EP2658612A2 - Flammendurchschlagsicherung - Google Patents
FlammendurchschlagsicherungInfo
- Publication number
- EP2658612A2 EP2658612A2 EP11831769.2A EP11831769A EP2658612A2 EP 2658612 A2 EP2658612 A2 EP 2658612A2 EP 11831769 A EP11831769 A EP 11831769A EP 2658612 A2 EP2658612 A2 EP 2658612A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- flame arrester
- flame
- wall
- area
- height
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007789 gas Substances 0.000 claims description 28
- 239000002360 explosive Substances 0.000 claims description 12
- 230000004888 barrier function Effects 0.000 claims description 9
- 239000011261 inert gas Substances 0.000 claims description 5
- 230000021715 photosynthesis, light harvesting Effects 0.000 abstract description 3
- 239000002184 metal Substances 0.000 description 13
- 238000004804 winding Methods 0.000 description 10
- 230000005855 radiation Effects 0.000 description 9
- 238000004880 explosion Methods 0.000 description 6
- 238000001816 cooling Methods 0.000 description 5
- 230000002093 peripheral effect Effects 0.000 description 5
- 230000017525 heat dissipation Effects 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 231100001261 hazardous Toxicity 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000004200 deflagration Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C4/00—Flame traps allowing passage of gas but not of flame or explosion wave
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D14/00—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
- F23D14/46—Details, e.g. noise reduction means
- F23D14/72—Safety devices, e.g. operative in case of failure of gas supply
- F23D14/82—Preventing flashback or blowback
Definitions
- the invention relates to a flame arrester with a built in a wall that separates an endangered area from an outdoor cylindrical flame arrester with a plurality of fürströmspalte having cross-sectional area and the length of the fürströmspalte determining height and a directed explosive area underside and a Exterior directed top.
- Such flame arresters are known in numerous embodiments. They are used everywhere where an area endangered by explosive or flammable gases has to be protected against flame propagation into the endangered area in order to prevent an explosion catastrophe in the endangered area.
- the vulnerable area can be formed by a container in the broadest sense, including by a pipeline leading to a container or stock of explosive or combustible gas.
- the flame arrester Since the burning off of the gases can take place over a longer period of time, the flame arrester must reliably prevent the flame penetration, even if the burning off of the gas on the upper side lasts for a longer period of time, for example 2 hours or longer. If the flame arrester is suitable for this, it is called a "permanent fire" flame arrester. If, due to the design, only a short-term development of flame can occur, a short-fire flame arrester is sufficient.
- flame arresters come for the realization of the present invention, all designs into consideration, which ensure a predetermined maximum gap width and a predetermined minimum gap length.
- a preferred construction is achieved by the common circular or spiral winding of a smooth metal strip with a corrugated metal strip in a simple manner, wherein the width of the bands defines the height of the flame arrester and the length of fürströmspalte formed by the corrugated band.
- several such flame arresters can be arranged one behind the other - with or without intermediate spaces or intermediate elements.
- Durable flame arresters are realized in a known technique in that the flame arrestors are used in stable metallic enclosing cages, through which the best possible heat dissipation from the flame arrester into the surrounding housing is to take place.
- the sufficient heat dissipation tion which is required for endurance burning, requires a substantial amount of metal.
- the length of the fürströmspalte must be chosen so that the Abbran.dtemperatur on the outside to the end of the passage column at the bottom, which is directed towards the vulnerable area, has fallen so far that in the hazardous area there explosive or flammable gas will certainly no longer be ignited.
- the present invention is based on the object to be able to realize a flame arrester of the type mentioned in a simpler, less bulky design.
- a flame arrester according to the invention of the type mentioned above is characterized in that the flame arrester is inserted into one of the cross-sectional area of the flame arrester corresponding opening of the wall and projects beyond the wall with at least one fifth of its height in the outdoor area.
