EP2953739A1 - Verfahren und vorrichtung zum reinigen von innenräumen von behältern und anlagen - Google Patents
Verfahren und vorrichtung zum reinigen von innenräumen von behältern und anlagenInfo
- Publication number
- EP2953739A1 EP2953739A1 EP14705470.4A EP14705470A EP2953739A1 EP 2953739 A1 EP2953739 A1 EP 2953739A1 EP 14705470 A EP14705470 A EP 14705470A EP 2953739 A1 EP2953739 A1 EP 2953739A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- outlet
- explosive mixture
- feed pressure
- pressure line
- cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 178
- 238000000034 method Methods 0.000 title claims abstract description 60
- 239000002360 explosive Substances 0.000 claims abstract description 227
- 239000000203 mixture Substances 0.000 claims abstract description 226
- 238000004880 explosion Methods 0.000 claims abstract description 57
- 238000005516 engineering process Methods 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims description 22
- 230000015572 biosynthetic process Effects 0.000 claims description 17
- 238000009434 installation Methods 0.000 claims description 10
- 230000007704 transition Effects 0.000 claims description 4
- 230000000977 initiatory effect Effects 0.000 claims description 3
- 239000008246 gaseous mixture Substances 0.000 abstract description 9
- 239000007789 gas Substances 0.000 description 98
- 239000002826 coolant Substances 0.000 description 26
- 238000001816 cooling Methods 0.000 description 23
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 17
- 239000001301 oxygen Substances 0.000 description 17
- 229910052760 oxygen Inorganic materials 0.000 description 17
- 230000008569 process Effects 0.000 description 13
- 238000011049 filling Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 238000005192 partition Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 5
- 238000010790 dilution Methods 0.000 description 5
- 239000012895 dilution Substances 0.000 description 5
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 4
- 239000003570 air Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 239000003546 flue gas Substances 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000035939 shock Effects 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 239000012527 feed solution Substances 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- 239000012080 ambient air Substances 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000005474 detonation Methods 0.000 description 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000589614 Pseudomonas stutzeri Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000012611 container material Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
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- 230000002349 favourable effect Effects 0.000 description 1
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- 230000000149 penetrating effect Effects 0.000 description 1
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- 238000003825 pressing Methods 0.000 description 1
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- 239000001294 propane Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
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- 238000005488 sandblasting Methods 0.000 description 1
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- 238000003260 vortexing Methods 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B7/00—Cleaning by methods not provided for in a single other subclass or a single group in this subclass
- B08B7/0007—Cleaning by methods not provided for in a single other subclass or a single group in this subclass by explosions
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B37/00—Component parts or details of steam boilers
- F22B37/02—Component parts or details of steam boilers applicable to more than one kind or type of steam boiler
- F22B37/48—Devices for removing water, salt, or sludge from boilers; Arrangements of cleaning apparatus in boilers; Combinations thereof with boilers
- F22B37/54—De-sludging or blow-down devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28G—CLEANING OF INTERNAL OR EXTERNAL SURFACES OF HEAT-EXCHANGE OR HEAT-TRANSFER CONDUITS, e.g. WATER TUBES OR BOILERS
- F28G1/00—Non-rotary, e.g. reciprocated, appliances
Definitions
- the invention relates to the field of cleaning of interiors of containers and equipment. It relates to a method and a cleaning device for removing deposits in the interior of containers and plants by means of explosion technology.
- the cleaning device is designed in particular for carrying out the method according to the invention.
- the method and the device are used in particular for the cleaning of dirty and garbage containers and equipment with caking on the inner walls, in particular of incinerators.
- Heating surfaces z. B. of waste incineration plants or generally of combustion boilers are generally subject to heavy pollution. These contaminants have inorganic compositions and typically result from deposition of ash particles on the wall. Coatings in the range of high flue gas temperatures are usually very hard, since they either remain melted or fused onto the wall or are glued together by lower-melting or condensing substances as they solidify on the colder wall of the boiler. Such deposits are difficult and insufficient to remove by known cleaning process. As a result, the boiler must be periodically shut down and cooled for cleaning. Since such boilers usually have quite large dimensions, this is often the structure of a Scaffolding in the oven necessary.
- a cleaning method in which the cooled or the operating, hot boiler is cleaned by introducing and igniting explosive devices.
- a cooled explosive device is brought by means of a cooled lance in the vicinity of the soiled heating surface, where the explosive charge is ignited.
- the heating surface caking is blown off by the force of the detonation and by the wall vibrations generated by the shock waves.
- the cleaning time can be significantly reduced with this method compared to the conventional cleaning methods.
- the cleaning can take place with the necessary safety precautions during the operation of the incinerator or even in the hot condition of the container. So it is possible to clean a boiler in this way within hours and without interruption of operation, which are needed with a conventional cleaning method days.
- EP 1 067 349 A disadvantage of the process described in EP 1 067 349 is the need for explosives. In addition to the high cost of the explosives must be operated to avoid accidents or theft, for example, during storage of the explosive, a large security effort.
- the introduction of Explosive material in a hot container also requires a completely reliable and efficient cooling system to prevent premature detonation of the explosive.
- a further cleaning method is known, which also uses the means of explosion generation.
- an inflatable container with an explosive gas mixture container shell is attached to the end of a cleaning lance.
- the cleaning lance is introduced together with the empty container shell into the boiler room and positioned near the point to be cleaned.
- the container shell is inflated with an explosive gas mixture.
- an explosion is generated whose shock waves lead to the detachment of dirt on the boiler walls.
- the container shell is shredded and burned by the explosion. It therefore represents commodity.
- This method and the associated device have the advantage over the above-mentioned explosive blasting technology that the method is favorable in operation. So z.
- a gas mixture comprising oxygen and a combustible gas, compared to explosive cost.
- the procurement and handling of said gases unlike explosives, does not require any special permits or qualifications so that anyone with appropriate training can perform the procedure.
- the starting components are supplied via separate supply lines of the cleaning lance and the dangerous explosive lahige gas mixture is therefore produced only in the cleaning lance shortly before the explosion.
- explosives is namely dealing with the individual components of the gas mixture much less dangerous, since these are the single highest combustible but not explosive.
- the associated method has the disadvantage that the handling of the container shell is quite cumbersome.
- a container casing must be fastened in each case via the outlet opening of the cleaning device.
- This process is also quite time consuming, so that the individual cleaning processes each take a comparatively long time.
- the BelüHungsvorgang is comparatively slow. This is due to the fact that the explosive mixture can be introduced into the container envelope only at a relatively low filling rate so that it can unfold and expand in a controlled manner without damaging it. If the explosive mixture is admitted into the container casing at high speed, it is contracted by the generated negative pressure and does not expand. Furthermore, even individual layers of the container casing can be peeled off on the inside.
- the expanded container shell can not be introduced into narrow areas, such as those present in tube bundles. This means that the explosive mixture can not be conducted into the narrow areas to be cleaned on site and exploded there. Rather, the explosive mixture can only be ignited from outside these areas, with the explosion waves penetrating into the narrow areas ensuring a limited cleaning effect.
- the cleaning method disclosed in connection with the invention is based on bringing an explosive mixture in the vicinity of a point to be cleaned, in order then to cause the mixture to explode.
- the explosive mixture is gaseous at least in the explosive state.
- the explosive mixture can be formed from a gaseous component introduced into the cleaning device.
- the explosive mixture of two or more, and in particular two, separately introduced into the cleaning device, gaseous components are formed.
- the gaseous components are mixed together in the cleaning device in a mixing zone to the explosive, gaseous mixture.
- the mixing zone is arranged in particular in front of or in the feed pressure line.
- Gaseous components means that they are gaseous in the formation of the explosive mixture in the receiving space and in particular already during the introduction into the cleaning device.
- the gaseous components also called starting components, may be in pressure vessels under pressure in liquid form.
- the gaseous component may in particular be a rapidly evaporating liquid.
- the explosive mixture contains in particular a fuel and an oxidizing agent, such as. As gaseous oxygen or an oxygen-containing gas.
- the fuel may be liquid or gaseous.
- the explosive mixture is provided in particular in the receiving space of the cleaning device.
- the mixture is ignited in particular via an ignition device.
- the force of the explosion and the surface vibrated by the shock waves such as a container or pipe wall, cause the cracking off of the wall caking and slagging and thus the cleaning of the surface.
- the strength of the explosion required for cleaning, and thus the amount of gaseous components used to produce the explosive mixture depends on the type of contamination and the size and type of contaminated container.
- the dosage and strength of the explosion can be and are preferably chosen so that no damage to installations. The possibility of optimally dosing the substances used reduces on the one hand the cleaning costs, on the other hand the danger and damage risk for plant and persons.
- the cleaning device contains, in particular, a feed pressure line, also called feed line, via which the explosive mixture is conducted to an outlet opening.
- the feed pressure line forms a closed feed channel, also called a feed channel.
- This may form a circular cross section and have a diameter of 150 mm (millimeters) or less, or 100 mm or less, or 60 mm or less, and more preferably 55 mm or less.
- the diameter may also be 20 mm or greater, or 30 mm or greater, in particular 40 mm or greater.
