (248 nm) or ArF excimer laser (193 nm), a very thin silicon membrane or carbon membrane is investigated as the pellicle membrane for the EUV lithography.
  • porous films as used in high-efficiency particulate air (HEPA) filters and ultra-low penetration air (ULPA) filters are used because of their contaminant-capturing capability.
  • HEPA high-efficiency particulate air
  • ULPA ultra-low penetration air
  • the interior of the EUV exposure apparatus is filled with hydrogen gas for efficient removal of contaminants, known as scattering debris, which are generated upon emission of EUV radiation.
  • the EUV radiation acts on hydrogen gas to generate hydrogen radicals.
  • the EUV lithography pellicle is thus required to have high resistance to hydrogen radicals, which is not needed in the prior art KrF and ArF lithography pellicles.
  • the filter has a porous film for collecting contaminants so that upon passage of gas through pores in the porous film, the porous film captures contaminants and only contaminant-free gas passes across the film.
  • the porous film has the largest surface area and the most chance of exposure to hydrogen radical-containing gas among the members of which the pellicle is composed.
  • the porous film is degraded by hydrogen radicals and its contaminant capture rate can be reduced as pores are enlarged. For this reason, the porous film used in the filter is required to have high hydrogen radical resistance.
  • Patent Document 1 WO 2016/043292
  • An object of the invention which has been made under the above-mentioned circumstances, is to provide a pellicle frame having satisfactory resistance to hydrogen radicals in the EUV lithography, a pellicle comprising the pellicle frame, a pellicle-covered exposure original, a method for manufacturing a semiconductor device, a method for manufacturing a LC display panel, and an exposure method.
  • the inventor has found that the object of providing a pellicle frame having satisfactory resistance to hydrogen radicals in the EUV lithography is attained by providing the pellicle frame with a ventilating port and attaching a filter having a resin-coated porous film inside the ventilating port, and preferably by using a silicone or epoxy resin as the resin for coating the porous film.
  • the invention is predicated on this finding.
  • the invention provides a pellicle frame, pellicle, pellicle-covered exposure original, method for manufacturing semiconductor device, method for manufacturing LC display panel, and exposure method as defined below.
  • a pellicle frame and a pellicle having satisfactory resistance to hydrogen radicals in the EUV lithography are provided. They are useful in an EUV exposure method, semiconductor device manufacturing method, and LC display panel manufacturing method using a pellicle-covered exposure original.
  • the invention provides a pellicle frame in a frame shape having an upper end surface adapted to bear a pellicle membrane and a lower end surface adapted to face a photomask.
  • the pellicle frame As long as the pellicle frame is in a frame shape, its shape corresponds to the shape of a photomask on which a pellicle is mounted. In general, it is a four-sided (rectangular or square) frame.
  • the shape of corners or edges of the pellicle frame may be an angular or pointed shape as primarily machined or another shape, typically curvilinear shape as homed or chamfered such as by rounding or chamfering.
  • the pellicle frame further has a surface (referred to as upper end surface) on which a pellicle membrane is to be extended and a surface (referred to as lower end surface) adapted to face a photomask when the frame is mounted on the photomask.
  • the pellicle frame is provided on its upper end surface with a pellicle membrane via an adhesive and on its lower end surface with a PSA layer for mounting the pellicle on the photomask although the invention is not limited thereto.
  • the material of the pellicle frame is not particularly limited, any well-known material may be used. Since the pellicle frame for the EUV lithography can be exposed to high temperature, a material having a low coefficient of thermal expansion is preferred. Exemplary materials include Si, SiO 2 , SiN, quartz, Invar, titanium and titanium alloys. Inter alia, titanium and titanium alloys are preferred for ease of working and light weight.
  • the size of the pellicle frame is not particularly limited. Since the height of the pellicle for the EUV lithography is limited to 2.5 mm or less, the thickness of the pellicle frame for the EUV lithography is smaller than the height, i.e., less than 2.5 mm.
  • the thickness of the pellicle frame for the EUV lithography is preferably equal to or less than 1.5 mm in view of the thickness of the pellicle film and mask PSA.
  • the lower limit of thickness of the pellicle frame is preferably at least 1.0 mm.
  • the side surface of the pellicle frame is typically provided with a jig hole which is utilized during handling or dismounting of the pellicle from the photomask.
  • a jig hole which is utilized during handling or dismounting of the pellicle from the photomask.
  • the length of the jig hole in thickness direction of the pellicle frame is 0.5 to 1.0 mm.
  • shape of the hole is not particularly limited, it may be either circular or rectangular.
  • the pellicle frame is provided with a ventilating port for mitigating a change of pressure across the pellicle.
