EP2892955A1 - Composition de promoteur d'adhérence pour des membranes à base de polyoléfine - Google Patents
Composition de promoteur d'adhérence pour des membranes à base de polyoléfineInfo
- Publication number
- EP2892955A1 EP2892955A1 EP13756906.7A EP13756906A EP2892955A1 EP 2892955 A1 EP2892955 A1 EP 2892955A1 EP 13756906 A EP13756906 A EP 13756906A EP 2892955 A1 EP2892955 A1 EP 2892955A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- substrate
- composition according
- group
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 70
- 239000012528 membrane Substances 0.000 title claims description 18
- 239000002318 adhesion promoter Substances 0.000 title claims description 5
- 239000000178 monomer Substances 0.000 claims abstract description 24
- 239000002904 solvent Substances 0.000 claims abstract description 23
- 239000003054 catalyst Substances 0.000 claims abstract description 22
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims abstract description 12
- 150000001412 amines Chemical class 0.000 claims abstract description 10
- 229920000620 organic polymer Polymers 0.000 claims abstract description 10
- 239000000758 substrate Substances 0.000 claims description 72
- 239000000853 adhesive Substances 0.000 claims description 38
- 230000001070 adhesive effect Effects 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 18
- 229920000098 polyolefin Polymers 0.000 claims description 17
- 229920002397 thermoplastic olefin Polymers 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 11
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 10
- 238000005660 chlorination reaction Methods 0.000 claims description 10
- -1 polypropylene Polymers 0.000 claims description 9
- 238000007789 sealing Methods 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 7
- 239000008096 xylene Substances 0.000 claims description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 3
- LCXXNKZQVOXMEH-UHFFFAOYSA-N Tetrahydrofurfuryl methacrylate Chemical class CC(=C)C(=O)OCC1CCCO1 LCXXNKZQVOXMEH-UHFFFAOYSA-N 0.000 claims description 3
- 230000000977 initiatory effect Effects 0.000 claims description 3
- 150000002978 peroxides Chemical class 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 238000004381 surface treatment Methods 0.000 claims description 2
- 238000009413 insulation Methods 0.000 claims 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 1
- 150000001448 anilines Chemical class 0.000 claims 1
- RZXMPPFPUUCRFN-UHFFFAOYSA-N p-toluidine Chemical compound CC1=CC=C(N)C=C1 RZXMPPFPUUCRFN-UHFFFAOYSA-N 0.000 claims 1
- 150000004992 toluidines Chemical class 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 20
- 230000032683 aging Effects 0.000 description 8
- 239000000470 constituent Substances 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000002203 pretreatment Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 229920002959 polymer blend Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- JUVSRZCUMWZBFK-UHFFFAOYSA-N 2-[n-(2-hydroxyethyl)-4-methylanilino]ethanol Chemical compound CC1=CC=C(N(CCO)CCO)C=C1 JUVSRZCUMWZBFK-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 150000003513 tertiary aromatic amines Chemical class 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- HYVGFUIWHXLVNV-UHFFFAOYSA-N 2-(n-ethylanilino)ethanol Chemical compound OCCN(CC)C1=CC=CC=C1 HYVGFUIWHXLVNV-UHFFFAOYSA-N 0.000 description 1
- ZFGRWTCBGWXDTD-UHFFFAOYSA-N 2-[n-(2-hydroxyethyl)-2,3-dimethylanilino]ethanol Chemical group CC1=CC=CC(N(CCO)CCO)=C1C ZFGRWTCBGWXDTD-UHFFFAOYSA-N 0.000 description 1
- OJPDDQSCZGTACX-UHFFFAOYSA-N 2-[n-(2-hydroxyethyl)anilino]ethanol Chemical compound OCCN(CCO)C1=CC=CC=C1 OJPDDQSCZGTACX-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000085 borane Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- GYVGXEWAOAAJEU-UHFFFAOYSA-N n,n,4-trimethylaniline Chemical compound CN(C)C1=CC=C(C)C=C1 GYVGXEWAOAAJEU-UHFFFAOYSA-N 0.000 description 1
- QBGXPOGIVFAFPC-UHFFFAOYSA-N n-(2-ethyl-4-methylphenyl)-n-methylhydroxylamine Chemical compound CCC1=CC(C)=CC=C1N(C)O QBGXPOGIVFAFPC-UHFFFAOYSA-N 0.000 description 1
- 150000004995 p-toluidines Chemical class 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/26—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/26—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
- C09D123/28—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2351/06—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Definitions
- polyolefinic substrates for example in the form of polyolefinic membranes
- other substrates for example in the form of polyolefinic membranes
- Tunnel seal can be used.
