EP3019652B1 - Tampon à récurer pour le lavage de la vaisselle - Google Patents

Tampon à récurer pour le lavage de la vaisselle Download PDF

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Publication number
EP3019652B1
EP3019652B1 EP14823762.1A EP14823762A EP3019652B1 EP 3019652 B1 EP3019652 B1 EP 3019652B1 EP 14823762 A EP14823762 A EP 14823762A EP 3019652 B1 EP3019652 B1 EP 3019652B1
Authority
EP
European Patent Office
Prior art keywords
scouring pad
yarns
divided
yarn
pla
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP14823762.1A
Other languages
German (de)
English (en)
Other versions
EP3019652A4 (fr
EP3019652A1 (fr
Inventor
Sang-Won EUN
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of EP3019652A1 publication Critical patent/EP3019652A1/fr
Publication of EP3019652A4 publication Critical patent/EP3019652A4/fr
Application granted granted Critical
Publication of EP3019652B1 publication Critical patent/EP3019652B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
    • A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
    • A47L13/16—Cloths; Pads; Sponges
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
    • A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
    • A47L13/12—Implements with several different treating devices
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L17/00—Apparatus or implements used in manual washing or cleaning of crockery, table-ware, cooking-ware or the like
    • A47L17/04—Pan or pot cleaning utensils
    • A47L17/08—Pads; Balls of steel wool, wire, or plastic meshes
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J13/00—Heating or cooling the yarn, thread, cord, rope, or the like, not specific to any one of the processes provided for in this subclass
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00—Woven fabrics designed to make specified articles
    • D03D1/0017—Woven household fabrics
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/43—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with differing diameters
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2509/00—Medical; Hygiene
    • D10B2509/02—Bandages, dressings or absorbent pads
    • D10B2509/026—Absorbent pads; Tampons; Laundry; Towels

