EP3849502A1 - Schäumende reinigungszubereitung auf basis einer emulsion - Google Patents
Schäumende reinigungszubereitung auf basis einer emulsionInfo
- Publication number
- EP3849502A1 EP3849502A1 EP19756347.1A EP19756347A EP3849502A1 EP 3849502 A1 EP3849502 A1 EP 3849502A1 EP 19756347 A EP19756347 A EP 19756347A EP 3849502 A1 EP3849502 A1 EP 3849502A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- preparation according
- emulsifier
- preparation
- cleaning preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 133
- 238000004140 cleaning Methods 0.000 title claims abstract description 57
- 239000000839 emulsion Substances 0.000 title claims abstract description 17
- 238000005187 foaming Methods 0.000 title claims abstract description 8
- 239000002537 cosmetic Substances 0.000 claims abstract description 14
- 239000003995 emulsifying agent Substances 0.000 claims description 67
- 239000000203 mixture Substances 0.000 claims description 27
- 239000003795 chemical substances by application Substances 0.000 claims description 25
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 25
- 239000000194 fatty acid Substances 0.000 claims description 25
- 229930195729 fatty acid Natural products 0.000 claims description 25
- 239000011734 sodium Substances 0.000 claims description 25
- -1 alkyl sulfate ethers Chemical class 0.000 claims description 24
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 23
- 229910052708 sodium Inorganic materials 0.000 claims description 23
- 150000002148 esters Chemical class 0.000 claims description 18
- 229920000642 polymer Polymers 0.000 claims description 18
- 125000002091 cationic group Chemical group 0.000 claims description 17
- 230000003750 conditioning effect Effects 0.000 claims description 17
- 239000003945 anionic surfactant Substances 0.000 claims description 15
- 229920006395 saturated elastomer Polymers 0.000 claims description 15
- 239000002280 amphoteric surfactant Substances 0.000 claims description 14
- 150000002191 fatty alcohols Chemical class 0.000 claims description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 239000004094 surface-active agent Substances 0.000 claims description 12
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 11
- 229920006317 cationic polymer Polymers 0.000 claims description 11
- 150000004665 fatty acids Chemical class 0.000 claims description 11
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 150000001447 alkali salts Chemical class 0.000 claims description 9
- 229940075529 glyceryl stearate Drugs 0.000 claims description 9
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 9
- 244000007835 Cyamopsis tetragonoloba Species 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000003605 opacifier Substances 0.000 claims description 7
- 229940114930 potassium stearate Drugs 0.000 claims description 7
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 claims description 7
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 6
- 229920005862 polyol Polymers 0.000 claims description 6
- 150000003077 polyols Chemical class 0.000 claims description 6
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 229940081733 cetearyl alcohol Drugs 0.000 claims description 3
- 229960000541 cetyl alcohol Drugs 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 229940012831 stearyl alcohol Drugs 0.000 claims description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 2
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 2
- 229940049294 glyceryl stearate se Drugs 0.000 claims description 2
- 239000000126 substance Substances 0.000 description 13
- 239000006260 foam Substances 0.000 description 11
- 239000000178 monomer Substances 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 10
- 239000002562 thickening agent Substances 0.000 description 10
- 239000002245 particle Substances 0.000 description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 8
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- 239000002453 shampoo Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 5
- 239000005711 Benzoic acid Substances 0.000 description 4
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 235000010233 benzoic acid Nutrition 0.000 description 4
- 229940073609 bismuth oxychloride Drugs 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003974 emollient agent Substances 0.000 description 4
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 4
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 4
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- 229960004889 salicylic acid Drugs 0.000 description 4
- 235000010199 sorbic acid Nutrition 0.000 description 4
- 239000004334 sorbic acid Substances 0.000 description 4
- 229940075582 sorbic acid Drugs 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 229920000426 Microplastic Polymers 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000010696 ester oil Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000010445 mica Substances 0.000 description 3
- 229910052618 mica group Inorganic materials 0.000 description 3
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical class OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 2
- RMTFNDVZYPHUEF-XZBKPIIZSA-N 3-O-methyl-D-glucose Chemical compound O=C[C@H](O)[C@@H](OC)[C@H](O)[C@H](O)CO RMTFNDVZYPHUEF-XZBKPIIZSA-N 0.000 description 2
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229960004365 benzoic acid Drugs 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000003749 cleanliness Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- UYTPUPDQBNUYGX-UHFFFAOYSA-N guanine Chemical compound O=C1NC(N)=NC2=C1N=CN2 UYTPUPDQBNUYGX-UHFFFAOYSA-N 0.000 description 2
- FDGQSTZJBFJUBT-UHFFFAOYSA-N hypoxanthine Chemical compound O=C1NC=NC2=C1NC=N2 FDGQSTZJBFJUBT-UHFFFAOYSA-N 0.000 description 2
