EP3118296A1 - Pastille nettoyante pour carafes - Google Patents

Pastille nettoyante pour carafes Download PDF

Info

Publication number
EP3118296A1
EP3118296A1 EP15176976.7A EP15176976A EP3118296A1 EP 3118296 A1 EP3118296 A1 EP 3118296A1 EP 15176976 A EP15176976 A EP 15176976A EP 3118296 A1 EP3118296 A1 EP 3118296A1
Authority
EP
European Patent Office
Prior art keywords
cleaning
cleaning tablet
bicarbonate
citric acid
tablet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP15176976.7A
Other languages
German (de)
English (en)
Inventor
Josef LUKASSER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clearwhite GmbH
Original Assignee
Clearwhite GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clearwhite GmbH filed Critical Clearwhite GmbH
Priority to EP15176976.7A priority Critical patent/EP3118296A1/fr
Priority to US15/742,950 priority patent/US20190002806A1/en
Priority to PCT/EP2016/066874 priority patent/WO2017009447A1/fr
Priority to EP16738813.1A priority patent/EP3322791B1/fr
Publication of EP3118296A1 publication Critical patent/EP3118296A1/fr
Priority to HK18114985.8A priority patent/HK1255899A1/zh
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0091—Dishwashing tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0052—Gas evolving or heat producing compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3907—Organic compounds
    • C11D3/3917—Nitrogen-containing compounds
    • C11D3/392—Heterocyclic compounds, e.g. cyclic imides or lactames
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces
    • C11D2111/18—Glass; Plastics