- the flame arrester according to the invention is thus not used in a stable enclosing cage, but only in an opening of the wall, and this only with a part of its height. This means that the thickness of the wall is definitely lower than the height of the flame barrier. With a standard wall thickness of 8 mm, therefore, the height of the flame arrester is at least 10 mm.
- the flame arrester protrudes according to the invention with at least a fifth, preferably at least one third, more preferably with at least a quarter of its height out of the wall.
- Particularly effective is the flame arrester according to the invention, if the part of the flame arrester projecting out of the wall into the outer area makes up at least half, preferably at least two thirds of its height.
- the flame arrestor is radially limited by a thin plate, which may be formed for example by the smooth sheet, which is wound up together with a sleek sheet to the flame arrester. But it is also possible to attach a similar stabilizing sheet whose thickness is in any case less than 1 mm, preferably less than 0.5 mm, on the circumference of the cylindrical flame arrester.
- the thus formed flame arrester invention thus requires only the insertion into the opening of the wall, which is formed as a plate.
- the flame arrester according to the invention therefore has a low mass, since a surrounding cage is not required. The heat is released on the one hand to the gas flowing through and on the other hand in a decisive way by heat radiation.
- the flame arrester Since the flame arrester protrudes beyond the wall into the outer area, preferably with the largest part of its height, the flame arrester can radiate heat not only over the top, but over the entire jacket wall, which protrudes from the opening of the wall into the outer area , It is therefore important for the flame arrester according to the invention that there is no massive enclosure of the jacket wall, but at most a mechanical stabilization is carried out with a metal sheet surrounding the peripheral surface and assuming the temperature of the peripheral surface substantially loss-free and without delay so as to emit radiation Contribute heat from the flame arrester.
- the flame arrester according to the invention allows a much more effective energy dissipation through the thermal radiation than through the heat conduction into a surrounding " cage cage.
- the flame arrester fuse can therefore adapt very rapidly to changing flow velocities and quickly assume an equilibrium state through energy absorption from the combustion process and energy output by the heat radiation and the heat conduction to the gas flowing through. Since it is important for the effectiveness of the flame arrestor according to the invention that as large a part of the height of the flame arrester protrudes from the opening of the wall, it is preferred if the flame arrester flush with the lower edge of its height with the directed to the vulnerable area bottom of the Wall closes.
- a cross-section of the flame arrester crossing first Befest Trentsseiement is attached to the underside of the wall.
- This fastening element can provide for an axial securing of the flame arrester, without substantially impairing the flow cross section through the flame arrester.
- the fastener may be formed in a preferred embodiment by a mere rod which is fixed on both sides of the cross section of the flame arrester on the underside of the wall.
- the fastener may also be formed by a known per se rib ring or a coarse mesh screen or fabric or a coarse mesh grid.
- a mechanical stabilization in particular a flame arrester formed by winding a smooth strip together with a corrugated strip, is achieved in that the first fixing element is connected via a protruding through a central opening of the flame arrester connecting element with a second fastening element which rests on the top of the flame arrester.
- the flame arrester is thus mechanically stabilized on the upper side by the second fastening element, wherein the second fastening element does not have to be connected in a complex manner with the corresponding upper side of the wall because of the difference in height, since the connection via the connecting element and the first fastening element with the bottom of the wall is stable to produce.
- a single connecting element is sufficient, which is guided centrally through the flame arrester.
- the winding of the smooth belt together with the corrugated belt is expediently carried out around a winding core designed as a sleeve.
- the flame arrester is preferably designed as a disk with a height that is smaller than a cross-sectional length.
- the cross section of the disk essentially represents the clear cross section, which is provided with the passage gaps. If necessary, only the cross-sectional area which is occupied by a winding core, possibly in the form of a sleeve closed by the connecting element, is not available for the passage gaps.
- the large energy dissipation by thermal radiation which is the aim of the invention presupposes that a large free surface of the flame arrester exists in comparison to its mass.
- a single large flame arrester for this flow mungsquerites is used, but in the flow cross-section a plurality of smaller flame arresters is introduced, which are inserted into corresponding openings of the flow cross-section closing wall.