  • the shape and number of the ventilating port(s) are not particularly limited.
  • the ventilating port is provided with a filter for preventing contaminant ingress into the pellicle interior.
  • the location site of the filter is not particularly limited, that is, the filter may be disposed inside the pellicle frame, inside the ventilating port, or outside the pellicle frame.
  • the pellicle frame of the invention is characterized by comprising a filter having a porous film coated with a hydrogen radical-resistant resin.
  • the porous film is preferably made of at least one resin selected from the group consisting of fluoro-resins, polyester resins, polyimide resins, polycarbonate resins, and polyolefin resins.
  • fluoro-resins which have been used in KrF and ArF lithography pellicles are more preferred, with polytetrafluoroethylene (PTFE) being most preferred.
  • the PTFE porous film is generally composed of nodes which are aggregates of PTFE and a multiplicity of fibrils in the form of minute fibrous structures, each linked at both ends to the nodes. Adjacent nodes are connected by the fibril.
  • the PTFE porous film has such air permeability in film thickness direction that voids or pores between adjoining fibrils become ventilating passages.
  • the PTFE porous film is also known as stretched porous film and formed by stretching a PTFE sheet which is an aggregate of PTFE. By stretching a PTFE sheet, nodes and fibrils are formed and their arrangement varies, for example, with the PTFE sheet stretching conditions.
  • the resin with which the porous film is coated should preferably have sufficient resistance to hydrogen radicals.
  • Illustrative examples include silicone resins, epoxy resins, acrylic resins, fluoro-resins and urethane resins. Among these, silicone resins and epoxy resins are preferred from the standpoint of hydrogen radical resistance, with the silicone resins being more preferred.
  • the coating of the porous film with the resin does not necessarily require that the overall surface of the porous film be coated with the resin.
  • the coating weight and percent coverage may be adjusted in accordance with the desired level of hydrogen radical resistance.
  • the filter may include another optional member other than the porous film.
  • the other member is, for example, an air-permeable support layer.
  • the filter includes the porous film and an air-permeable support layer disposed on one major surface of the porous film. By disposing the air-permeable support layer, the filter is improved in strength and becomes easier to handle.
  • the air-permeable support layer is preferably a layer having higher air permeability and moisture permeability in thickness direction than the porous film.
  • the air-permeable support layer for example, woven fabric, non-woven fabric, net or mesh may be used.
  • the material of which the air-permeable support layer is made is, for example, polyester, polyethylene and aramide resins.
  • the shape of the air-permeable support layer may be identical with or different from the shape of the porous film.
  • the air-permeable support layer is attached to the porous film, for example, by such means as heat fusion or adhesive bonding.
  • the air-permeable support layer may be disposed on one major surface or both major surfaces of the porous film.
  • the air-permeable support layer may be coated with the above-mentioned resin.
  • the material of the pellicle membrane is not particularly limited, a material having a high transmittance at the wavelength of the exposure light source and high light resistance is preferred.
  • a very thin silicon membrane, carbon membrane or the like is used in the EUV lithography.
  • the carbon membrane include membranes of graphene, diamond-like carbon, and carbon nanotubes.
  • a pellicle membrane supported by a rim of silicon or the like may be used. In this case, a pellicle can be readily constructed by bonding the region of the rim to the pellicle frame.
  • the pellicle of the invention includes the pellicle frame and a pellicle membrane disposed on the upper end surface thereof via a PSA or adhesive. While the material of the PSA or adhesive is not particularly limited, any well-known ones may be used. A PSA or adhesive having a strong bonding force is preferred for firmly holding the pellicle membrane.
  • the pellicle frame is provided on its lower end surface with a mask PSA for mounting the frame on a photomask.
  • the mask PSA is preferably extended along the overall periphery of the pellicle frame.
  • the mask PSA used herein may be any of well-known ones, with acrylic PSA and silicone-based PSA being preferably used.
  • the PSA may be worked to any desired shape if necessary.
  • a release layer or separator may be attached for protecting the PSA.
  • the material of the release layer is not particularly limited, use may be made of polyethylene terephthalate (PET), polytetrafluoroethylene (PTFE), tetrafluoroethylene-perfluoroalkyl vinyl ether copolymers (PFA), polyethylene (PE), polycarbonate (PC), polyvinyl chloride (PVC), and polypropylene (PP), for example.
  • PET polyethylene terephthalate
  • PTFE polytetrafluoroethylene
  • PFA tetrafluoroethylene-perfluoroalkyl vinyl ether copolymers
  • PE polyethylene
  • PC polycarbonate
  • PVC polyvinyl chloride
  • PP polypropylene
  • release agents as silicone-based release agents and fluorochemical release agents may be coated on the surface of the release layer.
