EP2847140A1 - Ébauche préfrittée à usage dentaire - Google Patents

Ébauche préfrittée à usage dentaire

Info

Publication number
EP2847140A1
EP2847140A1 EP13721758.4A EP13721758A EP2847140A1 EP 2847140 A1 EP2847140 A1 EP 2847140A1 EP 13721758 A EP13721758 A EP 13721758A EP 2847140 A1 EP2847140 A1 EP 2847140A1
Authority
EP
European Patent Office
Prior art keywords
blank
glass
ceramic
sintered
dental
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP13721758.4A
Other languages
German (de)
English (en)
Inventor
Harald Bürke
Christian Ritzberger
Marcel Schweiger
Volker Rheinberger
Diana Tauch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ivoclar Vivadent AG
Original Assignee
Ivoclar Vivadent AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ivoclar Vivadent AG filed Critical Ivoclar Vivadent AG
Priority to EP13721758.4A priority Critical patent/EP2847140A1/fr
Publication of EP2847140A1 publication Critical patent/EP2847140A1/fr
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C13/00—Dental prostheses; Making same
    • A61C13/0003—Making bridge-work, inlays, implants or the like
    • A61C13/0022—Blanks or green, unfinished dental restoration parts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C13/00—Dental prostheses; Making same
    • A61C13/08—Artificial teeth; Making same
    • A61C13/082—Cosmetic aspects, e.g. inlays; Determination of the colour
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/15—Compositions characterised by their physical properties
    • A61K6/16—Refractive index
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/802—Preparations for artificial teeth, for filling teeth or for capping teeth comprising ceramics
    • A61K6/827—Leucite
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/831—Preparations for artificial teeth, for filling teeth or for capping teeth comprising non-metallic elements or compounds thereof, e.g. carbon
    • A61K6/833—Glass-ceramic composites
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B32/00—Thermal after-treatment of glass products not provided for in groups C03B19/00, C03B25/00 - C03B31/00 or C03B37/00, e.g. crystallisation, eliminating gas inclusions or other impurities; Hot-pressing vitrified, non-porous, shaped glass products
    • C03B32/02—Thermal crystallisation, e.g. for crystallising glass bodies into glass-ceramic articles
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/095—Glass compositions containing silica with 40% to 90% silica, by weight containing rare earths
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00—Compositions for glass with special properties
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C13/00—Dental prostheses; Making same
    • A61C13/0003—Making bridge-work, inlays, implants or the like
    • A61C13/0004—Computer-assisted sizing or machining of dental prostheses
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C13/00—Dental prostheses; Making same
    • A61C13/08—Artificial teeth; Making same
    • A61C13/083—Porcelain or ceramic teeth
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2204/00—Glasses, glazes or enamels with special properties
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00—Compositions for glass with special properties
    • C03C4/0007—Compositions for glass with special properties for biologically-compatible glass
    • C03C4/0021—Compositions for glass with special properties for biologically-compatible glass for dental use
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00—Compositions for glass with special properties
    • C03C4/0028—Compositions for glass with special properties for crystal glass, e.g. lead-free crystal glass
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49567—Dental appliance making
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree

Definitions

  • the invention relates to a pre-sintered blank for dental purposes based on lithium metasilicate glass ceramic, which is particularly suitable for the production of dental restorations.
  • WO 2010/010087 describes porous silicate-ceramic molded bodies which are processed to veneer shells for dental technology.
  • the moldings are intended to have a specific density in order to avoid damage during processing with milling or grinding systems, e.g. by preventing material outbreaks and being suitable for the selected system.
  • No. 5,106,303 describes the manufacture of dental crowns and inlays by copying grinding compacted ceramic bodies, which may optionally be pre-sintered. to To achieve the desired geometry, the bodies are ground to an enlarged shape to account for the shrinkage that occurs in the subsequent sintering to the desired high density.
  • the ceramic material used is in particular aluminum oxide, which may optionally have reinforcing additives.
  • US Pat. No. 5,775,912 describes presintered pellets of dental porcelain, from which a tooth structure is ground by means of CAD / CAM systems. This tooth structure is embedded in potting material, sintered, and stripped of the potting material to give the desired dental restoration.
  • the dental porcelains used are glass ceramics based on leucite.
  • US 6,354,836 discloses methods of making dental restorations using CAD / CAM methods.
  • Unsintered or pre-sintered blocks of ceramic material and in particular aluminum oxide and zirconium oxide are used, which after grinding lead to an enlarged mold and subsequent dense sintering to high-strength dental restorations.
  • it is considered essential that the temperature differences in the sintering furnace used are less than 10 ° C, in order to ensure small variations in the finally achieved dimensions of the restorations.
  • the invention is therefore based on the object to provide blanks available that avoid these disadvantages and therefore are less susceptible to variations in the sintering temperature used to produce them. Likewise, these blanks should be easily deformed by conventional grinding and milling process to dental restorations with the desired geometry without the supply of liquid would be required in these methods. Furthermore, these blanks should be processable by dense sintering to high-strength and visually very appealing dental restorations. This object is achieved by the pre-sintered blank according to claims 1 to 9. The invention likewise provides the process for producing the blank according to claims 10 and 11, the process for producing dental restorations according to claims 12 to 15 and the use of the blank according to claim 16.
  • the pre-sintered blank for dental purposes according to the invention is characterized in that it is based on lithium metasilicate glass ceramic and has a relative density of 66 to 90%, in particular 68 to 88% and preferably 70 to 86%, based on the true density of the corresponding densely sintered Having lithium disilicate glass ceramic.
  • the relative density is the ratio of the density of the pre-sintered blank to the apparent density of the corresponding densely sintered lithium disilicate glass ceramic.
  • the determination of the true density of the corresponding densely sintered lithium disilicate glass-ceramic is carried out by heat-treating the pre-sintered blank in a furnace heated to 920 ° C. for 20 minutes.
  • the resulting dense-sintered lithium disilicate glass-ceramic is converted into a powder having a mean particle size of 10 to 30 ⁇ m. in particular of 20 ym, based on the number of particles, is ground and the density of the powder is determined by means of pycnometer.
  • the particle size was determined using the CILAS® Particle Size Analyzer 1064 from Quantachrome GmbH & Co. KG by means of laser diffraction according to ISO 13320 (2009).
  • the blank according to the invention can not only be machined dry in a simple manner, but it can also be produced at significantly different Vorsintertemperaturen without this would lead to a significant change in shrinkage, which in a subsequent dense sintering occurs.
  • the enlargement factor taking into account the shrinkage occurring can be determined very accurately.
  • the blank consists essentially of the lithium metasilicate glass ceramic.
  • the blank consists of the lithium metasilicate glass ceramic.
  • the glass ceramic has lithium metasilicate as main crystal phase.
  • the term "main crystal phase” designates the crystal phase, which has the highest volume fraction compared to other crystal phases.
  • the glass ceramic contains more than 20% by volume, preferably more than 25% by volume and particularly preferably more than 30 Vol .-% of lithium metasilicate crystals, based on the total glass ceramic.
  • the lithium metasilicate glass-ceramic preferably contains S1O 2 and L1 2 O in a molar ratio ranging from 1.75 to 3.0, more preferably from 1.8 to 2.6, and most preferably from 2.2 to 2.5.
  • the lithium metasilicate glass ceramic contains at least one of the following components:
  • Me (I) is selected from 2 0 Na 2 ⁇ 0, K 2 0, Rb 2 ⁇ 0, CS 2 O or mixtures thereof,
  • Me (II) O is selected from CaO, BaO, MgO, SrO, ZnO and mixtures thereof,
  • Me (III) 2 0 3 is selected from A1 2 0 3 , La 2 0 3 , Bi 2 0 3 , Y 2 0 3 , Yb 2 0 3 and mixtures thereof, Me (IV) 0 2 is selected from Zr0 2 , Ti0 2 , Sn0 2 , Ge0 2 and
  • Me (V) 2O5 is selected from Ta 2 O, M 2 O 5 , V 2 O 5 and mixtures thereof,
  • Me (VI) 0 3 is selected from WO 3 , M0O3 and mixtures thereof, and
  • Nucleating agent is selected from P 2 O 5 , metals and mixtures thereof.
  • oxides of monovalent elements Me (I) are 2 0 Na 2 ⁇ 0 and K 2 O are preferred.
  • oxides of divalent elements Me (II) O, CaO, MgO, SrO and ZnO are preferable.
  • oxides of tetravalent elements Me (IV) O 2, ZrO 2, TiO 2 and GeO 2 are preferred.
  • the lithium metasilicate glass ceramic preferably contains colorants and / or fluorescers.
  • colorants and fluorescers are oxides of d and f elements, such as the oxides of Ti, V, Sc, Mn, Fe, Co, Ta, W, Ce, Pr, Nd, Tb, Er, Dy, Gd, Eu and Yb and ceramic color pigments, such as colored spinels. It is also possible to use as colourants metal colloids, eg of Ag, Au and Pd, which in addition may also function as nucleating agents. These Metal colloids can be formed, for example, by reduction of corresponding oxides, chlorides or nitrates during the melting and crystallization processes.
  • the blank according to the invention preferably has at least two regions, in particular layers, which differ in their coloration or translucency.