- polyolefinic substrates such as polyethylene, polypropylene or EPDM are known for their adhesion-unfriendly surface.
- Such materials can only be permanently and structurally bonded, if they are special
- Pretreatment methods are subjected. These are usually physical pretreatments in which the surface is oxidized, for example, so that the adhesive can bind physically or chemically after application.
- thermoplastic olefin thermoplastic olefin substrate to be welded to a TPO substrate.
- TPO substrate thermoplastic olefin
- PVC substrate polyvinyl graft polyethylene
- Another possibility for structural and permanent bonding in polyolefinic substrates with other substrates is the physical pretreatment of the surface of the polyolefinic substrate, for example by plasma treatment, flaming, etching or similar methods, which is followed by bonding to the other substrate following this physical pretreatment.
- pretreatment processes are expensive and expensive.
- the pre-treatment can not be carried out on site, but must already be integrated in the production. Since the effect of the pretreatment decays with time, the storage time for such pretreated substrates is limited, resulting in a lack of reproducibility of the bond strength after bonding of the substrates.
- polyolefin primers consisting of chloroprene rubber or chlorinated polyolefins in a suitable solvent.
- Bond strength can be achieved when new and after hot air aging. However, it has been shown that when stored under humid conditions (hot water or 100% humidity) at elevated temperatures (eg 60 ° C) the adhesion decreases rapidly within a very short time.
- compositions which permit a permanent and structural bonding of polyolefinic substrates to other substrates.
- Another object of the present invention is a method
- composition comprising
- the solvent-containing composition described is capable of activating the surface of polyolefinic substrates in such a way that they can be permanently and structurally bonded to other substrates with an adhesive, in particular with an acrylate adhesive.
- composition according to the invention is a low-viscosity solvent-containing liquid which is preferably applied to the surface to be treated by brushing or spraying.
- the composition forms a film on the film after drying Surface which acts as a "polarity mediator" between the materials and can interact with the polyolefins of the substrate as well as the constituents of the adhesive.
- the composition contains reactive
- polymer in the present document comprises on the one hand a collective of chemically unified, but with respect to
- Macromolecules which were produced by a polyreaction (polymerization, polyaddition, polycondensation).
- the term also encompasses derivatives of such a collective of macromolecules from polyreactions, ie compounds which are predetermined by reactions, such as additions or substitutions, of functional groups
- Macromolecules have been obtained and may be chemically uniform or chemically nonuniform.
- the term also includes so-called prepolymers, ie reactive oligomeric pre-adducts whose functional groups are involved in the construction of macromolecules.
- prepolymers ie reactive oligomeric pre-adducts whose functional groups are involved in the construction of macromolecules.
- molecular weight is meant in this document always the number average molecular weight M n .
- compositions according to the invention are preferably such that the organic polymer, the monomer from the group of the acrylates and the catalyst from the group of the tertiary organic amines are completely dissolved in the solvent.
- the preparation of the composition according to the invention takes place
- compositions according to the invention for a permanent bonding of polyolefinic membranes called FPO or TPO (flexible polyolefin or thermoplastic polyolefin), with adhesives, with acrylate adhesives being particularly preferred.
