EP2835462B1 - Revêtement de sol CV comprenant un non-tissé et non-tissé - Google Patents

Revêtement de sol CV comprenant un non-tissé et non-tissé Download PDF

Info

Publication number
EP2835462B1
EP2835462B1 EP14002745.9A EP14002745A EP2835462B1 EP 2835462 B1 EP2835462 B1 EP 2835462B1 EP 14002745 A EP14002745 A EP 14002745A EP 2835462 B1 EP2835462 B1 EP 2835462B1
Authority
EP
European Patent Office
Prior art keywords
range
nonwoven
fibres
hybrid
hybrid nonwoven
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP14002745.9A
Other languages
German (de)
English (en)
Other versions
EP2835462A1 (fr
Inventor
Elvira Rempt
Stefan Gröger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johns Manville Europe GmbH
Original Assignee
Johns Manville Europe GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johns Manville Europe GmbH filed Critical Johns Manville Europe GmbH
Priority to PL14002745T priority Critical patent/PL2835462T3/pl
Priority to RS20180591A priority patent/RS57245B1/sr
Publication of EP2835462A1 publication Critical patent/EP2835462A1/fr
Application granted granted Critical
Publication of EP2835462B1 publication Critical patent/EP2835462B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4209Inorganic fibres
    • D04H1/4218Glass fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0011Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326Condensation or reaction polymers
    • D04H1/435Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/002Inorganic yarns or filaments
    • D04H3/004Glass yarns or filaments
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0022Glass fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0036Polyester fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0005Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface
    • D06N7/006Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by the textile substrate as base web
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10Organic non-cellulose fibres
    • D21H13/20Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/24Polyesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/36Inorganic fibres or flakes
    • D21H13/38Inorganic fibres or flakes siliceous
    • D21H13/40Inorganic fibres or flakes siliceous vitreous, e.g. mineral wool, glass fibres
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18Paper- or board-based structures for surface covering
    • D21H27/22Structures being applied on the surface by special manufacturing processes, e.g. in presses
    • D21H27/26Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/06Building materials
    • D06N2211/063Wall coverings
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/06Building materials
    • D06N2211/066Floor coverings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23907Pile or nap type surface or component
    • Y10T428/23957Particular shape or structure of pile