- the length of the feed pressure line may, for. 1 m (meter) or more, or 2m or more, or 3m or more, or 4m or more.
- the cleaning device in particular contains an outlet device, which contains the outlet opening.
- the outlet device is arranged in the outflow direction, in particular downstream of the feed pressure line.
- the outlet device forms a receiving space for receiving at least part of the supplied explosive mixture.
- the feed pressure line and the outlet device form a receiving space for receiving at least part of the supplied explosive mixture.
- the receiving space is open in particular via the outlet opening to the outside.
- the explosive mixture is z. B. in the receiving space, especially in the feed pressure line, exploded.
- the explosion pressure wave propagates through the outlet opening into the interior of the plant or the container.
- Such a method with the associated device can be used, for example, for purifying catalysts in flue gas purification devices.
- the exiting through the outlet opening of the cleaning device explosion pressure waves act on the catalyst and solve soiling.
- the outlet opening is z. B. during ignition and explosion of the explosive mixture to the outside.
- the outlet opening is open to the outside, in particular during the ignition and explosion of the explosive mixture.
- the outlet opening is open in particular during the introduction of the explosive mixture into the receiving space to the outside.
- the outlet opening is open to the outside, in particular during a complete cleaning cycle, comprising the introduction of an explosive mixture and the ignition and explosion of the explosive mixture.
- the outlet opening can in particular be non-closable.
- the total volume of explosive mixture is formed at least by the volume of explosive mixture in the receiving space.
- the outlet opening may be closed during the introduction of the explosive mixture into the receiving space.
- the outlet opening may be closed by means of a cover.
- the cover is z. B. mountable.
- the cover can be flexible or rigid.
- the cover can be made of plastic.
- the cover may be plate-like.
- the cover may be designed such that it is destroyed by the explosion of the explosive mixture and thus releases the way for the explosion pressure wave through the outlet opening to the outside.
- the total volume of explosive mixture is formed here exclusively by the volume of explosive mixture in the receiving space.
- the total volume of explosive mixture comprises the volume of explosive mixture in the receiving space of the cleaning device and the volume of formed outside the cleaning device cloud of explosive mixture.
- the cloud is characterized in particular by the fact that they are not exposed to the ambient atmosphere in the interior via physical means or via a barrier such. B. a container shell is delimited. Rather, the edge area of the cloud is in direct contact with the ambient atmosphere.
- the total volume of the explosive mixture is controlled via an ignition device in the receiving space and in particular in the feed pressure line to ignite. If the total volume of the explosive mixture comprises a cloud, this too, together with the volume in the receiving space, is controlled to explode via the ignition device.
- the ignition-effective component of the ignition device is arranged in particular in the cleaning appliance.
- the ignition-effective component of the ignition device is arranged, for example, in the feed pressure line or is at least in operative connection therewith.
- the named period comprises in particular the introduction of the explosive mixture into the receiving space.
- the said period of time is calculated in particular by opening the metering device (s) described below for introducing the at least one gaseous component into the feed pressure line of the cleaning device until the closing of the metering device (s) to terminate the introduction.
- the ignition and consequently the explosion of the explosive mixture is adjusted in terms of control technology in particular to the time of closing the metering device (s).
- the ignition takes place in particular directly on the closing of the metering valves. In particular, the ignition has at most a very short delay.
- the period of time between the opening of the metering valve (s) for the purpose of introducing the at least one gaseous component and the ignition of the explosive mixture is therefore also in particular in the above-described period.
- the lower limit of this period is technically determined in particular by the arrangement and switchability of the metering device (s) for introducing the at least one gaseous component into the cleaning device.
- the at least one gaseous component is introduced into the cleaning device via the at least one metering device, in particular at such a high speed, that the explosive mixture in the supply pressure line forms a pressure front, also called a shock front.
- the pressure front exposes the boundary between the explosive mixture behind the pressure front and the ambient atmosphere in front of the pressure front.
- the explosive mixture has in the flow direction behind the pressure front in particular an overpressure.
- the overpressure corresponds to the pressure difference between the actual pressure and the (atmospheric) ambient pressure.
- This overpressure may be 0.5 bar or more, or 1 bar or more, and more preferably 2 bar or more.
- the overpressure may also be 2.5 bar or more or even 3 bar or more.
- the ignition of the explosive mixture takes place in particular in the aforementioned overpressure conditions.
- the introduction of the gaseous components under pressure and correspondingly high density allows to provide a high mass of explosive mixture within a very short time. That is, the erfmdungsgemässe method allows to initiate a large mass flow in a very short time in the cleaning device and ignite.
- the explosion performance also becomes higher density of the explosive mixture at a constant volume correspondingly larger.
- the pressure front pushes the surrounding layer in the flow direction in front of it.
- the pressure front in particular discharges the ambient air via the outlet opening out of the cleaning device.
- mixing between the explosive mixture and the ambient air in the feed pressure channel or in the outlet device remains or remains minimal.
- the explosive mixture and with it the pressure front can move towards the outlet opening at a speed of 100 m / s or more, in particular of 200 m / s or more, or flow towards it.
- the explosion pressure is in each case a multiple of the pressure of the explosive mixture before the explosion.
- the explosion pressure may be, for example, 25 times the outlet pressure. If the explosive mixture now has an overpressure, the explosion pressure also increases by the corresponding multiple.
- the explosion pressure corresponds to a 25-fold gain of around 25 bar.
- the explosive mixture has a pressure of 2 bar (in the overpressure range, higher density)
- the explosion pressure already equals approximately 50 bar with a gain of 25 times. Accordingly, the Explosion pressure and thus the cleaning effect much higher, if the set for ignition explosive mixture in the cleaner has an overpressure.
- the explosive mixture is ignited when the pressure front is still in the feed pressure line.
- the explosive mixture is ignited when the pressure front is still in the outlet device.
- the cloud of explosive mixture at the time of ignition is not yet formed or not fully formed.
- the cloud can only be formed or finished when the explosive mixture is ignited.
- the explosive mixture can be expelled from the outlet opening by the explosive pressure wave propagating in the feed pressure line in the direction of the outlet opening with the formation of the explosive cloud and be immediately exploded.
- An explosion cycle can be divided into different cycles, similar to an internal combustion engine.
- the metering valve (s) is opened to the feed pressure line and the at least one gaseous omponent is, for. B. from at least one pressure vessel, introduced into the cleaning device with pressure and passed as explosive, gaseous mixture via the feed pressure line to the outlet. If necessary, the cloud is formed via the outlet device outside the outlet opening.
- the at least one metering valve After introducing the predetermined amount of gaseous component, the at least one metering valve is closed. The ignition is then activated and the entire volume of explosive mixture formed is exploded. Following the explosion, you can reopen the At least one metering again a gaseous, explosive mixture can be generated in the receiving space.
- pulsed explosions can also be generated by the method according to the invention. That is, it is at short intervals in a row z. B. each corresponding total volumes of explosive mixture produced and exploded. It can z. B. one second or more explosions are generated. So it is possible to generate 2 to 10 explosions within one second. Furthermore, pulsed explosions can produce vibrations in the system or in the container, which lordern the cleaning process.
- the method for generating pulsed explosions also has the advantage that several total volumes of explosive mixture, each comprising one cloud, can be generated in succession in a short time. The volumes of these clouds can be dimensioned smaller in comparison to the generation of individual clouds at a greater time interval from each other.
- the clouds of pulsed explosions can, for. B. have a volume of 1 to 5 liters. Bigger clouds are also possible.
- the losses due to demixing in the edge zones, especially in the case of strong flow in the ambient atmosphere, are smaller, so that a comparatively high explosive force is achieved despite the smaller size of the cloud.
- the risk of auto-ignition at high temperatures is much lower.
- the generation of smaller clouds also has the advantage that the cleaning device can be made smaller.
- the formation of the explosive mixture in the feed pressure line is accompanied by the formation of the cloud from the explosive mixture at the outlet from the outlet opening of the cleaning device at the end of the feed pressure line. The shorter this period, the lower the degree of mixing of the cloud with the ambient atmosphere in the interior of the container or the system in the ignition of the mixture.
- the degree of mixing of the explosive mixture emerging from the outlet opening with the ambient atmosphere does not only depend on the time span over which the formation of the cloud and the subsequent ignition extend.
- the geometry of the outlet device which adjoins the at least one feed pressure line and which forms at least one outlet opening is also decisive.
- the erfmdungsgemässe cleaning device includes a feed pressure line and arranged at the end of the feed pressure line outlet with at least one outlet opening.
- the feed pressure line and the outlet device form z. B. a receiving space for receiving at least a portion of the introduced explosive mix.
- the recording room is z. B. over the at least one outlet opening to the outside.
- the cleaning device and in particular its outlet device is z. B. designed to introduce the explosive mixture into the interior of the container or the system and to form a cloud of the explosive mixture in the interior of the container or the system.
- the cross-sectional area of the at least one outlet opening is preferably greater than the cross-sectional area of the feed pressure channel of the at least one feed pressure line.
- the outlet device may also contain a plurality of outlet openings. Furthermore, a plurality of feed pressure lines can also be led to the outlet device.
- the outlet device contains in particular one or a plurality of outlet bodies, which form the outlet opening or the outlet openings.