  • the pellicle of the invention may serve not only as a protective member for protecting an exposure original from particulate contamination in an exposure unit, but also as a protective member for protecting an exposure original during its storage or transportation.
  • a protective member for protecting an exposure original during its storage or transportation typically photomask, an electrostatic chucking method, mechanical securing method or the like may be used as well as the aforementioned method of bonding with the mask PSA.
  • a further embodiment of the invention is a method for manufacturing a semiconductor device or LC display panel, which includes the step of exposing a substrate (semiconductor wafer or LC matrix) to radiation through the pellicle-covered exposure original.
  • a substrate semiconductor wafer or LC matrix
  • the stepper is installed with the pellicle-covered exposure original and exposure is performed to form a photoresist pattern corresponding to an integrated circuit or the like on a substrate.
  • a projection optical system is used in the EUV lithography such that EUV radiation is reflected by the exposure original and directed to the substrate.
  • the exposure step is performed under reduced pressure or in vacuum.
  • the yield of the lithography step can be improved by using the pellicle-covered exposure original.
  • a filter (TEMISH S-NTF 1033-N01 by Nitto Denko Corp.) consisting of a 15-cm square porous film of polytetrafluoroethylene (PTFE porous film) and a mesh-form support of polypropylene.
  • the filter was spin coated with a 1 wt% solution of each of the following resins (1) to (6) at 800 rpm for 60 seconds, which was air dried at room temperature for 12 hours to volatilize off the solvent.
  • the filter coated with the resin was subjected to hydrogen plasma exposure in the system shown below.
  • Plasma source inductively coupled plasma (ICP) Treating conditions: pressure 80 mTorr, H 2 flow rate 50 sccm Power: 200 W Treating temperature: 100°C Treating time: 600 s
  • ICP inductively coupled plasma
  • a pellicle frame (outer dimensions 150 mm ⁇ 118 mm ⁇ 1.5 mm, width 4.0 mm) of titanium.
  • the pellicle frame 1 was provided with a ventilating port 10 of L shape which extends from the outside to the lower end surface of the frame.
  • the pellicle frame 1 has an upper end surface 1a and a lower end surface 1b.
  • the pellicle frame 1 is provided at an opening in the lower end surface with a filter 20, which is coated with a selected resin though not shown.
  • TEMISH S-NTF 1033-N01 by Nitto Denko Corp. consisting of a PTFE porous film and a mesh-form support of polypropylene.
  • curing agent PT-56 by Shin-Etsu Chemical Co., Ltd.
  • silicone resin base PSA X-40-3264 by Shin-Etsu Chemical Co., Ltd.
  • the filter at its center was impregnated with 1 mL of the solution, followed by air drying at room temperature for 2 hours until the solvent was completely volatilized off.
  • the filter designated at 20 in FIG. 2 was attached to the opening in the lower end surface of the pellicle frame with a double-side tape.
  • the pellicle frame was washed with a neutral detergent and pure water. Then a material obtained by adding 1 part by weight of curing agent (PT-56 by Shin-Etsu Chemical Co., Ltd.) to 100 parts by weight of silicone resin base PSA (X-40-3264 by Shin-Etsu Chemical Co., Ltd.) and stirring was coated onto the upper end surface of the frame to form a PSA layer of 1 mm wide and 0.1 mm thick.
  • curing agent PT-56 by Shin-Etsu Chemical Co., Ltd.
  • silicone resin base PSA X-40-3264 by Shin-Etsu Chemical Co., Ltd.
  • curing agent L-45 by Soken Chemical & Engineering Co., Ltd.
  • acrylic resin base PSA SK-Dyne 1499M by Soken Chemical & Engineering Co., Ltd.
  • the pellicle frame was heated at 100°C for 12 hours to cure the PSA layers on the upper and lower end surfaces. Subsequently, a very thin silicon membrane as the pellicle membrane was compression bonded to the PSA layer on the upper end surface of the pellicle frame to complete a pellicle.
  • a filter of 10 mm long and 2.5 mm wide (TEMISH S-NTF 1033-N01 by Nitto Denko Corp.) consisting of a PTFE porous film and a mesh-form support of polypropylene.
  • epoxy resin base adhesive (1001T75 by Mitsubishi Chemical Co., Ltd.) was dissolved in toluene to form a 1 wt% solution.
  • the filter at its center was impregnated with 1 mL of the solution, followed by air drying at room temperature for 2 hours until the solvent was completely volatilized off.
  • the filter was attached to the opening in the lower end surface of the pellicle frame with a double-side tape. Otherwise, the procedure is the same as in Example 1 to complete a pellicle.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Epidemiology (AREA)
  • Public Health (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Atmospheric Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical & Material Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Preparing Plates And Mask In Photomechanical Process (AREA)
  • Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
EP21805081.3A 2020-05-14 2021-05-12 Pellicle frame, pellicle, pellicle-attached exposure original plate, method for manufacturing semiconductor, method for manufacturing liquid crystal display plate, and exposure method Pending EP4152094A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2020085355 2020-05-14
PCT/JP2021/017960 WO2021230262A1 (ja) 2020-05-14 2021-05-12 ペリクルフレーム、ペリクル、ペリクル付露光原版、半導体の製造方法、液晶表示板の製造方法及び露光方法