- the flame arrester according to the invention allows, for the first time, a long-term fire protection even for extremely flammable gases, for example hydrogen. Therefore, according to the invention, it is possible to create a long-term fire protection suitable for the explosion group HC.
- Flame barrier be formed, in which the passage column extends in an annular space surrounding an interior.
- the interior is completed in relation to the endangered area and thus communicates with the outside area.
- a flow channel for an inert gas is formed with the interior, wherein the inert gas may be taken in from the outside air, when the not connected to the interior end of the flow channel is connected to the outside.
- the effect of the heat radiation is thus supplemented by a cooling effect by means of a flowing inert gas.
- the focus of application is on the creation of a continuous fire safety device for flammable gases, the flow velocity of the explosive or combustible gas through the flame arrester is of minor importance. It is essential that over the Height of the flame arrester uses such a cooling that the highly flammable gases are not ignited in the hazardous area. According to the invention, this is even achieved for a continuous fire on the top of the flame arrester in the explosion class HC.
- the preferred application of the present invention is in the formation of a flameproof flame arrester, although the construction according to the invention is also advantageous for flame arresters which need not be flameproof, in particular short fire arresters and atmospheric deflagration safeguards.
- a shorter protruding out of the flame barrier out of the wall in the outdoor area so for example between one fifth and half the height of the flame arrester, while for a long-fire backup protruding with at least half the height of the flame arrester is required regularly.
- FIG. 1 shows a high section through a flame arrester according to a first embodiment of the invention with a single flame arrester
- Figure 2 is a perspective view obliquely from above on a
- Rotary breakthrough protection according to a second embodiment example! the invention with a plurality of flame arresters mounted on a common wall;
- Figure 3 is a schematic plan view of the arrangement according to
- Figure 4 is a partial high-sectional view of the arrangement according to Figures 2 and 3;
- Figure 5 shows a high section through a sluice arrester according to a third embodiment of the invention with a formed in the form of a ring cylinder flame arrester;
- FIG. 6 shows a schematic perspective view obliquely from above to the embodiment according to FIG. 5;
- FIG. 7 shows a plan view of the embodiment according to FIG. 5.
- FIG. 1 shows a connection part 1 which is not specified in greater detail.
- the connection part 1 merges from a tubular conduit cross-section 2 into a conical enlargement 3 and ends in an annular attachment.
- a wall 6 in the form of a metal plate is screwed to the fastening flange 4 by means of screw connections 5.
- tubular conduit cross-section 2 In continuation of the tubular conduit cross-section 2 is located in the wall 6, a circular opening 7, in which a disc-shaped flame arrester 8 is inserted with a circular cross-section so that a bottom 9 of the flame arrester 8 with a tubular conduit cross section 2 facing bottom 10 of the wall 6 is aligned.
- a first fastening element 1 1 On the underside 10 of the wall 6, a first fastening element 1 1 is fixed in the form of a rod by screwing 12 and thus abuts against the bottom 9 of the flame arrester 8.
- the tubular conduit cross-section 2 and the conical extension 3 form an endangered by explosive or flammable gases area 1 3, which is completed by the wall 6 and the opening 7 of the wall 6 passively inserted flame arrester 8.
- the underside 10 of the wall 6 opposite upper side 14 of the wall points to an outer region 15 of the flame arrester, in which the. Flame barrier 8 protrudes with a major part of their height and is completed with a top 6 side of the face.
- a second fastener 17 which is also formed in the embodiment shown in Figure 1 by a rod.
- the rod is inserted through a central opening of a bolt-shaped connecting element 18 therethrough.
- the connecting element 1 8 protrudes beyond the bottom 9 of the flame arrester and here also has a passage opening through which the first fastening element 1 1 is also inserted through.
- the designedswarid 19 of the flame arrester 8 can be formed by a thin metal sheet of not more than 1 mm thickness and fixed to the flame arrester 8 by laser dotting o. ⁇ .