Definitions

  • the field of the present invention is that of the cleaning agents for the inside of decanters, in particular of wine decanters, for the removal of wine residues and limescale.
  • the cleaning of the inside of decanters in general and of wine decanters in particular presents a challenge in catering and household, especially the more intricate these vessels are made (e.g., by providing a narrower, longer neck).
  • the cleaning result achieved with conventional cleaning methods is at least unsatisfactory, at least after reasonable effort, and often not all areas of the inside are accessible to such cleaning methods.
  • limescale limestone scale, chalk stains, limescale
  • cleaning beads eg of metal
  • decanters especially for wine decanters
  • marketed to remove the impurities on the inside of the carafe by mechanical action during agitation of the decanter.
  • the cleaning is sometimes not successful, bottlenecks are not accessible to the cleaning beads and because of their size Repeated use for a long time can scratch the inside of the carafe.
  • the handling of cleaning beads is rather expensive.
  • the US 2014/0283877 A1 also discloses a device for cleaning vessels, in particular weed edgers (see paragraph [0024] of the document).
  • the removal of wine or lime residues should be facilitated.
  • the formation of lime residues by the cleaning itself should be avoided as far as possible.
  • the generation of scratches, clouding and / or discoloration on the inside should also be contained or prevented over a long period of time by repeated application of the present invention, in comparison to methods or products known in the art for cleaning.
  • the present invention provides a cleaning tablet.
  • the cleaning tablet according to the present invention comprises bicarbonate, citric acid, surfactant, bleach, bleach activator and complexing agent.
  • the common mass fraction of bicarbonate and citric acid in the cleaning tablet according to the invention is 30% -70%, and the molar ratio between bicarbonate and citric acid between 1: 1 and 4: 1.
  • dentifrice purging tablet typical flavoring agent (0.5% by weight peppermint powder) in the embodiment of the document demonstrates that the denture purging tablets are unsuitable for use in accordance with the present invention, because flavors typical of denture purging tablets (even in traces) are sensory of taste when distilling the water or, to a particular extent, the wine from the carafe.
  • the use of the cleaning tablet is as follows: The carafe is pre-filled with warm tap water and the cleaning tablet is placed in the decanter for dissolution. The dissolved cleaning tablet is allowed to act on the inside of the decanter for 10 to 20 minutes (or even overnight), after which the decanter is rinsed several times with tap water until no more foam is visible. Since the capacity of the in situ citrate for the complexation of lime is temperature dependent, a water temperature of 40 ° C-50 ° C is recommended at the beginning of the cleaning - the use of much hotter water is usually to be avoided.
  • the combined mass fraction of bicarbonate and citric acid in the cleaning tablet according to the invention is at least 32%, more preferably at least 34%, even more preferably at least 36%. Furthermore, the combined mass fraction of bicarbonate and citric acid in the cleaning tablet according to the invention is preferably at most 65%, more preferably at most 60%, even more preferably at most 55%, in particular at most 50%.
  • the bicarbonate is preferably in the form of sodium bicarbonate or potassium bicarbonate, in particular potassium hydrogen carbonate, in the cleaning tablet according to the present invention.
  • the citric acid is preferably present in anhydrous form in the cleaning tablet according to the invention.
  • citrate for example trisodium citrate, as complexing agent
  • carbonate for example sodium carbonate
  • the molar ratio between bicarbonate and citric acid in the cleaning tablet is between 1.5: 1 and 3.75: 1, preferably between 2: 1 and 3.5: 1, more preferably between 2.5: 1 and 3.25: 1, more preferably between 2.75: 1 and 3.125: 1, in particular substantially 3: 1, because this corresponds to the stoichiometry of the reaction of bicarbonate with citric acid upon dissolution of the cleaning tablet.
  • the pH when the cleaning tablet is dissolved in water, the pH is between 6.5 and 8.5, in particular between 7 and 8 or even between 7.25 and 7.75.
  • the pH value of the cleaning tablet according to the invention after solution is therefore more in the neutral than in the alkaline range.
  • the cleaning tablet in this embodiment of the invention is particularly suitable for use in cleaning the inside of a carafe.
  • the surfactant of the cleaning tablet according to the invention is selected from the group of low foaming anionic, nonionic and zwitterionic Surfactants and mixtures thereof.
  • the anionic surfactants are preferably selected from the group of branched C 6 -C 12 -alkyl sulfates and their mixtures.
  • the nonionic surfactants are preferably alkoxylated fatty alcohols, in particular ethoxylated and / or propoxylated fatty alcohols, and mixtures thereof.
  • the zwitterionic surfactants preferably originate from the group of C 6 -C 12 -alkyliminopropionates, C 6 -C 12 -alkylamidopropylbetaines and mixtures thereof. Particular preference is given to surfactants selected from the group of isooctyl sulfates, isooctyl sulfosuccinates, alkoxylated fatty alcohols, capryliminopropionates, caprylamidopropylbetaines and mixtures thereof.
  • the surfactants are very particularly preferably selected from the group of the alkoxylated fatty alcohols, preferably the ethoxylated and / or propoxylated C 12 -C 14 fatty alcohols, and mixtures thereof, such as, for example, MARLOX® MO 154 (manufacturer: Sasol Ltd., South Africa).
  • the mass fraction of the surfactants in the cleaning tablet according to the invention is preferably 0.5% to 5%, in particular 1% -3%.
  • bleach systems i.e., bleach and bleach activator
  • bleach activator and bleach of the cleaning tablet in another preferred embodiment of the present invention are suitable for use at a temperature between 40 ° C-50 ° C.
  • the bleach system is a percarbonate / tetraacetylethylenediamine (TAED) system or a percarbonate / 4-decanoyloxybenzoic acid (DOPA) system or similar system.
  • the complexing agent in the cleaning tablet of the present invention is selected from ethylenediaminotetraacetate (TED), ethylenediaminetetraacetate (EDTA), methylglycinediacetic acid (MGDA) (preferably the trisodium salt thereof, eg Trilon M), glutamic acid-N, N-diacetic acid (GLDA), preferably tetrasodium salt thereof (eg Dissolvine GL ® ex Akzo Nobel, the Netherlands), oxalate, maleate, tartrate, citrate (are particularly preferably the sodium salts of the latter four) or mixtures thereof;
  • the complexing agent is selected from MGDA (or a salt thereof), citrate and mixtures thereof.
  • the inventive Cleaning tablet a phosphonate as another complexing agent.
  • the cleaning tablet according to the invention contains as complexing agent, if appropriate inter alia, methylglycinediacetic acid, or a salt thereof, and phosphonate, for example hydroxyethylidene-1,1-diphosphonic acid.
  • the cleaning tablet is free of enzymes, perfumes (flavorings) and / or polycarboxylates.
  • Enzymes are used in commercial cleansers against heavy soiling (e.g., noodle, egg, milk residues). For the purification of carafes these are usually not necessary, in addition, residues of the enzymes after cleaning, for example, affect the taste quality of a wine. Flavorings can also negatively affect the flavor quality of water or wine.
  • Polycarboxylates (used as builders in commercially available cleaning agents) can in turn form visible deposits on glass with the naked eye, which is likewise undesirable according to the invention.
  • the cleaning tablet of the invention is water-soluble, because at least visible to the naked eye visible residues on the inside of the carafe after cleaning are undesirable.
  • the cleaning tablet dissolves in a period of at least 10 seconds, preferably at least 20 seconds, more preferably at least 30 seconds, even more preferably at least 1 minute, especially at least 2 minutes and at most 30 minutes, preferably at most 20 minutes , more preferably at most 15 minutes, even more preferably at most 10 minutes, especially at most 5 minutes in water at a temperature of 30 ° C at atmospheric pressure completely on.
  • the detergent tablet dissolves in water by the reaction of bicarbonate with citric acid at least 0.1 g, preferably at least 0.25 g, more preferably at least 0.5 g, even more preferably at least 1 g, in particular at least 1, 5g or even at least 1.8g carbon dioxide gas free.
  • the cleaning tablet has one or more Fracture notches to allow, for example, a comminution of the cleaning tablet for use in very narrow-necked decanters.
  • the cleaning tablet according to the invention may further comprise tableting aids and / or a tablet disintegrant.
  • the person skilled in the art can provide further ingredients for the tablet according to the invention.
  • the present invention provides the use of the cleaning tablet for cleaning the inside of a carafe, preferably made of glass, in particular of crystal glass.
  • a carafe preferably made of glass, in particular of crystal glass.
  • the carafe is a wine decanter.
  • the use according to the invention is characterized in that wine residues, in particular red wine residues, and / or lime residues are removed from the inside of the carafe to a significant extent.
  • the use according to the invention is characterized in that the formation of deposits, in particular lime residues, on the inside of the carafe after use is substantially prevented.
  • the decanter may additionally be agitated during the dissolution of the cleaning agent and / or after the dissolution of the cleaning agent in order, if appropriate, to accelerate the cleaning.
  • the cleaning tablet according to the invention is particularly suitable for cleaning decanters, in particular wine decanters - preferably made of glass, in particular of (high-quality) crystal glass.
  • the cleansing tablet of the present invention is generally also suitable for gentle cleansing (e.g., removal of limescale) from other narrow-necked and / or entangled vessels that are particularly designed to contain water. These may include: vases, (sports) bottles, thermoses and CAMELBAK® hydration backpacks (manufacturer: CamelBak Products, LLC, USA).
  • a wine decanter contaminated with red wine residues (model Eve from Riedel Glas Austria, volume 1.4L, article number 1950/09) was filled with tap water (temperature: 40 ° C, water hardness: 15 dH °). Following was the cleaning tablet introduced into the wine decanter and dissolved within 2.5 minutes with strong carbon dioxide bubbles in the tap water. After 20 minutes at room temperature, the wine decanter was emptied and rinsed three times with tap water (temperature: 10 ° C, water hardness: 15 dH °). There were no more red wine residues detectable with the naked eye, also were no limescale visible to the naked eye.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
EP15176976.7A 2015-07-16 2015-07-16 Pastille nettoyante pour carafes Withdrawn EP3118296A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP15176976.7A EP3118296A1 (fr) 2015-07-16 2015-07-16 Pastille nettoyante pour carafes
US15/742,950 US20190002806A1 (en) 2015-07-16 2016-07-15 Cleaning tablet for decanters
PCT/EP2016/066874 WO2017009447A1 (fr) 2015-07-16 2016-07-15 Pastille nettoyante pour carafes
EP16738813.1A EP3322791B1 (fr) 2015-07-16 2016-07-15 Pastille nettoyante pour carafes
HK18114985.8A HK1255899A1 (zh) 2015-07-16 2018-11-22 用於玻璃瓶的清潔片