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 2
- 229940075495 isopropyl palmitate Drugs 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
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- 238000004321 preservation Methods 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 229940057950 sodium laureth sulfate Drugs 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
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- 238000003756 stirring Methods 0.000 description 2
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- 239000004408 titanium dioxide Substances 0.000 description 2
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- FKKAGFLIPSSCHT-UHFFFAOYSA-N 1-dodecoxydodecane;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC FKKAGFLIPSSCHT-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- AOHBGMDQHXJADT-UHFFFAOYSA-N 2-(2-dodecanoyloxypropanoyloxy)propanoic acid Chemical compound CCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C(O)=O AOHBGMDQHXJADT-UHFFFAOYSA-N 0.000 description 1
- OLKHAEAHXPXJPP-UHFFFAOYSA-N 2-(2-dodecoxy-2-oxoethyl)-2-hydroxybutanedioic acid;2-sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O.CCCCCCCCCCCCOC(=O)CC(O)(C(O)=O)CC(O)=O OLKHAEAHXPXJPP-UHFFFAOYSA-N 0.000 description 1
- OUNZARDETXBPIX-UHFFFAOYSA-N 2-(2-dodecoxyethoxy)acetic acid Chemical compound CCCCCCCCCCCCOCCOCC(O)=O OUNZARDETXBPIX-UHFFFAOYSA-N 0.000 description 1
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- HJDITXMCJQRQLU-UHFFFAOYSA-N 2-[dodecanoyl(methyl)amino]acetate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCC(=O)N(C)CC(O)=O HJDITXMCJQRQLU-UHFFFAOYSA-N 0.000 description 1
- OPJWPPVYCOPDCM-UHFFFAOYSA-N 2-ethylhexyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC OPJWPPVYCOPDCM-UHFFFAOYSA-N 0.000 description 1
- MWKPHOIHTLQZIY-UHFFFAOYSA-N 2-hexyldecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CCCCCC)CCCCCCCC MWKPHOIHTLQZIY-UHFFFAOYSA-N 0.000 description 1
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- 125000004442 acylamino group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
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- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
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- OEUVSBXAMBLPES-UHFFFAOYSA-L calcium stearoyl-2-lactylate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O.CCCCCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O OEUVSBXAMBLPES-UHFFFAOYSA-L 0.000 description 1
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- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229940074979 cetyl palmitate Drugs 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 229940071163 coco-sulfate Drugs 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000003766 combability Effects 0.000 description 1
- SASYSVUEVMOWPL-NXVVXOECSA-N decyl oleate Chemical compound CCCCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC SASYSVUEVMOWPL-NXVVXOECSA-N 0.000 description 1
- 239000003398 denaturant Substances 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 150000001983 dialkylethers Chemical class 0.000 description 1
- 229940100539 dibutyl adipate Drugs 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 229940047642 disodium cocoamphodiacetate Drugs 0.000 description 1
- 229940079868 disodium laureth sulfosuccinate Drugs 0.000 description 1
- 229940079886 disodium lauryl sulfosuccinate Drugs 0.000 description 1
- ZPRZNBBBOYYGJI-UHFFFAOYSA-L disodium;2-[1-[2-(carboxylatomethoxy)ethyl]-2-undecyl-4,5-dihydroimidazol-1-ium-1-yl]acetate;hydroxide Chemical compound [OH-].[Na+].[Na+].CCCCCCCCCCCC1=NCC[N+]1(CCOCC([O-])=O)CC([O-])=O ZPRZNBBBOYYGJI-UHFFFAOYSA-L 0.000 description 1
- YGAXLGGEEQLLKV-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-2-sulfonatobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)CC(C([O-])=O)S([O-])(=O)=O YGAXLGGEEQLLKV-UHFFFAOYSA-L 0.000 description 1
- KHIQYZGEUSTKSB-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-3-sulfobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O.CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O KHIQYZGEUSTKSB-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- JZKFHQMONDVVNF-UHFFFAOYSA-N dodecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(O)(=O)=O JZKFHQMONDVVNF-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 1
- GJQLBGWSDGMZKM-UHFFFAOYSA-N ethylhexyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(CC)CCCCC GJQLBGWSDGMZKM-UHFFFAOYSA-N 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- PXDJXZJSCPSGGI-UHFFFAOYSA-N hexadecanoic acid hexadecyl ester Natural products CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC PXDJXZJSCPSGGI-UHFFFAOYSA-N 0.000 description 1
- 229940100463 hexyl laurate Drugs 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 1
- 229940074928 isopropyl myristate Drugs 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940116335 lauramide Drugs 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 229940091250 magnesium supplement Drugs 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 235000021239 milk protein Nutrition 0.000 description 1
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- 229940078812 myristyl myristate Drugs 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 229940046947 oleth-10 phosphate Drugs 0.000 description 1
- NPKKRSHVJIQBKU-UHFFFAOYSA-N ornogenin Natural products CC(OC(=O)C=Cc1ccccc1)C2(O)CCC3(O)C4(O)CC=C5CC(O)CCC5(C)C4CC(OC(=O)C=Cc6ccccc6)C23C NPKKRSHVJIQBKU-UHFFFAOYSA-N 0.000 description 1
- 229940086615 peg-6 cocamide Drugs 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005464 sample preparation method Methods 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 229940080230 sodium c12-14 olefin sulfonate Drugs 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940079781 sodium cocoyl glutamate Drugs 0.000 description 1