Definitions

  • the present invention relates to a CV flooring comprising a nonwoven fabric as a structural layer. It further relates to a nonwoven fabric.
  • CV (Cushioned Vinyl) floor coverings are known.
  • fiber webs are used as a carrier material.
  • the fiber webs used here are typically made of glass fibers, whereby the use of specific mixtures of different glass fibers for the production of corresponding carrier glass fiber webs is known (see. DE 102011011056 A1 whose disclosure is included in the content of the present application).
  • DE 102011011056 A1 whose disclosure is included in the content of the present application.
  • a nonwoven fabric namely a hybrid nonwoven fabric comprising a base web having 10-80 wt.% glass fibers and 20-90 wt.% PET fibers.
  • polyvinyl alcohol is provided in an amount of 5-35% by weight based on the combined weight of the glass fibers and the PET fibers as a binder.
  • a secondary binder is provided in an amount of 5-35% by weight based on the combined weight of the glass fibers, the PET fibers and the polyvinyl alcohol.
  • the secondary binder may be, for example, styrene-acrylate.
  • the glass fibers preferably have a mean diameter between 6 and 16 ⁇ m and an average length between 4 and 25 mm.
  • the PET fibers likewise preferably have an average diameter of between 6 and 16 ⁇ m and an average length of between 4 and 25 mm.
  • the present invention is directed to providing a nonwoven fabric which can be produced cost-effectively and which is particularly suitable for use as a carrier material in floor coverings and thus has a favorable influence on the properties of the finished floor covering. Furthermore, it is an object of the present invention to provide a correspondingly favorable properties having CV floor covering with a nonwoven fabric as a carrier material.
  • a nonwoven which is designed as a hybrid nonwoven fabric by comprising glass fibers, polymer fibers and binder, wherein the glass fibers have an average diameter between 6 and 13 .mu.m and a
  • the polymer fibers are staple fibers having an average fineness between 0.2 and 0.6 dtex and an average length between 2 and 4 mm, and the weight fraction of the polymer fibers is between 5 and 20% of the dry nonwoven fabric ,
  • a specific combination of synergistically interacting features is characteristic of the nonwoven fabric according to the present invention in that it consists of relatively short fibers interconnected by a binder both in terms of material and in typical length and thickness dimensions -
  • the proportion by weight of the polymer fibers being substantially lower than that Weight fraction of glass fibers in that the polymer fibers make up only between 5 and 20, preferably between 10 and 15 percent by weight of the dry fiber web.
  • the ratio between the weight fraction of the glass fibers and that of the polymer fibers to the fibrous web is typically between 5 and 8, for example - at a weight fraction of the binder of between about 20 and 30% - about 6.5.
  • the hybrid nonwoven fabric according to the invention is characterized by a number of very advantageous for use as a support material in CV floor coverings properties.
  • such physical properties mechanical strength, density, pore volume, void structure, etc.
  • already particularly thin hybrid fiber webs according to the invention fulfill the requirements applicable to structural materials of floor coverings.
  • This is therefore a not to be underestimated advantage, because in this way (already due to the reduced thickness of the nonwoven fabric), the amount of impregnating agent with which the nonwoven fabric is to be treated, can be reduced.
  • the non-woven fabric according to the invention even has a surface structure of special quality and homogeneity, so that even a flooring produced using it is characterized by a special surface quality. This is an invaluable advantage for a surface finish, especially through printing.
  • the present invention provides excellent nonwoven fabrics in terms of their properties, namely, for example, by avoiding additional fiber coating disadvantageous in terms of material and processing costs, with minimal effort and without the use of health hazardous respirable micro-glass fibers.
  • the polymer fibers consist of a polymer having a density between about 1.2 and 1.6 g / cm 3 . It is particularly favorable if the polymer fibers consist entirely or at least predominantly of PET (polyethylene terephthalate). Because when using such a material for the production of polymer fibers, the latter have such properties that are suitable for the nonwoven fabric process, to which there are empirical values from the production of pure glass fiber webs.
  • the hybrid nonwoven fabric according to the invention is prepared by passing the glass fibers and the polymer fibers containing water in circulation through a belt filter, the fiber mixture thereby deposited in the form of a fiber layer with a predetermined layer thickness on the belt screen Excess circulating water is removed from the fibrous layer, the fibrous layer is mixed with binder and the binder-added fibrous layer is dried.
  • the particular advantages of the glass fiber fleece according to the invention set out above are particularly pronounced if the mean fineness of the polymer fibers is between 0.3 and 0.4 dtex. Excellent results can be achieved, for example, when using PET fibers with a fineness of 0.33 dtex and a mean length between 2.5 and 3.5 mm.
  • the mean fiber diameter of the glass fibers is between 7 and 10 ⁇ m and / or the mean length of the glass fibers is between 7 and 9 mm.
  • the glass fibers are not longer than 15 mm and not thicker than 10 ⁇ m; because at dimensions above these values, the surface properties of the hybrid nonwoven fabric deteriorate.
  • the glass fibers consist of C glass and / or E glass.
  • the basis weight of the glass fiber fleece is between 25 and 80 g / m 2 , more preferably between 40 and 60 g / m 2 . Again, this results in very particularly advantageous properties of the hybrid nonwoven fabric according to the invention in the In view of its use as a substrate in CV floorings having excellent properties.
  • the binder comprises urea resin or polyacrylic acid binder.
  • the binder may also include polyacrylic acid.
  • Outstanding properties result when the binder comprises a mixture of urea resin and polymer dispersion or a mixture of polyacrylic acid binder and polymer dispersion.
  • the binder may contain an additive (or additives) which may account for up to 50% of the total weight of the binder.
  • the additive (or the additives) can thereby the properties of the binder with regard to the individual Specifically modify or optimize the determination of the hybrid fiber fleece.
  • Typical additives include kaolin and TiO 2 .
  • additives can not only technically optimize the binder, but additives are also useful in reducing costs by reducing the need for expensive binders.
  • the present invention relates to the above statements equally on the untreated hybrid nonwoven fabric, on a pretreated for further processing to a CV flooring, in particular provided with an additional impregnation hybrid nonwoven fabric, wherein the impregnating agent in particular plastisol or another PVC-based agent, as well as on the finished CV flooring produced using the hybrid nonwoven fabric according to the invention, which comprises a wear layer and a structural layer, wherein the structural layer comprises an impregnated hybrid nonwoven fabric according to the invention (see above).
  • hybrid nonwoven fabric according to the invention in the production of CV floor coverings is in the foreground, which concerns the particular suitability of the hybrid nonwoven fabric according to the invention, various aspects of the hybrid fiber nonwoven according to the invention set out above make this possibly also for others Applications can be used with particular advantage.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Nonwoven Fabrics (AREA)
  • Floor Finish (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paper (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Laminated Bodies (AREA)

