EP2877748B1 - Dispositif compresseur ainsi qu'un dispositif de réfrigération ainsi équipé et une machine frigorifique ainsi équipée - Google Patents

Dispositif compresseur ainsi qu'un dispositif de réfrigération ainsi équipé et une machine frigorifique ainsi équipée Download PDF

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Publication number
EP2877748B1
EP2877748B1 EP13742442.0A EP13742442A EP2877748B1 EP 2877748 B1 EP2877748 B1 EP 2877748B1 EP 13742442 A EP13742442 A EP 13742442A EP 2877748 B1 EP2877748 B1 EP 2877748B1
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Prior art keywords
compressor
gas
working
volume
cooling device
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EP13742442.0A
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German (de)
English (en)
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EP2877748A2 (fr
Inventor
Jens HÖHNE
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Pressure Wave Systems GmbH
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Pressure Wave Systems GmbH
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B43/00Machines, pumps, or pumping installations having flexible working members
    • F04B43/02Machines, pumps, or pumping installations having flexible working members having plate-like flexible members, e.g. diaphragms
    • F04B43/06Pumps having fluid drive
    • F04B43/073Pumps having fluid drive the actuating fluid being controlled by at least one valve
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B45/00Pumps or pumping installations having flexible working members and specially adapted for elastic fluids
    • F04B45/02Pumps or pumping installations having flexible working members and specially adapted for elastic fluids having bellows
    • F04B45/033Pumps or pumping installations having flexible working members and specially adapted for elastic fluids having bellows having fluid drive
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B49/00Control, e.g. of pump delivery, or pump pressure of, or safety measures for, machines, pumps, or pumping installations, not otherwise provided for, or of interest apart from, groups F04B1/00 - F04B47/00
    • F04B49/22Control, e.g. of pump delivery, or pump pressure of, or safety measures for, machines, pumps, or pumping installations, not otherwise provided for, or of interest apart from, groups F04B1/00 - F04B47/00 by means of valves
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B53/00Component parts, details or accessories not provided for in, or of interest apart from, groups F04B1/00 - F04B23/00 or F04B39/00 - F04B47/00
    • F04B53/08Cooling; Heating; Preventing freezing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B31/00Compressor arrangements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B9/00Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B9/00Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
    • F25B9/14Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the cycle used, e.g. Stirling cycle