- FPO or TPO flexible polyolefin or thermoplastic polyolefin
- adhesives with acrylate adhesives being particularly preferred.
- Pre-treatment with these compositions allows FPO membranes to be bonded to other FPO membranes or to other substrates on which the adhesive exhibits a good and durable bond.
- non-FPO substrates include in particular PVC membranes and rigid substrates (plastic, concrete and / or metal).
- Present invention understood a bond that has a high bond strength even after natural and artificial aging.
- composition according to the invention is characterized in that it enables a combination of polyolefinic substrates with other substrates which have a markedly high aging capability.
- adhesives for bonding the substrates after pretreatment of the polyolefinic substrates with the composition of the invention are particularly suitable two-component acrylate adhesives, wherein
- Tetrahydrofurfuryl methacrylate or methyl methacrylate based systems with peroxide initiation are particularly preferred.
- the composition according to the invention is designed such that the at least one organic polymer is at least one polyolefin based on hard or soft polypropylene with a degree of chlorination of 20 to 30% and / or at least one maleic anhydride modified polyolefin includes.
- the at least one organic polymer comprises one or more polymers of the following: A hard polyolefin with a degree of chlorination of 20-30% and a
- a soft polyolefin with a degree of chlorination of 20-30% one
- compositions according to the invention furthermore have at least one monomer from the group of acrylates. While in principle all monomers from the group of acrylates are suitable, it has been found that particularly good results are achieved if the at least one monomer from the group of acrylates is an acrylate ester and / or a
- Methacrylate ester in particular in the form of one or more of
- Methyl methacrylate, butyl methacrylate and Lau rylmethacrylat comprises.
- the compositions according to the invention moreover have at least one catalyst from the group of tertiary organic amines.
- Aromatic tertiary amines have proven to be particularly suitable.
- Suitable tertiary aromatic amines are especially tertiary aromatic amines selected from the group consisting of: N, N-
- N, N-bis (hydroxyalkyl) aniline such as N, N-bis (2-hydroxyethyl) aniline, ⁇ , ⁇ -alkylhydroxyalkylaniline such as N-ethyl-N-hydroxyethyl Aniline, N, N-dimethyl-p-toluidine, ⁇ , ⁇ -diethyl-p-toluidine, N-methyl-N-hydroxy-ethyl-p-toluidine, N, N-bis (2-hydroxyethyl) -p-toluidine and alkoxylated N, N-bis- (hydroxyethyl) -p-toluidines, N-ethoxylated p-toluidine, N, N-bis (2-hydroxyethyl) -xylidine, N-alkylmorpholine and mixtures thereof.
- N, N-bis (hydroxyalkyl) aniline such as N, N-bis (2-hydroxyethyl) aniline, ⁇ , ⁇
- the composition according to the invention is designed so that the at least one catalyst from the group of tertiary organic amines comprises N, N-bis- (2-hydroxyethyl) -paratotoluidine (Bisomer PTE).
- the at least one solvent is an organic solvent, with solvents from the group of aromatic solvents, in particular alkylaromatics, being particularly preferred. It has been shown that especially good
- Results are achieved when xylene is used as the solvent.
- compositions according to the invention are present in such a way that all components are present dissolved in the solvent.
- composition according to the invention is designed such that the individual components are present in such a weight ratio that the
- Adhesion promoter composition comprises:
- compositions according to the invention act as adhesion promoters after application and drying on non-polar surfaces.
- the present invention also relates to the use of the composition according to the invention for the treatment of the surface of a polyolefinic substrate.
- This treatment preferably by brushing or spraying the surface of the treated
- Substrates are activated so that in a subsequent step, a permanent bonding of the thus treated surface with another substrate, for example by use of an acrylate adhesive, is made possible.
- Another object of the present invention is a process for the surface treatment of a polyolefinic substrate.
- the inventive method is designed so that a composition of the invention is applied to the surface of a polyolefinic substrate and then dried.