- the outlet body is a component which forms a flow channel for the explosive mixture, which opens in the outlet opening.
- the outlet opening refers to the transition from the cleaning device to the interior of the container or the system in which the outflowing explosive mixture is no longer passed through the cleaning device.
- the outlet body or its flow channel are part of the receiving space for the explosive mixture.
- the outlet bodies can be supplied with the explosive mixture by means of common or separate feed pressure lines. Accordingly, the outlet can be connected to one or more supply pressure lines be.
- the outlet device may also contain line branches, which lead the explosive mixture to the individual outlet bodies.
- a feed pressure line can also be guided into a distributor space, from which the explosive mixture is supplied via passages to the individual outlet bodies.
- the distributor space can be designed, for example, spherical or hemispherical.
- One or more flow guide elements can be arranged in the distributor space. Such a flow guide can, for. B. be designed as a baffle ball.
- the total cross-sectional area of the outlet openings is preferably larger than the cross-sectional area of the feed pressure channel or larger than the total cross-sectional area of the feed pressure channels.
- the total cross-sectional area of the passages in the distributor space can be from slightly larger to slightly smaller than the cross-sectional area of the feed pressure channel or as the total cross-sectional area of the feed pressure channels.
- the outlet device or its outlet body, which comprises the outlet opening, is preferably designed as a diffuser.
- the diffuser also forms part of the receiving space for an explosive mixture.
- the outlet device contains a plurality of outlet bodies, these may also have a cylindrical shape or another geometric shape.
- the outlet device or its outlet body may be formed as an end portion of the feed pressure line.
- a diffuser is a component that slows gas flows. It is characterized by an increase in cross section starting from the feed pressure line. extension to the outlet opening out. This cross-sectional enlargement is preferably continuous.
- the diffuser is in principle the reversal of a nozzle.
- the design of the end portion of the feed pressure line as a diffuser or the outlet of the outlet as a diffuser allows without this through a container shell must be protected.
- the diffuser causes a change in the introduction speed from a high value in the feed pressure line to a lower value in the region of the at least one outlet opening. Due to the slowing down of the explosive mixture towards the outlet opening, the vortex formation and thus the mixing of the mixture with the ambient atmosphere immediately after the outlet opening is prevented or at least considerably reduced.
- the explosive mixture is nevertheless supplied to the outlet device at comparatively high speed and under elevated pressure via the feed pressure line. This allows z. B. a rapid formation of the cloud in the interior. The same effect also allows fast filling of the receiving space with an explosive mixture.
- the gaseous components of the explosive mixture entering the diffuser from the feed pressure channel expand due to the increase in cross-section.
- a cooling of the explosive mixture is achieved.
- This cooling effect is advantageous in the formation of the cloud, since the temperature of the forming cloud in the interior is significantly lower than the autoignition temperature. This also reduces the risk of self- Ignition or ignition of the cloud through the hot ambient atmosphere in the interior of the container or the system reduced or excluded.
- a cloud generated by the inventive method is not ignited from an explosive mixture in the interior of a combustion system, even if the ambient temperature in the interior is far above the autoignition temperature. This is due, as mentioned, to the fact that, on the one hand, the cloud is formed and ignited in comparison to the filling of a container shell, so that it can not heat above the auto-ignition temperature in the interior and, on the other hand, is not mixed with the ambient atmosphere.
- the diffuser contains in particular a funnel-shaped extension or consists of such.
- the diffuser is made in particular of metal. It can be made of sheet metal, such as sheet steel.
- the funnel-shaped diffuser can, for. B. be formed collapsible to its longitudinal axis. In this way, the outlet of the cleaning device can be guided through a narrow opening in the interior and unfold there. To pull the outlet from the interior of the funnel-shaped diffuser is folded back to its longitudinal axis.
- the flow cross-section can be continuously increased, in particular starting from the feed pressure channel to the outlet opening.
- the feed pressure line goes to the outlet port z. B in a funnel-shaped expansion over. This transition is z. B. continuously.
- the feed pressure channel can have a constant cross section.
- the cross section of the feed pressure channel can also increase towards the outlet device.
- the cross-sectional enlargement can be continuous.
- the cross section in a defined section in the mixing zone increases.
- the cross-sectional enlargement can be divergent.
- the opening angle of the diffuser is preferably 45 ° (degrees) or smaller, preferably 30 ° or smaller, and more preferably 20 ° or smaller.
- the said opening angle may in particular also be 15 ° or smaller or even 10 ° or smaller.
- the opening angle corresponds to the angle between the longitudinal axis of the feed pressure line and the opening axis of the funnel-shaped extension.
- the opening axis connects the outermost in the direction of the longitudinal axis points of the funnel-shaped extension at the height of the outlet opening with that point at the feed pressure channel at which the feed pressure channel opens into the funnel-shaped extension.
- the ratio of the length of the diffuser to the largest diameter of the outlet opening is 2: 1 or more, and preferably 3: 1 and in particular 5: 1 or more.
- the length of the diffuser is measured along the longitudinal axis.
- the ratio of the largest diameter of the outlet opening to the inner diameter of the feed pressure line is 3: 1 or more, and in particular 5: 1 or more.
- the funnel-shaped extension at least approximately corresponds to an exponential funnel.
- the transverse sectional area of an exponential funnel is preferably described by an exponential function:
- a (x) A h ⁇ e kx
- A is the area cross section of the funnel neck
- k is the funnel constant or the opening dimension of the funnel
- a (x) is its area cross section at a distance X from the funnel neck.
- a swirling element is arranged in the diffuser.
- the turbulence element serves to additionally reduce the flow velocity in the diffuser before the mixture leaves the mixture.
- the outlet device may be configured to form a plurality or a common cloud of the explosive mixture.
- the outlet openings of a plurality of outlet bodies may be oriented in different spatial directions.
- the outlet body can be aligned with its outlet openings, for example, from a center or a center axis radially outward.
- the outlet bodies can in particular be aligned radially outwards from a center in different spatial directions.
- the different spatial directions may be in two dimensions, i. in one plane, or in three dimensions.
- outlet openings be directed radially outward from a center, the outlet openings defining a spherical or hemispherical outlet surface; - In a plane, ie, for example, be arranged disc-shaped from a center radially outward, wherein the outlet openings define an annular outlet surface; or
- outlet openings define a cylindrical outlet surface
- the outlet openings are always arranged radially outwards.
- All of the described outlet devices can be arranged on a cleaning-side end of a cleaning lance as described in the general description part and in particular in FIGS. 1 and 2.
- the explosive mixture conducted to the outlet device can be directed into the interior of the container or the system via a plurality of such outlet elements, forming a common cloud or several adjacent clouds.
- the outlet device this is constructed so that the gas flow undergoes a deflection by 90 ° from the longitudinal direction to the side.
- the at least one outlet opening is directed to the side.
- the outlet device is in particular T-shaped, with two outlet openings directed to the side.
- the gas stream divides in the outlet and is deflected by 90 ° to the side.
- at least one gaseous component from at least one pressure vessel is introduced into the cleaning device via at least one metering valve with overpressure.
- Pressure sensors for measuring the pressure in or in the pressure vessels may be provided on the pressure vessel (s).
- a first and second gaseous component from in each case at least one pressure vessel via each at least one metering device can be introduced separately into the cleaning device.
- gaseous components are introduced into the cleaning device, in particular in a stoichiometric ratio.
- the at least one metering device serves for metered introduction of the at least one gaseous component into the cleaning device.
- the metering valves are in particular valves.
- the valves can be solenoid valves.
- the at least one gaseous component can be introduced directly or indirectly via at least one inlet channel on the cleaning device in the feed pressure line.
- the pressure vessels may, for example, have a maximum pressure at the beginning of the introduction of several bars, such as 10 bar or more, and in particular 20 bar or more. Thus, a pressure of 20 to 40 bar can be provided. This allows the introduction of the gaseous component under high pressure and correspondingly at high speed in the cleaning device.
- the at least one gaseous component can be introduced at an average speed of over 50 m / s (meters per second), in particular of more than 100 m / s, advantageously of over 200 m / s.
- the average speed can be z. B. 200 to 340 m / s.
- the speed of sound is preferably not exceeded.
- the pressure vessels are not completely emptied, that is, to the ambient pressure.
- the residual pressure in particular has an overpressure.
- the residual pressure can z. B. 5 bar or more, in particular 1 0 bar or more, such as 10 to 15 bar, his. Thanks to the high residual pressure, high speeds can be achieved during initiation.
- the introduction of the at least one gaseous component can be carried out according to the principle of the differential pressure.
- the differential pressure method is characterized in that the residual pressure in the pressure vessel after completion of the introduction of the gaseous component is in the overpressure range.
- Overpressure is the pressure value which results from the difference between the pressure prevailing in the pressure vessel and the prevailing ambient pressure.
- the ambient pressure is in particular the pressure prevailing outside the pressure vessel.
- the ambient pressure is for example the atmospheric pressure. This means that the pressure vessel (s) are not emptied to ambient pressure.
- the control of the amount of gaseous component to be introduced can be done on the detection of the pressure in the pressure vessel.
