EP3359260B1 - Improvements relating to hair compositions - Google Patents
Improvements relating to hair compositions Download PDFInfo
- Publication number
- EP3359260B1 EP3359260B1 EP16770784.3A EP16770784A EP3359260B1 EP 3359260 B1 EP3359260 B1 EP 3359260B1 EP 16770784 A EP16770784 A EP 16770784A EP 3359260 B1 EP3359260 B1 EP 3359260B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- hair
- composition
- gas
- treatment composition
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 99
- 210000004209 hair Anatomy 0.000 title claims description 96
- 239000007788 liquid Substances 0.000 claims description 35
- 238000011282 treatment Methods 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 24
- 230000003750 conditioning effect Effects 0.000 claims description 23
- 229920000642 polymer Polymers 0.000 claims description 21
- 239000006260 foam Substances 0.000 claims description 17
- 238000005187 foaming Methods 0.000 claims description 17
- 239000004615 ingredient Substances 0.000 claims description 14
- 239000003093 cationic surfactant Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 8
- 239000002453 shampoo Substances 0.000 claims description 6
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 claims description 4
- 239000001569 carbon dioxide Substances 0.000 claims description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 4
- 238000002203 pretreatment Methods 0.000 claims description 3
- 239000001272 nitrous oxide Substances 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 239000007789 gas Substances 0.000 description 34
- 239000000047 product Substances 0.000 description 17
- 125000004432 carbon atom Chemical group C* 0.000 description 12
- 125000001183 hydrocarbyl group Chemical group 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000002537 cosmetic Substances 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 150000004665 fatty acids Chemical class 0.000 description 7
- 150000002191 fatty alcohols Chemical class 0.000 description 7
- 239000000499 gel Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 4
- 241000195940 Bryophyta Species 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 4
- AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 239000000443 aerosol Substances 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 235000011929 mousse Nutrition 0.000 description 4
- VXAPDXVBDZRZKP-UHFFFAOYSA-N nitric acid phosphoric acid Chemical compound O[N+]([O-])=O.OP(O)(O)=O VXAPDXVBDZRZKP-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 239000003380 propellant Substances 0.000 description 4
- 229910021653 sulphate ion Inorganic materials 0.000 description 4
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 125000003368 amide group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000008266 hair spray Substances 0.000 description 3
- -1 non-ionic Chemical group 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 2
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 2
- FLPJVCMIKUWSDR-UHFFFAOYSA-N 2-(4-formylphenoxy)acetamide Chemical compound NC(=O)COC1=CC=C(C=O)C=C1 FLPJVCMIKUWSDR-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 238000001856 aerosol method Methods 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 150000003868 ammonium compounds Chemical class 0.000 description 2
- 229940074979 cetyl palmitate Drugs 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 229920006037 cross link polymer Polymers 0.000 description 2
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 2
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- PXDJXZJSCPSGGI-UHFFFAOYSA-N hexadecanoic acid hexadecyl ester Natural products CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC PXDJXZJSCPSGGI-UHFFFAOYSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 210000002966 serum Anatomy 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 125000006274 (C1-C3)alkoxy group Chemical group 0.000 description 1
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- FSAMVJAGJWGWTQ-UHFFFAOYSA-N 2-hexadecoxyethanol Chemical compound CCCCCCCCCCCCCCCCOCCO FSAMVJAGJWGWTQ-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N Caprolactam Natural products O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- QCZAWDGAVJMPTA-RNFRBKRXSA-N ClC1=CC=CC(=N1)C1=NC(=NC(=N1)N[C@@H](C(F)(F)F)C)N[C@@H](C(F)(F)F)C Chemical compound ClC1=CC=CC(=N1)C1=NC(=NC(=N1)N[C@@H](C(F)(F)F)C)N[C@@H](C(F)(F)F)C QCZAWDGAVJMPTA-RNFRBKRXSA-N 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- OKIZCWYLBDKLSU-UHFFFAOYSA-M N,N,N-Trimethylmethanaminium chloride Chemical compound [Cl-].C[N+](C)(C)C OKIZCWYLBDKLSU-UHFFFAOYSA-M 0.000 description 1