- 229940079776 sodium cocoyl isethionate Drugs 0.000 description 1
- 229940102544 sodium laureth-13 carboxylate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 1
- 229940075560 sodium lauryl sulfoacetate Drugs 0.000 description 1
- 229940048109 sodium methyl cocoyl taurate Drugs 0.000 description 1
- 229960004025 sodium salicylate Drugs 0.000 description 1
- BCISDMIQYBCHAT-UHFFFAOYSA-M sodium;2-(dodecanoylamino)ethanesulfonate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCCS([O-])(=O)=O BCISDMIQYBCHAT-UHFFFAOYSA-M 0.000 description 1
- ZUFONQSOSYEWCN-UHFFFAOYSA-M sodium;2-(methylamino)acetate Chemical compound [Na+].CNCC([O-])=O ZUFONQSOSYEWCN-UHFFFAOYSA-M 0.000 description 1
- UAJTZZNRJCKXJN-UHFFFAOYSA-M sodium;2-dodecoxy-2-oxoethanesulfonate Chemical compound [Na+].CCCCCCCCCCCCOC(=O)CS([O-])(=O)=O UAJTZZNRJCKXJN-UHFFFAOYSA-M 0.000 description 1
- UPDATVKGFTVGQJ-UHFFFAOYSA-N sodium;azane Chemical compound N.[Na+] UPDATVKGFTVGQJ-UHFFFAOYSA-N 0.000 description 1
- JJMIAJGBZGZNHA-UHFFFAOYSA-N sodium;styrene Chemical compound [Na].C=CC1=CC=CC=C1 JJMIAJGBZGZNHA-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 150000003512 tertiary amines Chemical group 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 230000036642 wellbeing Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
Definitions
- the present invention relates to a foaming, cosmetic cleaning preparation with an opaque appearance, which is achieved in that the preparation is in the form of an emulsion.
- Cleaning products are designed to clean the skin and hair. After the cleaning process, the user ideally has a feeling of cleanliness, freshness and well-being. Humans have always had the need to cleanse themselves, i.e. Remove dirt from the skin or hair. Over time, the cleaning processes have changed, as have the products that are used for cleaning.
- the skin is cleaned, for example, by washing, shower baths or bath tubs, while the hair is often also cleaned during the shower bath or bath tub or also washed separately.
- Body cleansing products primarily serve to remove dirt from the skin surface.
- the dirt film consists of solid or liquid components that have reached the skin from the outside. Excess skin lipids and dead body cells also belong to the dirt film. The components of the dirt film get into the wash liquor through surface-active ingredients in the cleaning compositions and are removed from the skin by the rinsing process.
- the products should be easy to distribute in the hair, the foam should form quickly, the hair should be cleaned and cared for gently and gently. In addition, it should be easy to wash out and wet hair should have a pleasant feel and be easy to comb. Dry hair should also be easy to comb, the appearance of the hair should be natural and it should shine. The products are said to make the hair supple and not to weigh it down. In addition, rapid relubrication should be prevented. So there is a long catalog of requirements in the area of hair cleaning, which at least to a large extent has to be fulfilled in order to be able to sell a product that is accepted by the consumer.
- a cleaning preparation also plays an important role in the acceptance of a product by the consumer. Cleaning preparations in a white color are very attractive for the customer. The white color associates purity and cleanliness. If a white cleaning preparation also has a creamy consistency, the customer also associates good care with this product.
- Opaque or "white” cleaning compositions are known per se. To give cleaning compositions this appearance, opacifiers or pearlescent agents are generally used. Pearlescent agents can be heavy metal salts of higher fatty acids, fatty acid esters or fatty acid diesters of polyols or fatty acid alkanolamide derivatives. These substances exist as crystal platelets or rods and reflect the light. Opacifiers have no pearlescent effect per se.
- a known and frequently used group of opacifiers are sodium salts of a polymer of styrene monomers with monomers of acrylic acid, methacrylic acid and / or another olefin and / or one of their esters, e.g. Polymers with the INCI name Styrene / Acrylates Copolymer. Styrenes / acrylates copolymer is present in the cosmetic preparations in the form of particles with particle sizes of approximately 170 nm.
- This particle size is in the range of the particle size defined by some environmental organizations for the particle size of microplastics.
- Microplastics can be understood to mean plastic particles that are 5 mm and smaller. These particles can be detected in rivers and seas and are considered harmful to the environment.
- foam especially a creamy, soft foam
- foam is very important for cleaning preparations for cleaning the hair and the body.
- the consumer With a sufficient amount of foam, the consumer generally combines good cleaning performance.
- a good care performance is often associated with a creamy, soft foam.
- the solution to this problem can be to add foam-forming surfactants to the preparations mentioned.
- Conditioning shampoos are disclosed in document WO 2007/104740 A1. These shampoos can be in the form of an emulsion which contains an oil phase and a water phase, the emulsion
- One or more surfactants are provided.
- At least one surfactant preferably at least one anionic surfactant selected from alkyl ether sulfates and optionally at least one amphoteric surfactant and
- At least one conditioning agent in particular at least one cationic polymer and / or ampholytic polymer,
- the preparation according to the invention is a cosmetic preparation.