- the quantity of gaseous component to be introduced starting from a known maximum pressure at the beginning of the introduction process, the corresponding desired residual pressure or differential pressure can be determined.
- the metering valve (s) are opened via the control device until the desired residual pressure is measured via the pressure sensor.
- the pressure sensor is connected to the control device accordingly.
- the control of the amount to be introduced which z. B. should be in the case of two or more gaseous components in the stoichiometric ratio, in particular on the opening time of the metering valves, so time-controlled happen.
- the gas velocity through the metering valve can be determined mathematically or empirically. From this a direct relationship between the opening time and the introduced gaseous component can be deduced.
- the predetermined opening time of the metering valves is controlled by the control device.
- a feed line for. B. in the form of a hose, connect to the metering valve.
- the feed line may be for the supply of the gaseous component from the pressure vessel.
- the feed line can be part of the pressure vessel for the gaseous component or even form this.
- the gaseous component is in this case in the feed line under pressure.
- the pressure can take the above values.
- It can be both the feed line for oxygen and for the combustible gas as a 'filing the pressure vessel or can be designed as a pressure vessel for the gas according to the manner described above.
- One, several or all gaseous components can be introduced in each case via one or more metering valves in the cleaning device. If a gaseous component is introduced into the cleaning appliance via a plurality of metering valves, then these metering valves can be connected to a common or to a different pressure vessel.
- the number of metering valves per gaseous component can also be determined by the stoichiometric ratio with which the gaseous components are introduced into the cleaning device. Furthermore, the flow-through cross-sections of the metering valves can also be in a stoichiometric relationship.
- the flow-through cross sections of the inlet channels can also be in a stoichiometric relationship to one another.
- the Dosieramiaturen may be downstream of the check valves in the flow direction, such as check valves. These protect the metering valves against a backlash, which can occur, for example, when the explosive mixture is ignited. Further, the check members also prevent the exchange of gaseous components between the pressure vessels.
- the check members are arranged in the flow direction, in particular in front of the feed pressure line. Instead of non-return devices can be arranged at the same place a device for feeding an inert gas such as nitrogen.
- the introduced inert gas forms a kind of buffer and prevents the heating of the metering valve by hot explosion gases.
- the introduced inert gas forms a gas barrier and prevents the exchange of gaseous components between the metering valves.
- the cleaning device preferably further includes an ignition device.
- the explosive mixture is preferably ignited in the feed pressure line or in the outlet device by means of the ignition device.
- the initiated explosion is transmitted from the cleaning device to the cloud from the explosive mixture outside the diffuser or to the explosive mixture in the receiving space of the outlet.
- the ignition of the explosive mixture is carried out by means known from the prior art. This is preferably done by electrically triggered Spark ignition, by auxiliary flames or by pyrotechnic ignition with the help of appropriately mounted ignition means and ignition device.
- the ignition device is in particular an electrical ignition device. This is characterized by the fact that it forms a spark for ignition or in particular an arc.
- the cleaning device contains in particular a control device.
- the control device serves inter alia, in particular, the control of the ignition device.
- the control device also serves, in particular, for controlling the metering valves for introducing the gaseous components into the cleaning device.
- the control device therefore serves to generate the explosive mixture, in particular to form the cloud.
- the control of the metering valves and the ignition device are in particular coordinated with one another in terms of control technology.
- the control device is in particular designed to open and close the metering valves within the stated time periods.
- the cleaning device for carrying out the method according to the invention may in particular be a longitudinal component, such as a cleaning lance. Such a cleaning lance is described, for example, in EP 1 362 213 B1. Many of the features and Ausftihrungssectionn mentioned therein, with respect to the structure of the supply and cooling line or the supply device, can therefore also be applied to the present patent application.
- the longitudinal component is z. B. formed as a tube-like device.
- the cleaning device in particular the longitudinal component, contains in particular an inlet-side and a cleaning-side end section, wherein at the cleaning side end portion of the outlet opening, is arranged.
- the outlet device is also arranged on the cleaning-side end section.
- the feed side end portion is that end portion at which the at least one gaseous component is introduced into the cleaning device. As this end section usually also faces the user, the expression of the user-side end section also applies if appropriate.
- the feed side end portion may form a handle portion over which the cleaner may be held by the user.
- the cleaning-side end portion is that end portion which faces the cleansing point.
- the feed side end portion comprises z. B. a metering device in which the explosive mixture is provided. At the metering device said metering valves for introducing the gaseous components or the mixture are arranged.
- the discharge-side end portion includes the discharge port, and particularly the discharge device. Between the metering device and the outlet opening or outlet device, the feed pressure line is arranged. This can be designed as a feed pressure line.
- the longitudinal component or the cleaning lance can have a length of one to several meters, z. B. from 4 to 10 m.
- the cleaning lance also contains at least one supply pressure line for receiving the explosive mixture.
- the at least one feed pressure line is preferably integrated into the structure of the longitudinal component.
- the longitudinal member may be formed tube-like for this purpose.
- the one or more feed pressure lines can also be used as separate lines outside or inside the longitudinal component and z. B. be guided along desselbigen.
- the metering valves for the supply of oxygen and the combustible gas are arranged, for example, on the longitudinal component, in particular on the supply-side end portion of the longitudinal component.
- the metering valves are in particular arranged such that they introduce the gaseous components directly or indirectly into the feed pressure line or feed pressure lines of the longitudinal component.
- the gaseous components are z. B. mixed in a mixing zone in the longitudinal component.
- metering valves are provided for the explosive mixture or for each gaseous component, these can be used, for example.
- B. be arranged in succession in the longitudinal direction of the longitudinal component.
- metering valves for each gaseous component can be arranged transversely to the longitudinal direction along the circumference of the associated inlet channel.
- the longitudinal component contains a gas guide tube, also called outer tube.
- the gas guide tube forms, for example, the feed pressure line with the feed pressure channel.
- an inner tube may be arranged in the gas guide tube.
- the inner tube forms a first introduction channel for a first gaseous component.
- a second, annular inlet channel for a second gaseous component is formed between the gas guide tube and the inner tube.
- the two tubes and corresponding to the inlet channels can be arranged concentrically with each other.
- the inner tube ends within the gas guide tube, so that the gas guide tube at the inner tube end merges into a feed pressure line.
- a first gaseous component in particular a combustible gas, is introduced into the first inlet channel via at least one first metering valve.
- a second gaseous component in particular an oxygen-containing gas, is introduced into the second inlet channel via at least one second metering valve.
- a mixing zone forms after the inner tube end, in which the two gaseous components mix with one another.
- the gaseous components are subsequently conducted as an explosive mixture through the feed pressure duct of the feed pressure line which adjoins the two inlet ducts to the cleaning end section.
- the feed pressure channel or the feed pressure line is formed by the outer tube.
- a supply device is provided on the supply side of the metering valves.
- the supply device supplies the cleaning device with the appropriate gaseous components.
- the supply device comprises z. B. one or more pressure vessel in which the gaseous components or the explosive mixture is stored under pressure.
- the metering valves to feeders, z. B. in the form of hoses connected.
- the feed lines can be connected to pressure vessels.
- the metering valves can also be connected directly to appropriate pressure vessels.
- a narrowing of the cross section is provided in the region of the inner tube end.
- This constriction may be such that the cross section of the first, annular inlet channel narrows towards the inner tube end, for. B. narrowed conically.
- the cross section may in particular be convergent.
- the constriction may be such that the cross section of the subsequent feed pressure duct increases in the feed direction following the inner tube end, for example increases conically.
- the cross section can be divergent.
- the inner tube end may be in the region of increasing cross-section in the feed direction.
- the narrowest point can be arranged in the feed direction behind the inner tube end.
- the geometric configuration of the cross-sectional change may in particular be such that the cleaning device forms a Laval nozzle in the region of the inner tube end with appropriate introduction of the gaseous components into the inlet channels.
- the flow direction of the gaseous mixture in the feed pressure line is in particular in the longitudinal direction of the longitudinal component.
- z. B. also provided the ignition device for ignition and thus to trigger the explosion.
- these and in particular the associated cleaning device can also be designed as a permanent installation on the container or on the system, in particular on a wall.
- the outlet of such a permanent installation is preferably arranged in the interior of the container or the system.
- the at least one outlet opening of the outlet device is arranged in the wall of the container or the system or integrated into it.
- a designed as a permanent installation eriindungsdorfe cleaning device has the advantage that it can be operated by the operator of a system itself and no service team must be called for cleaning. This can save considerable costs. Furthermore, more frequent cleaning can be carried out thereby, whereby the degree of contamination and thus the cost of a single cleaning process can be kept within limits.
- FIG. 1 shows a first embodiment of a cleaning device according to the invention with an outlet device
- FIG. 2 shows a second embodiment of a cleaning device according to the invention with an outlet device
- Figure 5 shows another embodiment of an outlet device
- Figure 6 shows another embodiment of an outlet device
- Figure 7 is a schematic representation of an aspect of the outlet of Figure 5;
- FIG. 8a shows a further embodiment of an outlet device
- FIG. 8b shows a further embodiment of an outlet device
- FIG. 9a shows a further embodiment of an outlet device
- FIG. 9b shows a further embodiment of an outlet device
- Figure 10 shows a furthersatisbeispie an outlet device
- Figure 1 1 shows a furthersatisbeispie an outlet device
- FIG. 12 shows a further embodiment of an outlet device
- FIG. 13 shows a further embodiment of an outlet device
- FIG. 14 schematic representation of a feed solution for an outlet device according to the invention
- FIG. 15 schematic representation of a further feed solution for an inventive outlet device
- FIG. 16 schematic representation of a further feed solution for an inventive outlet device.
