Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
  • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
  • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
  • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
  • C08G18/6696—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/36 or hydroxylated esters of higher fatty acids of C08G18/38
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B62—LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
  • B62J—CYCLE SADDLES OR SEATS; AUXILIARY DEVICES OR ACCESSORIES SPECIALLY ADAPTED TO CYCLES AND NOT OTHERWISE PROVIDED FOR, e.g. ARTICLE CARRIERS OR CYCLE PROTECTORS
  • B62J1/00—Saddles or other seats for cycles; Arrangement thereof; Component parts
  • B62J1/002—Saddles having a seating area with a central cavity or depression
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
  • C08G18/30—Low-molecular-weight compounds
  • C08G18/36—Hydroxylated esters of higher fatty acids
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
  • C08G18/40—High-molecular-weight compounds
  • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
  • C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
  • C08G18/40—High-molecular-weight compounds
  • C08G18/48—Polyethers
  • C08G18/4833—Polyethers containing oxyethylene units
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
  • C08G18/40—High-molecular-weight compounds
  • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
  • C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G2110/00—Foam properties
  • C08G2110/0008—Foam properties flexible
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G2110/00—Foam properties
  • C08G2110/0033—Foam properties having integral skins

Definitions

• the present invention generally finds application in the field of human body support devices, and particularly relates to an improved and eco-friendly support structure.
• Human body-support devices such as saddles for bicycles or other pedal- powered machines, e.g. exercise bicycles and spinning bikes, but also seats and armchairs of machines in general, generally have a structure composed of at least one shell, designed to be fixed to the frame of the machine, a pad overlying the shell and a cover, designed to cover the pad and to contact the user body.
• Patent application CH-A-71 6/12 by the Applicant hereof discloses a human body support structure, such as a saddle or a seat for a vehicle or a similar machine, which basically comprises a shell, a pad overlying the shell and a cover for covering the pad.
• the pad and/or the cover are made from a formulation comprising at least one fossil-derived polymer material and at least one renewable source-derived material.
• the materials in this formulation are selected such that the carbon footprint, as defined in accordance with the standard ISO 14067 in terms of amount of carbon dioxide equivalent per unit weight of the formulation is relatively low and the percent radiocarbon-14, as defined according to the standard ASTM D6866 per unit weight of the formulation is relatively high.
• the formulation for forming the lower layer of the pad comprises a foamed polymeric preparation comprising a polyol phase, an isocyanate phase, an additive phase, and a plasticizer phase.
• the additive phase comprises fossil source-derived and renewable source-derived additives, the latter comprising additives, wherein the renewable source derivatives include additives selected from the group comprising hydrogenated castor oil-derived plasticizers, crosslinking agents, catalysts, foaming agents.
• the components of prior art support structures as defined above, which are commercially available, are typically made from fossil-derived polymer materials and wherein, preferably, the plasticizers are derived from castor oil.
• the comfort of the saddle as a whole may be associated with its compliance or resilience.
• the shell has the purpose of supporting the weight of the user and is made of a relatively rigid or semi-rigid plastic material, such as high-density polyethylene, polypropylene, polyethylene, polyamide, PVC and other similar resins
• the pad and the cover have the purpose of adding comfort to the saddle. Since these components are placed one on top of the other, and hence connected "in series", their compliance, and the comfort resulting therefrom, is given by the sum of the reciprocals of the stiffnesses of the individual components of the saddle and the stiffness of the saddle depends on the stiffness of the individual components, on the modulus of elasticity of the base material, the thickness and the residual stress state.
• the polymer materials are selected from those having a relatively low modulus of elasticity, i.e. a relatively low Shore hardness.
• plasticizer agents are a compound made of molecules that are much smaller than the macromolecules of the polymer, such that they may more evenly fit in between the macromolecules during mixing. Furthermore, the plasticizer must be able to be thoroughly mixed with the polymer, such that it may be stably and homogeneously incorporated in its mass and would not tend to migrate to the surface of the plastic material with time (which is known as "exudation"). The plasticizer shall also have little or no volatility, i.e. a high boiling point, because its effect would vanish when leaving the plastic material.