Definitions

  • the present disclosure relates to a scouring pad for washing dishes. More particularly, the present disclosure relates to a scouring pad for washing dishes, which contains a biodegradable polymer.
  • a scouring pad for washing dishes is widely used for removing contaminants stained on dishes and the like.
  • the scouring pad is generally formed of a polymer fiber. Accordingly, when the scouring pad is discarded after it is used, there may incur an environmental pollution problem according to processing of a waste polymer.
  • a scouring pad for washing dishes manufactured by using an environmentally-friendly polymer have been developed. An example can be seen in WO02/071914 .
  • Korean Patent Registration No. 10-0501468 discloses high intensity biodegradable polyester resin and manufacturing method thereof.
  • Korean Patent Application Laid-Open No. 10-2012-0114507 also teaches thermally adhesive co-polyester having excellent biodegradable feature, manufacturing method thereof, and binder fiber containing the same.
  • the scouring pad products using the environmentally-friendly polymer in prior art have a problem that cleaning power is low, or bubble are not generated well. The aforementioned products may occur a problem of making scratches on surfaces of dishes which are cleaning targets.
  • the disclosed scouring pad provides an environmentally-friendly scouring pad for washing dishes, which exhibits excellent cleaning power and forms bubbles better, does not cause scratches of surfaces of dishes, by resolving the problems mentioned above.
  • An exemplary embodiment of the present disclosure provides a scouring pad for washing dishes comprising: (a) a plurality of degradable polyester divided yarns heat-treated at 120°C to 170°C and (b) a plurality of degradable polyester filament yarns, wherein the individual filament yarns are aligned in parallel to each other and the individual divided yarns are positioned between the adjacent two filament yarns and are connected to the adjacent two filaments.
  • the divided yarn may be the divided yarns heat-treated at 130°C to 160°C, preferably, poly-lactic acid heat-treated at 130°C to 160°C.
  • the divided yarn may have a thickness of 550 to 650 deniers, and may be formed of 23 to 30 filaments.
  • the filament yarn may be poly-lactic acid, and may have a thickness of 350 to 450 deniers.
  • the scouring pad may have a border sewing line.
  • the border sewing thread may be biodegradable polyester filament yarn, and preferably, may be poly-lactic acid.
  • the present disclosure also provides the scouring pad for washing dishes further comprising a sponge.
  • an environmentally-friendly scouring pad for washing dishes which exhibits excellent cleaning power and forms bubbles better even without abrasives, does not cause scratches of surfaces of dishes, and naturally degrades when being discarded.
  • a scouring pad for washing dishes comprises (a) a plurality of degradable polyester divided yarns 20 heat-treated at 120°C to 170°C and (b) a plurality of degradable polyester filament yarns 10, wherein the individual filament yarns 10 are aligned in parallel to each other and the individual divided yarns 20 are positioned between the adjacent two filament yarns 10 and are connected to the adjacent two filaments 10.
  • the filament yarns 10 correspond to basic frames of the pad, and the divided yarns 20 are positioned next to the filament yarns.
  • a fiber may be divided into cotton yarn and filament yarn according to a length and a manufacturing method thereof.
  • the cotton yarn is manufactured by performing a cotton carding process of evenly engaging and arranging single fibers, such as cotton, linen, and wool, in a direction of a fiber axis several times, and twisting the single fibers at the last stage.
  • the filament yarn is manufactured by combining several strands of infinitely long fibers (filament yarn), such as a silk fiber or an artificial fiber, side by side, and twisting the fibers.
  • biodegradable polyester may be used as the filament yarn.
  • the biodegradable polyester may be derived and obtainable from nature, such as biomass, and thus is a naturally degradable environmentally-friendly material.
  • poly-lactic acid may be used as the biodegradable polyester.
  • the biodegradable polyester filament yarn may also be used for forming a basic frame of the scouring pad, but may be used for forming a border sewing thread.
  • the border sewing thread formed of the biodegradable polyester filament yarn is more environmentally-friendly, compared to a border sewing thread formed of a non-biodegradable fiber, such as nylon.
  • the filament yarn forms the basic frame
  • the biodegradable polyester particularly, poly-lactic acid
  • a thickness of, for example, 350 to 650 deniers When the thickness of the biodegradable polyester filament yarn has lower than 350 deniers, it is difficult to maintain an intensity of the biodegradable polyester filament yarn.
  • the thickness of the biodegradable polyester exceeds 650 deniers, the scouring pad is stiff, such that flexibility deteriorates.
  • the filament yarn forms the border sewing thread of the scouring pad
  • the biodegradable polyester particularly, poly-lactic acid
  • a thickness of, for example, 800 to 1200 deniers When the thickness of the biodegradable polyester filament yarn has lower than 800 deniers, the intensity thereof is weak, so that there are concerns regarding unraveling of the sewing thread.
  • the biodegradable polyester filament yarn exceeds 1,200 deniers, cost is increased, thereby degrading economical feasibility, and the scouring pad becomes stiff, thereby degrading flexibility.