Claims (15)

  1. Non-tissé, à savoir non-tissé hybride, comprenant des fibres de verre, des fibres polymères et des agents liants, présentant les caractéristiques suivantes :
    les fibres de verre présentent un diamètre moyen compris entre 6 et 13 µm et une longueur moyenne comprise entre 6 et 15 mm ;
    les fibres polymères sont des fibres courtes, d'une finesse moyenne comprise entre 0,2 et 0,6 dtex et d'une longueur moyenne comprise entre 2 et 4 mm ;
    la part en poids des fibres polymères est comprise entre 5 et 20 % du non-tissé sec ;
    l'agent liant comprend de la résine d'urée, de préférence un mélange de résine d'urée et d'une dispersion polymère, ou un liant d'acide polyacrylique, de préférence, un mélange d'un liant d'acide polyacrylique et d'une dispersion polymère ;
    le grammage est compris entre 25 g/m2 et 80 g/m2.
  2. Non-tissé hybride selon la revendication 1, caractérisé en ce que les fibres polymères sont en PET.
  3. Non-tissé hybride selon la revendication 1 ou la revendication 2, caractérisé en ce que la part en poids de l'agent liant est comprise entre 15 et 35 %, de préférence est comprise entre 20 et 30 % du non-tissé sec.
  4. Non-tissé hybride selon l'une quelconque des revendications 1 à 3, caractérisé en ce que les fibres polymères présentent une finesse moyenne comprise entre 0,3 et 0,4 dtex.
  5. Non-tissé hybride selon l'une quelconque des revendications 1 à 4, caractérisé en ce que les fibres polymères présentent une longueur moyenne comprise entre 2,5 et 3,5 mm.
  6. Non-tissé hybride selon l'une quelconque des revendications 1 à 5, caractérisé en ce que les fibres de verre présentent un diamètre moyen compris entre 7 et 10 µm.
  7. Non-tissé hybride selon l'une quelconque des revendications 1 à 6, caractérisé en ce que le diamètre des fibres de verre est d'un maximum de 10 µm et en ce que la longueur des fibres de verre est d'un maximum de 15 mm.
  8. Non-tissé hybride selon l'une quelconque des revendications 1 à 7, caractérisé en ce que les fibres de verre présentent une longueur moyenne comprise entre 7 et 9 mm.
  9. Non-tissé hybride selon l'une quelconque des revendications 1 à 8, caractérisé en ce que les fibres de verre sont en verre C et/ou en verre E-Glas.
  10. Non-tissé hybride selon l'une quelconque des revendications 1 à 9, caractérisé en ce qu'il présente un grammage compris entre 40 g/m2 et 60 g/m2.
  11. Non-tissé hybride selon l'une quelconque des revendications 1 à 10, caractérisé en ce que la part en poids des fibres polymères est comprise entre 10 et 15 % du non-tissé sec.
  12. Non-tissé hybride selon l'une quelconque des revendications 1 à 11, caractérisé en ce qu'il est muni d'une imprégnation supplémentaire.
  13. Non-tissé hybride selon la revendication 12, caractérisé en ce que le produit d'imprégnation est un plastisol.
  14. Revêtement de sol en CV, avec une couche d'usure et une couche de structure, la couche de structure comprenant un non-tissé hybride muni d'une imprégnation selon la revendication 12 ou la revendication 13.
  15. Procédé destiné à la fabrication du non-tissé hybride selon la revendication 1, en ce
    - qu'on fait passer de l'eau, contenant les fibres de verre et les fibres polymères en circuit à travers un tamis en bande,
    - qu'on dépose à cet effet le mélange fibreux sur le tamis en bande sous la forme d'une couche de fibres d'une épaisseur de couche prédéfinie,
    - qu'on retire l'excédent d'eau de circuit de la couche de fibres,
    - qu'on mélange la couche de fibres avec l'agent liant et
    - qu'on fait sécher la couche de fibres mélangée à l'agent liant.
EP14002745.9A 2013-08-09 2014-08-06 Revêtement de sol CV comprenant un non-tissé et non-tissé Active EP2835462B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PL14002745T PL2835462T3 (pl) 2013-08-09 2014-08-06 Amortyzująca, winylowa wykładzina podłogowa (typu cv), zawierająca włókninę oraz włóknina
RS20180591A RS57245B1 (sr) 2013-08-09 2014-08-06 Netkani tekstil i cv podna obloga koja sadrži netkani tekstil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE201310013321 DE102013013321A1 (de) 2013-08-09 2013-08-09 Faservlies sowie Faservliese enthaltende Erzeugnisse