• plasticizers containing pure castor oil i.e. ricinoleic acid
• plasticizers containing pure castor oil may be particularly compact and characterized by a high hardness, e.g. of the order of 60 Shore C.
• the pad may be less comfortable for users.
• a general object of this invention is to overcome the above drawbacks, by providing a human body support structure that exhibits characteristics of eco- friendliness, reduced environmental impact, comfort, durability and cost- effectiveness.
• a particular object is to provide an eco-friendly human body support structure that is made of material having a maximized renewable source-based content and, as a whole, a low carbon footprint, thereby assisting an eco-friendly development.
• a further object is to provide a human body support structure having a minimized environmental impact, due to reduced employment synthetic materials derived from fossil sources.
• Another object is to provide a human body support structure that has high softness and mechanical properties, namely low dynamic flex fatigue and high resilience.
• FIG. 1 is a perspective view of a support structure, particularly a bicycle saddle, according to the invention.
• FIG. 2 shows a partially broken-away view of the saddle structure of FIG. 1 , to highlight its main components
• FIG. 3 is a plan view of the saddle structure of FIG. 1 ;
• FIG. 4 shows a view of the saddle structure of FIG. 3, as taken in a broken away view, along a longitudinal plane IV-IV;
• FIG. 5 shows a view of the saddle structure of FIG. 3, as taken in a broken away view, along a transverse plane V-V.
• a human body support structure particularly a saddle for bicycles, motorbikes or pedal-powered machines, such as an outdoor or indoor exercise bicycle.
• the saddle has a substantially elongate conventional shape, with a longitudinal symmetry axis, a tapered front portion designed for support of the scrotal or inguinal region of a user and a widened rear portion designed for support of the ischiadic region of the same user.
• the support structure may also have a different shape, such as the shape of a seat, an armrest or a headrest, for a vehicle of any type, such as a motor vehicle, a boat, an aircraft, a work machine, without departure from the scope of the invention.
• the saddle structure generally designated by numeral 1 , comprises a support shell 2 which is adapted to be secured to a frame 3, the latter being designed to be fixed to a bicycle or a similar vehicle.
• a pad is formed on the shell 2, and comprises a lower layer 5 of a foamed polymer, with a layer 6 of a polymer gel lying thereon, which has at least a partial shape memory effect.
• a cover 7 is formed on the pad 4, for covering the top surface of the pad and contact the body of the user.
• the shell 2 is of conventional type and is made of a synthetic material, such as high-density polyethylene, polypropylene, polyethylene, polyamide, PVC and other similar polymer materials.
• the shell 2 may be made of polypropylene.
• the upper layer 6 of the pad may be formed with a polyurethane or silicone gel.
• the coating 7 contains polymer materials such as PVC, thermoplastic polyurethane, polyurethane, Pebax® based on PA1 1 -Polyamide 1 1 .
• the support is allowed to be eco-friendly by forming the pad 4 and the cover 7 with a formulation comprising at least one fossil-derived polymer material and at least one renewable source-derived material.
• these generally consist of a foam or a gel which, as mentioned above, are generally of polyurethane nature, i.e. made of polymer chains consisting of urethane bonds.
• Urethane polymers or PUs are obtained by reacting a diisocyanate (of aromatic or aliphatic type) and a polyol (polyethylene glycol or polyester) in the presence of catalysts and other additives to impart the desired characteristics to the material. If so-called “foaming" agents are added to polyol formulations, foamed polyurethanes may be obtained.
• Foamed PUs may be found in the form of soft and flexible PUs, soft and integral or self-skinning PUs, rigid/structural PUs, rigid and compact PUs, and elastic and compact PUs.
• the first mechanism is the reaction of excess isocyanate with the hydroxyl groups of polyol
• the second mechanism produces a blowing gas and generates the foam structure.
• This latter process may be of chemical or physical nature: in the former case, the base synthesis reaction is combined with the reaction of the isocyanate group with water, whereby foam is obtained by the formation of urethane bonds and by simultaneous development of carbon dioxide gas resulting from the reaction with water.
• physical expansion utilizes part of the heat of the polymerization reaction to vaporize a chemically inert, low-boiling point liquid (blowing agent).