- the flame arrester 8 is produced in a preferred embodiment in that a smooth metal strip is wound together with a corrugated metal strip on a winding core 20, so that the corrugations of the corrugated metal strip defined between two winding layers of the smooth metal strip fürströmspalte, axi al by the gas the endangered area 13 can flow into the outer area 15.
- the length of the passage column is thus determined by the width of the two jointly wound metal bands.
- the winding core 20 is designed as a sleeve with an axial cavity, so that the bolt-shaped connecting element 18 can be inserted into the interior of the winding core 20.
- Figures 2 and 3 show a second embodiment of the invention with a wall 6 ', which terminates an endangered area 13 ( Figure 4).
- the wall 6 ' has a number of nine orifices 7' arranged on a circular path, into which flame arresters 8 are inserted, which protrude from the upper side 14 of the wall 6 'with a predominant part of their height, and with a rod-shaped one second fastening element 17 are fixed, which are defined by a central bolt-shaped connecting element 18 on the underside 10 of the wall 6 '.
- the new flame arresters 8 are four other flame arresters 8 ', which are inserted into corresponding openings 7' of the wall 6 '.
- the flame arresters 8 ' have a significantly smaller diameter than the finned barriers 8.
- the four flame arresters 8 ' are also arranged with their central connecting elements 18 on a circular path about a center of the wall 6' around. net.
- the wall 6 ' as illustrated in FIG. 4, is fastened with numerous screwed connections 5 to an annular fastening flange 4 of a connection part 1. The fastening of the flame arresters 8, 8 'takes place in the same way as has been explained with reference to the first exemplary embodiment according to FIG.
- the arrangement of the numerous flame arresters 8, 8 'on the wall 6' has the advantage that very large proportions of the peripheral walls 19 of the flame arresters 8, 8 'protrudes from the top of the wall 6' and together with the tops 16 of the flame arresters 8 large surfaces form, of which heat is radiated into the outer region 5.
- FIG. 5 to 7 third embodiment of the invention shows a connector part 1, which is similar to the connector part 1 in Figure 1.
- the wall 6 is attached in the form of a plate to the connector part 1.
- the wall 6 likewise has a circular central opening 7, into which a flame arrester 21 in the form of a circular cylinder is inserted, so that within the flame arrester 21 a circular cylindrical interior 22 results, which communicates with the outside area 1 5.
- an intermediate piece 23 is used here, with which the guide channels 24, 25 are formed.
- a guide channel 24 is connected to the explosive region 13, while a guide channel 25 has a radial end 26 which forms an inlet opening for air from the predominantlybe rich 1 5 and an axial central end 27 which opens into the interior 22 of the flame arrester 21.
- the guide channel 24 axially continues the explosive region 13 and ends in an annular space 28, which is located below the annular space provided with the passage gaps by the flame barrier 21. det, can be blown by the explosive or combustible gas in the outdoor area 1 5, there to be burned if necessary immediately. It is ensured by a sealing piece 29 that no explosive or combustible gas enters the interior 22 of the flame arrester 21.
- a peripheral wall 30 closes the annular space 28 radially outward.
- Figure 6 illustrates the structure of the flame arrester according to the third embodiment of the invention in a perspective view view. It can be seen that a plurality of orifices 26 may be provided for the suction of air from the outer region 15 in order to effect an additional cooling of the flame arrester 21 by a Konvekomsströmung through the interior 22 of the flame arrester 21.
- FIG. 7 illustrates in plan view an annular cross-sectional area 31 of the flame arrester 21 in which axial passage gaps are close together and separated from one another by the corrugation of a corrugated metal strip on the one hand and the winding layers of the smooth metal strip on the other hand.
- the energy output by the heat radiation at the large surfaces of the hollow cylindrical flame arrester 21 is supported in this embodiment by a convection flow of air from the outer region 15 through the interior 22 of the flame arrester 21. By this convection, the heat dissipation of the flame arrester 21 is supported.