  • the divided yarn refers to filament yarn obtained by applying static electricity to the multifilament, and then opening the multifilament (spreading a bundle of fibers and making the spread fibers sparse) to be divided. It is more economical to make thread by dividing the multifilament as described above, compared to making thin thread from the beginning.
  • biodegradable polyester heat-treated at 120°C to 170°C, and preferably at 130°C to 160°C may be used as the divided yarn.
  • poly-lactic acid heat-treated at 120°C to 170°C, preferably at 130°C to 160°C may be used.
  • the divided yarn may be broken when temperature of the heat treatment exceeds 170°C, and the divided yarn may not be hard under the heat treatment at the temperature lower than 120°C.
  • the biodegradable polyester used as the divided yarn provides excellent cleaning power, and exhibits an excellent effect of forming bubbles even without abrasives. The reason seems to be that many air-contact surfaces exist between the divided yarn fibers, and that bubbles are stored in the air contact surfaces, so that the bubbles are maintained for a longer time.
  • a thickness of the heat-treated biodegradable polyester is 550 to 650 deniers, and polylactic acid divided yarn with 23 to 30 fils is preferably used as the heat-treated biodegradable polyester.
  • the divided yarn having the aforementioned thickness prevents foreign materials, such as rice paste, from being easily stuck in a scouring pad in a process of washing dishes, and allows the scouring pad to be easily dry and simultaneously prevents germs from easily living.
  • the scouring pad according to the present disclosure has the aforementioned divided yarn structure, thereby preventing minimal scratches on the surfaces of dishes, which are targets for cleaning.
  • the reason is that the scouring pad according to the present disclosure does not include an abrasive film, contrary to the conventional scouring pad.
  • the filament yarn may be manufactured by a common method widely known to the field.
  • the filament yarn may be manufactured by spinning a PLA fiber extracted from corn.
  • the filament yarn formed of 100% of poly-lactic acid may be manufactured.
  • the filament yarn manufactured may have excellent durability and excellent biodegradability, thereby securing basic mechanical performance as a scouring pad.
  • the manufactured filament yarn is formed of a natural component, so that the manufactured filament yarn may naturally degrade in land even when the manufactured filament yarn is discarded after it is used.
  • the filament yarn is woven to a PLA mesh net by a spinning process.
  • the divided yarn and the filament yarn are woven by a comed method, which is a method in which the divided yarns connect the filament yarns in a zigzag manner in a state that the filament yarns form a basic frame.
  • the manufactured mesh net has a shape of a checkerboard having openings (see FIG. 3 ).
  • the scouring pad manufactured by the present disclosure may have one layer, or may have a structure in which two scouring pads enclose sponge in a sandwiched shape while having the sponge interposed therebetween.
  • the sponge may be manufactured from bean produced from nature as a raw material. Accordingly, the scouring pad having the sandwiched shape may be an environmentally-friendly product.
  • Filament yarn with 100% of poly-lactic acid was manufactured by spinning a PLA fiber extracted from corn.
  • the manufactured filament yarn was woven to a PLA mesh net by a spinning process. Details of the manufactured PLA mesh net are represented in Table 1 below.
  • Table 1 Fiber Material Function and role Denier Filament yarn 100% PLA Basic frame 400 Divided yarn 100% PLA Strong cleaning power Form sufficient bubbles 600, 25 fils Filament yarn 100% PLA Sewing 1000
  • FIG. 2 A full sized picture of the sample manufactured in the example is represented in FIG. 2
  • FIG. 3 A partially enlarged picture of the sample manufactured in the example is represented in FIG. 3 .
  • FIG. 4 A picture of the samples of the example and comparative examples 1 to 5 is represented in FIG. 4 .
  • the first row shows the full sized pictures of the respective samples
  • the second row shows the partially enlarged pictures of the respective samples.
  • the result of the cleaning power test is represented in FIG. 5 .
  • the sample according to the example exhibits excellent bubble forming performance, compared to the samples of comparative examples 2 to 5, and exhibits the same level of bubble forming performance as that of the sample of comparative example 1.
  • the result of the test is represented in FIG. 6 .
  • the sample according to the example exhibits little scratches compared to the samples of Comparative Examples 1 to 5.
  • FIG. 7a shows a state in which oil is adsorbed to the sample according to the example when taken from a top.
  • FIG. 7B shows a state in which oil is adsorbed to the sample according to the example when taken from a side.
  • the sample according to the example exhibits an excellent oil adsorption ratio compared to the samples of comparative examples 1 to 3.
  • a component of a sewing thread of the sample of comparative example 4 is nylon, so that the sample is not biodegradable.
  • the sample of comparative example 4 is formed of the second component of the PLA film, but is not formed of the divided yarn, thereby having a problem of causing scratches.
  • the sample of Comparative Example 5 uses the PLA fiber which is not heat-treated, so that cleaning power deteriorates.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Knitting Of Fabric (AREA)