• foaming agents products such as hydrocholorofluorocarbons (HCFC) are used, in combination with water or alone.
• HCFC hydrocholorofluorocarbons
• the foaming agent is added to polyols and its action appears by vaporization induced by the heat developed by the main reaction, which is of exothermic type. All the other additives and catalysts are also added to the polyols.
• TDI toluene diisocyanate
• MDI diphenylmethane diisocyanate polymer
• integral self-skinning foams are used in seats and bicycle saddles. These foams are characterized by a cellular inner structure and a non- cellular outer surface, and are formed in a mold in a single step.
• the principle of their synthesis is the use of halogenated hydrocarbons as a blowing agent, without water, as well as the use of molds having cold metal walls. As the foam contacts the cold wall of the mold, the blowing agent condenses at the operating pressure (1 -4 bar). This will cause a solid outer cover to be formed, whereas the reaction mixture is still hot inside and cures into foam.
• Polyol oligomers are used whose molecular weight ranges from 3000 to 6500, whereas for isocyanate the choice depends on the type of process. TDI isocyanates are typically used for bicycle saddles.
• the formulation that is used for making the pad 4 and the cover 7 of the human body support comprises at least one fossil-derived polymer material and at least one renewable source-derived material.
• the amount of renewable source-derived polymer materials in the formulation ranges from 5% to 60%, preferably from 1 0% to 40% and more preferably from 1 5% to 35% by weight.
• a peculiar characteristic of the material is that the materials in the above formulation are selected such that the carbon footprint, as defined in accordance with the standard ISO 14067 in terms of amount of carbon dioxide equivalent (CO 2 e) is relatively low and the percent radiocarbon-14 (pMC), as defined according to the standard ASTM D6866 is relatively high.
• the amount of carbon dioxide equivalent (CO2e) associated with 1 kg of the formulation to form the pad is ⁇ 9.5kg, and preferably ranges from 9.3kg to 1 .9kg, more preferably from 4.9kg to 3.5kg.
• the percent radiocarbon-14(pMC) associated with 1 kg of the formulation to form the pad 4 is > 0.01 %, and preferably ranges from 60% to 5%, more preferably from 40% to 1 0%.
• the amount of carbon dioxide equivalent (CO2e) associated with 1 kg of the formulation to form the cover is ⁇ 9.5kg, and preferably ranges from 9.3kg to 1 .9kg, more preferably from 3.6kg to 2kg.
• the percent radiocarbon-14 (pMC) associated with 1 kg of the formulation of the cover 7 is > 0.01 %, and preferably ranges from 70% to 30%, more preferably from 60% to 40%.
• the lower layer 5 may be a foam obtained from a foamed polymer preparation, such as a foamed polyurethane adapted to form a high-performance product.
• the above mentioned polyurethane foam is selected with a relatively low Carbon Footprint value and a relatively high radiocarbon value pMC.
• the above mentioned polyurethane preparation is obtained by mixing a polyol phase composed of a blend of polyols for integral PU and flexible PU with different molecular weights, an isocyanate phase composed of a blend of isocyanates for integral PU and flexible PU, a fossil source-based and renewable source-based additive phase.
• the weight percent of the isocyanates for integral PU based on the total preferably ranges from 30% to 1 0%, more preferably from 25% to 1 5% and still more preferably from 20% to 3%.
• the weight percent of the isocyanates for flexible PU based on the total preferably ranges from 20% to 0.01 %, more preferably from 1 5% to 5% and still more preferably from 10% to 3%.
• the weight percent of the fossil source-derived additives based on the total preferably ranges from 15% to 0.01 %, more preferably from 1 0% to 5% and still more preferably from 6% to 5%.
• biological additives may be selected from glucides (carbohydrates), particularly from disaccharides.
• Sucrose may be selected from disaccharides, in the form of "icing sugar".
• Sucrose i.e. 0 6 ⁇ 2 ⁇ 6
• Sucrose is known to be formed by the reaction of a glucose molecule with a fructose molecule and the release of a water molecule.
• the hydroxyl groups of sucrose bond with those of isocyanate thereby assisting polymerization of the polyurethane mixture.