- the flame arresters 21 it is also possible with the flame arresters 21 to form an arrangement in which a plurality of flame arresters 21 are inserted into corresponding openings 7 of the wall 6 in order to provide a higher flow rate.
- the flame arresters 21 are not optimized for high flow rates, but offer a high energy output in the outdoor area 1 5, so that for the first time a flameproof flame arrester can be created for the gases of the Expionsi- onssti HC, such as hydrogen for gases Explosion group IIB and for other gases with high energy content, is permanently fireproof. So it has been possible with a flame arrester with a diameter of 65 mm, an interior space 22 with a diameter of 51 mm and a height of 50 mm in forming a maximum gap width of 0.2 mm in the annular cross-sectional area a fireproof fire prevention for a to achieve stoichiometric hydrogen / air mixture composition.
Landscapes
- Engineering & Computer Science (AREA)
- Public Health (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Gas Burners (AREA)
- Building Environments (AREA)
- Lighters Containing Fuel (AREA)
- Fuses (AREA)
- Fireproofing Substances (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL11831769T PL2658612T3 (pl) | 2010-12-30 | 2011-11-29 | Zabezpieczenie przeciw rozprzestrzenianiu się płomieni |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102010056590A DE102010056590A1 (de) | 2010-12-30 | 2010-12-30 | Flammendurchschlagsicherung |
PCT/DE2011/002051 WO2012089187A2 (de) | 2010-12-30 | 2011-11-29 | Flammendurchschlagsicherung |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2658612A2 true EP2658612A2 (de) | 2013-11-06 |
EP2658612B1 EP2658612B1 (de) | 2016-10-12 |
Family
ID=45928591
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP11831769.2A Active EP2658612B1 (de) | 2010-12-30 | 2011-11-29 | Flammendurchschlagsicherung |
Country Status (18)
Country | Link |
---|---|
US (3) | US20130277073A1 (de) |
EP (1) | EP2658612B1 (de) |
JP (1) | JP6219169B2 (de) |
KR (1) | KR20130133825A (de) |
CN (1) | CN103328048B (de) |
AU (1) | AU2011352484B2 (de) |
BR (1) | BR112013016997B1 (de) |
CA (1) | CA2823424C (de) |
DE (1) | DE102010056590A1 (de) |
DK (1) | DK2658612T3 (de) |
ES (1) | ES2610960T3 (de) |
HU (1) | HUE032437T2 (de) |
MX (1) | MX342507B (de) |
PL (1) | PL2658612T3 (de) |
RU (1) | RU2589480C2 (de) |
TW (1) | TWI542833B (de) |
WO (1) | WO2012089187A2 (de) |
ZA (1) | ZA201304850B (de) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102016220995A1 (de) * | 2016-10-25 | 2018-04-26 | Bayerische Motoren Werke Aktiengesellschaft | Druckbehälter mit einem Auslass für zwischen einem Liner und einer faserverstärkten Schicht angesammelten Brennstoff |
DE102018120877B4 (de) | 2018-08-27 | 2021-09-30 | R.Stahl Schaltgeräte GmbH | Explosionsgeschütztes Gehäuse |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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DE1023409B (de) * | 1956-05-24 | 1958-01-23 | Wilke Werke Ag | Sicherheitsvorrichtung fuer Behaelter mit brennbaren Fluessigkeiten |
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DE10326150B4 (de) * | 2003-06-06 | 2005-12-15 | Leinemann Gmbh & Co. Kg | Dauerbrandsichere Flammensperre |
DE10336530B3 (de) * | 2003-08-05 | 2005-02-17 | Leinemann Gmbh & Co. | Flammendurchschlagsicherung |