- FIG. 17 a a cross-sectional view of a further embodiment of an outlet device
- FIG. 17b shows a front view of the outlet device according to FIG. 17a
- Figure 1 8 a particular embodiment of the mixing zone of a cleaning device
- FIG. 19a shows a further embodiment of a cleaning device
- Figure 1 9b a cross-sectional view along the section line A-A according to Figure 19a.
- FIG. 1 shows a first exemplary embodiment of a cleaning device 1 according to the invention for carrying out the inventive cleaning method.
- the cleaning device 1 comprises a cooling bare cleaning lance 2.
- the cleaning lance 2 includes an outer casing tube 8, and disposed within the outer casing tube 8 inner gas guide tube 7, which forms, among other things, the feed pressure line.
- the outer jacket tube 8 surrounds the inner gas guide tube 7 and thereby forms an annular cooling channel.
- the inner gas guide tube 7 forms, inter alia, a closed feed pressure channel.
- the cleaning lance 2 has at a feed side end portion 4a a metering device with connections for the supply of gaseous components to form an explosive gas mixture.
- An outlet device in the form of a funnel-shaped diffuser 5 adjoins the inner gas guide tube 7 at the cleaning-side end section 4b.
- the cleaning lance 2 is supplied via a filling device 3 with the gaseous components for producing the explosive mixture. Furthermore, the cleaning lance 2 is controlled via a control device 17.
- the control device 17 is used in particular for controlling the supply of the gaseous components in the feed pressure line and the ignition of the explosive mixture.
- the cooling can be continuous cooling or manually controlled. However, a control of the cooling via the control device 1 7 is also possible.
- the supply of gaseous components for generating the explosive mixture via two gas supply lines 10, 1 1, which are directly or indirectly connected to the inner gas guide tube 7.
- a first gas feed line 10 is connected via a first valve 23 to a pressure vessel 22, which in turn is connected via a second valve 15 to a commercially available first gas bottle 20, e.g. Oxygen bottle, connected.
- a check valve 39 is arranged between the first valve 23 and the junction of the gas feed line 10 in the inner gas guide tube 7, .
- a second gas feed line 1 1 is also connected via a first valve 25 to a second pressure vessel 24. This is in turn connected via a second valve 16 to a commercially available second gas cylinder 21.
- the second gas Flask 21 accordingly includes a combustible gas such as acetylene, ethylene or ethane.
- a check valve 39 is arranged between the first valve 25 and the junction of the gas feed lines 1 1 in the inner gas guide tube 7 .
- the pressure vessels 22, 24 can also be fed with the appropriate gaseous components for producing the explosive mixture. After opening the second valves 15, 16, the pressure vessels 22, 24 are filled with the corresponding gases.
- the pressure vessel volumes may, for example, have values in a stoichiometric ratio of 3.7 liters for ethane and 12.5 liters for oxygen or a multiple thereof.
- Means may also be provided via which the pressure in the pressure vessels 22, 24 can be adjusted independently of the pressure in the gas cylinders 20, 21 or the gas otherwise supplied to the pressure vessels 22, 24. As a result, for example, higher pressures can be generated in the pressure vessel 22, 24 than they prevail in the gas cylinders 20, 21.
- These means may include, for example, a compressor.
- the pressure vessels 22, 24 thus serve to meter the gaseous components.
- the metering takes place in each case before the introduction of the gaseous components into the inner gas guide tube 7.
- the explosive mixture is ignited by means of an ignition device 18.
- the ignition device 18 is attached to the cleaning lance 2 and causes the ignition of the explosive mixture in the feed pressure channel.
- the initiation of a cleaning cycle with the steps comprising the generation of an explosive mixture and ignition of the mixture can be initiated via the control device 1 7 by means of a switch 19.
- the annular channel formed by the outer jacket tube 8 around the inner gas guide tube 7 serves, as already mentioned, as a cooling channel. By this a viscous coolant is circulated, which is to cool the inner gas guide tube 7.
- the cleaning lance 2 has at its feed-side end portion 4a or in the vicinity corresponding respectively to terminals for the feed lines 12, 1 3 of the coolant supply.
- a first feed line 12 for example, water and a second feed line 1 3, for example, air is supplied. It may also only adeschzubuchleiLung for supplying only a coolant, for. For example, water. be seen.
- the coolant for example a water / air mixture, is guided between the outer jacket tube 8 and the inner gas guide tube 7.
- the coolant is used to protect the cleaning lance 2 from excessive heating.
- the coolant exits at the cleaning-side end portion 4b again, which is indicated by arrows 9.
- the guided through the cleaning lance 2 and cleaning side escaping coolant also cools the diffuser 5.
- the coolant exits the cleaning side and cools the diffuser.
- the coolant supply into the coolant channel of the cleaning lance is controlled via corresponding valves 14. Pressing the same allows the cooling to be switched on and off.
- the valves can be manually operated or controlled via a control device. Continuous cooling is also possible.
- a lance cooling designed in this way is preferably activated before the introduction of the cleaning lances 2 into the hot interior space of a combustion installation 30 to be cleaned. It typically remains on throughout the entire time the cleaning lances 2 are exposed to heat.
- Such active lance cooling can be done by the control device 17 by the valves 14 of the cleaning lance 2 are actuated via the control device 17. It is of course also possible to introduce a coolant through a cooling connection on the feed side end portion of the lance and to let it flow back to the same end portion. This would be possible, for example, in the case of the outer jacket tube closed on one side.
- the active cooling described above is optional and not a mandatory feature of the present invention.
- the outer Ummantelungsroh 8 and the annular channel can, for. B. also be designed only for passive cooling and insulating effect and in this way the cleaning lance 2 and the therein befind liehe explosive gas mixture or its gaseous components protect against heating.
- the cleaning-side end section 4b of the cleaning lance 2 is introduced through a passage opening 33 in the insertion direction E into the interior 31 of a combustion system 30 and z. B. placed in front of a bundle of tubes 32. Thereafter or simultaneously, first the first valves 23, 25 are briefly, e.g. for less than a second, open. The gas contents of the pressure vessels 22, 24 flow during this time via the gas feed lines 10, 1 1 in the inner gas guide tube 7 of the cleaning lances second
- the gaseous components are mixed with each other to the explosive gas mixture and passed through the feed pressure line in the direction of the diffuser 5.
- the feed pressure line and the diffuser 5 form a receiving space 27 for at least part of the introduced explosive mixture.
- Another part of the gaseous mixture for example, flows outward via the diffuser 5 and forms a cloud.
- only the receiving space 27 can be filled with the explosive mixture. In this case, for example, no cloud is formed outside the diffuser 5.
- the formation of the cloud 6 from the explosive mixture takes 0.015 to 0.03 seconds.
- the explosive mixture is ignited immediately or after a selected time delay by means of the ignition device and the cloud 6 is made to explode.
- the exemplary embodiment of a cleaning device 51 according to the invention shown in FIG. 2 includes a coolable cleaning lance 52, which is guided in the insertion direction E through the passage opening 76 of an incinerator 70 into its interior 71.
- the cleaning lance 52 in each case contains a gas guide tube 67, which extends from a feed-side end section 65 to a cleaning-side end section 66, through which the explosive mixture or its gaseous components are directed in the direction of the outlet opening 69.
- the gas guide tube 67 forms, among other things, a closed feed pressure channel 78 of a feed pressure line.
- a metering device is provided at the feed side end portion 65 .
- a gas guide tube 67 concentrically arranged inner tube 53, also called inlet nozzle.
- the inner tube 54 forms a first inlet channel and terminates within the gas guide tube 67.
- the gas guide tube 67 is at this point in a supply pressure line with feed pressure channel over.
- a first gaseous component of the explosive mixture is introduced into the gas guide tube 67 via the inner tube 53.
- the inner tube 53 is connected via a connection with a first gas feed line 57 for this purpose.
- annular, second inlet channel is formed, in which via a further connection, a second gas feed line 56 for supplying a second gaseous component of the explosive mixture in the gas guide tube 67 opens.
- valves 72. 73 are arranged, via which the supply of the gaseous components in the gas guide tube 67 can be controlled. Between the valves 72, 73 and the confluence of the gas feed lines 56, 57 in the gas guide tube 67, a check valve 79 is arranged in each case.
- the first gaseous component mixes in a mixing zone immediately at the inner tube end in the gas guide tube 67 with the second gaseous component to an explosive mixture.
- the first gaseous component may, for. Example, a gaseous or liquid fuel, in particular a hydrocarbon compound be.
- the second gaseous component may be oxygen or an oxygen-containing gas.