- 229920000289 Polyquaternium Polymers 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- TTZLKXKJIMOHHG-UHFFFAOYSA-M benzyl-decyl-dimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 TTZLKXKJIMOHHG-UHFFFAOYSA-M 0.000 description 1
- PXFDQFDPXWHEEP-UHFFFAOYSA-M benzyl-dimethyl-octylazanium;chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(C)CC1=CC=CC=C1 PXFDQFDPXWHEEP-UHFFFAOYSA-M 0.000 description 1
- XKXHCNPAFAXVRZ-UHFFFAOYSA-N benzylazanium;chloride Chemical compound [Cl-].[NH3+]CC1=CC=CC=C1 XKXHCNPAFAXVRZ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 229960001927 cetylpyridinium chloride Drugs 0.000 description 1
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- WLCFKPHMRNPAFZ-UHFFFAOYSA-M didodecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCC WLCFKPHMRNPAFZ-UHFFFAOYSA-M 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- ZCPCLAPUXMZUCD-UHFFFAOYSA-M dihexadecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCC ZCPCLAPUXMZUCD-UHFFFAOYSA-M 0.000 description 1
- TWFQJFPTTMIETC-UHFFFAOYSA-N dodecan-1-amine;hydron;chloride Chemical class [Cl-].CCCCCCCCCCCC[NH3+] TWFQJFPTTMIETC-UHFFFAOYSA-N 0.000 description 1
- BKRJTJJQPXVRRY-UHFFFAOYSA-M dodecyl-(2-hydroxyethyl)-dimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CCO BKRJTJJQPXVRRY-UHFFFAOYSA-M 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 229940032044 quaternium-18 Drugs 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- YMBCJWGVCUEGHA-UHFFFAOYSA-M tetraethylammonium chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC YMBCJWGVCUEGHA-UHFFFAOYSA-M 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- AQZSPJRLCJSOED-UHFFFAOYSA-M trimethyl(octyl)azanium;chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(C)C AQZSPJRLCJSOED-UHFFFAOYSA-M 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008256 whipped cream Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/22—Gas releasing
- A61K2800/222—Effervescent
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
Definitions
- This invention relates to a non-aerosol method of making foamed compositions for the treatment of hair, to the foamed compositions obtainable thereby and to a method of use thereof.
- Hair conditioner products are liquids (including herein soft-solids), which are normally packaged into bottles, sachets or jars. Hair conditioner products may be rinse-off conditioners or leave-in, where product is left on the hair for an extended period of time.
- Foamed products for application to hair are known, particularly in the styling sector, where styling mousses are a popular product format.
- Foam leave-on conditioners, delivered from an aerosol are also known.
- WO 13/014139 discloses a post-foaming aqueous hair styling gel composition
- a post-foaming aqueous hair styling gel composition comprising one or more thickening polymer, one or more film forming polymer, one or more polyol, one or more surfactant and one or more C4-C5 isoalkane, which is foamed after release from its packaging and applied to hair to improve shine and curl retention of hair, reduce flyaway and confer moderately good setting effect.
- a pressurised product for treating hair which comprises two chambers wherein one of the chambers comprises the post foaming aqueous gel composition and the other chamber comprises one or more propellant wherein the pressure inside the vessel does not exceed 12 bar.
- Two chambered aerosol cans, pressurised with liquid nitrogen or carbon dioxide are exemplified.
- US 2014/093468 (Henkel) Discloses a cosmetic agent for the temporary shaping of keratinic fibers, comprising a carrier, a) 0.1 to 15 wt. % of monoesters of optionally alkylated sugars with C 6 -C 30 fatty acids, b) 0.1 to 15 wt. % of diesters of optionally alkylated sugars with C 6 -C 30 fatty acids, c) 0 to 50 wt. % of at least one film-forming polymer, and d) 0 to 50 wt. %of at least one wax with a melting point in a range from 40°C.