Publications (2)

Publication Number Publication Date
EP2835462A1 EP2835462A1 (fr) 2015-02-11
EP2835462B1 true EP2835462B1 (fr) 2018-04-18

Family

ID=51298512

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14002745.9A Active EP2835462B1 (fr) 2013-08-09 2014-08-06 Revêtement de sol CV comprenant un non-tissé et non-tissé

Country Status (9)

Country Link
US (1) US20150044414A1 (fr)
EP (1) EP2835462B1 (fr)
CA (1) CA2858588A1 (fr)
DE (1) DE102013013321A1 (fr)
DK (1) DK2835462T3 (fr)
HU (1) HUE036808T2 (fr)
PL (1) PL2835462T3 (fr)
RS (1) RS57245B1 (fr)
RU (1) RU2669166C2 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102015200453A1 (de) * 2015-01-14 2016-07-14 Vitrulan Textile Glass Gmbh Flächiges Textilsubstrat mit einer mit Wasser aktivierbaren Klebstoffbeschichtung, Verfahren zu dessen Herstellung und dessen Verwendung
US11261602B2 (en) 2016-12-21 2022-03-01 Cretainteed Llc Fiber mat, method of making the fiber mat, and bituminous roofing product
US11332881B2 (en) 2018-01-05 2022-05-17 Certainteed Llc Fiber mat, method of making the fiber mat, and bituminous roofing product

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4056161A (en) * 1975-10-30 1977-11-01 Tillotson Corporation Sound attenuation material
US4618530A (en) * 1983-11-09 1986-10-21 Congoleum Corporation Process for the preparation of a composite mat
US4681798A (en) * 1984-12-24 1987-07-21 Manville Service Corporation Fibrous mat facer with improved strike-through resistance
US4637951A (en) * 1984-12-24 1987-01-20 Manville Sales Corporation Fibrous mat facer with improved strike-through resistance
FR2677672B1 (fr) * 1991-06-12 1994-11-04 Dumas Bernard Nouvelle feuille obtenue par procede humide et son application.
US5935879A (en) * 1994-09-21 1999-08-10 Owens Corning Fiberglas Technology, Inc. Non-woven fiber mat and method for forming same
CA2133522A1 (fr) * 1994-10-03 1996-04-04 Armstrong World Industries, Inc. Sous-couche de revetement de plancher
CA2157337C (fr) * 1995-06-07 2006-01-31 Debbie O'haver-Smith Mat fibreux ameliore et plaque de platre revetue dudit mat
US5772846A (en) * 1997-01-09 1998-06-30 Johns Manville International, Inc. Nonwoven glass fiber mat for facing gypsum board and method of making
US20030109190A1 (en) * 2001-12-12 2003-06-12 Geel Paul A. Wet-laid nonwoven reinforcing mat
US20110139386A1 (en) * 2003-06-19 2011-06-16 Eastman Chemical Company Wet lap composition and related processes
US20120251597A1 (en) * 2003-06-19 2012-10-04 Eastman Chemical Company End products incorporating short-cut microfibers
US7842629B2 (en) * 2003-06-27 2010-11-30 Johns Manville Non-woven glass fiber mat faced gypsum board and process of manufacture
US8283266B2 (en) * 2003-11-20 2012-10-09 Johns Manville Method of making tough, flexible mats and tough, flexible mats
US7662258B2 (en) * 2006-12-28 2010-02-16 Johns Manville Roofing mat using urea-formaldehyde binder of particular viscosity and surface tension
DE102011011056A1 (de) 2011-02-11 2012-08-16 Johns Manville Europe Gmbh Glasfaservlies sowie Glasfaservliese enthaltende Erzeugnisse

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Also Published As

Publication number Publication date
CA2858588A1 (fr) 2015-02-09
HUE036808T2 (hu) 2018-07-30
RU2014132898A (ru) 2016-02-27
EP2835462A1 (fr) 2015-02-11
RU2669166C2 (ru) 2018-10-08
DK2835462T3 (en) 2018-07-23
DE102013013321A1 (de) 2015-02-12
PL2835462T3 (pl) 2018-08-31
RS57245B1 (sr) 2018-07-31
US20150044414A1 (en) 2015-02-12