US6854428B1 (en) * | 2004-06-22 | 2005-02-15 | The Water Heater Industry Joint Research And Development Consortium | Water heater with normally closed air inlet damper |
CN201342199Y (zh) * | 2008-12-29 | 2009-11-11 | 启东市天宇石化冶金设备有限公司 | 蜂窝状波纹板阻火器 |
US10151239B1 (en) * | 2017-12-05 | 2018-12-11 | Penn-Troy Manufacturing Inc. | Explosion relief valve with annular flame arrestor |
-
2010
- 2010-12-30 DE DE102010056590A patent/DE102010056590A1/de not_active Ceased
-
2011
- 2011-11-29 PL PL11831769T patent/PL2658612T3/pl unknown
- 2011-11-29 CA CA2823424A patent/CA2823424C/en active Active
- 2011-11-29 EP EP11831769.2A patent/EP2658612B1/de active Active
- 2011-11-29 BR BR112013016997-4A patent/BR112013016997B1/pt active IP Right Grant
- 2011-11-29 DK DK11831769.2T patent/DK2658612T3/en active
- 2011-11-29 MX MX2013007618A patent/MX342507B/es active IP Right Grant
- 2011-11-29 KR KR1020137020109A patent/KR20130133825A/ko not_active Application Discontinuation
- 2011-11-29 JP JP2013546586A patent/JP6219169B2/ja active Active
- 2011-11-29 AU AU2011352484A patent/AU2011352484B2/en active Active
- 2011-11-29 HU HUE11831769A patent/HUE032437T2/en unknown
- 2011-11-29 RU RU2013135483/12A patent/RU2589480C2/ru active
- 2011-11-29 WO PCT/DE2011/002051 patent/WO2012089187A2/de active Application Filing
- 2011-11-29 CN CN201180063795.5A patent/CN103328048B/zh active Active
- 2011-11-29 US US13/977,037 patent/US20130277073A1/en not_active Abandoned
- 2011-11-29 ES ES11831769.2T patent/ES2610960T3/es active Active
- 2011-11-30 TW TW100143847A patent/TWI542833B/zh active
-
2013
- 2013-06-28 ZA ZA2013/04850A patent/ZA201304850B/en unknown
-
2017
- 2017-07-18 US US15/544,420 patent/US20200298037A1/en not_active Abandoned
-
2023
- 2023-09-15 US US18/468,281 patent/US20240001182A1/en active Pending
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DE1023409B (de) * | 1956-05-24 | 1958-01-23 | Wilke Werke Ag | Sicherheitsvorrichtung fuer Behaelter mit brennbaren Fluessigkeiten |
Non-Patent Citations (1)
Title |
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See also references of WO2012089187A2 * |
Also Published As
Publication number | Publication date |
---|---|
HUE032437T2 (en) | 2017-09-28 |
MX342507B (es) | 2016-10-03 |
EP2658612B1 (de) | 2016-10-12 |
ES2610960T3 (es) | 2017-05-04 |
AU2011352484A1 (en) | 2013-07-25 |
WO2012089187A2 (de) | 2012-07-05 |
JP2014502718A (ja) | 2014-02-03 |
US20200298037A1 (en) | 2020-09-24 |
CA2823424C (en) | 2018-01-02 |
US20240001182A1 (en) | 2024-01-04 |
WO2012089187A3 (de) | 2013-07-25 |
CN103328048A (zh) | 2013-09-25 |
PL2658612T3 (pl) | 2017-04-28 |
ZA201304850B (en) | 2014-09-25 |
TWI542833B (zh) | 2016-07-21 |
BR112013016997B1 (pt) | 2021-01-26 |
AU2011352484B2 (en) | 2016-04-28 |
US20130277073A1 (en) | 2013-10-24 |
DE102010056590A1 (de) | 2012-07-05 |
DK2658612T3 (en) | 2017-01-23 |
RU2589480C2 (ru) | 2016-07-10 |
KR20130133825A (ko) | 2013-12-09 |
BR112013016997A2 (pt) | 2016-10-25 |
TW201233955A (en) | 2012-08-16 |
CN103328048B (zh) | 2016-09-14 |
RU2013135483A (ru) | 2015-02-10 |
CA2823424A1 (en) | 2012-07-05 |
JP6219169B2 (ja) | 2017-10-25 |
MX2013007618A (es) | 2013-10-14 |
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