- the cosmetic agent is also disclosed in the form of a foam, which has a density below 0.9 g/cm.
- Methods for producing the cosmetic agent by mixing an optionally premixed blend of the ingredients of the cosmetic agent, characterized in that the density of the resulting cosmetic agent is at least 10% below the density of the blend; and for the temporary shaping of hair, comprising: pressurizing the cosmetic agent with a gas, and applying the agent to the hair, are also disclosed.
- EP 1792600 and US 2008/152610 Disclose an aerosol foam wax composition with superior hair styling and conditioning effects and unusual foam appearance.
- an aqueous aerosol foam composition for keratin fibres especially for hair characterised in that it comprises at least one hair styling polymer selected from anionic, non-ionic, cationic and/or amphoteric or zwitterionic ones, at least one oil or oily compound, at least one fatty acid soap, at least one emulsifier and at least one propellant.
- WO2011/116227 , EP2062562 , EP1342465 , JP2003261430 disclose a foaming device with a dispensing nozzle, wherein a liquid hair composition is mixed with pressurised gas, wherein a foam is created and ejected via the nozzle.
- liquid compositions including packaged compositions, that comprise at least one conditioning agent and that are free from hair styling polymer, may be transformed into foams, using a non-aerosol method, said foams giving unexpected improvement in conditioning and style benefits, including increased conditioning feel, shine, smoothness, fibre alignment, volume and shape benefit over the non-foamed composition, compared with the same composition that was not foamed.
- the invention may be applied to a wide range of formulations.
- the invention provides a process for making the foamed composition of the first aspect, comprising the steps of
- the invention provides a foamed composition for the treatment of hair, obtainable from the method of the first aspect.
- a third aspect of the invention provides a method of treating hair comprising the step of applying the foamed composition of the first aspect or as prepared by the first aspect, to hair.
- liquid is intended to include soft solid compositions, for example those that may be scooped out of a jar.
- the liquid hair treatment composition for use in the method of the invention is capable of holding bubbles of gas in order to form a foam that is stable. It may comprise a polymer or structuring agent to enable a stable foam to be produced. In the context of the invention, by stable is meant that the foam lasts for at least sufficient time following production, to be used by the consumer in a hair treatment process.
- the liquid hair treatment composition is a packaged formulation.
- the liquid hair treatment composition is preferably selected from a shampoo, a rinse-off hair conditioner, a hair mask, a leave-on conditioner composition, and a pre-treatment composition, more preferably selected from a rinse-off hair conditioner, a hair mask, a leave-on conditioner composition, and a pre-treatment composition, for example an oil treatment, and most preferably selected from a rinse-off hair conditioner, a hair mask and a leave-on conditioner composition.
- liquid hair treatment composition is a shampoo
- it is not a high foaming shampoo
- the composition does not contain corrosive or reactive ingredients.
- Reactive ingredients include hair dyes, for example.
- Corrosive ingredients include bleach and peroxides, for example. Corrosive ingredients may cause corrosion of the chamber.
- Rinse off conditioners for use in the invention are conditioners that are typically left on wet hair for 1 to 2 minutes before being rinsed off.
- Hair masks for use in the present invention are treatments that are typically left on the hair for 3 to 10 minutes, preferably from 3 to 5 minutes, more preferably 4 to 5 minutes, before being rinsed off.
- Leave-on conditioners for use in the invention are typically applied to the hair and left on the hair for more than 10 minutes and preferably are applied to the hair after washing and not rinsed out until the next wash.
- liquid hair treatment composition is a rinse-off hair conditioner, a hair mask or a leave-on conditioner composition
- it suitably has a viscosity of from 5,000 to 750,000 centipoise, preferably from 50,000 to 600,000 centipoise, more preferably from 50,000 to 450,000 as measured at 30°C on a Brookfield RVT using a Spindle A or B at 0.5 rpm for 60 seconds on a Helipath stand.