Claims (10)

  1. Tampon à récurer pour le lavage de la vaisselle, comprenant :
    (a) une pluralité de fils divisés de polyester dégradables (20) traités thermiquement à une température de 120 °C à 170 °C et
    (b) une pluralité de fils de filaments de polyester dégradables (10), dans lequel les fils de filaments individuels (10) sont alignés en parallèle les uns aux autres et les fils divisés individuels (20) sont positionnés entre les deux fils de filaments adjacents (10) et sont reliés aux deux filaments adjacents.
  2. Tampon à récurer selon la revendication 1, dans lequel (a) les fils divisés sont les fils divisés traités thermiquement à une température de 130 °C à 160 °C.
  3. Tampon à récurer selon la revendication 1 ou 2, dans lequel (a) les fils divisés sont formés d'acide polylactique.
  4. Tampon à récurer selon la revendication 1, dans lequel (b) les fils de filaments sont formés d'acide polylactique.
  5. Tampon à récurer selon la revendication 1, ayant une ligne de couture de bordure.
  6. Tampon à récurer selon la revendication 5, dans lequel la ligne de couture de bordure est formée de fils de filaments de polyester biodégradables.
  7. Tampon à récurer selon la revendication 6, dans lequel la ligne de couture de bordure est formée d'acide polylactique.
  8. Tampon à récurer selon la revendication 1, dans lequel (a) les fils divisés ont une épaisseur de 550 à 650 deniers, et sont formés de 23 à 30 filaments.
  9. Tampon à récurer selon la revendication 1, dans lequel (b) les fils de filaments ont une épaisseur de 350 à 450 deniers.
  10. Tampon à récurer selon la revendication 1, comprenant en outre une éponge.
EP14823762.1A 2013-07-12 2014-07-09 Tampon à récurer pour le lavage de la vaisselle Active EP3019652B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020130082366A KR102104135B1 (ko) 2013-07-12 2013-07-12 설거지용 수세미
PCT/US2014/045904 WO2015006415A1 (fr) 2013-07-12 2014-07-09 Tampon à récurer pour laver la vaisselle

Publications (3)

Publication Number Publication Date
EP3019652A1 EP3019652A1 (fr) 2016-05-18
EP3019652A4 EP3019652A4 (fr) 2017-04-19
EP3019652B1 true EP3019652B1 (fr) 2018-08-22

Family

ID=52280555

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14823762.1A Active EP3019652B1 (fr) 2013-07-12 2014-07-09 Tampon à récurer pour le lavage de la vaisselle

Country Status (6)

Country Link
US (1) US20160106291A1 (fr)
EP (1) EP3019652B1 (fr)
KR (1) KR102104135B1 (fr)
CN (1) CN105358752B (fr)
MX (1) MX356670B (fr)
WO (1) WO2015006415A1 (fr)

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KR20160144700A (ko) * 2015-06-09 2016-12-19 쓰리엠 이노베이티브 프로퍼티즈 컴파니 수세미
US20190000293A1 (en) * 2016-09-12 2019-01-03 Naturezway, Inc. Compostable and biodegradable scrubbing sponge
US10915856B2 (en) 2017-10-16 2021-02-09 Florence Corporation Package management system with accelerated delivery
US11144873B2 (en) 2017-10-16 2021-10-12 Florence Corporation Package management system with accelerated delivery
US11410118B2 (en) 2018-06-01 2022-08-09 Florence Corporation Package management system
KR102284215B1 (ko) 2018-09-28 2021-07-30 주식회사 플로스코리아 세제가 도포된 생분해성 일회용 수세미 및 이를 제조하는 방법
USD954481S1 (en) 2019-12-13 2022-06-14 Florence Corporation Double walled locker door
US11529011B2 (en) 2019-06-11 2022-12-20 Florence Corporation Package delivery receptacle and method of use
KR102392213B1 (ko) * 2021-07-23 2022-04-29 (주)유진 친환경 수세미의 제조방법 및 이에 따라 제조된 친환경 수세미
KR102610358B1 (ko) * 2022-01-03 2023-12-05 동의대학교 산학협력단 생분해성 일회용 수세미 및 이의 제조방법
USD1004873S1 (en) * 2023-06-01 2023-11-14 Giant Media Network Culture (Shenzhen) Co., Ltd. Mop pad

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Also Published As

Publication number Publication date
WO2015006415A1 (fr) 2015-01-15
MX356670B (es) 2018-06-08
CN105358752B (zh) 2017-06-09
KR102104135B1 (ko) 2020-04-23
MX2016000361A (es) 2016-04-28
EP3019652A4 (fr) 2017-04-19
CN105358752A (zh) 2016-02-24
KR20150007830A (ko) 2015-01-21
US20160106291A1 (en) 2016-04-21
EP3019652A1 (fr) 2016-05-18

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