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP15176976.7A EP3118296A1 (fr) 2015-07-16 2015-07-16 Pastille nettoyante pour carafes

Publications (1)

Publication Number Publication Date
EP3118296A1 true EP3118296A1 (fr) 2017-01-18

Family

ID=53673026

Family Applications (2)

Application Number Title Priority Date Filing Date
EP15176976.7A Withdrawn EP3118296A1 (fr) 2015-07-16 2015-07-16 Pastille nettoyante pour carafes
EP16738813.1A Active EP3322791B1 (fr) 2015-07-16 2016-07-15 Pastille nettoyante pour carafes

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP16738813.1A Active EP3322791B1 (fr) 2015-07-16 2016-07-15 Pastille nettoyante pour carafes

Country Status (4)

Country Link
US (1) US20190002806A1 (fr)
EP (2) EP3118296A1 (fr)
HK (1) HK1255899A1 (fr)
WO (1) WO2017009447A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023070137A1 (fr) * 2021-10-29 2023-05-04 Martin Lasnik Procédé et ensemble de nettoyage de lunettes

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3825392A1 (fr) * 2019-11-21 2021-05-26 Dalli-Werke GmbH & Co. KG Pastille de détergent comprenant un système effervescent
BR112022022264A2 (pt) * 2020-05-28 2022-12-20 Unilever Ip Holdings B V Tablete para formar uma composição para lavagem de louças líquida e método para formar um líquido para lavagem de louças manual
EP4166638A1 (fr) 2021-10-13 2023-04-19 CLARO Products GmbH Pastille de nettoyage destinée au nettoyage des lunettes