Definitions

  • the invention relates to a compressor device and a cooling device equipped therewith or a refrigeration machine equipped therewith.
  • a helium compressor 100 is connected to a rotary valve 106 via a high pressure line 102 and a low pressure line 104.
  • the rotary valve 106 is connected via a gas line 108 to a cooling device 110 in the form of a Gifford-McMahon cooler or a pulse tube cooler.
  • the rotary valve 106 alternately the high and low pressure side of the gas compressor 100 is connected to the pulse tube cooler or the Gifford-McMahon cooler.
  • the rate at which compressed helium is introduced and re-exported to the cooling device 100 is in the range of 1 Hz.
  • a disadvantage of such cooling or compressor systems is that the motorized rotary valve 106 causes losses of up to 50% of the input power of the compressor.
  • acoustic compressors or high-frequency compressors in which one or more pistons are caused by a magnetic field in linear resonant vibrations. These resonant frequencies are in the range of a few 10 Hz and are therefore not suitable for use with pulse tube coolers and Gifford-McMahon coolers to produce very low temperatures in the lower than 10 K range.
  • a membrane compressor or pump which has a working space that is divided into a gas volume and a liquid volume by an elastic, gas and liquid-tight membrane.
  • a Liquid pump liquid is periodically pressed into the liquid volume of the working space, whereby the elastic membrane expands in the direction of gas volume and this compresses - compressor function - or pushes out of the gas volume - pump function.
  • a disadvantage is the fact that the gas-liquid-tight and pressure-resistant sealing of the elastic membrane in the working space is comparatively expensive. Especially in the field of sealing, the membrane is heavily loaded, so that either very expensive materials must be used or a shorter life has to be accepted.
  • the US 5,181,383 shows a cooling device in which compressed helium gas is expanded in a pressure transmission tube with a piston and a bellows.
  • the compression of the helium gas takes place in the compressor, which is not described in detail.
  • this compression obviously only serves to adapt the gas pressure in the pressure transfer tube to the pressure of the compressed helium gas, so that in subsequent step b), Fig. 3b the controlled expansion of the helium gas can take place.
  • a linear compressor in which a compressor piston driven by a linear motor compresses a gas.
  • a piston is displaced by a liquid pressed into a bellows, thereby changing the dead volume and the resonance frequency of the compressor.
  • the bellows is not used to compress a gas.
  • a heat pump and a refrigerator with a compressor device are known.
  • the compressor device comprises a compressor chamber in which a balloon is arranged.
  • the balloon is periodically pressurized with liquid so that the gas surrounding the balloon is periodically compressed and relaxed again.
  • the disadvantage here is that the balloon envelope can scrape or rub in certain operating conditions on the hard and possibly edged inner surface of the compressor chamber. As a result, due to the pressure conditions hole or cracking in the balloon envelope occur.
  • cryogenic cooling device with a compressor device with gas-filled bellows known, which are surrounded by a periodically pumped liquid.
  • the balloon envelope Due to the fact that the gas volume in the balloon and the volume of liquid on the outside, the balloon envelope is always protected by a liquid film on the hard inside (usually metal) from damage when due to irregular operating conditions rubs the balloon envelope on the hard inside of the compressor room. Since the working fluid is usually hydraulic oil (claim 8), the protective effect is additionally improved by the lubricating oil effect.
  • a tubular bellows can be used as a membrane.
  • a bellows has the advantage that due to the construction and the arrangement of the folds, the volume increase or volume reduction takes place "directed" along the longitudinal direction of the bellows. Frictional contact of the bellows with the hard inside of the compressor chamber is thus almost impossible.
  • the gas volume can also be provided in the interior of the bellows. This "directionality" of the volume change can be improved by positive guidance of the bellows along a rod with longitudinal bearings.
  • the bellows usually consists of a stainless steel alloy and, with the exception of hydrogen, is extremely gastight for all relevant working gases.
  • a working fluid reservoir is provided. This makes it possible conventional liquid pumps, eg. b. Gear pumps - claim 7 - to use.
  • the working fluid reservoir ensures that the correct amount of working fluid in the correct pressure range is always available for the pumping device.
  • the compressor device may be formed as a non-gas-conveying compressor or as a gas-conveying compressor - claim 3 -.
  • a gas-conveying compressor compressed working gas is supplied via a first working gas connection, which is designed as a high pressure port, a downstream device.