  • the blank has at least 3 and up to 10, more preferably at least 3 and up to 8, and most preferably at least 4 and up to 6 different in coloration or translucency areas, especially layers. Just by the presence of several differently colored areas, especially layers, it is very good to imitate natural tooth material. It is also possible that at least one of the regions or the layers has a color gradient in order to ensure a stepless color transition.
  • the blank according to the invention has a holder for attachment in a processing device.
  • the blank according to the invention has an interface for connection to a dental implant.
  • the holder allows the attachment of the blank in a processing device, such as in particular a milling or
  • the holder is usually in the form of a pin and is preferably made of metal or plastic.
  • the interface provides a connection between an implant and the dental restoration placed thereon, such as abutment crowns obtained by machining and densely sintering the blank.
  • This compound is preferably rotationally stable.
  • the interface is in particular in the form of a recess, such as a bore before.
  • the specific geometry of the interface is usually chosen as a function of the particular implant system used.
  • the invention also relates to a method for producing the blank according to the invention, in which
  • Lithium silicate glass in powder or granular form is pressed into a glass blank
  • the glass blank is heat-treated to produce a pre-sintered lithium metasilicate glass ceramic-based blank, the temperature of the heat treatment
  • At least 500 ° C in particular at least 540 ° C and preferably at least 580 ° C, and is in a range which extends over at least 30K, in particular at least 50K and preferably at least 70K and in which the relative density by less than 2.5%, in particular less than 2.0% and preferably less than 1.5% varies.
  • step (a) lithium silicate glass in powder or granular form is pressed into a glass blank.
  • the lithium silicate glass employed is usually prepared by mixing a mixture of suitable starting materials, e.g. Carbonates, oxides, phosphates and fluorides, is melted at temperatures of in particular 1300 to 1600 ° C for 2 to 10 h. To obtain a particularly high homogeneity, the glass melt obtained is poured into water to form a glass granulate, and the granules obtained are then remelted.
  • suitable starting materials e.g. Carbonates, oxides, phosphates and fluorides
  • the granules are then comminuted to the desired particle size and in particular ground into powder having an average particle size of ⁇ 50 ym, based on the number of particles.
  • the granules or powder is then, if appropriate with the addition of pressing aids or binders, usually placed in a mold and pressed into a glass blank.
  • the case applied pressure is in particular in the range of 20 to 200 MPa.
  • uniaxial presses are preferably used.
  • the pressing can also be carried out in particular as isostatic pressing, preferably as cold isostatic pressing.
  • glass powders or granules with different coloration or translucency it is possible to produce glass blanks which have differently colored or differently translucent areas and in particular layers.
  • differently colored powders or granules may be stacked in a mold to form a multi-colored glass blank. This multicolor makes it possible to give the final dental restorations the appearance of natural tooth material.
  • step (b) the obtained single or multi-colored glass blank is subjected to a heat treatment to effect the presintering and controlled crystallization of lithium metasilicate and thus the formation of lithium metasilicate glass-ceramic.
  • the heat treatment takes place in particular at a temperature of 500 to 800 ° C, preferably from 540 to 800 ° C and more preferably from 580 to 750 ° C instead.
  • the heat treatment is carried out in particular for a period of 5 to 60 minutes, preferably 10 to 40 minutes and particularly preferably 15 to 30 minutes.
  • the temperature range (b) (ii) describes a range in which, despite change of the temperature, the relative density scarcely changes. This range is therefore also referred to below as "plateau.”
  • the possible variation in the relative density in this range is calculated as a percentage of the maximum and minimum values of the relative density in the range
  • lithium metasilicate glass ceramics in the presintering in certain Temperature ranges show essentially no change in the relative density and thus the linear shrinkage and the magnification factor in dense sintering.
  • These areas can be recognized as "plateaus" in the graphical representation of relative density, linear shrinkage or magnification factor against the temperature Accordingly, important properties of the blank in this area are essentially independent of the temperature for the accuracy of fit of the later dental restoration the practice important advantage that the blank is rather insensitive to temperature fluctuations or temperature gradients in the sintering furnace, for example, as long as the temperature is in the range of the "plateau".
  • the resulting glass powder compact is heat treated for 5 to 60 minutes, preferably 10 to 40 minutes and more preferably 15 to 30 minutes at a temperature which
  • (ii) is within a range of at least 30K, more preferably at least 50K and preferably at least
  • FIG. 2 illustrates the phases which are usually carried out during heat treatment of a glass powder compact by plotting the enlargement factor against the temperature for a compact having a composition according to Example 1.
  • phase I up to about 400 ° C, the heating and the removal of any existing binder take place.
  • phase II of about 400 to about 600 ° C sintering and crystallization, and in phase III, the plateau, from about 600 to about 700 ° C is an inventive pre-sintered blank based on lithium metasilicate glass ceramic before.
  • phase IV starting from about 700 ° C, the sintering and crystallization of lithium disilicate.
  • the pre-sintered blank according to the invention is preferably in the form of blocks, disks or cylinders. In these forms, further processing is the desired one
  • the pre-sintered blank is further processed in particular for dental restorations.
  • the invention therefore also relates to a method for producing dental restorations in which (i) the presintered blank based on lithium metasilicate glass ceramic according to the invention is shaped by machining into a preliminary stage of the dental restoration,
  • the precursor is substantially densely sintered to give the dental restoration
  • step (iii) optionally finishing the surface of the dental restoration.