- leave-on conditioner compositions for use in the invention have a viscosity of from 50,000 to 250, 000 centipoise; preferred hair masks have a viscosity of 150,000 to 600,000 centipoise and preferred rinse off conditioners have a viscosity of from 150,000 to 400,000 centipoise as measured at 30°C on a Brookfield RVT using a Spindle A or B at 0.5 rpm for 60 seconds on a Helipath stand.
- liquid hair treatment composition is a shampoo, or other isotropic product
- it suitably has a viscosity of from 5,000 to 100,000, preferably from 10,000 to 75,000, more preferably from 20,000 to 50,000 centipoise, as measured at 30°C on a Brookfield RV5 at 20 rpm for 60 seconds.
- the liquid composition is not a hair styling gel, a hair styling mousse, a hair styling serum or a hairspray.
- the composition comprises less than 0.5 wt %, by weight of the total composition, preferably less than 0.1 wt %, more preferably less than 0.05 wt % and most preferably less than 0.01 wt % of hair styling polymer.
- Hair styling polymers are polymers or resins that provide elements of style to hair, such as hold, general shape definition, shape retention, defined straightening, curling and so on, typically included in gels, mousses, serums, and hair sprays.
- Some styling polymers are classed as film-forming polymers, which are often the source of "hold” in styling products such as hair gels and hairsprays. These polymers deposit onto the surface of the hair and then dry to form clear films that are strong and hold the hairs together until the film is either removed via washing or the film is broken due to mechanical forces on the hair (combing).
- PVP poly N-vinyl-2-pyrrolidone
- PVA polyvinyl acetate
- PVP/VA copolymer examples include PVP (poly N-vinyl-2-pyrrolidone), PVA (polyvinyl acetate) and PVP/VA copolymer, amongst others.
- styling polymers used in soft styling products are acrylate based, such as polyacrylates (for example polyacrylate-32, polyacylate-14), acrylates crosspolymers (for example acrylates crosspolymer-3, polyacrylate-2 crosspolymer) and AMO-acrylates/allyl methacrylate copolymer, amongst others.
- polyacrylates for example polyacrylate-32, polyacylate-14
- acrylates crosspolymers for example acrylates crosspolymer-3, polyacrylate-2 crosspolymer
- AMO-acrylates/allyl methacrylate copolymer amongst others.
- styling polymers include polyquaternium compounds, polyvinyl caprolactam copolymers and esters of PVM/MA(methyl vinyl ether and maleic anhydride).
- compositions for use in the method of the current invention comprise conditioning agents.
- Conditioning agents are preferably selected from cationic surfactants, used singly or in admixture.
- Cationic surfactants useful in compositions for use in the method of the invention contain amino or quaternary ammonium hydrophilic moieties which are positively charged when dissolved in aqueous composition.
- Suitable cationic surfactants are those corresponding to the formula: [N (R 1 ) (R 2 ) (R 3 ) (R 4 )] + (X) - in which R 1 , R 2 , R 3 and R 4 are independently selected from (a) an aliphatic group of from 1 to 22 carbon atoms, or (b) an aromatic, alkoxy, polyoxyalkylene, alkylamido, hydroxyalkyl, aryl or alklaryl group having up to 22 carbon atoms; and X is a salt-forming anion such as those selected from halogen, (e.g. chloride, bromide), acetate, citrate, lactate, glycolate, phosphate nitrate, sulphate, and alkylsulphate radicals.
- halogen e.g. chloride, bromide
- the aliphatic groups can contain, in addition to carbon and hydrogen atoms, ether linkages, and other groups such as amino groups.
- the longer chain aliphatic groups e.g., those of about 12 carbons, or higher, can be saturated or unsaturated.
- the most preferred cationic surfactants for compositions for use in the method of the present invention are monoalkyl quarternary ammonium compounds in which the akyl chain lengthy is C 8 to C 14 .