- an adhesive is applied to the site thus pretreated and the polyolefinic substrate is then bonded to another substrate.
- the bonding of the pretreated polyolefinic substrate is preferably a
- Acrylic adhesive in particular in the form of a two-component
- Acrylate adhesive used wherein preferably tetrahydrofurfuryl methacrylate or methyl methacrylate-based systems are used with peroxide initiation.
- the polyolefinic substrate is a Sealing web, in particular from the field of flat roofing, pitched roofing, building sealing and / or tunnel seal, wherein bonding takes place for example with a thermoplastic olefin membrane, a PVC membrane, a metallic substrate or a concrete substrate.
- Composition produced wherein the following proportions were used: Polymer component 0, 1,2,3,4,5,6,7,8, 9 and 10 wt.%
- the substrate Sarnafil FPO roofing membrane was pretreated with the compositions of the invention and adhered after drying for 30 minutes by using the adhesive SikaFast®-5221 with the substrate Sarnafil FPO roofing membrane.
- the peel force of the adhesive bond for the compositions was determined with the different polymer proportions.
- a composition was prepared for the pretreatment of polyolefinic substrates with the following components: Polymer blend Polyl, Poly2, Poly3 and Poly4 (see page 6)
- composition produced wherein the following proportions were used:
- the substrate Sarnafil FPO roofing membrane was pretreated with the composition of the invention and adhered after drying for 30 minutes by using the adhesive SikaFast®-5221 with the substrate Sarnafil FPO roofing membrane. After curing the adhesive bond for 4 hours at 23 ° C was the
- a composition was prepared for the pretreatment of polyolefinic substrates with the following components:
- composition produced wherein the following proportions were used:
- the substrate Sarnafil FPO roofing membrane was pretreated with the composition of the invention and adhered after drying for 30 minutes by using the adhesive SikaFast®-5221 with the substrate Sarnafil FPO roofing membrane.
- the peel force of the adhesive bond for the compositions was determined with the different polymer proportions.
- composition according to the invention which contained the following constituents in the following ratios by weight:
- pretreated composition according to the invention and adhered after drying for 30 minutes by using the adhesive SikaFast®-5221 with a TPO substrate.
- pretreated composition according to the invention and adhered after drying for 30 minutes by using the adhesive SikaFast ® -5221 with a PVC substrate.
- peel force peel force of the adhesive bond was determined. Furthermore, the peel force after aging in water was determined at 70 ° C for 28 days. The same experiments were also conducted with pretreatment compositions known in the art. The result is shown in Table 5.
- composition according to the invention 140,200 Composition according to the invention 140,200
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13756906.7A EP2892955A1 (fr) | 2012-09-05 | 2013-09-04 | Composition de promoteur d'adhérence pour des membranes à base de polyoléfine |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12183170.5A EP2706093A1 (fr) | 2012-09-05 | 2012-09-05 | Composition d'agent adhésif pour membranes finies au polyol |
EP13756906.7A EP2892955A1 (fr) | 2012-09-05 | 2013-09-04 | Composition de promoteur d'adhérence pour des membranes à base de polyoléfine |