Similar Documents

Publication Publication Date Title
DE60107223T2 (de) Herstellung von fasermatte aus gehackten strängen
DE3546114C2 (fr)
DE60108121T2 (de) Laminatdeckblatt mit schutzpressplatte-eigenschaften und verfahren zu dessen herstellung
EP1492666B1 (fr) Materiau composite, procede de fabrication et utilisation dudit materiau composite
DE102011008909A1 (de) Verbundlaminate und Verfahren zur Herstellung derselben
EP2673408B1 (fr) Non-tissé en fibres de verre et produits contenant des non-tissés en fibres de verre
DE1962331C3 (de) Wundauflagematerial
DE102009006586B4 (de) Filtermedium sowie Filterelement für die Flüssigkeitsfiltration
EP2835462B1 (fr) Revêtement de sol CV comprenant un non-tissé et non-tissé
EP0095527A2 (fr) Elément de rembourrage
DE1475768B2 (de) Dichtung aus einer imprägnierten Glasfaserstruktur
DE2900771C2 (de) Dekorativer Schichtstoff
DE102008051317B4 (de) Verfahren zur Herstellung einer Reinigungstextilie
WO2008058924A1 (fr) Procédé de production de matériaux composites à fibres ignifugés ou pré-imprégnés
DE1619252B2 (de) Kunstleder und verfahren zur herstellung desselben
DE60111232T2 (de) Reinigungswerkzeug und dessen herstellung
DE102008057058B4 (de) Verfahren zur Herstellung eines Vliesstoffes mit geringer Dichte und erhöhter Stabilität, nach diesem Verfahren hergestellter Vliesstoff sowie Verwendungen des Vliesstoffes
DE112017000099T5 (de) Schalldämpfungsmaterial
DE102016209244A1 (de) Verfahren zur Herstellung eines Garnes, Verfahren zur Herstellung eines Vlieses und Vlies
DE102007028531A1 (de) Neue Verbundwerkstoffe, Verfahren zu deren Herstellung und deren Verwendung
DE1571503C3 (de) Rollbarer Faserkörper
DE202008018271U1 (de) Reinigungstextilie
DE3435640A1 (de) Vliesstoff
DE102011122595A1 (de) Neue Verbundwerkstoffe, Verfahren zu deren Herstellung und deren Verwendung für den Fußbodenbereich
DE3446632A1 (de) Zur herstellung dekorativer schichtstoffe geeignetes leitfaehiges papier

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20140806

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

R17P Request for examination filed (corrected)

Effective date: 20150807

RBV Designated contracting states (corrected)

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

17Q First examination report despatched

Effective date: 20160523

REG Reference to a national code

Ref country code: DE

Ref legal event code: R079

Ref document number: 502014007967

Country of ref document: DE

Free format text: PREVIOUS MAIN CLASS: D04H0001421800

Ipc: D04H0001587000

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RIC1 Information provided on ipc code assigned before grant

Ipc: D21H 13/24 20060101ALI20171013BHEP

Ipc: D04H 3/004 20120101ALI20171013BHEP

Ipc: D04H 1/58 20120101ALI20171013BHEP

Ipc: D06N 3/00 20060101ALI20171013BHEP

Ipc: D21H 13/40 20060101ALI20171013BHEP

Ipc: D21H 27/26 20060101ALI20171013BHEP

Ipc: D04H 1/587 20120101AFI20171013BHEP

Ipc: D04H 1/4218 20120101ALI20171013BHEP

Ipc: D04H 1/64 20120101ALI20171013BHEP

Ipc: D04H 1/435 20120101ALI20171013BHEP

INTG Intention to grant announced

Effective date: 20171110

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 990589

Country of ref document: AT

Kind code of ref document: T

Effective date: 20180515

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502014007967

Country of ref document: DE

REG Reference to a national code

Ref country code: NL

Ref legal event code: FP

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

Effective date: 20180716

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

REG Reference to a national code

Ref country code: HU

Ref legal event code: AG4A

Ref document number: E036808

Country of ref document: HU

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 5

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180718

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180719

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180820

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 502014007967

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

26N No opposition filed

Effective date: 20190121

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20180806

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180831

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180831

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180806

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180806

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180418

Ref country code: MK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180418

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180818

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 990589

Country of ref document: AT

Kind code of ref document: T

Effective date: 20190806

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190806

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 20230827

Year of fee payment: 10

Ref country code: RS

Payment date: 20230718

Year of fee payment: 10

Ref country code: PL

Payment date: 20230719

Year of fee payment: 10

Ref country code: HU

Payment date: 20230725

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: LU

Payment date: 20240827

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20240826

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20240828

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DK

Payment date: 20240826

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20240827

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20240826

Year of fee payment: 11