- the preparation according to the invention is an aqueous preparation
- the water content is advantageously 50 to 80% by weight, preferably 60 to 70% by weight, based on the total weight of the preparation.
- the preparation according to the invention is used to clean the hair and skin.
- the product forms include body cleansing products such as shower baths, bubble baths, liquid soaps, foaming facial cleansers, and others.
- Body cleansing products such as shower baths, bubble baths, liquid soaps, foaming facial cleansers, and others.
- Product forms for hair cleaning for example hair shampoos, conditioning shampoos and others, are also included.
- the present invention also relates to the use of a cosmetic cleaning preparation comprising
- the at least one O / W emulsifier being in the form of an emulsifier mixture, comprising at least one glyceryl partial ester with fatty acids saturated with C14-C22 and at least one alkali salt of a C14-C22 fatty acid, in particular comprising an emulsifier mixture Glyceryl stearate and sodium and / or potassium stearate,
- At least one fatty alcohol at least one surfactant, preferably at least one anionic surfactant, selected from alkyl ether sulfates and optionally at least one amphoteric surfactant and
- At least one conditioning agent in particular at least one cationic polymer, for the nourishing cleaning of the skin and hair.
- the present invention also relates to a process for producing a foaming, opaque cleaning preparation, no opacifiers and no pearlescent agents being added to the preparation, and the preparation being in the form of an emulsion.
- the present invention likewise relates to a method for producing an opaque, stable cleaning preparation in that the preparation comprises at least one O / W emulsifier consisting of a mixture of at least one glyceryl partial ester with fatty acids saturated with C14-C22 and at least one alkali metal salt C14-C22 fatty acid, in particular an emulsifier mixture comprising glyceryl stearate and sodium and / or potassium stearate, is added.
- O / W emulsifier consisting of a mixture of at least one glyceryl partial ester with fatty acids saturated with C14-C22 and at least one alkali metal salt C14-C22 fatty acid, in particular an emulsifier mixture comprising glyceryl stearate and sodium and / or potassium stearate, is added.
- Emulsifiers ensure that two immiscible liquids (e.g. oil in water) can form a stable emulsion.
- Emulsifiers have an amphiphilic character, some of the molecule is lipophilic, the other hydrophilic.
- the lipophilic part of the emulsifier is soluble in oil and protrudes into the oil.
- An oil droplet is formed by stirring and is dispersed in the aqueous environment by the hydrophilic part of the emulsifier.
- emulsifiers have no wash-active, surfactant character.
- Emulsifiers reduce the interfacial tension between the two phases and, in addition to reducing the interfacial work, they also stabilize the emulsion formed. They stabilize the emulsion formed by interfacial films and by the formation of steric or electrical barriers, which prevents the coalescence of the emulsified particles.
- emulsifiers In order for compounds to be effective as emulsifiers, they must have a certain molecular structure.
- the structural characteristic of such compounds is their amphiphilic molecular structure.
- the molecule of such a compound has at least one group with affinity for substances of strong polarity (polar group) and at least one group with affinity for non-polar substances (apolar group).
- polar group substances of strong polarity
- apolar group a distinction is made between nonionic, anionic and cationic emulsifiers.
- emulsifiers with an HLB value of up to approx. 8 are considered W / O emulsifiers.
- O / W emulsifiers have HLB values of greater than 8 to 15.
- Substances with HLB values greater than 15 are often referred to as solubilizers.
- the preparation according to the invention contains O / W emulsifiers in the form of an emulsifier mixture comprising at least one glyceryl partial ester with C14-C22 saturated fatty acids and at least one alkali salt of a C14-C22 fatty acid, in particular an emulsifier mixture comprising glyceryl stearate and sodium and / or potassium Stearate.
- the emulsifier mixture contains at least 30% monoglyceride esters, advantageously between 32 and 50%.
- the content of the alkali salt in the emulsifier mixture is advantageously between 2 and 10% by weight, particularly advantageously between 4 and 6% by weight, based on the emulsifier mixture.
- Such mixtures are available, for example, with the INCI name Glyceryl Steakate SE and can be obtained as Tegin® from Evonik, as Cutina® GMS SE from BASF and as Imwitor® 960K from Sasol.
- An HLB value of 12 is given for the emulsifier Gly ceryl Stearate SE.
- the content of O / W emulsifiers in the form of an emulsifier mixture and comprising at least one glyceryl partial ester saturated with C14-C22 fatty acids and at least one alkali salt of a C14-C22 fatty acid is preferably at least 1.5% by weight from 2 to 8% by weight, particularly preferably from 3 to 7% by weight, based on the total weight of the preparation. This information relates to the raw material content.
- the preparation according to the invention can additionally contain at least one W / O emulsifier.
- This additional W / O emulsifier is preferably selected from partial esters of polyols with 3 to 6 carbon atoms with saturated C8-C22 carboxylic acids, particularly preferably from glycerol partial esters with saturated C14-C20 fatty acids, particularly preferred is glyceryl stearate, that for example, under the trade name Tegin M from Evonik who can.