- An ignition device 60 with a spark plug 61 which opens into the gas guide tube 67 and is designed to ignite the explosive mixture in the gas guide tube 67 electrically, is additionally attached to the cleaning lance 52.
- the gas guide tube 67 is encased by a jacket tube 55. Between the jacket tube 55 and the gas guide tube 67, an annular cooling channel 68 is formed, in which a coolant for cooling the gas guide tube 67 is introduced.
- a first and second connection is provided, to which for supplying a first and second coolant, a first and second coolant supply line 58, 59 are connected.
- the first coolant may include a coolant, such as water, and the second coolant, a gas, such as water. As air, be.
- valves 74, 75 are arranged, via which the coolant supply into the coolant channel 68 can be controlled.
- the valves 74, 75 may be manually operated or controlled via a controller. Continuous cooling is also possible.
- a coolant supply line for supplying only a coolant, for.
- a coolant for.
- the coolant e.g. a water / air mixture is thus guided between the jacket tube 55 and the gas guide tube 67.
- the coolant serves to protect the cleaning lance 52 against excessive heating.
- the coolant 64 can emerge from the cooling channel 68 at the cleaning-side end section 66 via an axial outlet opening.
- the guided through the cleaning lance 52 coolant can cool in this way, the diffuser 62 described below.
- a lance cooling designed in this way is preferably activated before the introduction of the cleaning lances 52 into a hot container to be cleaned. It typically remains energized throughout the time the cleaning lance 52 is exposed to heat.
- the active cooling described above is optional and not a mandatory feature of the present invention.
- the feed side end portion 65 opposite cleaning-side end portion 66 connects to the gas guide tube 67 an outlet in the form of a funnel-shaped diffuser 62, at the end of which the outlet opening 69 is located for the explosive mixture.
- the diffuser 62 forms an opening angle.
- the diffuser 62 forms a ratio of diffuser length to the largest diameter of the outlet opening 69 L: D off.
- the length L of the diffuser 62 is measured along its longitudinal axis A (see also FIG. 1).
- the feed rate in the feed pressure channel can be reduced from about 300 m / s (sound velocity) to 4 m / s at the outlet opening, whereby cloud formation becomes possible in the first place.
- the feed pressure channel and the diffuser 62 also form a receiving space 80 for at least a portion of the introduced explosive mixture.
- another part of the gaseous mixture can flow outward via the diffuser 62 and form a cloud.
- only the receiving space 80 can be filled with the explosive mixture here, too. In this case, for example, no cloud is formed outside the diffuser.
- the cleaning device according to the embodiment of Figure 3 includes an outlet device in the form of a diffuser 93 with an outlet opening 95.
- a swirling element 94 In the center of a swirling element 94 is arranged.
- the Verwirbelungs- element 94 serves the additional Vei slowing down the flow and mixing of the entering from the feed pressure line 92 in the diffuser 93, explosive mixture.
- the swirling element 94 is in the feed pressure line 92 fixed.
- the swirling element 94 comprises a platelet-shaped component which is arranged transversely to the outflow direction R (see also FIG. 1).
- the diffuser 93 also forms a receiving space 99 for a part of the introduced explosive mixture. Another part of the gaseous mixture flows outward via the diffuser 93 and forms the cloud 96.
- the outlet device of Figure 3 and the operation thereof may be designed so that only the receiving space 99 of the diffuser 93 is filled with an explosive mixture and exploded.
- the explosion pressure waves 97 propagate from the outlet port 95. In this case, no cloud is generated outside the diffuser 93.
- the explosion pressure waves 97 and the cloud 96 in Figure 3 represent corresponding alternative representations.
- the cleaning device 81 contains a cleaning device with an outlet device 83, which is designed in the form of a truncated icosahedron.
- This contains a plurality of outlet bodies in the form of diffusers 84, which constitute funnel-shaped extensions.
- the diffusers are oriented radially outwardly from a center.
- the outlet openings 85 are arranged directed radially outwards.
- the feed pressure line 82 with the explosive mixture feed pressure channel 88 extends to the center of the icosahedral outlet device 83, from where the explosive mixture is directed into the funnel-shaped extensions 84.
- the outlet device 1 03 of the cleaning device 101 is spherical. It contains a plurality of outlet bodies in the form of diffusers 104, which are in the form of funnel-shaped extensions. ments are configured. The diffusers are radially aligned from a center. The outlet openings 105 are arranged directed radially outwards.
- the feed pressure line 102 with the feed pressure duct 108 for the explosive mixture runs to the center of the spherical outlet 103 and opens into a central spherical distribution space 1 1 1, from where the explosive mixture through passages in the peripheral region of the spherical distribution space 1 1 1 in the funnel-shaped extensions 104 is directed radially outward.
- flow guide can be arranged (not shown).
- the diameter of the feed pressure channel 108 may, for. B. 15 to 30 mm or more, in particular 20 to 25 mm, such as 21 mm.
- the outlet 123 of the cleaning device 121 according to the embodiment of Figure 6 is similar to the structure of the outlet 1 03 according to the embodiment of Figure 5. However, the present outlet 123 is formed only hemispherical. It also contains a plurality of outlet bodies in the form of diffusers 124 which are designed as funnel-shaped extensions. The diffusers are directed radially outward from a center. The outlet openings 125 are arranged radially outward.
- the hemispherical outlet device Since the hemispherical outlet device is arranged in particular on the wall, no separation of the cloud can take place in the boundary region towards the wall. If the hemispherical outlet device is used at a distance from the wall, then the hemispherical outlet device can have a circumferential collar to achieve the same effect.
- the feed pressure line 122 with the explosive mixture feed pressure channel 128 opens on the flat side of the hemispherical outlet device 123 in a central position in the outlet 123, from where the explosive mixture is passed into the funnel-shaped extensions 124.
- the outlet 123 is configured mushroom-shaped in combination with the feed pressure line 122.
- the flat side of the outlet 123 is directed towards the wall 130 of the container or plant.
- the outlet 123 may be retractable in the wall 130.
- the outlet devices according to FIGS. 4, 5 and 6 allow a spatial outlet of the explosive mixture in all directions. This promotes the formation of a cloud in the interior of the container or the system, because the explosive mixture is evenly distributed in the room.
- the outlet velocity of the explosive mixture at the outlet openings of the diffusers may be even higher than the single diffuser of FIGS. 1 and 2.
- the diffusers can be made shorter in relation to the ratio length to opening diameter than those according to Figure 1 and 2.
- the opening angle can also be made smaller.
- FIG. 7 shows a schematic sketch of the arrangement of the diffusers 104 according to the exemplary embodiments according to FIG. 5.
- the diameter d of the diffuser at its narrowest point at the beginning of the funnel-shaped extension can, for. B. 1 to 5 mm, in particular 1 to 2 mm, such as 1 .5 mm amount.
- the length L of the diffuser 104 to the confluence in the central space of the outlet 123 is z. B. 30 to 50 mm, in particular 35 to 45 mm, such as 39 mm.
- the ratio D ⁇ : d can z. B. 75 or less.
- FIG. 8a shows the outlet device 143 of a cleaning device 141, into which the explosive mixture flows via the feed pressure channel 148 of a feed pressure line 142.
- the outlet device 143 forms a receiving space 147 for at least part of the introduced explosive mixture.
- the outlet device 143 has laterally arranged outlet openings 145.
- a funnel-shaped main body 1 44 opens with its extended cross-section in a transverse to this arranged outlet body, which is in each case also funnel-shaped expanded to the two outlet openings 145. Accordingly, the explosive mixture flowing in axially through the main body 144 is deflected by approximately 90 ° (degrees of angle) towards the lateral outlet openings 145 (see arrows).
- the main body or the outlet body are thus formed as diffusers.
- the explosive mixture forms a cloud 146 outside the diffusers.
- the outlet device 163 of a further cleaning device 161 shown in FIG. 8b likewise contains a funnel-shaped main body 164, in which the explosive mixture flows in via the feed pressure channel 168 of a feed pressure line 162.
- the outlet device 1 63 also forms here a receiving space 1 67 for at least part of the introduced explosive mixture.
- the Outlet device 163 also has laterally arranged outlet openings 165.
- the funnel-shaped main body 164 opens with its extended cross-section in a transverse to this arranged outlet body, which is in each case also funnel-shaped expanded to the two outlet openings 165.
- the main body 164 contains a flow guide wall 170 which divides the flow of explosive mixture directed towards the outlet body towards the two outlet openings 165. The flow is also deflected by approximately 90 ° to the lateral outlet openings 165 (see arrows).
- the main body and the outlet body are designed as diffusers.
- the explosive mixture forms a cloud 166 outside the diffusers.
- the outlet devices according to FIGS. 8a and 8b have the particular advantage that, due to the lateral exit of the explosive mixture, lower or no recoil forces occur.
- FIG. 9a shows a cleaning device 341 with an outlet device 343 of similar construction to the outlet device according to FIG. 8a.
- the explosive mixture flows into the outlet device 343 via the feed pressure channel 348 of a feed pressure line.
- the outlet device 343 forms a receiving space 347 for the introduced explosive mixture.
- the outlet device 443 has laterally arranged outlet openings 345.
- a base body 344 opens out with a cross-section which is widened in relation to the feed pressure line into an outlet body 349 arranged transversely to the latter.