  • the machining usually takes place by means of material-removing processes and in particular by milling and / or grinding. It is preferred that the machining with computer-controlled milling and / or Grinding devices takes place. Particularly preferably, the machining takes place in the context of a CAD / CAM method.
  • the blank according to the invention can be machined very easily, in particular because of its open porosity and low strength. It is of particular advantage that the use of liquids during grinding or milling is not required. In contrast, conventional blanks often require so-called wet grinding processes.
  • the machining is carried out regularly so that the precursor obtained represents an enlarged form of the desired dental restoration.
  • the blank according to the invention has the particular advantage that the enlargement factor to be applied to it can be determined very accurately.
  • the magnification factor is the factor by which the precursor has to be enlarged or ground from the pre-sintered blank in order that, after dense sintering, the dental restoration obtained has the desired dimensions.
  • the magnification factor F v , the relative density p r and the remaining linear shrinkage S can be converted into each other as follows:
  • the blank produced by the method according to the invention described above is used as the pre-sintered blank.
  • the resulting precursor is substantially densely sintered to produce the dental restoration of the desired geometry.
  • the precursor is preferably heat-treated at a temperature of 800 to 1000 ° C, in particular 850 to 950 ° C.
  • the heat treatment is usually carried out for a period of 2 to 40 minutes, in particular 2 to 30 minutes and particularly preferably 5 to 15 minutes. During this heat treatment, not only dense sintering, but also the conversion of the lithium metasilicate glass-ceramic takes place regularly
  • Lithium disilicate glass ceramic Lithium disilicate glass ceramic.
  • lithium disilicate glass ceramic preferably forms the main crystal phase.
  • This lithium disilicate glass ceramic has excellent optical and mechanical properties as well as high chemical stability.
  • the dental restorations are preferably selected from crowns, abutments, abutment crowns, inlays, onlays, veneers, shells and bridges, as well as throws for multi-part restorations, which are e.g. may consist of oxide ceramics, metals or dental alloys.
  • the precursor of the dental restoration is supported in order to avoid distortion. It is preferred that the support consists of the same material as the precursor and thus has the same sintering shrinkage.
  • the support may e.g. be in the form of a support structure or support form adapted from its geometry to the precursor.
  • the surface of the dental restoration can still be finished. It is in particular possible to perform a glaze firing at a temperature of 700 to 900 ° C or to polish the dental restoration. Due to the described properties of the pre-sintered blank according to the invention, it is particularly suitable for the production of dental restorations.
  • the invention therefore also relates to the use of the blank for the production of dental restorations and in particular of crowns, abutments, abutment crowns, inlays, onlays, veneers, shells and bridges and throws.
  • the starting glasses were first melted in 100 to 200 g scale from conventional raw materials at 1400 to 1500 ° C, the melting was very well possible without the formation of bubbles or streaks.
  • water glass frits were prepared, which were then melted for homogenization for a second time at 1450 to 1550 ° C for 1 to 3 h.
  • the resulting glass melts were then cooled to 1400 ° C and converted by pouring into water to finely divided granules.
  • the granules were dried and ground into powders having an average particle size of ⁇ 100 ⁇ m, based on the number of particles.
  • These powders were spray-dried with a moistened commercially available binder and then pressed at a pressure of 20 to 200 MPa to powder compacts.
  • the powder compacts were then heat treated for 2 to 120 minutes at a temperature within the range indicated in Table I for each composition as a plateau. After this heat treatment, blanks according to the invention were pre-sintered and based on lithium metasilicate glass ceramic.
  • Example 17 Investigation of the sintering behavior of the composition according to Example 1
  • a glass having the composition of Example 1 was melted and ground to a glass powder having an average particle size of 20 ⁇ m, based on the number of particles.
  • This glass powder was provided with a commercially available binder and pressed uniaxially to cylinders at a pressure of 80 MPa.
  • the sintering behavior of these cylindrical blanks was investigated by heat treating them at different temperatures in a Programat® P700 furnace from Ivoclar Vivadent AG. In each case, a heating rate of 10 ° C / min and a holding time of 15 min at the respective temperature was selected. Thereafter, the blanks were cooled to room temperature, and then the specific gravity of the blanks was determined with respect to the pure density of the corresponding dense-sintered lithium disilicate glass-ceramic. From the relative density, the remaining linear shrinkage and therefrom the magnification factor to be selected were calculated.
  • Example 18 Investigation of the sintering behavior of the composition according to Example 8
  • Example 8 On the composition according to Example 8, the sintering behavior was investigated analogously to Example 17. A glass having the composition of Example 8 was melted and ground to a glass powder having an average particle size of 15 ⁇ m, based on the number of particles. This glass powder was compressed into cylinders as previously described. The sintering behavior of these cylindrical blanks was investigated by heat-treating the test specimens at different temperatures in a Programat® P700 furnace from Ivoclar Vivadent AG. In each case, a heating rate of 10 ° C / min and a holding time of 2 min at the respective temperature was selected.
  • the blanks were cooled to room temperature, and then the relative density of the blanks was respectively determined with respect to the density of the corresponding dense-sintered lithium disilicate glass-ceramic. From the relative density, the remaining linear shrinkage and therefrom the magnification factor to be selected were calculated.
  • the calculated magnification factor is plotted against the Vorsintertemperatur. It can be seen that the magnification factor surprisingly remains substantially constant in the range of 580 to 700 ° C and the curve forms a plateau. Thus, when using a pre-sintering in this area, a blank according to the invention can be generated, for which a very accurate indication of the magnification factor to be selected is possible.