Citations (9)

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Publication number Priority date Publication date Assignee Title
EP0334060A2 (fr) 1988-03-19 1989-09-27 Reckitt Gmbh Comprimé pour le nettoyage de prothèses dentaires
US5384062A (en) * 1993-12-01 1995-01-24 Warner-Lambert Company Perborate persulfate: protease denture cleanser tablet composition
DE19926376A1 (de) * 1999-06-10 2000-12-14 Henkel Kgaa Lagerstabile Brausetabletten
US6194368B1 (en) * 1995-07-13 2001-02-27 Joh A. Benckiser, Gmbh Dishwasher product in tablet form
WO2003089560A2 (fr) * 2002-04-16 2003-10-30 Colgate-Palmolive Company Compositions de nettoyage sous forme de comprime
US20060252666A1 (en) * 2005-05-09 2006-11-09 Dennis Sheirs Household cleaning composition
EP1891871A2 (fr) 2006-08-26 2008-02-27 Bleuel, Norbert Dispositif de polissage, de nettoyage ou de séchage de l'intérieur d'un récipient pour recevoir des liquides
US20140000658A1 (en) * 2011-03-07 2014-01-02 Clean Ethics Cleaning formulations and uses thereof
US20140283877A1 (en) 2012-11-26 2014-09-25 Naoki Sonoda Method and Apparatus for Cleaning Vessels

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ZA752732B (en) * 1974-05-15 1976-12-29 Colgate Palmolive Co Unitary detergent compositions and washing methods
US4540504A (en) * 1983-04-22 1985-09-10 Warner-Lambert Company Denture cleaner having improved dissolution time and clarity and method of preparation
US5980641A (en) * 1997-06-13 1999-11-09 Jakubowski; Henryk P. Methods and solutions for cleaning dentures
US8846593B2 (en) * 2012-04-25 2014-09-30 Basf Se Dishwashing composition comprising a covalently modified alkyleneimine polymer
US20130284210A1 (en) * 2012-04-25 2013-10-31 Basf Se Solid formulations, their preparation and use
US8940679B2 (en) * 2013-01-25 2015-01-27 Pollets S.A. Cleaning and deodorizing compositions and methods
EP2961822B1 (fr) * 2013-02-28 2017-04-12 Basf Se Formules, leur utilisation comme détergent pour lave-vaisselle ou destinées à sa fabrication, ainsi que leur fabrication
KR101925274B1 (ko) * 2013-04-02 2018-12-05 바스프 에스이 제형, 식기세정 세제로서의 또는 식기세정 세제의 생산을 위한 그의 용도 및 그의 제조
AU2015313913B2 (en) * 2014-09-09 2019-07-25 Graff Pehrson Vesterager Gmbh Highly alkaline detergent composition
ES2586461B1 (es) * 2015-03-12 2017-12-01 Lorena MARTÍ COMA Composición detergente en forma de pastilla efervescente

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0334060A2 (fr) 1988-03-19 1989-09-27 Reckitt Gmbh Comprimé pour le nettoyage de prothèses dentaires
US5384062A (en) * 1993-12-01 1995-01-24 Warner-Lambert Company Perborate persulfate: protease denture cleanser tablet composition
US6194368B1 (en) * 1995-07-13 2001-02-27 Joh A. Benckiser, Gmbh Dishwasher product in tablet form
DE19926376A1 (de) * 1999-06-10 2000-12-14 Henkel Kgaa Lagerstabile Brausetabletten
WO2003089560A2 (fr) * 2002-04-16 2003-10-30 Colgate-Palmolive Company Compositions de nettoyage sous forme de comprime
US20060252666A1 (en) * 2005-05-09 2006-11-09 Dennis Sheirs Household cleaning composition
EP1891871A2 (fr) 2006-08-26 2008-02-27 Bleuel, Norbert Dispositif de polissage, de nettoyage ou de séchage de l'intérieur d'un récipient pour recevoir des liquides
US20140000658A1 (en) * 2011-03-07 2014-01-02 Clean Ethics Cleaning formulations and uses thereof
US20140283877A1 (en) 2012-11-26 2014-09-25 Naoki Sonoda Method and Apparatus for Cleaning Vessels

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023070137A1 (fr) * 2021-10-29 2023-05-04 Martin Lasnik Procédé et ensemble de nettoyage de lunettes

Also Published As

Publication number Publication date
EP3322791A1 (fr) 2018-05-23
WO2017009447A1 (fr) 2017-01-19
EP3322791C0 (fr) 2023-08-16
US20190002806A1 (en) 2019-01-03
HK1255899A1 (zh) 2019-08-30
EP3322791B1 (fr) 2023-08-16

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