EP3861579A4 - Matériaux d'électrode comprenant un oxyde lamellaire de sodium et de métal, électrodes les comprenant et leur utilisation en électrochimie - Google Patents

Matériaux d'électrode comprenant un oxyde lamellaire de sodium et de métal, électrodes les comprenant et leur utilisation en électrochimie Download PDF

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Publication number
EP3861579A4
EP3861579A4 EP19868747.7A EP19868747A EP3861579A4 EP 3861579 A4 EP3861579 A4 EP 3861579A4 EP 19868747 A EP19868747 A EP 19868747A EP 3861579 A4 EP3861579 A4 EP 3861579A4
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EP
European Patent Office
Prior art keywords
flameform
electrochemistry
electrodes
sodium
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP19868747.7A
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German (de)
English (en)
French (fr)
Other versions
EP3861579A1 (fr
Inventor
Yuesheng Wang
Abdelbast Guerfi
Karim Zaghib
Gilles Lajoie
Marie-Josée VIGEANT
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Hydro Quebec
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Hydro Quebec
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Publication date
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Publication of EP3861579A1 publication Critical patent/EP3861579A1/fr
Publication of EP3861579A4 publication Critical patent/EP3861579A4/fr
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00Compounds of manganese
    • C01G45/12Complex oxides containing manganese and at least one other metal element
    • C01G45/1221Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1228Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (MnO2)-, e.g. LiMnO2 or Li(MxMn1-x)O2
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00Compounds of cobalt
    • C01G51/40Complex oxides containing cobalt and at least one other metal element
    • C01G51/42Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C01G51/44Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese
    • C01G51/50Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese of the type (MnO2)n-, e.g. Li(CoxMn1-x)O2 or Li(MyCoxMn1-x-y)O2
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/054Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • H01M4/366Composites as layered products
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621Binders
    • H01M4/622Binders being polymers
    • H01M4/623Binders being polymers fluorinated polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624Electric conductive fillers
    • H01M4/625Carbon or graphite
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00Compounds of cobalt
    • C01G51/40Complex oxides containing cobalt and at least one other metal element
    • C01G51/42Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/70Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/40Electric properties
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
EP19868747.7A 2018-10-02 2019-10-02 Matériaux d'électrode comprenant un oxyde lamellaire de sodium et de métal, électrodes les comprenant et leur utilisation en électrochimie Pending EP3861579A4 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201862740185P 2018-10-02 2018-10-02
PCT/CA2019/051412 WO2020069618A1 (fr) 2018-10-02 2019-10-02 Matériaux d'électrode comprenant un oxyde lamellaire de sodium et de métal, électrodes les comprenant et leur utilisation en électrochimie

Publications (2)

Publication Number Publication Date
EP3861579A1 EP3861579A1 (fr) 2021-08-11
EP3861579A4 true EP3861579A4 (fr) 2022-07-06

Family

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Family Applications (1)

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EP19868747.7A Pending EP3861579A4 (fr) 2018-10-02 2019-10-02 Matériaux d'électrode comprenant un oxyde lamellaire de sodium et de métal, électrodes les comprenant et leur utilisation en électrochimie

Country Status (6)

Country Link
US (1) US12272820B2 (https=)
EP (1) EP3861579A4 (https=)
JP (2) JP7710982B2 (https=)
KR (1) KR102851179B1 (https=)
CN (1) CN112913052A (https=)
WO (1) WO2020069618A1 (https=)