- R 5 is a hydrocarbon chain having 8 to 14 carbon atoms or a functionalised hydrocarbyl chain with 8 to 14 carbon atoms and containing ether, ester, amido or amino moieties present as substituents or as linkages in the radical chain
- R 6 , R 7 and R 8 are independently selected from (a) hydrocarbyl cahins of from 1 to about 4 carbon atoms, or (b) functionalised hydrocarbyl chains having from 1 to about 4 carbon atoms and containing one or more aromatic, ether, ester, amido or amino moieties present as substituents or as linkages in the radical chain
- X is a salt-forming anion such as those selected from halogen, (e.g. chloride, bromide), acetate, citrate, lactate, glycolate, phosphate nitrate, sulphate and
- the functionalised hydrocarbyl cahins (b) may suitably contain one or more hydrophilic moieties selected from alkoxy (preferably C 1 -C 3 alkoxy), polyoxyalkylene, alkylester, and combinations thereof.
- the hydrocarbon chains R 1 have 12 to 14 carbon atoms, most preferably 12 carbon atoms. They may be derived from source oils which contain substantial amounts of fatty acids having the desired hydrocarbyl chain length.
- the fatty acids from palm kernel oil or coconut oil can be used as a source of C 8 to C 12 hydrocarbyl chains.
- Typical monoalkyl quarternary ammonium compounds of the above general formula for use in compositions for use in the method of the invention include:
- suitable cationic surfactants include those materials having the CTFA designations Quaternium-5, Quaternium-31 and Quaternium-18. Mixtures of any of the foregoing materials may also be suitable.
- a particularly useful cationic surfactant is cetyltrimethylammonium chloride, available commercially, for example as DEHYQUART, ex Henkel.
- the level of cationic surfactant is preferably from 0.01 to 10, more preferably 0.05 to 5, most preferably 0.1 to 2 w.t. % of the total composition.
- a preferred conditioner comprises a conditioning gel phase.
- Such conditioners and methods for making them are described in WO2014/016354 , WO2014/016353 , WO2012/016352 and WO2014/016351 .
- the conditioning compositions may also comprise other optional ingredients.
- Such ingredients include, but are not limited to; fatty material, deposition polymers and further conditioning agents.
- Conditioner compositions preferably additionally comprise fatty materials.
- fatty materials and cationic surfactants in conditioning compositions is believed to be especially advantageous, because this leads to the formation of a structured lamellar or liquid crystal phase, in which the cationic surfactant is dispersed.
- fatty material is meant a fatty alcohol, an alkoxylated fatty alcohol, a fatty acid or a mixture thereof.
- the alkyl chain of the fatty material is fully saturated.
- Representative fatty materials comprise from 8 to 22 carbon atoms, more preferably 16 to 22.
- suitable fatty alcohols include cetyl alcohol, stearyl alcohol and mixtures thereof. The use of these materials is also advantageous in that they contribute to the overall conditioning properties of compositions.
- Alkoxylated, (e.g. ethoxylated or propoxylated) fatty alcohols having from about 12 to about 18 carbon atoms in the alkyl chain can be used in place of, or in addition to, the fatty alcohols themselves. Suitable examples include ethylene glycol cetyl ether, polyoxyethylene (2) stearyl ether, polyoxyethylene (4) cetyl ether, and mixtures thereof.
- the level of fatty material in conditioners is suitably from 0.01 to 15, preferably from 0.1 to 10, and more preferably from 0.1 to 5 percent by weight of the total composition.
- the weight ratio of cationic surfactant to fatty alcohol is suitably from 10:1 to 1:10, preferably from 4:1 to 1:8, optimally from 1:1 to 1:7, for example 1:3.
- Further conditioning ingredients include esters of fatty alcohol and fatty acids, such as cetyl palmitate.
- a conditioning composition for use in the present invention may preferably comprise a miscellar structured liquid.
- the pH of a conditioner comprising the present composition is preferably 3-5. More preferably the pH of the composition is 4.5-5.5.