  • Working gas at a lower pressure is returned via a second working gas connection, which is designed as a low-pressure connection, in the compressor device-claim 13.
  • the working gas reservoir is connected via a differential pressure regulator with the gas volume of the compressor device. This ensures that the working gas is already precompressed available.
  • the working gas in the gas reservoir is located approximately at the level of the low pressure of the compressor device. If the pressure of the working gas in the compressor device drops below the pressure in the gas reservoir during the expansion phase, working gas flows via the differential pressure regulator from the gas reservoir into the gas volume of the compressor device.
  • the pumping device preferably comprises an electric drive, claim 6, since such a can be easily controlled.
  • Gear pumps are characterized by a long service life, low maintenance and low dead volume and are suitable for high pressure applications up to 300 bar.
  • a working fluid preferably hydraulic oil according to DIN 51524 is used, which is additionally dehydrated or anhydrous.
  • the hydraulic oil is in a closed system of pumping device, working fluid equalizing device and fluid volume in the compressor chamber, so that during operation no water from the environment can be absorbed by the hydraulic oil.
  • water can be used as a working fluid, especially when extremely impermeable membrane materials, eg. B. bellows made of stainless steel, are applied.
  • Water as a working fluid is also advantageous, since in the event of defects, water that has penetrated into a downstream cryocooler can be removed more easily than has penetrated into a downstream cooler Hydraulic oil.
  • water is suitable as a working medium in explosion-protected applications, since water is non-flammable and non-explosive. In addition, water is non-toxic and therefore environmentally friendly - claim 8.
  • helium or nitrogen is preferably used as the working gas.
  • the balloon-shaped membrane or the tubular bellows must be impermeable and resistant both for the particular working gas used and for the working fluid. Since a material can not always meet these different requirements, these membranes are preferably multi-layered of different materials - claim 10. Thus, the membrane can be adjusted both in terms of working fluid and with respect to the working gas.
  • the compressor device according to the invention provides compressed working gas in the frequency range necessary for the Gifford-McMahon cooler and pulse tube cooler - claims 11 to 13.
  • the compressor device is designed as a conveying compressor device, it can be used as a drive for a conventional refrigerating machine.
  • Fig. 1 shows a first exemplary embodiment for explaining the compressor device according to the invention, which is designed as a gas or working gas-promoting compressor device.
  • the compressor device comprises a compressor device 2, which has a gas-tight closed compressor chamber 4.
  • a balloon or a balloon-shaped membrane 6 is arranged in the compressor chamber 4.
  • the balloon 6 divides the compressor chamber 4 into a gas volume 8 for a working gas 10 and a liquid volume 12 for a working fluid 14.
  • the gas volume 8 is the interior of the balloon 6 and the fluid volume 12 is the area of the compressor chamber 4 outside the balloon 6
  • Fluid volume 12 outside of the balloon 6 is connected to a first working fluid line 18 which leads out of the compressor chamber 4.
  • the balloon 6 includes a first balloon port 19 connected to the high pressure gas outlet 20 and a second balloon port 21 connected to the low pressure gas outlet 22.
  • the first working fluid line 18 opens into a pumping device 24, which via a second working fluid line 26th is connected to a working fluid equalization device 28 in the form of a working fluid reservoir.
  • working fluid 14 is periodically pressed into the liquid volume 12 via the first working fluid line 18 and let out again.
  • the working gas 10 is compressed in the balloon 6.
  • the working gas 10 expands in the balloon 6 and thereby relaxes.
  • the compressed working gas 10 is the high-pressure gas outlet 20 a downstream consumer, z. B. a cryocooler - not shown - supplied.
  • the working gas 10 is returned to the gas volume 8 in the balloon 6 at a lower pressure, so that the circuit is closed.
  • the working fluid compensation device 28 ensures that sufficient working fluid 14 is always present and can be pumped into the fluid volume 12 in the compressor chamber 4 in order to compress the working gas 10 in the gas volume 8 in the balloon 6.
  • the working gas 10 expands the balloon 6 and working fluid 14 is forced into the working fluid equalizing device 28 via the first working fluid line 18, the pumping device 24 and the second working fluid line 26.
  • Fig. 2 shows a second exemplary embodiment for explaining the invention, which differs from the first exemplary embodiment Fig. 1 only differs in that a gear pump 30 is used as a pumping device, which is driven by an electric motor 32.