- the outlet body 349 has in each case a funnel-shaped enlargement towards the outlet openings 345 lying opposite each other.
- FIG. 9b shows a cleaning device 441 with an outlet device 443 of similar design as the outlet device according to FIG. 8b.
- the outlet 443 includes a main body 444, in which flows through the feed pressure duct 448 a feed pressure line, the explosive mixture.
- the outlet device 443 also forms a receiving space 447 for at least part of the introduced explosive mixture.
- the outlet device 443 further has outlet openings 445 which are also arranged laterally.
- the main body 444 opens with its opposite the feed pressure line extended cross-section into a transverse to this arranged outlet body 449, which is also extended in each case funnel-shaped to the two outlet openings 445 out.
- the explosive mixture is ignited in the receiving space 447.
- the explosion pressure waves 446 are deflected toward the lateral outlet openings 445 by approximately 90 ° (degrees) and laterally extend from the outlet openings 445.
- the outlet devices according to FIGS. 9a and 9b in particular have the advantage that, due to the lateral exit of the explosion pressure waves, less or no recoil forces occur.
- the feed pressure line 182 contains corresponding passages, which open into the diffusers 1 84.
- the diffusers 1 84 are arranged both in a circle around the feed pressure line 182 and in the longitudinal direction of the feed pressure line one behind the other. They form a cylindrical outlet device 1 83.
- a shielding member 1 86 may each be arranged, which shields the explosive mixture emerging from the outlet bodies 184 at the front and rear axial end of the outlet device 183 viewed in the exit direction to the side, so that no separation of the cloud can take place in this border area.
- the shielding elements 1 86 form a kind of funnel-shaped extension following the outlet area formed by the outlet opening 185.
- the shape of the shielding elements 1 86 may also be formed differently than shown.
- outlet body At the front end of the outlet also outlet body are arranged with an axial direction component.
- the outlet openings of the outlet body can, for. B. form a hemispherical outlet surface, as z. B. the embodiment of Figure 6 shows.
- the outlet device 203 shown in FIG. 11 contains a diffuser field. This consists of a plurality of juxtaposed outlet bodies in the form of funnel-shaped diffusers 204 which are aligned the same. In the present embodiment, the outlet openings 205 are in a common plane, which is not mandatory. The outlet openings 205 form a flat outlet surface.
- the outlet 203 is particularly suitable for installation on or in a wall.
- the outlet 203 may, for. B. recessed in the wall, the outlet openings 205 are aligned with the wall.
- the cleaning device 221 shown in Figure 12 includes an outlet device 223. This includes a plurality along the circumference of the feed pressure line 222 arranged and radially leading away from this outlet body in the form of funnel-shaped diffusers 224 with outwardly directed outlet openings 225.
- the diffusers 224 lie in a common plane and thereby form a disc-shaped arrangement.
- a recess or recess corresponding to the diffuser arrangement can be provided, into which the disk-shaped diffuser arrangement can be stowed, embedded or sunk by retracting (arrow) the outlet device 203 (see FIG. 12a).
- the disc-shaped diffuser arrangement is extended out of the depression into the space of the container or installation (arrow direction) (see FIG. 12b).
- FIG. 12c further shows a plan view of the diffuser arrangement of the outlet device 203.
- the cleaning device 221 is particularly suitable for cleaning the wall 230, on which it is arranged.
- the explosion pressure generated by the cleaning device 221 unfolds a shearing effect on the dirt adhering to the wall 230.
- the cleaning device 241 shown in Figure 13 includes an outlet 243. This has similar to a rotary valve from the feed pressure line 242 radially projecting partitions 251, which are arranged parallel to the longitudinal direction of the feed pressure line 242. Two adjacent partitions 251 form an outlet body by their radial orientation.
- the outlet body forms a wedge-shaped space which acts as a diffuser 244.
- passages 250 are provided, which open into the wedge-shaped space between the partitions 251. Through these passages 250, the explosive mixture flows into the wedge-shaped diffuser chamber and is calmed in this before the mixture escapes through the formed between two partitions slot-shaped outlet opening to the outside.
- the cleaning-side end portion of the feed pressure line 242 forms the distribution space.
- the partitions provide additional protection against strong currents in the ambient atmosphere.
- the cloud can be protected and ignited between the dividing walls. Since the explosion pressure is built up on both sides of the partitions in the explosion, they are not deformed, even if they are designed to be relatively thin-walled.
- the outlet device according to the embodiments of Figure 3 to 13 may, for. B. be attached to a cleaning-side end portion of a cleaning lance described above.
- a plurality of diffusers 504 are supplied with the explosive mixture by separate feed pressure lines 502 in each case.
- the individual gaseous components of the mixture are fed via respective feed lines 512, 51 3 from a respective common pressure vessel 510. 51 1 to the individual diffusers 504 or their feed pressure lines 502.
- a plurality of diffusers 524, 544 are supplied with the explosive mixture via a collecting feed.
- the diffusers 524 are fed by a common feed pressure line 522, which branches off to the individual diffusers 524, 544.
- FIGS. 1 5 and 1 6 can be combined with the embodiment according to FIG. That instead of a single diffuser 504 according to Figure 14, the feed pressure line 502 can branch and feed several diffusers.
- FIGS. 17a and 17b show a further embodiment of an outlet device 463 of a cleaning device with an outlet opening 465.
- the outlet device 463 forms a diffuser in the form of a funnel-shaped enlargement toward the outlet opening 465.
- the outlet device 463 with the diffuser also forms a receiving space 467 for a part of the introduced explosive mixture. Another part of the gaseous mixture is calmed in the diffuser and flows outwardly via the outlet opening 465 and forms the cloud 466.
- annular flow guide elements 469 Arranged in the funnel-shaped extension of the diffuser are annular flow guide elements 469, which likewise have a funnel-shaped enlargement toward the outlet opening 465.
- An annular flow channel 471 is formed between the outer wall of the diffuser and the flow guide element 469 or between the flow guide elements 469. This also has a conical enlargement towards the outlet opening 465.
- the annular flow channel 471 is interrupted by radially arranged connecting webs 470, which connect the flow guide elements 469 with each other and with the outer wall of the diffuser.
- the flow guide 469 wear also to calm and homogenize the flow at.
- the number of flow directors 469 may vary.
- the flow guide elements 469 can have an increasing angle with respect to a longitudinal axis A from the inside to the outside. In the embodiment shown here, this angle increases in steps of 10 ° (degrees) to the outside.
- the innermost flow guide elements 469 has, for example, an angle of 10 ° with respect to the longitudinal axis A, the second outer flow element 469 has an angle of 20 ° and the outer wall an angle of 30 °.
- FIG. 18 shows a special embodiment of the cleaning device 651 in the region of the mixing zone 664.
- the cleaning device 651 is a cleaning lance with a feed pressure line 656 with feed pressure channel 657.
- An ignition device 668 is provided on the feed pressure line 656.
- the metering device 654 comprises a gas guide tube 658, also called outer tube, and an inner tube 659.
- the inner tube 659 forms a first inlet channel 652, via which a combustible, gaseous component is introduced into the feed pressure channel 657.
- the latter component is introduced via the metering valves 663 into the first introduction channel 652, which are shown only by way of example.
- annular, second inlet channel 653 is formed, via which gaseous oxygen or an oxygen-containing, gaseous component is introduced into the feed pressure channel 657 of the feed pressure line 656.
- the inner tube 659 terminates within the gas guide tube 658.
- the second, annular inlet channel 653 is at this point in the feed pressure channel 657 on.
- a mixing zone 664 is formed, in which the from the first and second inlet channel 652, 653 in the common feed pressure channel 657 incoming gaseous components mix together.
- a narrowing of the cross section is provided in the region of the inner tube end.
- This constriction is such that the cross section of the second, annular inlet channel 653 conically narrows toward the inner tube end.
- the constriction is such that the cross section of the feed pressure channel 657 increases conically in the feed direction R following the inner tube end.
- the inner tube end lies in the region of the cross section which increases again in the feed direction R.
- the narrowest point is located behind the inner tube end.
- the geometric configuration of the cross-sectional change is such that the cleaning device 651 forms a Laval nozzle in the region of the inner tube end with corresponding flow conditions.
- FIGS. 19a and 19b shows a cleaning lance with a side-end section on which a metering device 604 is formed and a cleaning-side end section on which an outlet device 605 is arranged. Between the metering device 604 and the outlet device 605, a feed pressure line 606 with a feed pressure channel 607 is arranged, via which the explosive mixture is conveyed from the metering device 604 to the outlet device 605.
- the outlet 605 is formed in the present example as a conical diffuser with an outlet opening. However, the outlet 605 may also be designed differently.
- the cleaning lance can be inserted through an opening in the container wall 630 into the interior of a container to be cleaned.
- the metering device 604 comprises a gas guide tube 608 and an inner tube 609.
- the inner tube 609 forms a first inlet channel 602, via which a combustible, gaseous component is introduced into the feed pressure channel 607.
- a second, annular inlet channel 603 is formed, via which oxygen or an oxygen-containing, gaseous component is introduced into the feed pressure channel 607 of the feed pressure line 606.
