EP3861579A4 - Matériaux d'électrode comprenant un oxyde lamellaire de sodium et de métal, électrodes les comprenant et leur utilisation en électrochimie - Google Patents

Matériaux d'électrode comprenant un oxyde lamellaire de sodium et de métal, électrodes les comprenant et leur utilisation en électrochimie Download PDF

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Publication number
EP3861579A4
EP3861579A4 EP19868747.7A EP19868747A EP3861579A4 EP 3861579 A4 EP3861579 A4 EP 3861579A4 EP 19868747 A EP19868747 A EP 19868747A EP 3861579 A4 EP3861579 A4 EP 3861579A4
Authority
EP
European Patent Office
Prior art keywords
electrochemistry
electrodes
electrode materials
sodium metal
metal lamellar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP19868747.7A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP3861579A1 (fr
Inventor
Yuesheng Wang
Abdelbast Guerfi
Karim Zaghib
Gilles Lajoie
Marie-Josée VIGEANT
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hydro-Québec
Original Assignee
Hydro-Québec
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Filing date
Publication date
Application filed by Hydro-Québec filed Critical Hydro-Québec
Publication of EP3861579A1 publication Critical patent/EP3861579A1/fr
Publication of EP3861579A4 publication Critical patent/EP3861579A4/fr
Pending legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1228—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (MnO2)-, e.g. LiMnO2 or Li(MxMn1-x)O2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Complex oxides containing cobalt and at least one other metal element
    • C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C01G51/44—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese
    • C01G51/50—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese of the type (MnO2)n-, e.g. Li(CoxMn1-x)O2 or Li(MyCoxMn1-x-y)O2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • C01G53/51—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing sodium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H01M4/623—Binders being polymers fluorinated polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Complex oxides containing cobalt and at least one other metal element
    • C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
EP19868747.7A 2018-10-02 2019-10-02 Matériaux d'électrode comprenant un oxyde lamellaire de sodium et de métal, électrodes les comprenant et leur utilisation en électrochimie Pending EP3861579A4 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201862740185P 2018-10-02 2018-10-02
PCT/CA2019/051412 WO2020069618A1 (fr) 2018-10-02 2019-10-02 Matériaux d'électrode comprenant un oxyde lamellaire de sodium et de métal, électrodes les comprenant et leur utilisation en électrochimie

Publications (2)

Publication Number Publication Date
EP3861579A1 EP3861579A1 (fr) 2021-08-11
EP3861579A4 true EP3861579A4 (fr) 2022-07-06

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP19868747.7A Pending EP3861579A4 (fr) 2018-10-02 2019-10-02 Matériaux d'électrode comprenant un oxyde lamellaire de sodium et de métal, électrodes les comprenant et leur utilisation en électrochimie

Country Status (6)

Country Link
US (1) US12272820B2 (enExample)
EP (1) EP3861579A4 (enExample)
JP (2) JP7710982B2 (enExample)
KR (1) KR102851179B1 (enExample)
CN (1) CN112913052A (enExample)
WO (1) WO2020069618A1 (enExample)

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WO2022169737A1 (en) * 2021-02-02 2022-08-11 The University Of Chicago Mixed sodium and lithium period four transition metal oxides for electrochemical lithium extraction
CN116364921B (zh) * 2021-12-29 2026-05-08 中国科学院苏州纳米技术与纳米仿生研究所 一种钠离子电池正极材料及其制备方法与应用
US12555767B2 (en) 2022-03-02 2026-02-17 The University Of Chicago Methods for the controlled synthesis of layered lithium and sodium transition metal oxides using electrochemically assisted ion-exchange
CN114715953A (zh) * 2022-03-14 2022-07-08 中国科学技术大学 一种前驱体辅助制备Cu,Zn掺杂的层状氧化物钠离子电池正极材料的方法及其应用
CN114725346B (zh) * 2022-03-31 2023-04-07 钠远新材科技(无锡)有限公司 钠离子电池正极材料及其制备方法和钠离子电池
CN117049606B (zh) * 2022-05-06 2025-11-04 浙江钠创新能源有限公司 一种改性正极材料及其制备方法、应用和钠离子电池
CN114927681B (zh) * 2022-05-16 2024-03-12 华侨大学 一种p2型五元高熵钠层状正极材料及其制备方法和应用
CN121439775A (zh) * 2022-06-24 2026-01-30 宁德时代新能源科技股份有限公司 电极活性材料、二次电池及用电装置
EP4322260A4 (en) * 2022-06-24 2024-07-31 Contemporary Amperex Technology Co., Limited Electrode active material, secondary battery, and electrical device
US20240158257A1 (en) * 2022-11-11 2024-05-16 Honda Motor Co., Ltd. Manganese oxides and cathode active materials
CN118588883B (zh) * 2023-03-02 2025-09-30 中国科学院物理研究所 提高钠离子层状氧化物空气稳定性的方法、材料及应用
CN116789183B (zh) * 2023-07-28 2026-06-19 广东工业大学 一种Ca掺杂钠离子电池层状氧化物正极材料的制备方法
CN122249887A (zh) * 2023-12-20 2026-06-19 株式会社Lg新能源 钠二次电池用正极和包含其的钠二次电池
CN118841550A (zh) * 2024-07-19 2024-10-25 广东工业大学 一种多巴胺碳包覆的p2型钠离子电池层状氧化物正极材料及其制备方法和应用
CN119038635B (zh) * 2024-11-01 2025-04-08 宁波维科电池有限公司 一种非晶金属氧化物正极材料的制备方法及其应用

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WO2016033422A1 (en) * 2014-08-29 2016-03-03 Massachusetts Institute Of Technology Sodium transition metal oxide electroactive compounds
EP3048659A1 (en) * 2014-10-16 2016-07-27 Institute of Physics, The Chinese Academy of Sciences Layered oxide material and preparation method therefor, pole piece, secondary cell and application thereof

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JP2014160653A (ja) * 2013-01-23 2014-09-04 Tokyo Univ Of Science 複合金属酸化物、ナトリウム二次電池用正極活物質、ナトリウム二次電池用正極、及びナトリウム二次電池
CN105185978A (zh) * 2014-06-20 2015-12-23 中国科学院物理研究所 用作负极活性物质的含锰氧化合物及其制备方法和用途
WO2016033422A1 (en) * 2014-08-29 2016-03-03 Massachusetts Institute Of Technology Sodium transition metal oxide electroactive compounds
EP3048659A1 (en) * 2014-10-16 2016-07-27 Institute of Physics, The Chinese Academy of Sciences Layered oxide material and preparation method therefor, pole piece, secondary cell and application thereof

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Also Published As

Publication number Publication date
JP2025036725A (ja) 2025-03-14
JP2022503995A (ja) 2022-01-12
US20220052330A1 (en) 2022-02-17
CN112913052A (zh) 2021-06-04
US12272820B2 (en) 2025-04-08
WO2020069618A1 (fr) 2020-04-09
EP3861579A1 (fr) 2021-08-11
KR102851179B1 (ko) 2025-08-28
JP7710982B2 (ja) 2025-07-22
KR20210062701A (ko) 2021-05-31
CA3112163A1 (fr) 2020-04-09

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