• the amount of "icing sugar” that can be added to the polyol-based formulation is limited because, as the percentage of this bio-based additive increases, firmness increases, and resilience decreases.
• this bio-based additive is advantageous due to the reduced cost of the material, i.e. about 1 €/kg.
• renewable source-derived additives may include additives selected from the group comprising plasticizers, cross-linking agents, catalysts, foaming agents.
• plasticizers may comprise ricinoleic acid, whose weight percent ranges from 15% to 1 8%, and is preferably of about 1 7%.
• the ricinoleic acid may be added by mixing castor oil as it is with the other components of the pad 4.
• the resulting pad 4 is not adequately comfortable, as it exhibits relatively high density and hardness.
• plasticizers containing hydrogenated castor oil both for the lower portion 5 of the pad 4 and for the gel 6 was found to improve the mechanical properties and the softness of the pad of the support, thereby increasing comfort for the user.
• plasticizers comprising acetylated monoglycerides, particularly derived from completely hydrogenated castor oil.
• a preferred component may be the acetic ester of monoglyceride (also known as acetylated monoglyceride) with CAS number 736150-63-3.
• the weight percent of the renewable source-derived additives based on the total preferably ranges from 55% to 0.01 %, more preferably from 45% to 10% and still more preferably from 33% to 10%.
• the weight percent of the renewable source-derived plasticizers based on the total preferably ranges from 30% to 0.01 %, more preferably from 25% to 5% and still more preferably from 1 7% to 5%.
• the weight percent of the renewable source-derived fillers based on the total ranges from 25% to 0.01 %, more preferably from 20% to 5% and still more preferably from 1 6% to 5%.
• the upper layer 6 of the pad 4 may comprise a polyurethane gel having a relatively low Carbon Footprint value and a relatively high radiocarbon value pMC.
• the weight percent of the fossil source-derived additives based on the total preferably ranges from 2% to 0.01 %, more preferably from 1 .75% to 0.25% and still more preferably from 1 % to 0.5%.
• the weight percent of the renewable source-derived additives based on the total preferably ranges from 70% to 0.01 %, more preferably from 45% to 25% and still more preferably from 35% to 5%.
• the weight percent of the isocyanates for integral PU based on the total preferably ranges from 5% to 0.01 %, more preferably from 4% to 1 % and still more preferably from 2.5% to 1 %.
• the weight percent of the isocyanates for flexible PU based on the total preferably ranges from 2% to 0.01 %, more preferably from 1 .75% to 0.25% and still more preferably from 1 % to 0.5%.
• the configuration of the product of this invention allows the provision of human body supports, and particularly bicycle saddles, characterized by a renewable source-derived (i.e. bio-based) material content that may even be 44% higher than in similar competitors' products, such as the saddle structure as disclosed and claimed in the European patent application EP 21 39751 .
• a renewable source-derived (i.e. bio-based) material content that may even be 44% higher than in similar competitors' products, such as the saddle structure as disclosed and claimed in the European patent application EP 21 39751 .
• polyurethane foam Two examples of polyurethane foam are provided below for the lower layer 5 of the padding, as obtained with products sold by Dow Chemical, with different amounts of renewable source-derived polymer materials, according to the following percentages, which are determined with reference to a 1 00% weight of the polyurethane foam.
• MONOETHYLENE GLYCOL cross-linking agent
• MONOETHYLENE GLYCOL cross-linking agent 1 .67%
• MONOETHYLENE GLYCOL cross-linking agent
• MONOETHYLENE GLYCOL cross-linking agent 1 .71 %

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• Chemical & Material Sciences (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Organic Chemistry (AREA)
• Engineering & Computer Science (AREA)
• Mechanical Engineering (AREA)
• Polyurethanes Or Polyureas (AREA)

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• 2012
  • 2012-06-27 CH CH00904/12A patent/CH706685A2/it not_active Application Discontinuation
• 2013
  • 2013-06-27 WO PCT/IB2013/055288 patent/WO2014002047A1/en active Application Filing
  • 2013-06-27 EP EP13765772.2A patent/EP2867107A1/en not_active Withdrawn

Non-Patent Citations (1)

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