- This emulsifier has an HLB value of about 4 and can therefore be classified as a W / O emulsifier.
- the preparation according to the invention contains at least one additional W / O emulsifier, this is at least one additional W / O emulsifier in the preparation according to the invention with a total content of 2 to 6% by weight, preferably 3 to 5% by weight. based on the active content and the total weight of the preparation included.
- emulsifiers in particular O / W emulsifiers, which are distinguished by the fact that they contain ethylene oxide residues and / or propylene oxide residues. Ethoxylated and / or propoxylated fatty acids and / or fatty alcohols are often used.
- the preparation according to the invention contains no polyethoxylated and / or polypropoxylated emulsifiers, in particular no polyethoxylated and / or polypropoxylated O / W emulsifiers.
- the preparation according to the invention is therefore free from ethoxylated and / or propoxylated emulsifiers;
- the preparation according to the invention is therefore in particular free of ethoxylated and / or propoxylated O / W emulsifiers.
- Free from in the sense of the present invention means that 0 to 0.1% by weight, preferably 0 to 0.01% by weight, particularly preferably 0% by weight, based on the total weight of the preparation, of the particular Substance present in the preparation.
- the preparation according to the invention contains at least one fatty alcohol.
- Fatty alcohols are e.g. straight or branched chain aliphatic monohydric alcohols with 6 - 22 carbon atoms.
- Straight-chain fatty alcohols with a chain length of 12 - 18 carbon atoms are preferably used in cosmetics. These fatty alcohols are soft, colorless masses, practically non-toxic and well tolerated by the skin.
- Cetyl alcohol, stearyl alcohol and cetearyl alcohol are of particular importance in cosmetics.
- the preparation according to the invention advantageously contains at least one fatty alcohol which is selected from the group consisting of cetyl alcohol, stearyl alcohol and cetearyl alcohol.
- the at least one fatty alcohol is advantageously present in the preparation according to the invention with a content of 1.0 to 10.0% by weight, preferably 3.0 to 7.0% by weight, based on the total weight of the preparation.
- the preparation according to the invention contains at least one surfactant.
- Surfactants can be divided into anionic, cationic, amphoteric and nonionic surfactants.
- the surfactants which are used in the preparation according to the invention are partially anionic surfactants, optionally in combination with amphoteric surfactants.
- Anionic surfactants generally have carboxylate, sulfate or sulfonate groups as functional groups. In aqueous solution they form negatively charged organic ions in an alkaline or neutral environment.
- Suitable anionic surfactants are
- acylglutamates for example sodium acylglutamate, sodium cocoylglutamate, di-TEA-palmitoylaspartate and sodium caprylic / capric glutamate,
- acyl peptides for example palmitoyl-hydrolyzed milk protein, sodium cocoyl-hydrolyzed soy protein and sodium / potassium-cocoyl-hydrolyzed collagen,
- sarcosinates for example myristoyl sarcosin, TEA-lauroyl sarcosinate, sodium lauroyl sarcosinate and sodium cocoyl sarcosinate,
- Carboxylic acids and derivatives such as
- ester carboxylic acids for example acyl lactylates, such as lauroyl lactylate, caproyl lactylate, calcium stearoyl lactylate, laureth-6-citrate and sodium PEG-4-lauramide carboxylate,
- ether carboxylic acids for example sodium laureth-13 carboxylate and sodium
- Phosphoric acid esters and salts such as DEA-oleth-10-phosphate and dilaureth-phosphate,
- acyl isethionates e.g. Sodium / ammonium cocoyl isethionate, sodium lauryl methyl isethionate,
- taurates for example sodium lauroyl taurate and sodium methyl cocoyl taurate
- alkyl sulfonates for example sodium coconut monoglyceride sulfate, sodium C12-14 olefin sulfonate, sodium lauryl sulfoacetate and magnesium PEG-3 cocamide sulfate, 5.
- Sulfosuccinates for example dioctyl sodium sulfosuccinate, disodium laureth sulfosuccinate, disodium lauryl sulfosuccinate, disodium undecylenamido MEA sulfosuccinate and PEG-5 lauryl citrate sulfosuccinate. such as
- Sulfuric acid esters such as
- Alkyl sulfates for example sodium, ammonium and TEA lauryl sulfate, sodium ammonium and TEA coco sulfate.
- the preparation according to the invention contains at least one alkyl ether sulfate, it is particularly preferred if the alkyl groups of the at least one alkyl ether sulfate according to the invention have 8 to 18, particularly preferably 10 to 14, carbon atoms. It is also particularly preferred if Na + is selected from the group of suitable cations of the alkyl ether sulfates.
- the incorporation of sodium laureth sulfate into the preparation according to the invention is very particularly particularly preferred, and it is also very particularly preferred if the content of sodium laureth sulfate is greater than 2% by weight, based on the total weight of the preparation.
- the total content of the at least one anionic surfactant in the preparation according to the invention is 2.0 to 20.0% by weight, preferably 5 to 18% by weight, particularly preferably 7 to 16% by weight, based on the total weight of the preparation and the respective active content.