- composition has a pH of less than 3.10 it is preferred that it is in the form of a conditioning mask for intense treatment.
- conditioning ingredients include conditioning oils, preferably selected from coconut oil and olive oil.
- the foamed composition is not produced by aerosolisation.
- the foamed composition is produced without the use of propellant.
- the foamed composition has a physical appearance similar to that of whipped cream.
- the colour of the foam will vary according to the colour of the original liquid composition.
- the chamber is only intended to provide temporary storage for the foamed composition.
- the foamed composition is used fresh, preferably within 24 hours, more preferably within 8 hours, even more preferably within 1 hour. Most preferably, the composition is foamed at point of use.
- the foamed composition is not stored in the chamber for longer than 24 hours, more preferably for more than 8 hours, most preferably more than 1 hour.
- a method of the invention comprises the step of applying the foamed composition of the invention to hair.
- the foamed composition is used within 24 hours of being produced, more preferably within 8 hours, even more preferably within 1 hour, most preferably within 10 minutes.
- the Foaming Device The Foaming Device
- the foaming device for use in the method of the invention comprises a chamber, a removable or rechargeable pressurised gas unit and a dispensing nozzle.
- It is preferably a portable, hand held device.
- the chamber preferably has a capacity of 0.5 to 1.0 litres. It is preferably made from metal, for example stainless steel.
- the dispensing nozzle is for the purpose of dispensing the foamed composition.
- the nozzle is detachable.
- the nozzle is operated by a lever.
- the nozzle may be shaped so as to result in a foamed product having a particular shape.
- the foamed composition is produced by the use of pressurised gas from a removable or rechargeable pressurised gas unit.
- Suitable examples of removable or rechargeable pressurised gas units include a gas canister and a gas cylinder.
- a gas canister Preferably it is a gas canister, more preferably a mini gas canister, preferably of length 6 to 15 cm, more preferably less than 10 cm.
- the capacity of the preferred mini canisters is suitably from 10 to 100 ml.
- the gas is preferably selected from carbon dioxide and nitrous oxide.
- the gas is introduced into the chamber from the pressurised gas unit.
- the pressurised gas unit is preferably directly attachable to the device.
- a preferred foaming device comprises a chamber which is detachably connected to a head, preferably by a screw thread.
- the head houses a connection port for a gas supply unit, a nozzle and a lever.
- the gas supply unit is connected to the head at the connection port to supply gas to the inside of the chamber.
- the device is first opened by removing the head from the chamber and the liquid composition is added to the chamber.
- the head is then re-connected to the chamber.
- a gas supply is connected to the connection port on the head and gas is then injected into the chamber.
- a foam is generated by mixing the liquid composition and the gas, preferably by shaking.
- the foamed composition is then dispensed via the nozzle, preferably by operation of the lever.
- the gas is pressurised gas and, therefore, cannot be atmospheric air, for example.
- the process of the invention comprises the steps of
- Mixing of the liquid hair treatment composition and the gas is preferably achieved by shaking the device to mix the composition and the gas.
- an essentially vertical shaking motion is carried out for 10 to 30 s.
- a commercially available food whipper namely an "iSi Gourmet Whip", of 0.5 L capacity, fitted with a carbon dioxide mini pressurised gas canister, was used to whip the mask into a foam.
- the liquid mask composition was placed in the chamber of the foaming device, before charging the chamber with the gas.
- the whipper was shaken and the lever depressed to emit a foamed product.
- Three mannequin heads with bleached human hair were provided. For each head, the hair was parted down the middle and each side washed with a non-conditioning shampoo, following an identical protocol.
- 16 g of the mask, in liquid form, was applied to one side of the mannequin head. 16 g of the foamed mask was applied to the other side. The conditioner was left on the hair for 5 minutes and then rinsed off with water.
- Table 1 Smoothness, shine and alignment of hair treated with non-foamed (standard) mask and foamed mask.