PCT/EP2013/068294 WO2014037407A1 (fr) | 2012-09-05 | 2013-09-04 | Composition de promoteur d'adhérence pour des membranes à base de polyoléfine |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2892955A1 true EP2892955A1 (fr) | 2015-07-15 |
Family
ID=46826281
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12183170.5A Withdrawn EP2706093A1 (fr) | 2012-09-05 | 2012-09-05 | Composition d'agent adhésif pour membranes finies au polyol |
EP13756906.7A Withdrawn EP2892955A1 (fr) | 2012-09-05 | 2013-09-04 | Composition de promoteur d'adhérence pour des membranes à base de polyoléfine |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12183170.5A Withdrawn EP2706093A1 (fr) | 2012-09-05 | 2012-09-05 | Composition d'agent adhésif pour membranes finies au polyol |
Country Status (5)
Country | Link |
---|---|
US (1) | US9732250B2 (fr) |
EP (2) | EP2706093A1 (fr) |
KR (1) | KR102121085B1 (fr) |
CN (1) | CN104603199B (fr) |
WO (1) | WO2014037407A1 (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102018007330B3 (de) | 2018-09-15 | 2019-08-22 | Institut für Kunststofftechnologie und -recycling e.V. | Halogenfreier Haftvermittler zur Beschichtung von Polyolefinen, Verfahren zur Herstellung und Verwendung |
FR3098818B1 (fr) | 2019-07-18 | 2021-06-25 | Bostik Sa | Composition adhésive bi-composante comprenant un complexe organoborane-amine |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3890407A (en) * | 1972-07-20 | 1975-06-17 | Du Pont | Novel adhesive compositions |
JPS5975958A (ja) | 1982-10-26 | 1984-04-28 | Sanyo Kokusaku Pulp Co Ltd | ポリプロピレン系樹脂用塗料組成物 |
DE3534858A1 (de) | 1985-09-30 | 1987-04-02 | Basf Lacke & Farben | Loesliches carboxylgruppenhaltiges acrylatcopolymerisat, verfahren zu seiner herstellung und ueberzugsmittel auf der basis des acrylatcopolymerisats |
DE3829461A1 (de) * | 1988-08-31 | 1990-04-26 | Henkel Kgaa | Neue radikalisch polymerisierbare mehrstoffgemische und ihre verwendung (ii) |
GB9112141D0 (en) * | 1991-06-05 | 1991-07-24 | Ici Resins Bv | Aqueous coating compositions |
KR100418322B1 (ko) * | 1995-04-24 | 2005-05-18 | 미네소타 마이닝 앤드 매뉴팩춰링 캄파니 | 폴리올레핀표면용감압성접착제 |
US6989416B2 (en) * | 2002-05-07 | 2006-01-24 | Sika Technology Ag | Methacrylate structural adhesive |
US20040176541A1 (en) * | 2003-02-21 | 2004-09-09 | Jackson Michael L. | Chlorine free and reduced chlorine content polymer and resin compositons for adhesion to plastics |
JP2008184542A (ja) * | 2007-01-30 | 2008-08-14 | Three M Innovative Properties Co | プライマ組成物及び接着性基材 |
FR2928931B1 (fr) * | 2008-03-21 | 2011-03-25 | Jacret | Composition pour adhesif structural |
JP7033411B2 (ja) | 2017-09-06 | 2022-03-10 | 昭和電工パッケージング株式会社 | 成形用包装材、蓄電デバイス用外装ケース及び蓄電デバイス |
-
2012
- 2012-09-05 EP EP12183170.5A patent/EP2706093A1/fr not_active Withdrawn
-
2013
- 2013-09-04 US US14/425,682 patent/US9732250B2/en not_active Expired - Fee Related
- 2013-09-04 KR KR1020157005093A patent/KR102121085B1/ko active IP Right Grant
- 2013-09-04 EP EP13756906.7A patent/EP2892955A1/fr not_active Withdrawn
- 2013-09-04 CN CN201380046241.3A patent/CN104603199B/zh not_active Expired - Fee Related
- 2013-09-04 WO PCT/EP2013/068294 patent/WO2014037407A1/fr active Application Filing
Non-Patent Citations (2)
Title |
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None * |
See also references of WO2014037407A1 * |
Also Published As
Publication number | Publication date |
---|---|
KR102121085B1 (ko) | 2020-06-10 |
US9732250B2 (en) | 2017-08-15 |
CN104603199A (zh) | 2015-05-06 |
CN104603199B (zh) | 2017-11-14 |
WO2014037407A1 (fr) | 2014-03-13 |
KR20150052038A (ko) | 2015-05-13 |
US20150232686A1 (en) | 2015-08-20 |
EP2706093A1 (fr) | 2014-03-12 |
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