- the total amount of the anionic surfactant (s) contains the content of at least one alkyl ether sulfate.
- the preparation according to the invention contains photic surfactants.
- Suitable amphoteric surfactants are
- Acyl- / dialkylethylenediamine for example sodium acylamphoacetate, disodium macylamphodipropionate, disodium alkylamphodiacetate, disodium cocoamphodiacetate, disodium cocoamphomonoacetate, sodium acylamphohydroxypropylsulfonate, disodium triamylamphamiacodiacetate and sodium acacid
- N-alkylamino acids for example aminopropylalkylglutamide, alkylaminopropionic acid, sodium alkylimidodipropionate and lauroamphocarboxyglycinate.
- betaines for example coco betaines, cocoamidopropyl betaines,
- Sultaine for example Lauryl Hydroxy Sultaine.
- the at least one amphoteric surfactant is preferably selected from the group alkylamido propyl betaines and alkyl betaines. It is particularly preferred if the amphoteric surfactant is cocamidopropyl betaine.
- the total content of the at least one amphoteric surfactant is 0.5 to 10.0% by weight, preferably 1.0 to 7.0% by weight, particularly preferably 2.0 to 5 , 0 wt .-%, based on the total weight of the preparation and the respective active content.
- the preparation according to the invention contains at least one conditioning agent.
- Conditioning agents belong to different chemical classes of compounds. However, the conditioners have in common that they interact with the surface of the skin and / or hair. With regard to hair, conditioners are often described with the term that the conditioners apply to the hair. After the respective preparation has been rinsed out, the conditioning agents should at least partially remain on the hair and thus improve the combability, the feel and the shine of the hair.
- the conditioning agents can be roughly divided into water-soluble and water-insoluble conditioning agents.
- Cationic surfactants and polymers can be added to the water-soluble conditioning agents.
- Oils, fats, waxes and silicones can be added to the water-insoluble conditioning agents.
- Cationic polymers are polymeric compounds which have cationic groups in the main and / or side chain. These groups can be temporarily cationic. These are, for example, primary, secondary or tertiary amine groups which are present as positively charged groups at suitable pH values.
- Permanent cationic groups are always positively charged regardless of the pH. It is usually a quaternary nitrogen atom, for example in the form of an ammonium group.
- Cationic polymers can be natural polymers which have been modified such that, for example, permanent cationic groups, in particular quaternary ammonium groups, have been introduced into the molecule. Quaternary ammonium groups are preferred cationic groups according to the invention. These groups can be introduced into cellulose molecules or guar molecules, for example.
- Cationic guar derivatives are particularly preferred according to the invention in the preparation according to the invention, in particular guar hydroxypropyltrimonium chloride, which is available, for example, from the company Rhodia under the trade name Jaguar C-14 S.
- Cationic polymers can also be synthetic polymers containing monomers with cationic groups. It is preferred here if the monomer with the cationic group has a permanently cationic group; dimethyl dialyl ammonium chloride is particularly preferred as the monomer.
- a particularly preferred cationic synthetic polymer is Polyquaternium-6, which is available, for example, as Merquat 100 from Lubrizol.
- polyquaternium-7 Another particularly preferred synthetic cationic polymer which contains the monomer dimethyl diallyl ammonium chloride in addition to the monomer acrylamide is polyquaternium-7.
- This polymer is available, for example, as Mirapol 550 P from Sol vay.
- Ampholytic polymers can also be selected as conditioning agents to be used advantageously.
- these polymers also contain monomers with an anionic functionality.
- An example of such poly mers is Polyquaternium-53, which according to the invention is also particularly preferably used is.
- Polyquaternium-53 can be obtained, for example, from Lubrizol under the trade name Merquat 2003PR.
- the particularly preferred cationic polymers guar hydroxytrimonium chloride, polyquternium-6 and polyquaternium-7 and the ampholytic polymer polyquaternium-53 can be used individually in the preparation according to the invention or in combinations of two, three or four. It is furthermore advantageous if only the cationic polymers are selected from the group consisting of guar hydroxytrimonium chloride, polyquternium-6, polyquaternium-7 and / or polyquaternium-53.
- the total content of the at least one cationic and / or ampholytic polymer in the preparation according to the invention is 0.1 to 5.0% by weight, preferably 0.2 to
- the preparation according to the invention advantageously contains emollients. These components counteract drying out and help to reduce the loss of moisture in hair. In addition, they often also have a smoothing effect on the surface of the hair.
- Various classes of compounds can be included in the emollients.
- ester oils are characterized by the fact that saturated or unsaturated C6-C22 fatty acids are esterified with branched or unbranched C4-C20 alcohols. Examples of such compounds are ethylhexyl palmitate, ethylhexyl stearate, hexyl laurate, dibutyl adipate, decyl oleate, hexyl decyl stearate, isopropyl myristate, isopropyl palmitate, myristyl myristate and cetyl palmitate.
- the preparation according to the invention preferably contains isopropyl palmitate and / or isopropyl myristate.
- the total content of the at least one ester oil in the preparation according to the invention is 0.1 to 10.0% by weight, preferably 0.3 to 6.0% by weight, particularly preferably 0.5 to 4.0% by weight .