- Table 2 Smoothness, shine and alignment of hair treated with non-foamed (standard) mask and foamed mask.
- Table 3 Smoothness, shine and alignment of hair treated with non-foamed (standard) mask and foamed mask.
- a further mannequin head, treated in the same way with the foamed product was also deemed to be visibly more controlled with added volume, have more natural movement and to look and feel less coated.
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EP15188753 | 2015-10-07 | ||
PCT/EP2016/072924 WO2017060121A1 (en) | 2015-10-07 | 2016-09-27 | Improvements relating to hair compositions |
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US (1) | US10980716B2 (ko) |
EP (1) | EP3359260B1 (ko) |
JP (1) | JP6880008B2 (ko) |
KR (1) | KR102656915B1 (ko) |
CN (1) | CN108136221A (ko) |
AR (1) | AR106271A1 (ko) |
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GB1331518A (en) | 1970-01-09 | 1973-09-26 | Gen Foods Corp | Preparation os slush beverages |
US3801015A (en) * | 1972-10-27 | 1974-04-02 | Stoltz J | Foam generator |
LU83876A1 (fr) * | 1982-01-15 | 1983-09-02 | Oreal | Composition cosmetique destinee au traitement des fibres keratiniques et procede de traitement de celles-ci |
WO1996011162A1 (en) | 1994-10-11 | 1996-04-18 | Monson James A | Dispensing apparatus for foaming compositions and method |
GB9913951D0 (en) | 1999-06-15 | 1999-08-18 | Unilever Plc | Mousse-forming shampoo compositions |
EP1342465B1 (en) | 2002-03-05 | 2011-10-19 | Kao Corporation | Foam-type hair dye and foam-type hair dye discharge container |
JP4123795B2 (ja) | 2002-03-05 | 2008-07-23 | 花王株式会社 | 泡状染毛剤 |
US20050136011A1 (en) | 2003-12-23 | 2005-06-23 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Mousse product and method for conditioning hair |
JP5102934B2 (ja) | 2004-05-19 | 2012-12-19 | 株式会社ロッテ | 新規酒類 |
ES2371759T3 (es) | 2004-07-19 | 2012-01-09 | Unilever N.V. | Productos que contienen hielo. |
EP1792600B2 (en) | 2005-12-05 | 2012-07-25 | Kao Germany GmbH | Aerosol foam composition |
US8349296B2 (en) | 2006-12-21 | 2013-01-08 | Kpss-Kao Professional Salon Services Gmbh | Aerosol foam composition |
CA2683128C (en) * | 2007-04-27 | 2015-01-20 | Kao Corporation | Two-part hair dye or bleach composition |
WO2011115227A1 (ja) | 2010-03-18 | 2011-09-22 | ヴィータ株式会社 | 毛髪トリートメント方法及びこれに使用する薬剤の包装体 |
US9053189B2 (en) | 2010-03-19 | 2015-06-09 | Ifwe Inc. | Customizing content displayed for a user based on user preferences of another user |
CN102215893A (zh) | 2010-08-03 | 2011-10-12 | 史建民 | 一种湿化瓶及带有该湿化瓶的氧气吸入器 |
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DE102011077365A1 (de) | 2011-06-10 | 2012-12-13 | Henkel Ag & Co. Kgaa | Stylingmittel mit interessanter Textur |
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JP6880008B2 (ja) | 2021-06-02 |
KR20180058721A (ko) | 2018-06-01 |
BR112018005585B1 (pt) | 2021-10-19 |
BR112018005585A2 (ko) | 2018-10-02 |
JP2018530552A (ja) | 2018-10-18 |
CN108136221A (zh) | 2018-06-08 |
US20180280260A1 (en) | 2018-10-04 |
US10980716B2 (en) | 2021-04-20 |
WO2017060121A1 (en) | 2017-04-13 |
AR106271A1 (es) | 2017-12-27 |
KR102656915B1 (ko) | 2024-04-16 |
EP3359260A1 (en) | 2018-08-15 |
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