Publications (1)

Publication Number Publication Date
EP4152094A1 true EP4152094A1 (en) 2023-03-22

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EP21805081.3A Pending EP4152094A1 (en) 2020-05-14 2021-05-12 Pellicle frame, pellicle, pellicle-attached exposure original plate, method for manufacturing semiconductor, method for manufacturing liquid crystal display plate, and exposure method

Country Status (7)

Country Link
US (1) US20230236497A1 (zh)
EP (1) EP4152094A1 (zh)
JP (1) JPWO2021230262A1 (zh)
KR (1) KR20230011957A (zh)
CN (2) CN115485618A (zh)
TW (2) TWM621314U (zh)
WO (1) WO2021230262A1 (zh)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000305254A (ja) * 1999-04-22 2000-11-02 Shin Etsu Chem Co Ltd フィルター付きペリクル
JP2007333910A (ja) * 2006-06-14 2007-12-27 Shin Etsu Chem Co Ltd ペリクル
JP6246907B2 (ja) * 2013-05-22 2017-12-13 カール・ツァイス・エスエムティー・ゲーエムベーハー 光学素子及び当該光学素子に対する放射の影響を低減する手段を備えた光学コンポーネント
JP6275270B2 (ja) 2014-09-19 2018-02-07 三井化学株式会社 ペリクル、その製造方法及び露光方法
JP6395320B2 (ja) * 2015-03-30 2018-09-26 信越化学工業株式会社 ペリクル
WO2018116517A1 (ja) * 2016-12-19 2018-06-28 日東電工株式会社 ポリテトラフルオロエチレン多孔質膜とこれを用いた防水通気膜及び防水通気部材

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CN215986893U (zh) 2022-03-08
CN115485618A (zh) 2022-12-16
JPWO2021230262A1 (zh) 2021-11-18
WO2021230262A1 (ja) 2021-11-18
TW202142952A (zh) 2021-11-16
TWM621314U (zh) 2021-12-21
US20230236497A1 (en) 2023-07-27
KR20230011957A (ko) 2023-01-25

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