- Polyols can also be counted among the emollients. Polyols are distinguished by the presence of at least two hydroxyl groups. Polyols having 3 to 6 carbon atoms are preferred.
- the preparation according to the invention particularly preferably contains propylene glycol, glycerol, sorbitol.
- the at least one emollient selected from propylene glycol, glycerol and / or sorbitol is present with a content of 2.0 to 6.0% by weight, based on the total weight of the preparation.
- the preparation according to the invention contains at least one thickener.
- the viscosity and consistency of cosmetic preparations can be influenced.
- Advantageous viscosity ranges can be set.
- the consistency can be designed in such a way that corresponding products can be made available to consumer wishes.
- thickening cleaning preparations for example electrolytes, in particular NaCl, alkanolamides, highly ethoxylated ethers and esters, polymeric thickeners and associative thickeners.
- the preparation according to the invention contains at least one thickener which is selected from the group of highly ethoxylated ethers and / or esters.
- This group of thickeners can also have a foam-boosting effect, they are then referred to as so-called “foam boosters”.
- PEG-150 distearates PEG-120 methyl glucose dioleates, PEG-120 methyl glucose trioleates, PEG-160 sorbitan isostearates and PEG-150 pentaerythrityl tetrastates can be listed as examples. It is preferred if the preparation according to the invention contains PEG-150 pentaerythrityl tetrastearates.
- the preparation according to the invention contains at least one thickener selected from the group of highly ethoxylated esters, the content is in a range from 0.01 to 0.4% by weight, preferably 0.02 to 0.3% by weight, based on its active content and the total weight of the preparation.
- polymeric thickeners which are composed of monomer units which are present in a large number in the molecule. Methacrylic acid and acrylic acid and their derivatives are frequently used for the synthesis of polymeric thickeners. These polymers can be referred to as methacrylate or acrylate based. be net. It is advantageous according to the invention if the preparation of the present invention is free of methacrylate- or acrylate-based thickening polymers, with the proviso that polyquaternium-6, polyquaternium-7 and polyquaternium-53 are not included.
- the preparation according to the invention can be preserved in the manner customary for cosmetic preparations.
- the concentration of preservatives according to the invention is 0.05 to 3.3% by weight, preferably 0.1 to 2.6% by weight, based on the total weight of the preparation according to the invention.
- the preservatives mentioned can each be contained individually or in suitable combinations in the preparation according to the invention.
- Preservation with benzoic acid and / or a salt of benzoic acid, with salicylic acid and / or a salt of salicylic acid and / or with sorbic acid and / or a salt of sorbic acid is advantageous.
- Preservation with sodium benzoate and / or sodium salicylate is particularly advantageous.
- Benzoic acid, salicylic acid, sorbic acid and / or their salts are advantageously present with contents of 0.05 to 1.5% by weight, preferably 0.1 to 1.0% by weight, based on the total weight of the preparation.
- the concentration information relates to the total amount of the advantageous preservative substances mentioned.
- substances that are usually used to adjust the pH of the preparation according to the invention and to keep it stable.
- These substances can advantageously be selected from the group of citric acid and lactic acid and / or from the group of aminomethylpropanol, sodium hydroxide solution, potassium hydroxide solution and triethanolamine.
- the additives and auxiliaries common in cosmetics can be incorporated into the preparation if necessary, such as deodorizing substances, antiperspirants, insect repellents, vitamins, pigments with a coloring effect, flavoring agents, denaturants, perfumes, antioxidants, UV filter substances, sensor additives, active ingredients.
- Pearlescent pigments belong to different chemical substance classes. Natural pearlescent pigments are, for example, "fish silver” (guanine / hypoxanthine mixed crystals from fish scales) or “mother-of-pearl” (ground mussel shells), monocrystalline pearlescent pigments are, for example, bismuth oxychloride (BiOCI) and layered substrates are, for example, mica / metal oxide.
- Natural pearlescent pigments are, for example, "fish silver” (guanine / hypoxanthine mixed crystals from fish scales) or "mother-of-pearl” (ground mussel shells)
- monocrystalline pearlescent pigments are, for example, bismuth oxychloride (BiOCI) and layered substrates are, for example, mica / metal oxide.
- Pearlescent pigments are based, for example, on powdered pigments or castor oil dispersions of bismuth oxychloride and / or titanium dioxide and bismuth oxychloride and / or titanium dioxide on mica. It can also other substrates besides mica coated with other metal oxides, such as. B. silica and the like.
- dialkyl ethers which are solid at 30 ° C. can be used as pearlescent agents and have, for example: the following formula: ROR ' .
- R and R ' can be the same or different; straight-chain or branched, saturated or unsaturated alkyl radicals. These can consist of 12 to 30 carbon atoms, preferably 14 to 24 carbon atoms.
- Acylated radicals consisting of a fatty acid chain with 8 to 30 carbon atoms can also be used.
- Such compounds are, for example, ethylene glycol monostearate and ethylene glycol distearate.