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WO2022169737A1 (en) * 2021-02-02 2022-08-11 The University Of Chicago Mixed sodium and lithium period four transition metal oxides for electrochemical lithium extraction
CN116364921A (zh) * 2021-12-29 2023-06-30 中国科学院苏州纳米技术与纳米仿生研究所 一种钠离子电池正极材料及其制备方法与应用
US12555767B2 (en) 2022-03-02 2026-02-17 The University Of Chicago Methods for the controlled synthesis of layered lithium and sodium transition metal oxides using electrochemically assisted ion-exchange
CN114715953A (zh) * 2022-03-14 2022-07-08 中国科学技术大学 一种前驱体辅助制备Cu,Zn掺杂的层状氧化物钠离子电池正极材料的方法及其应用
CN114725346B (zh) * 2022-03-31 2023-04-07 钠远新材科技(无锡)有限公司 钠离子电池正极材料及其制备方法和钠离子电池
CN117049606B (zh) * 2022-05-06 2025-11-04 浙江钠创新能源有限公司 一种改性正极材料及其制备方法、应用和钠离子电池
CN114927681B (zh) * 2022-05-16 2024-03-12 华侨大学 一种p2型五元高熵钠层状正极材料及其制备方法和应用
CN121439775A (zh) * 2022-06-24 2026-01-30 宁德时代新能源科技股份有限公司 电极活性材料、二次电池及用电装置
CN121460566A (zh) * 2022-06-24 2026-02-03 宁德时代新能源科技股份有限公司 电极活性材料、二次电池及用电装置
US20240158257A1 (en) * 2022-11-11 2024-05-16 Honda Motor Co., Ltd. Manganese oxides and cathode active materials
CN118588883B (zh) * 2023-03-02 2025-09-30 中国科学院物理研究所 提高钠离子层状氧化物空气稳定性的方法、材料及应用
CN116789183A (zh) * 2023-07-28 2023-09-22 广东工业大学 一种Ca掺杂钠离子电池层状氧化物正极材料的制备方法
WO2025135882A1 (ko) * 2023-12-20 2025-06-26 주식회사 엘지에너지솔루션 소듐 이차 전지용 양극 및 이를 포함하는 소듐 이차 전지
CN118841550A (zh) * 2024-07-19 2024-10-25 广东工业大学 一种多巴胺碳包覆的p2型钠离子电池层状氧化物正极材料及其制备方法和应用
CN119038635B (zh) * 2024-11-01 2025-04-08 宁波维科电池有限公司 一种非晶金属氧化物正极材料的制备方法及其应用

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JP2014160653A (ja) * 2013-01-23 2014-09-04 Tokyo Univ Of Science 複合金属酸化物、ナトリウム二次電池用正極活物質、ナトリウム二次電池用正極、及びナトリウム二次電池
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WO2016033422A1 (en) * 2014-08-29 2016-03-03 Massachusetts Institute Of Technology Sodium transition metal oxide electroactive compounds
EP3048659A1 (en) * 2014-10-16 2016-07-27 Institute of Physics, The Chinese Academy of Sciences Layered oxide material and preparation method therefor, pole piece, secondary cell and application thereof

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JP2014160653A (ja) * 2013-01-23 2014-09-04 Tokyo Univ Of Science 複合金属酸化物、ナトリウム二次電池用正極活物質、ナトリウム二次電池用正極、及びナトリウム二次電池
CN105185978A (zh) * 2014-06-20 2015-12-23 中国科学院物理研究所 用作负极活性物质的含锰氧化合物及其制备方法和用途
WO2016033422A1 (en) * 2014-08-29 2016-03-03 Massachusetts Institute Of Technology Sodium transition metal oxide electroactive compounds
EP3048659A1 (en) * 2014-10-16 2016-07-27 Institute of Physics, The Chinese Academy of Sciences Layered oxide material and preparation method therefor, pole piece, secondary cell and application thereof

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See also references of WO2020069618A1 *

Also Published As

Publication number Publication date
KR20210062701A (ko) 2021-05-31
CN112913052A (zh) 2021-06-04
KR102851179B1 (ko) 2025-08-28
JP7710982B2 (ja) 2025-07-22
US12272820B2 (en) 2025-04-08
WO2020069618A1 (fr) 2020-04-09
EP3861579A1 (fr) 2021-08-11
US20220052330A1 (en) 2022-02-17
JP2022503995A (ja) 2022-01-12
CA3112163A1 (fr) 2020-04-09
JP2025036725A (ja) 2025-03-14

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Ipc: C01G 53/00 20060101ALI20220527BHEP

Ipc: C01G 51/00 20060101ALI20220527BHEP

Ipc: C01G 45/12 20060101ALI20220527BHEP

Ipc: H01M 4/134 20100101ALI20220527BHEP

Ipc: H01M 10/056 20100101ALI20220527BHEP

Ipc: H01M 10/054 20100101ALI20220527BHEP

Ipc: H01M 10/0525 20100101ALI20220527BHEP

Ipc: H01M 4/131 20100101AFI20220527BHEP