- the first, combustible component is introduced via a plurality of metering valves 612 from a first pressure vessel 621 into the first introduction channel 602.
- the oxygen or the oxygen-containing component is introduced via a plurality of metering valves 613 from a second pressure vessel 622 into the second inlet channel 603.
- the number of metering valves 612, 61 3 for the first and second gaseous components is selected so that the ratio of the number of metering valves 612, 61 3 corresponds to the stoichiometric ratio of the components to be supplied.
- the first component is oxygen and the second component is ethane. These are introduced in a stoichiometric ratio of 7: 2. Accordingly, two 612 and for the second component seven metering valves 61 3 are provided for the first component.
- the first pressure vessel 621 is supplied via a first feed line 610 and the second pressure vessel 622 via a second feed line 61 1 with the corresponding gaseous component.
- the inner tube 609 terminates within the gas guide tube 608.
- the second annular inlet channel 603 merges with the inner tube end into the feed pressure channel 607.
- a mixing zone 614 is formed, in which the gaseous components flowing from the first and second inlet channels 602, 603 into the common feed pressure channel 607 are interconnected. Mix.
- the cross section of the feed pressure channel 607 experiences a funnel-shaped enlargement in the mixing zone.
- an ignition device 668 is provided for igniting the explosive mixture.
- a control device 617 is connected via control lines 619 with the ignition device 668 and the metering valves 612, 613.
- the control lines 619 should also stand for a wireless connection. The opening and closing of the metering valves 612, 613 and the activation of the ignition device takes place via the control device 617.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Cleaning In General (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Incineration Of Waste (AREA)
- Cleaning By Liquid Or Steam (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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RS20201433A RS61131B1 (sr) | 2013-02-11 | 2014-02-11 | Postupak i uređaj za čišćenje unutrašnjosti kontejnera i postrojenja |
EP20187468.2A EP3753641A1 (de) | 2013-02-11 | 2014-02-11 | Vorrichtung zum reinigen von innenräumen von behältern und anlagen |
PL14705470T PL2953739T3 (pl) | 2013-02-11 | 2014-02-11 | Sposób i urządzenie do czyszczenia przestrzeni wewnętrznych zbiorników i instalacji |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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CH4292013 | 2013-02-11 | ||
PCT/CH2014/000018 WO2014121409A1 (de) | 2013-02-11 | 2014-02-11 | Verfahren und vorrichtung zum reinigen von innenräumen von behältern und anlagen |
Related Child Applications (2)
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EP20187468.2A Division-Into EP3753641A1 (de) | 2013-02-11 | 2014-02-11 | Vorrichtung zum reinigen von innenräumen von behältern und anlagen |
EP20187468.2A Division EP3753641A1 (de) | 2013-02-11 | 2014-02-11 | Vorrichtung zum reinigen von innenräumen von behältern und anlagen |
Publications (2)
Publication Number | Publication Date |
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EP2953739A1 true EP2953739A1 (de) | 2015-12-16 |
EP2953739B1 EP2953739B1 (de) | 2020-09-02 |
Family
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Family Applications (2)
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EP14705470.4A Active EP2953739B1 (de) | 2013-02-11 | 2014-02-11 | Verfahren und vorrichtung zum reinigen von innenräumen von behältern und anlagen |
EP20187468.2A Pending EP3753641A1 (de) | 2013-02-11 | 2014-02-11 | Vorrichtung zum reinigen von innenräumen von behältern und anlagen |
Family Applications After (1)
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EP20187468.2A Pending EP3753641A1 (de) | 2013-02-11 | 2014-02-11 | Vorrichtung zum reinigen von innenräumen von behältern und anlagen |
Country Status (26)
Country | Link |
---|---|
US (1) | US10065220B2 (de) |
EP (2) | EP2953739B1 (de) |
JP (2) | JP6895221B2 (de) |
KR (1) | KR101981839B1 (de) |
CN (1) | CN105228761B (de) |
AU (1) | AU2014214477B2 (de) |
BR (1) | BR112015019123B1 (de) |
CA (1) | CA2900103C (de) |
DK (1) | DK2953739T3 (de) |
EA (1) | EA031744B1 (de) |
ES (1) | ES2834112T3 (de) |
GE (1) | GEP201706711B (de) |
HK (1) | HK1218528A1 (de) |
HU (1) | HUE052287T2 (de) |
IL (1) | IL240435B (de) |
LT (1) | LT2953739T (de) |
MY (1) | MY177880A (de) |
NZ (1) | NZ710789A (de) |
PH (1) | PH12015501724A1 (de) |
PL (1) | PL2953739T3 (de) |
PT (1) | PT2953739T (de) |
RS (1) | RS61131B1 (de) |
SA (1) | SA515360876B1 (de) |
SG (2) | SG11201506181XA (de) |
WO (1) | WO2014121409A1 (de) |
ZA (1) | ZA201506337B (de) |
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ES1211164Y (es) * | 2018-03-27 | 2018-07-17 | Hernandez Fernando Campos | Dispositivo para limpiar, desinfectar y desatascar desagües de pilas de cocina, bano, trituradores de comida u otros usos. |
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CN109580433B (zh) * | 2018-10-26 | 2021-05-28 | 中国辐射防护研究院 | 一种常规爆炸放射性气溶胶扩散的源项估算方法 |
CN109764347A (zh) * | 2019-01-09 | 2019-05-17 | 永清环保股份有限公司 | 一种蒸汽喷砂吹灰器、垃圾焚烧吹灰系统及工作方法 |
JP6876884B2 (ja) * | 2019-05-07 | 2021-05-26 | 株式会社タクマ | 付着物除去装置 |
CN110102541A (zh) * | 2019-06-10 | 2019-08-09 | 福建省中瑞装备制造科技有限公司 | 一种水泥库高效清洁系统 |
FI130431B (en) * | 2019-06-12 | 2023-08-28 | Lassila & Tikanoja Oyj | Device and method for cleaning with explosive material |
JP7458180B2 (ja) * | 2019-12-23 | 2024-03-29 | 川崎重工業株式会社 | 衝撃波式スートブロワシステムおよびその運転方法 |
CN111486463A (zh) * | 2020-04-23 | 2020-08-04 | 北京宸控环保科技有限公司 | 一种除灰系统 |
CN111578245A (zh) * | 2020-04-29 | 2020-08-25 | 先尼科化工(上海)有限公司 | 一种余热锅炉及其除垢方法 |
JP7141436B2 (ja) * | 2020-11-02 | 2022-09-22 | 株式会社タクマ | ガス供給システム、ガス供給方法、及びガス供給プログラム |
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2014
- 2014-02-11 ES ES14705470T patent/ES2834112T3/es active Active
- 2014-02-11 AU AU2014214477A patent/AU2014214477B2/en active Active
- 2014-02-11 US US14/766,194 patent/US10065220B2/en active Active
- 2014-02-11 KR KR1020157024332A patent/KR101981839B1/ko active IP Right Grant
- 2014-02-11 MY MYPI2015001998A patent/MY177880A/en unknown
- 2014-02-11 NZ NZ710789A patent/NZ710789A/en active IP Right Revival
- 2014-02-11 EP EP14705470.4A patent/EP2953739B1/de active Active
- 2014-02-11 PL PL14705470T patent/PL2953739T3/pl unknown
- 2014-02-11 GE GEAP201413931A patent/GEP201706711B/en unknown
- 2014-02-11 DK DK14705470.4T patent/DK2953739T3/da active
- 2014-02-11 LT LTEP14705470.4T patent/LT2953739T/lt unknown
- 2014-02-11 CN CN201480020990.3A patent/CN105228761B/zh active Active
- 2014-02-11 EP EP20187468.2A patent/EP3753641A1/de active Pending
- 2014-02-11 JP JP2015556357A patent/JP6895221B2/ja active Active
- 2014-02-11 PT PT147054704T patent/PT2953739T/pt unknown
- 2014-02-11 BR BR112015019123-1A patent/BR112015019123B1/pt active IP Right Grant
- 2014-02-11 SG SG11201506181XA patent/SG11201506181XA/en unknown
- 2014-02-11 RS RS20201433A patent/RS61131B1/sr unknown
- 2014-02-11 EA EA201591493A patent/EA031744B1/ru unknown
- 2014-02-11 WO PCT/CH2014/000018 patent/WO2014121409A1/de active Application Filing
- 2014-02-11 SG SG10201706533QA patent/SG10201706533QA/en unknown
- 2014-02-11 HU HUE14705470A patent/HUE052287T2/hu unknown
- 2014-02-11 CA CA2900103A patent/CA2900103C/en active Active
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2015
- 2015-08-06 PH PH12015501724A patent/PH12015501724A1/en unknown
- 2015-08-09 IL IL240435A patent/IL240435B/en active IP Right Grant
- 2015-08-10 SA SA515360876A patent/SA515360876B1/ar unknown
- 2015-08-28 ZA ZA2015/06337A patent/ZA201506337B/en unknown
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2016
- 2016-06-07 HK HK16106537.9A patent/HK1218528A1/zh unknown
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2019
- 2019-07-05 JP JP2019126190A patent/JP2019195808A/ja active Pending
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