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Abstract

L'invention concerne des ébauches préfrittées à base de vitrocéramique au métasilicate de lithium, ces ébauches étant adaptées en particulier à la fabrication d'éléments de restauration dentaire.
EP13721758.4A 2012-05-11 2013-05-10 Ébauche préfrittée à usage dentaire Pending EP2847140A1 (fr)

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EP13721758.4A EP2847140A1 (fr) 2012-05-11 2013-05-10 Ébauche préfrittée à usage dentaire

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EP12167759 2012-05-11
PCT/EP2013/059699 WO2013167722A1 (fr) 2012-05-11 2013-05-10 Ébauche préfrittée à usage dentaire
EP13721758.4A EP2847140A1 (fr) 2012-05-11 2013-05-10 Ébauche préfrittée à usage dentaire

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CN104334509A (zh) 2015-02-04
HK1202521A1 (en) 2015-10-02
RU2014150037A (ru) 2016-07-10
US20150140513A1 (en) 2015-05-21
JP2019048179A (ja) 2019-03-28
KR102018937B1 (ko) 2019-09-05
KR20150030657A (ko) 2015-03-20
CA2872146A1 (fr) 2013-11-14
US20170340420A1 (en) 2017-11-30
JP6896695B2 (ja) 2021-06-30
RU2612707C2 (ru) 2017-03-13
US9757217B2 (en) 2017-09-12
KR20170007535A (ko) 2017-01-18
US10206761B2 (en) 2019-02-19
JP2015515897A (ja) 2015-06-04
IN2014DN09497A (fr) 2015-07-17
JP2017080528A (ja) 2017-05-18
WO2013167722A1 (fr) 2013-11-14
BR112014027613A2 (pt) 2017-06-27
MX2014013673A (es) 2015-05-11

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