- Opacifiers can include, for example, sodium salts of a polymer made from styrene with a monomer consisting of acrylic acid, methacrylic acid or another olefin and one of their esters, e.g. INCI: Sodium Styrene / Acrylates Copolymer,
- the preparation according to the invention is free from the pearlescent and opacifying agents mentioned.
- the preparation according to the invention can be produced using all methods known to the person skilled in the art and suitable for this type of preparation. However, it is advantageous if the preparation according to the invention is produced in the following way:
- Conditioners can also be added to the water phase if necessary.
- the preparation according to the invention is stable over a longer period of time, the preparation was stored at 25 ° C. for 8 months. The viscosity and pH were determined at selected times.
- the rating "ok” means no change in the general stability, no phase separation, no discoloration, no deposits, the opaque, white appearance remains.
- the viscosity values disclosed in the present document were measured with the Rheomat R123 from ProRheo at 25 ° C.
- the rotor of the device is immersed in the sample without bubbles up to the mark.
- the measuring body 1 was used for the measurements. Further information on the Rheomat R 123 is published on the Internet, see:
- the measured viscosity values fluctuate in the examined time interval by about 22%, this is in the usual range for such preparations.
- the preparations are all characterized by a simple method of preparation, develop a rich, creamy foam and have an opaque, white appearance that is retained over the storage period.
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Abstract
Description
Claims
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DE102018215330.2A DE102018215330A1 (de) | 2018-09-10 | 2018-09-10 | Schäumende Reinigungszubereitung auf Basis einer Emulsion |
PCT/EP2019/072081 WO2020052913A1 (de) | 2018-09-10 | 2019-08-19 | Schäumende reinigungszubereitung auf basis einer emulsion |
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EP19756347.1A Withdrawn EP3849502A1 (de) | 2018-09-10 | 2019-08-19 | Schäumende reinigungszubereitung auf basis einer emulsion |
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EP (1) | EP3849502A1 (de) |
DE (1) | DE102018215330A1 (de) |
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WO2022136095A1 (en) * | 2020-12-21 | 2022-06-30 | L'oreal | Composition comprising a silicone emulsion, a particular (meth)acrylamide polymer, a cationic polysaccharide and an alkyldiallylamine or dialkyldiallylammonium polymer |
FR3119768A1 (fr) * | 2021-02-12 | 2022-08-19 | L'oreal | Composition comprenant une émulsion de silicone, un polymère particulier de (méth)acrylamide, un polysaccharide cationique et un polymère d’alkyldiallylamine ou de dialkyldiallylammonium |
CN112494392A (zh) * | 2020-12-25 | 2021-03-16 | 彭氏(惠州)实业发展有限公司 | 一种清洁型水包油化妆品组合物及其制备方法 |
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DE19934943B4 (de) * | 1999-07-26 | 2007-08-02 | Beiersdorf Ag | Kosmetische und dermatologische Zubereitungen auf der Grundlage von O/W-Emulsionen |
DE10107216A1 (de) | 2001-02-16 | 2002-08-22 | Schwarzkopf Gmbh Hans | Wirkstoffkombination aus Kohlenwasserstoffen und Ölen in kosmetischen Mitteln |
DE10224024A1 (de) * | 2002-05-31 | 2003-12-11 | Beiersdorf Ag | Getrübtes Pflegeshampoo |
DE10237735A1 (de) * | 2002-08-17 | 2004-02-26 | Beiersdorf Ag | Kosmetikum zur Reinigung und Pflege |
US20050143268A1 (en) * | 2003-11-14 | 2005-06-30 | The Procter & Gamble Company | Personal care composition containing a cleansing phase and a benefit phase |
US20090257968A1 (en) * | 2004-03-25 | 2009-10-15 | Richard Walton | Gels containing anionic surfactants and coupling agents |
DE102006011884A1 (de) | 2006-03-13 | 2007-09-20 | Beiersdorf Ag | Silikonfreie Haarreinigungsemulsion |
DE102008036957A1 (de) * | 2008-08-08 | 2010-02-11 | Henkel Ag & Co. Kgaa | Mattierungsadditiv für Blondierungen |
DE102013226698A1 (de) * | 2013-12-19 | 2015-06-25 | Henkel Ag & Co. Kgaa | Oxidationsfärbemittel mit natürlichem Pflegestoff |
DE102015225003A1 (de) | 2015-12-11 | 2017-06-14 | Henkel Ag & Co. Kgaa | Emulsionen enthaltend mindestens drei voneinander verschiedene Konservierungsmittel |
DE102015225005A1 (de) | 2015-12-11 | 2017-06-14 | Henkel Ag & Co. Kgaa | Emulsionen enthaltend mindestens eine spezielle Konservierungsmittelkombination |
US10265261B2 (en) * | 2016-10-31 | 2019-04-23 | L'oreal | Cleansing compositions with conditioning properties |
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2018
- 2018-09-10 DE DE102018215330.2A patent/DE102018215330A1/de not_active Withdrawn
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2019
- 2019-08-19 EP EP19756347.1A patent/EP3849502A1/de not_active Withdrawn
- 2019-08-19 WO PCT/EP2019/072081 patent/WO2020052913A1/de unknown
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