  • This type of pumping device has proved to be particularly advantageous, since they are characterized by a long service life, low maintenance and low dead volume. Due to their construction, they are suitable for high pressure applications up to 300 bar.
  • Fig. 3 shows a third exemplary embodiment for explaining the invention, which differs from the first exemplary embodiment Fig. 1 only differs in that the compressor device is designed as a non-promotional compressor device.
  • the balloon 6 comprised a balloon opening 40 connected to a working gas port 42. This opens into the gas volume 8 in the working gas port 40. About this working gas port 40, the periodic pressure change generated in the gas volume 8 is not shown - transferred to the downstream cooler.
  • Fig. 4 shows a first embodiment of the invention, which differs from the third exemplary embodiment Fig. 3 distinguished by a working gas balancing device.
  • the working gas balancing device comprises a working gas reservoir 50, which is connected via a first gas line 52, a differential pressure regulator 54 and a common gas line 55 with the gas volume 8 in the balloon 6.
  • the working gas reservoir 50 is also connected via a second gas line 56, a pressure relief valve 58 and the common gas line 55 to the gas volume 8 in the balloon 6.
  • the common gas line 55 opens into the balloon opening 40.
  • the working gas connection 42 branches off from the common gas line 55 and ends in a cooling device 60.
  • Working gas 10 flows into the gas volume 8 in the balloon 6 via the first gas line 52, the differential pressure regulator 54 and the common gas line 55 when the pressure of the working gas 10 in the gas volume 8 drops below the pressure in the working gas reservoir 50 due to low temperatures.
  • working gas reservoir 50 thus "working gas losses", which can occur in a downstream cooler, are compensated.
  • the working gas 10 to be supplied is already pre-compressed by the differential pressure regulator 54 for further compression in the gas volume 8 in the balloon 6.
  • Working gas 10 can flow into the working gas reservoir 50 via the second gas line 56, the pressure relief valve 58 and the common gas line 55 if the pressure of the working gas 10 in the gas volume 8 becomes too high.
  • Fig. 5 shows a second embodiment of the invention, which differs from the first embodiment Fig. 4 only differs in that instead of a balloon, a tubular bellows 80 is used, which surrounds the gas volume 8.
  • the bellows 80 has the advantage over the balloon 6 that the increase in volume and the reduction in volume are in each case directed along the longitudinal extent of the tubular bellows 80.
  • the bellows 80 is made of a stainless steel alloy and is extremely gas-tight with the exception of hydrogen for all relevant working gases.
  • the tubular bellows 80 does not bend at maximum volume against the longitudinal extent, the bellows is usually by a arranged in the longitudinal direction of the Faltebalgs stable rod with longitudinal bearings - not shown - out. In this way, it is reliably prevented that the bellows 80 can be damaged by frictional contact with the inner surface of the compressor chamber 4.
  • a gear pump driven by an electric motor may be used as the pumping means 24.
  • Hydraulic oils according to DIN 51524 are suitable as working fluids. These H, HL, HLP and HVLP oils are oils which are well tolerated with common sealants such as NBR (acrylonitrile-butadiene rubber) etc. NBR, however, is not sufficiently helium-tight. HF oils are often incompatible with commonly used sealing materials (http://de.wikipedia.org/wiki/List_of_Plastic_materials). For helium-tight balloons is synthetic rubber such. For example, chlorobutyl. When using helium as working gas 10, it is therefore advantageous if the balloon-shaped membrane 6 consists of several layers, for. B. from a working fluid 14 in the form of hydraulic oil facing layer of NBR and from a helium as working gas 10 facing layer of chlorobutyl.
  • water can be used as a working fluid, especially when extremely impermeable membrane materials, eg. B. bellows made of stainless steel, are used.
  • Water as a working fluid is also advantageous because in the event of defects, water that has penetrated into a downstream cryocooler can be removed more easily than hydraulic oil that has entered a downstream cooler.
  • water is suitable as a working medium in explosion-protected applications, since water is non-flammable and non-explosive. In addition, water is non-toxic and therefore environmentally friendly.
  • valve is provided in the working gas connection 42 leading out of the gas volume 8.
  • a valve can be provided here in order to build up a higher pressure difference in the expansion phase of the compressor device 2. Ie. Although the gas volume 8 in the compressor chamber 4 already increases in the expansion phase, the valve in the working gas connection 42 is still closed. Only when a certain pressure difference has built up, this valve is opened. In this way, the backflow of the working gas 10 can be accelerated via the working gas connection 42 into the compressor device 2.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Reciprocating Pumps (AREA)
  • Compressor (AREA)
  • Compressors, Vaccum Pumps And Other Relevant Systems (AREA)

Claims (14)

  1. Dispositif compresseur, comportant
    un système de compresseur (2) qui présente un espace de compresseur (4) ayant un volume défini, et dans lequel une membrane élastique, étanche aux gaz et aux fluides (6) subdivise l'espace de compresseur (4) en un volume de gaz (8) comportant un gaz de travail (10) et un volume de fluide (12) comportant un fluide de travail (14),
    un raccord de gaz de travail (20, 22 ; 40) qui débouche dans le volume de gaz (8), et un système de pompe (24) qui pompe périodiquement le fluide de travail (14) dans le volume de fluide (12) et ainsi le gaz de travail (10) est comprimé périodiquement dans le volume de gaz (8),
    dans lequel la membrane est configurée comme un ballon (6) ou comme un soufflet, et
    dans lequel le ballon (6) ou le soufflet entoure le volume de gaz (8),
    caractérisé en ce que
    le volume de gaz (8) est relié dans l'espace de compresseur (4) par un troisième raccord de gaz de travail (52) à un réservoir de gaz de travail (50).
  2. Dispositif compresseur selon la revendication 1, caractérisé en ce que le système de pompe (24) est relié à un réservoir de fluide de travail (28).
  3. Dispositif compresseur selon l'une quelconque des revendications précédentes, caractérisé en ce que, dans le volume de gaz (8) débouche un deuxième raccord de gaz de travail (22), et en ce que le premier raccord de gaz de travail (20) est conçu comme une sortie à haute pression et le deuxième raccord de gaz de travail (22) est conçu comme une entrée à basse pression.
  4. Dispositif compresseur selon la revendication 3, caractérisé en ce qu'un réservoir de gaz de travail (50) est relié par un régulateur de pression différentielle (54) avec le volume de gaz (8) dans l'espace de compresseur (4).
  5. Dispositif compresseur selon la revendication 3 ou 4, caractérisé en ce qu'un réservoir de gaz de travail (50) est relié par une soupape de surpression (58) avec le volume de gaz (8) dans l'espace de compresseur (4).
  6. Dispositif compresseur selon l'une quelconque des revendications précédentes, caractérisé en ce que le système de pompe (24) présente un entraînement électrique (32).
  7. Dispositif compresseur selon l'une quelconque des revendications précédentes, caractérisé en ce que le système de pompe (24) comprend une pompe à roue dentée (30).
  8. Dispositif compresseur selon l'une quelconque des revendications précédentes, caractérisé en ce que le fluide de travail (14) est une huile hydraulique ou de l'eau.
  9. Dispositif compresseur selon l'une quelconque des revendications précédentes, caractérisé en ce que le gaz de travail (10) est de l'hélium ou de l'azote.
  10. Dispositif compresseur selon l'une quelconque des revendications précédentes, caractérisé en ce que la membrane en forme de ballon ou le soufflet est constitué(e) de plusieurs couches.
  11. Dispositif de réfrigération comportant un dispositif compresseur selon l'une quelconque des revendications précédentes et un refroidisseur Gifford-Mc Mahon ou un refroidisseur à tube à gaz pulsé, dans lequel le système de compresseur (2) est couplé au refroidisseur Gifford-Mc Mahon ou au refroidisseur à tube à gaz pulsé.
  12. Dispositif de réfrigération selon la revendication 11, caractérisé en ce que le système de compresseur (2) présente un raccord à haute pression (20) et en ce que le refroidisseur Gifford-Mc Mahon ou le refroidisseur à tube à gaz pulsé est relié au raccord à haute pression (20) du système de compresseur (2).
  13. Dispositif de réfrigération selon la revendication 12, caractérisé en ce que le système de compresseur (2) présente un raccord à basse pression (22) et en ce que le refroidisseur Gifford-Mc Mahon ou le refroidisseur à tube à gaz pulsé est relié au raccord à basse pression (22) du système de compresseur (2).
  14. Machine frigorifique à compresseur, en particulier pour des réfrigérateurs classiques, comportant un dispositif compresseur selon l'une quelconque des revendications 1 à 10 précédentes, un évaporateur et un condensateur.
EP13742442.0A 2012-07-27 2013-07-26 Dispositif compresseur ainsi qu'un dispositif de réfrigération ainsi équipé et une machine frigorifique ainsi équipée Active EP2877748B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102012213293.7A DE102012213293B4 (de) 2012-07-27 2012-07-27 Kompressorvorrichtung sowie eine damit ausgerüstete Kühlvorrichtung und eine damit ausgerüstete Kältemaschine
PCT/EP2013/065822 WO2014016415A2 (fr) 2012-07-27 2013-07-26 Dispositif compresseur ainsi qu'un dispositif de réfrigération ainsi équipé et une machine frigorifique ainsi équipée

Publications (2)

Publication Number Publication Date
EP2877748A2 EP2877748A2 (fr) 2015-06-03
EP2877748B1 true EP2877748B1 (fr) 2019-02-06

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EP13742442.0A Active EP2877748B1 (fr) 2012-07-27 2013-07-26 Dispositif compresseur ainsi qu'un dispositif de réfrigération ainsi équipé et une machine frigorifique ainsi équipée

Country Status (5)

Country Link
US (1) US11231029B2 (fr)
EP (1) EP2877748B1 (fr)
JP (1) JP6240190B2 (fr)
DE (1) DE102012213293B4 (fr)
WO (1) WO2014016415A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102022115715A1 (de) 2022-06-23 2023-12-28 Pressure Wave Systems Gmbh Kompressorvorrichtung und Kühlvorrichtung mit Kompressorvorrichtung

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Publication number Priority date Publication date Assignee Title
DE102014217897A1 (de) 2014-09-08 2016-03-10 Pressure Wave Systems Gmbh Kompressorvorrichtung, eine damit ausgerüstete Kühlvorrichtung und ein Verfahren zum Betreiben der Kompressorvorrichtung und der Kühlvorrichtung
FR3100319B1 (fr) * 2019-09-04 2021-08-20 Absolut System Machine cryogénique régénérative

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WO2014016415A3 (fr) 2014-05-15
JP6240190B2 (ja) 2017-11-29
WO2014016415A2 (fr) 2014-01-30
US11231029B2 (en) 2022-01-25
US20150128616A1 (en) 2015-05-14
EP2877748A2 (fr) 2015-06-03
DE102012213293B4 (de) 2018-03-29
JP2015524892A (ja) 2015-08-27
DE102012213293A1 (de) 2014-01-30

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